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At least 217 records · Page 12

Mineralogy and composition of Archean Crust, Greenland: A pilot study

The Portable Instant Display and Analysis Spectrometer (PIDAS) was taken to southwestern Greenland to investigate in situ the potential application of AVIRIS to estimate the mineralogy and composition of rocks exposed in Archean terranes. The goal was to determine the feasibility of using a high spectral resolution scanner to find and study pristine rocks, those that have not been altered by subsequent deformation and metamorphism. The application of AVIRIS data to the problems in Greenland is logical. However, before a costly deployment of the U-2 aircraft to Greenland is proposed, this study was undertaken to acquire the spectral data necessary to verify that mineralogical mapping in the environmental conditions found there is possible. Although field conditions were far from favorable, all of the major objectives of the study were addressed. One of the major concerns was that lichens would obscure the rock surfaces. It was found that the spectral signature of the lichens was distinct from the underlying rocks. Thus, a spectrum of a rock outcrop, with its partial cover of lichens, can be un-mixed into rock and lichen components. The data acquired during the course of this study supports the conclusion that areas of pristine Archean crust can be differentiated from that which has experienced low grade alteration associated with Proterizoic faulting.

Goetz, Alexander F. H.↗

Analysis of Remote Sensing Data

A brief assessment of remote sensing applied to geological studies is given. An analysis of thematic mapping data on oak-hickory forests in southern Missouri is discussed. It was found that there is a control on the infrared reflectance (bands 4, 5, and 7 of the Thematic Mapper (TM) of the forests that correlates with rock and soil types. During the growing season, soils with low water retention capacities correlate with high infrared (band 4, lesser with band 5 and 7) signatures. A metamorphic core complex called the Meatiq located in the Eastern Desert of Egypt was studied. The dome provides exposure of most of the rock units of the Arabian-Nubian Precambrian Shield. The dome bears many resemblances to Cordilleran metamorphic complexes. LANDSAT TM data was used to improve on reconnaissance maps of the dome. The remote sensing data was interpreted in the context of field observations, petrographic, and chemical analysis of rock units in the dome, in order to map similar domes in the Eastern Desert from TM data. Mapping projects such as the one just described will help constrain the geologic evolution of the Arabian-Nubian Shield. Two particular hypotheses that researchers hope to test for the development of the shield are: (1) closure of a proto-Red Sea; and (2) accretion of a primitive island arc system onto the shield.

Guiness, E. A.↗

A Model of the Chicxulub Impact Basin Based on Evaluation of Geophysical Data, Well Logs, and Drill Core Samples

Abundant evidence now shows that the buried Chicxulub structure in northern Yucatan, Mexico, is indeed the intensely sought-after source of the ejecta found world-wide at the Cretaceous-Tertiary (K/T) boundary. In addition to large-scale concentric patterns in gravity and magnetic data over the structure, recent analyses of drill-core samples reveal a lithological assemblage similar to that observed at other terrestrial craters. This assemblage comprises suevite breccias, ejecta deposit breccias (Bunte Breccia equivalents), fine-grained impact melt rocks, and melt-matrix breccias. All these impact-produced lithologies contain diagnostic evidence of shock metamorphism, including planar deformation features in quartz, feldspar, and zircons; diaplectic glasses of quartz and feldspar; and fused mineral melts and whole-rock melts. In addition, elevated concentrations of Ir, Re, and Os, in meteoritic relative proportions, have been detected in some melt-rock samples from the center of the structure. Isotopic analyses, magnetization of melt-rock samples, and local stratigraphic constraints identify this crater as the source of K/T boundary deposits.

