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At least 217 records · Page 12

Mass spectrometric measurements in the lower thermosphere

Several types of spectrometers are discussed along with their methods of operations. The open source magnetic deflection type mass spectrometer and the quadrupole mass spectrometer are described in detail. The calibration and mounting procedures used for satellite-borne mass spectrometers were reviewed.

Nier, A. O. C.↗

Response of Venus exospheric temperature measured by neutral mass spectrometer to solar EUV flux measured by Langmuir probe on the Pioneer Venus orbiter

The photoelectron current from the Pioneer Venus Langmuir probe has provided measurements of the total flux of solar EUV photons at Venus since 1979. The neutral oxygen scale height measured by the orbiter neutral mass spectrometer has permitted the exospheric temperature to be derived during the same mission. In this paper, the EUV observations are used to examine the response of exospheric temperature to changes in solar activity, primarily those related to solar rotation. It is found that the dayside exospheric temperature quite faithfully tracks variations in the EUV flux. Comparison is also made with the earth-based solar activity index F10.7 adjusted to the position of Venus. This index varied from 142 to 249 flux units during the period of measurements. The exospheric temperature is better correlated with EUV flux than with the 10.7-cm solar radio flux.

Mahajan, K. K.↗

Fluidic device for measuring constituent masses of a flowing binary gas mixture

Device consists of fluidic humidity sensor and specially designed flow calorimeter. Calorimeter provides readings of gas stream temperature rise produced by measured amount of heat that is dissipated into gas stream, and humidity sensor is used to obtain continuous calculation of specific heat capacity of gas mixture.

Prokopius, P. R.↗

Uncertainties in hot-wire measurements of compressible turbulent flows implied by comparisons with laser-induced fluorescence

A hot-wire anemometer and a new nonintrusive laser-induced fluorescence (LIF) technique are used to survey a Mach 2 turbulent boundary layer. The hot-wire anemometer's ability to accurately measure mass flux, temperature, and density fluctuations in a compressible flow is examined by comparing its results with those obtained using LIF. Several methods of hot-wire calibration are used, and the uncertainties in their measurements of various fluctuating flow parameters are determined. The results show that although a hot-wire operated at high overheat can measure mass flux fluctuations, temperature and density fluctuations are not determined accurately from such measurements. However, a hot-wire operated at multiple overheats can be used to measure static and total temperature fluctuations. The presence of pressure fluctuations and their correlation with density can prevent the use of hot-wire data to determine density fluctuations.

Mckenzie, R. L.↗

A new approach to mass spectrometer measurements of thermospheric density

The gas sampling problem in satellite and high velocity probes was investigated by applying the theory of a drifting Maxwellian gas. A lens system using a free stream ion source was developed and experimentally evaluated over the pressure range of 0.00001 to 0.01 N/m sq (approx. 10 to the minus 7th power to 0.0001 torr). The source has high beam transparency, which minimizes gas-surface collisions within, or near, the ionization volume. It is shown that for high ion energy (60 eV), the extracted ion beam has an on-axis energy spread of less than 4 eV, and that 90 percent of the ions are within 2.5 deg of the beam axis. It is concluded that the molecular beam mass spectrometer concept, developed for gas density measurements in the upper atmosphere, substantially reduces gas-surface scattering and gas-surface reactions in the sample, and preserves the integrity of the gas sample during the analysis process. Studies show that both the Scout and Delta launch vehicles have adequate volume, control, velocity, and data acquisition capability necessary to obtain thermospheric number density in real time.

Melfi, L. T., Jr.↗

Mass spectrometric measurements of atmospheric composition

The development of a magnetic sector field analyzer for continuous sampling and measurement of outer planetary atmospheres is discussed. Special features of the analyzer include a dynamic range of 10 to the minus 7th power, a mass range from 1 to 48 AMU, two ion sensitivities, a special scan time of 35 sec at 14 BPS, and the use of ion counting techniques for analysis.

Hoffman, J. H.↗

Black carbon aerosol number and mass concentration measurements by picosecond short-range elastic backscatter lidar

Abstract Black carbon aerosol emissions are recognized as contributors to global warming and air pollution. There remains, however, a lack of techniques to remotely measure black carbon aerosol particles with high range and time resolution. This article presents a direct and contact-free remote technique to estimate the black carbon aerosol number and mass concentration at a few meters from the emission source. This is done using the Colibri instrument based on a novel technique, referred to here as Picosecond Short-Range Elastic Backscatter Lidar (PSR-EBL). To address the complexity of retrieving lidar products at short measurement ranges, we apply a forward inversion method featuring radiometric lidar calibration. Our method is based on an extension of a well-established light-scattering model, the Rayleigh–Debye–Gans for Fractal-Aggregates (RDG-FA) theory, which computes an analytical expression of lidar parameters. These parameters are the backscattering cross-sections and the lidar ratio for black carbon fractal aggregates. Using a small-scale Jet A-1 kerosene pool fire, we demonstrate the ability of the technique to quantify the aerosol number and mass concentration with centimetre range-resolution and millisecond time-resolution.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Dynamic properties of the thermosphere inferred from Pioneer Venus mass spectrometer measurements

