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At least 217 records · Page 12

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NASA NTRS1985

Reassignment of the Iron (3) Absorption Bands in the Spectra of Mars

Absorption features in the near-infrared and visible region reflectance spectra of Mars have been assigned to specific Fe (3+) crystal-field and o(2-) yields Fe(3+) charge transfer transitions. Recently, near-ultraviolet absorption spectra of iron oxides were obtained and the energies of o(2-) yields Fe(3+) charge-transfer (LMCT) transitions were determined from accurate SCF-X # alpha-SW molecular orbital calculations on (FeO6)(9-) and (FeO4)(5-) clusters. Both the theoretical and experimental results, together with existing data in the literature, show that some of the previous Fe(3+) band assignments in the spectra of Mars need to be revised. The theory of Fe(3+) spectra in minerals is discussed and applied to the spectrum of Mars.

Sherman, D. M.↗

NASA NTRS1985

Spectral and other physicochemical properties of submicron powders of hematite (alpha-Fe2O3), maghemite (gamma-Fe2O3), magnetite (Fe3O4), goethite (alpha-FeOOH), and lepidocrocite (gamma-FeOOH)

The spectral properties (0.35-2.20 microns) of submicron powders of hematite, maghemite, magnetite, goethite, and lepidocrocite are determined. Other physicochemical data are obtained for the powders in order to determine if deviations from stoichiometry occur due to their small particle size, to determine their state of chemical and phase purity, and to determine the physical characteristics of the individual powders. The physicochemical data obtained include mean particle diameter, discrete particle shape, chemical composition, crystallographic phase, magnetic parameters, and Moessbauer parameters. The positions of the spectral features for the hematite, maghemite, and magnetite powders are independent of temperature over the interval between about +20 and -110 C. For the goethite and lepidocrocite powders, a small shift of about 0.02 micron to shorter wavelengths is observed for some of the features after cooling to about -110 C. The spectral properties of the iron oxides and oxyhydroxides are important not only for understanding the basic physics and chemistry of the compounds but also for applications such as the remote sensing of the earth and Mars.

Morris, R. V.↗

NASA NTRS1983

Spectral reflectance of surface soils: Relationships with some soil properties

Using a published atlas of reflectance curves and physicochemical properties of soils, a statistical analysis was carried out. Reflectance bands which correspond to five of the wavebands used by NASA's Thematic Mapper were examined for relationships to specific soil properties. The properties considered in this study include: Sand Content, Silt Content, Clay Content, Organic Matter Content, Cation Exchange Capacity, Iron Oxide Content and Moisture Content. Regression of these seven properties on the mean values of five TM bands produced results that indicate that the predictability of the properties can be increased by stratifying the data. The data was stratified by parent material, taxonomic order, temperature zone, moisture zone and climate (combined temperature and moisture). The best results were obtained when the sample was examined by climatic classes. The middle Infra-red bands, 5 and 7, as well as the visible bands, 2 and 3, are significant in the model. The near Infra-red band, band 4, is almost as useful and should be included in any studies. General linear modeling procedures examined relationships of the seven properties with certain wavebands in the stratified samples.

Kiesewetter, C. H.↗

NASA NTRS1986

Red/violet contrast reversal on Mars - Significance for eolian sediments

Viking Orbiter images of Mars are analyzed to define relationships between the observed contrast reversals (CR) and specific surface features. The link between CR phenomena and surface composition was first detected in contrast comparisons between UV and visible wavelength Mariner 9 data. Viking data, taken through red and violet filters, showed that the CRs occurred only with crater splotches and splotch-related streaks and in bright depositional and dark erosional streaks, both being low-albedo markings presumably caused by eolian forces. The splotch phenomena is confined mainly to the Oxia Palus region, although there are other regions where splotches and streaks commingle. Laboratory tests to mimic the CR characteristics showed that CRs are a common phenomena of different size fractions of iron oxides, e.g., goethite, where particles under 5 microns have been removed. The splotches, including dune formations, are therefore believed to indicate the presence of particles in the 100-800 microns diam range. Finer particles ride on the tops of the dust storms, and are continually removed from the surface by saltation.