Sharpton, Virgil L.↗

A Multispectral Micro-Imager for Lunar Field Geology

Field geologists routinely assign rocks to one of three basic petrogenetic categories (igneous, sedimentary or metamorphic) based on microtextural and mineralogical information acquired with a simple magnifying lens. Indeed, such observations often comprise the core of interpretations of geological processes and history. The Multispectral Microscopic Imager (MMI) uses multi-wavelength, light-emitting diodes (LEDs) and a substrate-removed InGaAs focal-plane array to create multispectral, microscale reflectance images of geological samples (FOV 32 X 40 mm). Each pixel (62.5 microns) of an image is comprised of 21 spectral bands that extend from 470 to 1750 nm, enabling the discrimination of a wide variety of rock-forming minerals, especially Fe-bearing phases. MMI images provide crucial context information for in situ robotic analyses using other onboard analytical instruments (e.g. XRD), or for the selection of return samples for analysis in terrestrial labs. To further assess the value of the MMI as a tool for lunar exploration, we used a field-portable, tripod-mounted version of the MMI to image a variety of Apollo samples housed at the Lunar Experiment Laboratory, NASA s Johnson Space Center. MMI images faithfully resolved the microtextural features of samples, while the application of ENVI-based spectral end member mapping methods revealed the distribution of Fe-bearing mineral phases (olivine, pyroxene and magnetite), along with plagioclase feldspars within samples. Samples included a broad range of lithologies and grain sizes. Our MMI-based petrogenetic interpretations compared favorably with thin section-based descriptions published in the Lunar Sample Compendium, revealing the value of MMI images for astronaut and rover-mediated lunar exploration.

Nunez, Jorge↗

Preliminary report on the geology and gold mineralization of the South Pass granite-greenstone terrain, Wind River Mountains, western Wyoming (US)

The South Pass granite-greenstone terrain lies near the southern tip of the Wind River Mountains of western Wyoming. This Archean supracrustal pile has been Wyoming's most prolific source of gold and iron ore. From 1962 to 1983, more than 90 million tons of iron ore were recovered from oxide-facies banded iron formation, and an estimated 325,000 ounces of gold were mined from metagreywacke-hosted shears and associated placers. Precambrian rocks at South Pass are unconformably overlain by Paleozoic sediments along the northeast flank, and a Tertiary pediment buries Archean supracrustals on the west and south. To the northwest, the supracrustals terminate against granodiorite of the Louis Lake batholith; to the east, the supracrustals terminate against granite of the Granite Mountains batholith. The Louis Lake granodiorite is approximately 2,630 + or - 20 m.y. old, and the Granite Mountains granite averages 2,600 m.y. old. The geometry of the greenstone belt is best expressed as a synform that has been modified by complex faulting and folding. Metamorphism is amphibolite grade surrounding a small island of greenschist facies rocks. The younger of the Archean supracrustal successions is the Miners Delight Formation. This unit yielded a Rb-Sr isochron of 2,800 m.y. A sample of galena from the Snowbird Mine within the Miners Delight Formation yielded a model age averaging 2,750 m.y. The Snowbird mineralization appears to be syngenetic and is hosted by metavolcanics of calc-alkaline affinity. Discussion follows.

Hausel, W. D.↗

Petrology and tectonic development of supracrustal sequence of Kerala Khondalite Belt, Southern India

The granulite terrain of southern India, of which the Kerala Khondalite belt (KKB) is a part, is unique in exposing crustal sections with arrested charnockite growth in different stages of transformation and in varied lithological association. The KKB with rocks of surficial origin and incipient charnockite development, poses several problems relating to the tectonics of burial of vast area and mechanisms involved in expelling initial H2O (causes of dryness) for granulite facies metamorphism. It is possible to infer the following sequence of events based on the field and laboratory studies: (1) derivation of protoliths of KKB from granitic uplands and deposition in fault bounded basin (cratonic rift); (2) subhorizontal deep burial of sediments; (3) intense deformation of infra and supracrustal rocks; (4) early granulite facies metamorphism predating F sub 2 - loss of primary structure in sediments and formation of charnockites from amphibole bearing gneisses and khondalites from pelites; (5) migmatisation and deformation of metasediments and gneisses; (6) second event of charnockite formation probably aided by internal CO2 build-up; and (7) isothermal uplift, entrapment of late CO2 and mixed CO2-H2O fluids, formation of second generation cordierites and cordierite symplectites.

Kumar, G. R. Ravindra↗

Geochemistry of granitoid rocks from the western Superior Province: Evidence for 2- and 3-stage crustal evolution models

The Superior Province is divisible into subprovinces that can be classified as greenstone-tonalite, paragneiss, or batholitic terranes and are distinguished by differences in lithologic proportions, metamorphic grade, and structural style. The origin and significance of contrasting geochemical characteristics of plutonic rocks from the Winnipeg River subprovince (a batholithic terrane) and the Wabigoon subprovince (a greenstone-tonalite terrane) are discussed.