The data obtained by the Pioneer Venus spectrometer experiments indicate that the day-night temperature contrast on Venus is associated with wind velocities of about 200 m/s which transport oxygen, helium, and hydrogen toward the night side. A mass exchange with the mesosphere commensurate with an eddy diffusion coefficient of 3 x 10 to the 7th is required to buffer the horizontal advection so as to reproduce the observed day time bulge in oxygen and the small diurnal variations in helium. The observed time response and magnitude of the day-night density variations require transport processes to be effective over time periods between five and ten days, implying a superrotation rate or prevailing winds in excess of 50 m/s at the equator. Nonlinear mass transport results in wave steepening and contributes to the amplification of the density extrema in hydrogen and helium.

Mayr, H. G.↗

The impact of gas-surface reactions on mass spectrometric measurements of atomic nitrogen

The paper presents a simplified model of the ion source chemistry, explains several details of the data reduction method used in obtaining atomic-nitrogen (N) densities from OSS data, and discusses implications of gas-surface reactions for the design of future satellite-borne mass spectrometers. Because of various surface reactions, N appears in three different forms in the ion source, as N, NO, and NO2. Considering the rather small spin modulation of NO and NO2 in the semi-open ionization chamber used in the OSS instrument, it is not surprising that these reaction products have not been previously identified in closed source instruments as a measure of the presence of atomic nitrogen. Warmup and/or outgassing of the ion source are shown to drastically reduce the NO2 concentration, thereby making possible reliable measurement of ambient N densities.

Engebretson, M. J.↗

Status of CHIP-TRAP: The Central Michigan University High-Precision Penning Trap

Precise and accurate atomic mass data provide crucial information for applications in a wide range of fields in physics and beyond, including astrophysics, nuclear structure, particle and neutrino physics, fundamental symmetries, chemistry, and metrology. The most precise atomic mass measurements are performed on charged particles confined in a Penning trap. Here, we describe the development, status, and outlook of CHIP-TRAP: the Central Michigan University high-precision Penning trap. CHIP-TRAP aims to perform ultra-high precision (~1 part in 10 11 fractional precision) mass measurements on stable and long-lived isotopes produced with external ion sources and transported to the Penning traps. Along the way, ions of a particular m/q are selected with a multi-reflection time-of-flight mass separator (MR-TOF-MS), with further filtering performed in a cylindrical capture trap before the ions are transported to a pair of hyperbolic measurement traps. In this paper, we report on the design and status of CHIP-TRAP and present results from the commissioning of the ion sources, MR-TOF-MS, and capture trap. We also provide an outlook on the continued development and commissioning of CHIP-TRAP.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

Chasing Shadows in the Night: How NASA's Kepler and TESS Missions Are Revolutionizing Exoplanet Science

The first planet outside our own solar system was discovered almost thirty years ago in an extremely unlikely place, orbiting a pulsar, and the first exoplanet orbiting a Sun-like star was discovered nearly 26 years ago. In the time since, we’ve detected over 5000 planets and over 75% of these have been detected by transit surveys. The Kepler Mission, launched in 2009, has found the lion’s share of these exoplanets, and demonstrated that each star in the night sky has, on average, at least one planet. Kepler’s success spurred NASA and ESA to select several exoplanet-themed missions to move the field of exoplanet science forward from discovery to characterization: How do these planets form and evolve? What is the structure and composition of the atmospheres and interiors of these planets? Can we detect biomarkers in the atmospheres of these planets and learn the answer to the fundamental question, are we alone? NASA selected the Transiting Exoplanet Survey Satellite (TESS) in 2014 to conduct a nearly all-sky survey for transiting planets with the goal of identifying at least 50 small planets with measured masses that can be followed up by large telescopic assets, such as the upcoming James Webb Space Telescope. TESS has discovered 266 exoplanets so far, 100 of which are smaller than earth with measured masses. In this talk I will describe how we detect weak transit signatures in noisy but beautiful transit survey data sets and present some of the most compelling discoveries made so far by Kepler and TESS.