Thomas, P.↗

NASA NTRS1986

New results for geologic units mapping of Utah test sites using Landsat TM data

This paper continues a study on the accuracy of geological mapping using Landsat Thematic Mapper data (Short, 1984). In June 1976, both the White Mountain alteration zone and the Waterpocket Fold sedimentary rock sites in Utah were surveyed by the Bendix 24-band scanner on a NASA NC-130B aircraft. Mid-June 1984 TM data for these two sites have been processed like the 1976 data to test the quality of simulation of TM data. Principal-components (PC) color composite images for White Mountain show close correspondence to the Bendix PC images. At this site carbonate strata are uniquely discriminated in both Bendix and TM composites that use an inverted PC 3 image. Alunite/kaolinite and hematite/limonite alteration zones developed on volcanic flows are also sharply separated, but iron oxide and silicified zones are less so. The accuracy of rock-units mapping at the Waterpocket Fold site by supervised classification of the June TM data is significantly better, reaching 70 percent in the best case, than for January 1983 data for that site.

Short, N. M.↗

NASA NTRS1986

Reactions occurring during the sulfation of sodium chloride deposited on alumina substrates

The reaction between solid NaCl and air containing 1 pct SO2 has been studied between 500 and 700 C. The reaction product, Na2SO4, forms not only on the surface of the NaCl but also on surrounding areas of the substrate due to the volatility of the NaCl at these temperatures. At the higher temperatures, the vapor pressure of NaCl is so high that the majority of the reaction product is distributed on the substrate. Above 625 C, the reaction product is a liquid solution of NaCl and Na2SO4 that exists only so long as NaCl is supplied from the original crystal source. Eventually, the liquid solidifies by constitutional solidification as the NaCl is converted to Na2SO4. While it exists, the liquid NaCl-Na2SO4 solution is shown to be highly corrosive to Al2O3 and, on a scale of Al2O3 growing on alloy HOS 875, particularly attacks the grain boundaries of the scale at preferred sites where chromium and iron oxides and sulfides rapidly develop. This is proposed as one mechanism by which NaCl deposition contributes to the initiation of low temperature hot corrosion.

Wu, C. S.↗

NASA NTRS1987

Surface catalytic degradation study of two linear perfluoropolyalkylethers at 345 C

Thin-liquid-film degradation studies of two commercially available perfluoropolyalkylether fluids (PFAE) were performed at 345 C, in nitrogen and air atmospheres, on iron and 440 C stainless steel surfaces. It was found that one fluid degraded on both iron and 440 C stainless steel surfaces in an air atmosphere, whereas the other fluid did not degrade. Chemical analysis revealed that the test fluid degraded to lower molecular weight products and that the degradation was accompanied by the formation of a brownish deposit on both the iron and 440 C stainless steel surfaces. Surface analysis of the deposit revealed a susbstantial amount of iron oxide (Fe2O3). It was hypothesized that the fluid which degraded did so because of its acetal structure. The other fluid, lacking the acetal structure, did not degrade.

Morales, Wilfredo↗

NASA NTRS1988

Development of remote sensing techniques capable of delineating soils as an aid to soil survey

Eighty-one benchmark soils from Alabama, Georgia, Florida, Tennessee, and Mississippi were evaluated to determine the feasibility of spectrally differentiating among soil categories. Relationships among spectral properties that occur between soils and within soils were examined, using discriminant analysis. Soil spectral data were obtained from air-dried samples using an Exotech Model 20C field spectroradiometer (0.37 to 2.36 microns). Differentiating among the orders, suborders, great groups, and subgroups using reflectance spectra achieved varying percentages of accuracy. Six distinct reflectance curve forms were developed from the air-dried samples based on the shape and presence or absence of adsorption bands. Iron oxide and organic matter content were the dominant soil parameters affecting the spectral characteristics for differentiating among and between these soils.

Coleman, T. L.↗

NASA NTRS1988

Compositional studies of primitive asteroids

The composition of primitive asteroids and their relationship to satellites in the solar system will be studied by analyzing existing narrowband charge coupled device (CCD) reflectance spectra, acquiring additional spectra of asteroids and small satellites in the 0.5 to 1.0 micrometer spectral range, and exploring possibilities for obtaining compositional information in the blue-UV spectral region. Comparison with laboratory spectra of terrestrial chlorites and serpentines (phyllosilicates) and the clay minerals found in carbonaceous chondrite meteorites will continue. During 1987, narrowband CCD reflectance spectra of 17 additional asteroids were acquired. These spectra and spectra of 34 other asteroids have been used primarily for two studies: weak absorption features similar to those due to Fe2(+) and Fe2(+) - Fe3(+) transitions in iron oxides f ound in terrestrial chlorites and serpentines and carbonaceous chondrites have been identified in some primitive asteroid spectra. There is a first indication that asteroids grouped by heliocentric distance show similar weak absorption features. Nonparametric statistics are being applied to test the hypothesis of discrete remnants of a gradation in composition of outer-belt asteroids.