Beakhouse, G. P.↗

REE chemistry and Sm-Nd systematics of late Archean weathering profiles in the Fortescue Group, Western Australia

Two weathering profiles, each consisting of an upper, sericite-rich zone and a lower, chlorite-rich zone, are preserved between flows of the Mt. Roe Basalt in the Fortescue Group, Hamersley Basin, Western Australia. REE concentrations in samples from these two profiles, which originally developed ca 2,760 Ma, show large variations depending on stratigraphic position. LREE abundances and (La/Yb)N are greatest at depths of 3-6 m below the paleosurface of the Mt. Roe #1 profile and are somewhat lower in samples above this level. The LREEs reach concentrations 6-9 times greater than in the underlying basalt, and thus appear to have been mobilized downward in the paleosol and concentrated in its middle part. LREE concentrations in the #2 profile show a similar distribution but with a sharp increase in all REE concentrations within 50 cm of the paleosurface. The distinction between the REE profiles in the two paleosols may be related to the difference in the overlying material. The #1 paleosol is overlain by a few meters of sediments and then by basalt, whereas the #2 paleosol is directly overlain by basalt. The LREEs appear to have been mobilized both during chemical weathering of the parental basalt and during later lower-greenschist-facies metamorphism and metasomatism of the paleosols. Remobilization of the REEs during the regional metamorphism of the Fortescue Group is confirmed by a whole-rock Sm-Nd reference isochron of Mt. Roe #1 samples with an age of 2,151 +/- 360 Ma. Variable initial 143Nd/144Nd values of unweathered basalt samples which may represent the paleosol protolith prevents a confident determination of the magnitude of LREE mobility. Both the initial mobilization of the REEs during weathering and the metasomatic remobilization appear to have taken place under redox conditions where Ce was present dominantly as Ce3+, because Ce anomalies are not developed within the sericite zone samples regardless of concentration. Europium anomalies in the paleoweathering profile are somewhat variable and were probably modified by mobilization of Eu2+ at metamorphic conditions. In all samples, the HREEs appear to have been relatively immobile and correlate with Al, Ti, Cr, V, Zr, and Nb. Sm-Nd systematics and REE patterns of four unweathered basalt samples indicate derivation of the Mt. Roe Basalts from a heterogeneous and enriched source having epsilon Nd between -4.0 and -7.4. Initial 143Nd/144Nd values of these basalts are even lower than those reported by NELSON et al. (1992) for Fortescue Group basalts and indicate a substantial crustal component in the generation of Mt. Roe Basalts.

NASA Discipline Exobiology↗

Meteorite regolithic breccias

In addition to endogenic processes such as heating and aqueous activity, meteorite parent bodies were subjected also to exogenic processing brought about by the impact of the other solar-system objects. Such impacts can produce a variety of effects, ranging from shock metamorphism of individual mineral grains to production of breccias; i.e., rocks consisting of mixtures of disparate lithic units. The present paper reviews recent studies of such breccias, which have generated significant information about the accretional growth of parent bodies, as well as their evolution, composition, stratigraphy, and geological processing.

Bunch, T. E.↗

Evidence for Life on Earth before 3,800 Million Years Ago

It is unknown when life first appeared on Earth. The earliest known microfossils (approx. 3,500 Myr before present) are structurally complex, and if it is assumed that the associated organisms required a long time to develop this degree of complexity, then the existence of life much earlier than this can be argued. But the known examples of crustal rocks older than approx. 3,500 Myr have experienced intense metamorphism, which would have obliterated any fragile microfossils contained therein. It is therefore necessary to search for geochemical evidence of past biotic activity that has been preserved within minerals that are resistant to metamorphism. Here we report ion-microprobe measurements of the carbon-isotope composition of carbonaceous inclusions within grains of apatite (basic calcium phosphate) from the oldest known sediment sequences a approx. 3,800 Myr-old banded iron formation from the Isua supracrustal belt, West Greenland, and a similar formation from the nearby Akilia island that is possibly older than 3,850 Myr. The carbon in the carbonaceous inclusions is isotopically light, indicative of biological activity; no known abiotic process can explain the data. Unless some unknown abiotic process exists which is able both to create such isotopically light carbon and then selectively incorporate it into apatite grains, our results provide evidence for the emergence of life on Earth by at least 3,800 Myr before present.

