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At least 217 records · Page 12

All sources NASA NTRS DOE OSTI

NASA NTRS1972

Methods of measurement for semiconductor materials, process control, and devices

Activities directed toward the development of methods of measurement for semiconductor materials, process control, and devices are described. Accomplishments include the determination of the reasons for differences in measurements of transistor delay time, identification of an energy level model for gold-doped silicon, and the finding of evidence that it does not appear to be necessary for an ultrasonic bonding tool to grip the wire and move it across the substrate metallization to make the bond. Work is continuing on measurement of resistivity of semiconductor crystals; study of gold-doped silicon; development of the infrared response technique; evaluation of wire bonds and die attachment; measurement of thermal properties of semiconductor devices, delay time, and related carrier transport properties in junction devices, and noise properties of microwave diodes; and characterization of silicon nuclear radiation detectors.

Bullis, W. M.↗

NASA NTRS1971

Remote sensing of vigor loss in conifers due to dwarf mistletoe

The initial operation of a multiband/multidate tower-tramway test site in northeastern Minnesota for the development of specifications for subsequent multiband aerial photography of more extensive study areas was completed. Multiband/multidate configurations suggested by the tower-tramway studies were and will be flown with local equipment over the Togo test site. This site was photographed by the NASA RB57F aircraft in August and September 1971. It appears that, of all the film/filter combinations attempted to date (including optical recombining of several spectral band images via photo enhancement techniques), Ektachrome infrared film with a Wratten 12 filter is the best for detecting dwarf mistletoe, and other tree diseases as well. Using this film/filter combination, infection centers are easily detectable even on the smallest photo scale (1:100,000) obtained on the Togo site.

Meyer, M. P.↗

NASA NTRS1972

Methods of measurement for semiconductor materials, process control, and devices

Significant accomplishments include development of a procedure to correct for the substantial differences of transistor delay time as measured with different instruments or with the same instrument at different frequencies; association of infrared response spectra of poor quality germanium gamma ray detectors with spectra of detectors fabricated from portions of a good crystal that had been degraded in known ways; and confirmation of the excellent quality and cosmetic appearance of ultrasonic bonds made with aluminum ribbon wire. Work is continuing on measurement of resistivity of semiconductor crystals; study of gold-doped silicon, development of the infrared response technique; evaluation of wire bonds and die attachment; and measurement of thermal properties of semiconductor devices, delay time and related carrier transport properties in junction devices, and noise properties of microwave diodes.

Bullis, W. M.↗

NASA NTRS1972

Energy distribution among reaction products. IV.

Use of an infrared chemiluminescence technique, called 'Method II,' or the 'method of arrested relaxation' to measure the distribution of energy among products of the Cl + HI and Cl + DI reactions. Preliminary results are also given for the Br + HI and Cl + HBr reactions. Instead of measuring vibrational relaxation, Method II attempts to arrest vibrational and rotational relaxation by the rapid removal of excited products at a cold surface.

Maylotte, D. H.↗

NASA NTRS1973

Methods of measurement for semiconductor materials, process control, and devices

This progress report describes NBS activities directed toward the development of methods of measurement for semiconductor materials, process control, and devices. Significant accomplishments during this reporting period include design of a plan to provide standard silicon wafers for four-probe resistivity measurements for the industry, publication of a summary report on the photoconductive decay method for measuring carrier lifetime, publication of a comprehensive review of the field of wire bond fabrication and testing, and successful completion of organizational activity leading to the establishment of a new group on quality and hardness assurance in ASTM Committee F-1 on Electronics. Work is continuing on measurement of resistivity of semiconductor crystals; characterization of generation-recombination-trapping centers in silicon; study of gold-doped silicon; development of the infrared response technique; evaluation of wire bonds and die attachment; and measurement of thermal properties of semiconductor devices, delay time and related carrier transport properties in junction devices, and noise properties of microwave diodes.

Bullis, W. M.↗

NASA NTRS1977

Some physical and thermodynamic properties of rocket exhaust clouds measured with infrared scanners

Measurements using infrared scanners were made of the radiation from exhaust clouds from liquid- and solid-propellant rocket boosters. Field measurements from four launches were discussed. These measurements were intended to explore the physical and thermodynamic properties of these exhaust clouds during their formation and subsequent dispersion. Information was obtained concerning the initial cloud's buoyancy, the stabilized cloud's shape and trajectory, the cloud volume as a function of time, and it's initial and stabilized temperatures. Differences in radiation intensities at various wavelengths from ambient and stabilized exhaust clouds were investigated as a method of distinguishing between the two types of clouds. The infrared remote sensing method used can be used at night when visible range cameras are inadequate. Infrared scanning techniques developed in this project can be applied directly to natural clouds, clouds containing certain radionuclides, or clouds of industrial pollution.