TESS↗

Synchrotron Photoionization Mass Spectrometry Measurements of Kinetics and Product Formation in the Allyl Radical (H2CCHCH2)Self Reaction

Product channels for the self-reaction of the resonance-stabilized allyl radical, C3H5 + C3H5, have been studied with isomeric specificity at temperatures from 300-600 K and pressures from 1-6 Torr using time-resolved multiplexed photoionization mass spectrometry. Under these conditions 1,5-hexadiene was the only C6H10 product isomer detected. The lack of isomerization of the C6H10 product is in marked contrast to the C6H6 product in the related C3H3 + C3H3 reaction, and is due to the more saturated electronic structure of the C6H10 system. The disproportionation product channel, yielding allene + propene, was also detected, with an upper limit on the branching fraction relative to recombination of 0.03. Analysis of the allyl radical decay at 298 K yielded a total rate coefficient of (2.7 +/- 0.8) x 10(exp -11) cu cm/molecule/s, in good agreement with pre.vious experimental measurements using ultraviolet kinetic absorption spectroscopy and a recent theoretical determination using variable reaction coordinate transition state theory. This result provides independent indirect support for the literature value of the allyl radical ultraviolet absorption cross-section near 223 nm.

Selby, Talitha M.↗

Precise determination of earth's center of mass using measurements from the Global Positioning System

Global Positioning System (GPS) data from a worldwide geodetic experiment were collected during a 3-week period early in 1991. Geocentric station coordinates were estimated using the GPS data, thus defining a dynamically determined reference frame origin which should coincide with the earth center of mass, or geocenter. The 3-week GPS average geocenter estimates agree to 7-13 cm with geocenter estimates determined from satellite laser ranging, a well-established technique. The RMS of daily GPS geocenter estimates were 4 cm for x and y, and 30 cm for z.

Vigue, Yvonne↗

GJ 1252 b: A 1.2 R⊕ Planet Transiting an M3 Dwarf at 20.4 pc

We report the discovery of GJ 1252 b, a planet with a radius of 1.193 ± 0.074 R⊕ and an orbital period of 0.52 days around an M3-type star (0.381 ± 0.019 M⊕, 0.391 ± 0.020 R⊕) located 20.385 ± 0.019 pc away. We use Transiting Exoplanet Survey Satellite (TESS) data, ground-based photometry and spectroscopy, Gaia astrometry, and high angular resolution imaging to show that the transit signal seen in the TESS data must originate from a transiting planet. We do so by ruling out all false-positive scenarios that attempt to explain the transit signal as originating from an eclipsing stellar binary. Precise Doppler monitoring also leads to a tentative mass measurement of 2.09 ± 0.56 M⊕. The host star proximity, brightness (V = 12.19 mag, K = 7.92 mag), low stellar activity, and the system's short orbital period make this planet an attractive target for detailed characterization, including precise mass measurement, looking for other objects in the system, and planet atmosphere characterization.

Avi Shporer↗

Measurements of mass flow in the transition region and inner corona

A solar rocket experiment launched on June 5, 1979 is described which provides high spectral resolution line profiles across the solar disk. The instrument consists of a small telescope with moderate spatial resolution and a spectrograph with stability and high spectroscopic resolution (about 0.028 A at 600 A). The detector system uses a microchannel plate array to provide 1,024 simultaneous measurements spanning approximately 30 A of the solar spectrum. The spectrograph uses a 3600 l/mm grating, and the spectral range 609-634 A is recorded in second order overlapping 1218-1268 A in first order. The position of the emission lines is determined by a center-of-mass routine and velocity shifts are evident. The qualitative results are in general agreement with the results of Cushman and Rense (1976).

Rottman, G. J.↗

Evaluation of Aerosol Mixing State Classes in the GISS Modele-matrix Climate Model Using Single-particle Mass Spectrometry Measurements

Aerosol particles in the atmosphere are composed of multiple chemical species. The aerosol mixing state, which describes how chemical species are mixed at the single-particle level, provides critical information on microphysical characteristics that determine the interaction of aerosols with the climate system. The evaluation of mixing state has become the next challenge. This study uses aerosol time-of-flight mass spectrometry (ATOFMS) data and compares the results to those of the Goddard Institute for Space Studies modelE-MATRIX (Multiconfiguration Aerosol TRacker of mIXing state) model, a global climate model that includes a detailed aerosol microphysical scheme. We use data from field campaigns that examine a variety of air mass regimens (urban, rural, and maritime). At all locations, polluted areas in California (Riverside, La Jolla, and Long Beach), a remote location in the Sierra Nevada Mountains (Sugar Pine) and observations from Jeju (South Korea), the majority of aerosol species are internally mixed. Coarse aerosol particles, those above 1 micron, are typically aged, such as coated dust or reacted sea-salt particles. Particles below 1 micron contain large fractions of organic material, internally-mixed with sulfate and black carbon, and few external mixtures. We conclude that observations taken over multiple weeks characterize typical air mass types at a given location well; however, due to the instrumentation, we could not evaluate mass budgets. These results represent the first detailed comparison of single-particle mixing states in a global climate model with real-time single-particle mass spectrometry data, an important step in improving the representation of mixing state in global climate models.

climate models↗