Mojzsis, S. J.↗

Chemical constraints on the evolution of Archean continental crust

One of the challenges of Archean geochronology is to find isotopic systems that preserve an indication of a rock's primary age in spite of the effects of later metamorphism. Zircon dating has been used widely with considerable success but not without difficulty, especially in polymetamorphic terrains. Zircons in such cases commonly are found to have lost radiogenic Pb, and despite fractionizing the zircons or abrading them to remove disturbed portions; it often is not possible to define a pattern of Pb loss from which the original age can confidently be inferred. The refinement of techniques to enable extremely small samples, or even single crystals, to be analyzed has contributed greatly to solving the problem but even those techniques cannot resolve the micron scale isotopic heterogeneities within single zircons in which much of their history is recorded. That can only be done by ion microprobe. Progress reports on studies of four Archean rocks, each of which illustrates the power and potential of ion microprobe analysis in solving problems of Archean geochronology are discussed.

Weaver, B. L.↗

Effects of Basalt Composition on a Martian Analogue Magma-Sediment Hydrothermal System Studied Through Thermochemical Modeling

High-temperature hydrothermal systems have been identified on Mars associated with both hypervelocity impacts and magmatic activity on Mars’s early history [1, 2]. These processes may have produced habitable environments by providing heat, energy, and volatile species necessary to support microbial life [3, 4]. Hydrothermal systems formed after the intrusion of mafic magmas in sedimentary rocks are of particular interest when investigating the habitability of high-temperature aqueous environments on Mars [5, 6],because during magma-sediment contact metamorphism bond fluids (e.g. in ice, pore spaces, minerals) are mobilized favoring the alteration of the country rocks and the release of bio-essential elements [7, 8]. The chemistry and mineralogy of these systems on Mars are not well constrained and, for this reason, terrestrial analogues need to be investigated. Costello et al. [5] and Crandall et al. [6] have studied a mafic dike intruding the Jurassic Entrada sandstone (Colorado Plateau, UT). The intrusion has produced a hydrothermal system with Cl-CO2 rich fluids and near-neutral pH, which induced chemical and mineralogical changes in the dike and in the sediments [5, 6]. The system reached temperatures higher than 700 °C around the contact zone [6], but lower temperatures (< 200 °C) were reached as the system cooled down [5] making the environment potentially habitable [6]. However, previous studies do not consider compositional differences between the terrestrial dike and basaltic rocks on Mars [9, 10] making difficult a direct comparison between alteration mineralogy and brine chemistry of terrestrial and martian systems. Here, we use thermochemical modelling to investigate how differences in bulk dike composition will affect secondary mineral assemblages and fluid chemistry.

S Cogliati↗

The distribution of zirconium and hafnium in terrestrial rocks, meteorites and the moon

It is shown that Zr and Hf are not always fractionated in terrestrial igneous differentiation or regional metamorphism. Data do support a Zr-Hf fractionation in the differentiation of the alkali olivine magma at St. Helena Island. A strong Zr-Hf fractionation exists among lunar rocks and minerals. Ilmenite is an excellent concentrator of Zr and Hf and always exhibits high Zr/Hf ratios. Chondritic meteorites exhibit rather uniform Zr abundances and Zr/Hf ratios but a distinct Zr-Hf fractionation is observed among the eucrite and diogenite achondrites.

Ehmann, W. D.↗

Direct evidence for eoarchean iron metabolism?