Gomberg, R. I.↗

NASA NTRS1977

Polarimeter measures sea state characteristics using emitted infrared radiation

An infrared polarimeter, capable of operating between 1 and 12 micrometers wavelength has been used to measure the polarization of emitted radiation from the sea. The observed polarization at 10.6 micrometers from a smooth sea was found to be positive, indicating the dominance of reflected infrared sky radiation over the emitted. With the appearance of waves, the percent polarization increased, as expected, for a zenith angle well above the Brewster angle for water. This is qualitatively in accordance with a model presented to explain the behavior. Initial analyses indicate that the polarized components of the sea's emitted and reflected radiation are affected by type and direction of waves, angle of viewing, and foam. The effects of variations in these parameters require further delineation. The infrared polarimetric technique appears to be a novel new passive method for remote monitoring of waves.

Egan, W. G.↗

NASA NTRS1978

Phytanyl-glycerol ethers and squalenes in the archaebacterium Methanobacterium thermoautotrophicum

Gas chromatographic and mass- and infrared-spectrometric techniques are used to assay the lipids of a thermophilic chemolithotroph, Methanobacterium thermoautotrophicum. Of the chloroform-soluble lipids, 79% are polar and 21% non-polar. Attention is given to the detection of squalene and hydrosqualene derivatives, which, coupled with 16S r-RNA sequence homologies, indicate that the extreme halophiles and the methanogens share a common ancestor.

Tornabene, T. G.↗

NASA NTRS1980

Detection of tanker defects with infrared thermography

Infrared scanning technique for finding defects in secondary barrier of liquid natural gas (LNG) tank has been successfully tested on ship under construction at Newport News Shipbuilding and Dry Dock Company. Technique determines defects with minimal expenditure of time and manpower. Tests could be repeated during life of tanker and make more complicated testing unnecessary. Tests also confirmed that tank did not have any major defects, and tank was certified.

Kantsios, A. G.↗

NASA NTRS1980

Infrared heterodyne spectroscopy in astronomy

A heterodyne spectrometer was constructed and applied to problems in infrared astronomical spectroscopy. The instrument offers distinct observational advantages for the detection and analysis of individual spectral lines at Doppler-limited resolution. Observations of carbon dioxide in planetary atmospheres and ammonia in circumstellar environments demonstrate the substantial role that infrared heterodyne techniques will play in the astronomical spectroscopy of the future.

Betz, A.↗

NASA NTRS1979

Overview of the NASA tropospheric environmental quality remote sensing program

This paper will summarize the current NASA Tropospheric Environmental Quality Remote Sensing Program for studying the global and regional troposphere from space, airborne and ground-based platforms. As part of the program to develop remote sensors for utilization from space, NASA has developed a series of passive and active remote sensors which have undergone field test measurements from airborne and ground platforms. Recent measurements with active lidar and passive gas filter correlation and infrared heterodyne techniques will be summarized for measurements of atmospheric aerosols, CO, SO2, O3, and NH3. These measurements provide the data base required to assess the sensitivity of remote sensors for applications to urban and regional field measurement programs. Studies of Earth Observation Satellite Systems are currently being performed by the scientific community to assess the capability of satellite imagery to detect regions of elevated pollution in the troposphere. The status of NASA sponsored research efforts in interpreting satellite imagery for determining aerosol loadings over land and inland bodies of water will be presented, and comments on the potential of these measurements to supplement in situ and airborne remote sensors in detecting regional haze will be made.

Allario, F.↗

NASA NTRS1981

Satellite estimation of the surface energy balance, moisture availability and thermal inertia

A method for inferring the distribution of surface heat and evaporative fluxes and the ground moisture availability and thermal inertia (ground conductive capacity) is used to analyze two urbanized areas, Los Angeles and St. Louis. The technique employs infrared satellite temperature measurements in conjunction with a one-dimensional boundary-layer model. Results show that there is a marked reduction of evaporation and moisture availability and a corresponding elevation of sensible heat flux over urbanized areas and over cropped areas with low vegetative cover. Conversely, low heat flux and high evaporation characterize vegetated and, especially, forested areas. Warm urban centers appear directly related to a reduction in vegetation, which normally allows for a greater fraction of available radiant energy to be converted into latent heat flux. The distribution of thermal inertia was surprisingly ill-defined and its variation between urban and rural areas was quite small. Thus, the increased heat storage within the urban fabric, which has been proposed as the underlying cause of the nocturnal heat island, may be caused mainly by enhanced daytime surface heating which occurs because of surface dryness, rather than by large spatial variations in the conductivity of the surface.

Carlson, T. N.↗

NASA NTRS1981

Infrared experiments for spaceborne planetary atmospheres research. Full report

The role of infrared sensing in atmospheric science is discussed and existing infrared measurement techniques are reviewed. Proposed techniques for measuring planetary atmospheres are criticized and recommended instrument developments for spaceborne investigations are summarized for the following phenomena: global and local radiative budget; radiative flux profiles; winds; temperature; pressure; transient and marginal atmospheres; planetary rotation and global atmospheric activity; abundances of stable constituents; vertical, lateral, and temporal distribution of abundances; composition of clouds and aerosols; radiative properties of clouds and aerosols; cloud microstructure; cloud macrostructure; and non-LTE phenomena.

Source record↗

NASA NTRS1981

Infrared spectroscopic analysis of the effects of simulated space radiation on a polyimide

Infrared spectroscopic techniques have been used to study the effects of electron radiation on the polyimide PMDA-p,p-prime- ODA. The radiation exposures were made at various dose rates, for a total dose approximately equal to that for 30 years of exposure to electron radiation in geosynchronous earth orbit. At high dose rates the major effect was probably the formation of a polyisoimide or a charged quaternary amine, and at the low dose rates the effect was a reduction in the amount or aromatic ether linkage. In addition, the effects of dose rate for a small total dose were studied. Elevated temperatures occurred at high dose rates and were, in part, probably the cause of the radiation product. The data suggest that dose rates for accelerated simulations of the space environment should not exceed 100,000 rads/sec.

Ferl, J. E.↗

NASA NTRS1982

Atmospheric trace molecule spectroscopy

The Spacelab investigation entitled Atmospheric Trace Molecule Spectroscopy (ATMOS) is designed to obtain fundamental information related to the chemistry and physics of the Earth's upper atmosphere using the techniques of infrared absorption spectroscopy. There are two principal objectives to be met. The first is the determination, on a global scale, of the compositional structure of the upper atmosphere and its spatial variability. The establishment of this variability represents the first step toward determining the characteristic residence times for the upper atmospheric constituents; the magnitudes of their sources and sinks; and, ultimately, an understanding of their effects on the stability of the stratosphere. The second objective is to provide the high-resolution, calibrated spectral information which is essential for the detailed design of advanced instrumentation for subsequent global monitoring of specific species found to be critical to atmospheric stability. This information will be disseminated in the form of a three dimensional atlas of solar absorption spectra obtained over a range of latitudes, longitudes, and altitudes.

Farmer, C. B.↗

NASA NTRS1984

Airborne Observations of Comets

The application of airborne infrared observational techniques to cometary problems is discussed. Several areas of cometary studies which should benefit from airborne observations were identified. Special attention is given to the 1985 to 1986 apparition of Halley's comet since it is a particularly favorable opportunity to make airborne observations of a comet; however, airborne observations of other comets are also possible and highly desirable. Various types of airborne observations which can be made of comets are enumerated.

Campins, H.↗

NASA NTRS1985

A measurement of the vibrational band strength for the upsilon sub 3 band of the HO2 radical

The HO2 radicals generated in a discharge-flow system were observed with tunable diode laser absorption in the P-branch of the nu(3) vibrationall band at 1080/cm. The observed line positions agree with those calculated from the molecular constants for the nu(3) bland obtained from a previous study using laser magnetic resonance spectroscopy. The band strength was determined by observing line center absoptions when HO2 is produced in the reaction F + H2O2 yields HO2 + HF (k1) with a measured concentration of atomic fluorine and excess hydrogen peroxide. F-atom concentrations are measured by diode laser absorption of the spin-orbit transition at 404/cm. The analysis accounts for HO2 losses due to the reactions of HO2 + HO2 yields H2O2 + O2 (k3) and F + HO2 yields HF + O2 (k4). The line strength for the 6(15) 7(16) F(1) transition is 2.9 x 10 to the 21st power sq cm/molecule/cm which corresponds to a nu(3) band strength of 34 +/- 9 sq/cm(STP atm). This value is a factor of 6 lower than previous ab initio calculations. These results will be useful in assessing the feasibility of atmospheric measurements of HO2 using infrared absorption techniques.

Zahniser, M. S.↗

NASA NTRS1985

Polyimide analysis using diffuse reflectance-FTIR

The thermal imidization of a number of polyimide precursors in the form of powders, films, and prepregs was examined by an in situ diffuse reflectance-FTIR technique where infrared spectra were determined while the material was being heated. An analysis of these spectra revealed that, with the exception of one water soluble adhesive, each precursor developed an anhydride band around 1850 cm/cu during imidization. This band diminished in intensity during final stages of cure. Efforts were made to quantify the amount of anhydride in several samples. Evidence obtained could be interpreted to mean that poly(amic acid) resins undergo an initial reduction in molecular weight during imidization before recombining to achieve their ultimate molecular weights as polyimides. Several reports in the literature are cited to support this interpretation. This report serves both to document anhydride formation during imidization and to increase our fundamental understanding of how polyimides cure.

Young, P. R.↗