Metasedimentary rocks from Isua, West Greenland (> 3,700 million years old) contain carbonaceous compounds, compatible with a biogenic origin. The metamorphic mineral assemblage with garnet and quartz intergrowths contains layers of carbonaceous inclusions contiguous with carbon–rich sedimentary beds in the host rock. Previous studies on Isua rocks focused on testing the biogenic origin of the carbonaceous material, but here we searched for evidence which could provide new insights into the nature of the life that generated this carbonaceous material. We studied material trapped in inclusions armoured within quartz grains inside garnet porphyroblasts by non–destructive ptychographic X–ray nanotomography (PXCT). The 3D electron density maps generated by PXCT were correlated with maps from X–ray fluorescence tomography and micro–Raman spectroscopy. We found that the material trapped inside inclusions in the quartz grains consist of disordered carbon material encasing domains of iron–rich carbonaceous material. These results corroborate earlier claims for biogenic origins and are compatible with relics of metamorphosed biological material originally containing high iron/carbon ratios, comparable to ratios found in most extant organisms. Finally, these iron–rich domains represent the oldest evidence for organic iron complexes in the geologic record and are consistent with Fe–isotopic evidence for metabolic iron fractionation in > 3,700 Ma Isua banded iron formation.

58 GEOSCIENCES↗

Shock metamorphic effects in lunar microcraters

Detailed petrographic descriptions and results of electron microprobe analyses are presented for impact glasses as well as shocked and unshocked minerals associated with individual lunar microcraters (diameters of 0.4 to 4.4 mm). Rocks of four typical lunar lithologies are studied: anorthosite, anorthositic norite, ophitic basalt, and polymict breccia. Textures, mineralogies, and chemical compositions are examined along a radial traverse through each microcrater; i.e., across the impact glasses lining the crater wall, the shock-metamorphosed zone immediately underlying the glass liner, and the unshocked host rock. The microcraters are discussed in a sequence of increasing mineralogical complexity of the host rock (from anorthosite to polymict breccia) in order to distinguish shock effects among mineral types. The shock metamorphic features observed are found to be comparable to those reported in shocked basalt from Lonar Crater, India, and are categorized into five shock-intensity classes with pressures experimentally calibrated.

Schaal, R. B.↗

Redistribution of volatiles during lunar metamorphism

Thermal release profiles of Pb, Zn, and Cd in sample 66095 (highly shocked breccia with melt rock matrix) showed that these volatiles were mostly present on the surface of the grains. Zn in rusty grains from 66095 was also mostly surface Zn, probably from sphalerite in grain boundaries and cracks. Simulation experiments of volatile transfer showed that Fe, FeCl2, iron phosphide, and troilite (FeS) can be produced and transported during subsolidus reactions. These results suggest that volatiles, rust, schreibersite, and possible siderophiles which are observed in lunar highland samples might have been redistributed during disequilibrium thermal metamorphism in hot ejecta blankets, and were not necessarily introduced by volcanic activity or meteoritic addition.

Cirlin, E. H.↗

The frequency dependence of the viscous component of the magnetic susceptibility of lunar rock and soil samples

The susceptibility of two lunar samples (a soil and a low metamorphic grade breccia) has been measured in a weak field - 0.001 Oe - and as a function of frequency from 0.032 to 1.0 Hz. The measurements were made using a superconducting magnetometer. The results show that the susceptibility decreases linearly with the log of frequency. This observation is in agreement with a theoretical model for viscous decay based on the Neel theory of single-domain and superparamagnetic grains. The relation derived agrees with a model in which there is a uniform distribution of relaxation times.

Hanneken, J. W.↗

Satellite and surface geophysical expression of anomalous crustal structure in Kentucky and Tennessee

An equivalent layer magnetization model is discussed. Inversion of long wavelength satellite magnetic anomaly data indicates a very magnetic source region centered in south central Kentucky. Refraction profiles suggest that the source of the gravity anomaly is a large mass of rock occupying much of the crustal thickness. The outline of the source delineated by gravity contours is also discernible in aeromagnetic anomaly patterns. The mafic plutonic complex, and several lines of evidence are consistent with a rift association. The body is, however, clearly related to the inferred position of the Grenville Front. It is bounded on the north by the fault zones of the 38th Parallel Lineament. It is suggested that such magnetization levels are achieved with magnetic mineralogies produced by normal oxidation and metamorphic processes and enhanced by viscous build-up, especially in mafic rocks of alkaline character.

Mayhew, M. A.↗