Vilas, F.↗

NASA NTRS1988

The soils of Mars

A mineralogical model for the Mars fine soil that includes as major components smectite clays absorbed and coated with amorphous iron oxyhydroxides and perhaps mixed with small amounts of better-crystalized iron oxides as separate phases is proposed. Also present as accessory minerals are sulfate minerals such as kieserite (MgSO4.H2O) and/or anhydrite (CaSO4), rutile (TiO2), and maghemite (Fe2O3) or magnetite (Fe3O4), the last two as magnetic components. Carbonates may be present at low concentrations only (less than 1 to 2 pct). However, a prime question to be addressed by a Mars Sample Return Mission shall be related to the mineralogical composition of the soil, and its spatial variability.

Banin, A.↗

NASA NTRS1987

Phase relations in iron-rich systems and implications for the earth's core

Recent experimental data concerning the properties of iron, iron sulfide, and iron oxide at high pressures are combined with theoretical arguments to constrain the probable behavior of the Fe-rich portions of the Fe-O and Fe-S phase diagrams. Phase diagrams are constructed for the Fe-S-O system at core pressures and temperatures. These properties are used to evaluate the current temperature distribution and composition of the core.

Anderson, William W.↗

NASA NTRS1988

Detection techniques using multispectral data to index soil erosional status

Indexing techniques that can be used to detect soil erosion utilizing the known band widths of the Landsat MSS and TM sensors are identified. The indexing techniques focus on iron oxides, clays, and organic matter as properties revealing soil erosional status. For data aquisition, a Collins visible and infrared intelligent spectrometer was used to collect data from 0.4-24 microns. Pressed polytetrafluorethylene was used as the reflectance standard and was aquired at the same time that the sample data were aquired.

Pelletier, R. E.↗

NASA NTRS1989

Remote sensing of soils in the eastern Palouse region with Landsat Thematic Mapper

Soils of the Palouse region of eastern Washington State were investigated using Landsat Thematic Mapper (TM) band ratios to discriminate areas where erosion has caused paleosols to be exposed. Ratioed data were clustered and plotted to show soil lines which could be subdivided into various levels of organic matter and iron oxides. Successfully classified scenes of a summer fallow (bare soil) field were obtained with band ratios 1/4, 3/4, and 5/4 to map organic carbon and 3/4, 5/4, and 5/3 for the iron/carbon ratio indicator of erosion. Regression models were made with 5/4 data and organic carbon and 5/3 data and the iron/carbon ratio. Based on this analysis, 21 percent of the test field soils are exposed or nearly exposed paleosols.

Frazier, B. E.↗

NASA NTRS1989

Phyllosilicate absorption features in main-belt and outer-belt asteroid reflectance spectra

Absorption features having depths up to 5 percent are identified in high-quality, high-resolution reflectance spectra of 16 dark asteroids in the main belt and in the Cybele and Hilda groups. Analogs among the CM2 carbonaceous chondrite meteorites exist for some of these asteroids, suggesting that these absorptions are due to iron oxides in phyllosilicates formed on the asteroidal surfaces by aqueous alteration processes. Spectra of ten additional asteroids, located beyond the outer edge of the main belt, show no discernible absorption features, suggesting that aqueous alteration did not always operate at these heliocentric distances.

Vilas, Faith↗

NASA NTRS1991

Options for Martian propellant production

A quantitative evaluation methodology for utilizing in-situ resources on Mars for the production of useful substances. The emphasis is on the chemical processes. Various options considering different feedstock (mostly, carbon dioxide, water, and iron oxides) are carefully examined for the product mix and the energy needs. Oxygen, carbon monoxide, alcohols, and other chemicals are the end products. The chemical processes involve electrolysis, methanation, and variations. It is shown that maximizing the product utility is more important than the production of oxygen, methane, or alcohols. An important factor is the storage of the chemicals produced. The product utility is dependent, to some extent, upon the mission. A combination of the stability, the enthalpy of formation, and the mass fraction of the products is seen to yield a fairly good quantitative feel for the overall utility and maximum mission impact.

Dowler, Warren↗

NASA NTRS1990

Process engineering concerns in the lunar environment

The paper discusses the constraints on a production process imposed by the lunar or Martian environment on the space transportation system. A proposed chemical route to produce oxygen from iron oxide bearing minerals (including ilmenite) is presented in three different configurations which vary in complexity. A design for thermal energy storage is presented that could both provide power during the lunar night and act as a blast protection barrier for the outpost. A process to release carbon from the lunar regolith as methane is proposed, capitalizing on the greater abundance and favorable physical properties of methane relative to hydrogen to benefit the entire system.

Sullivan, T. A.↗

NASA NTRS1990

Magnetic beneficiation of highland and hi-Ti mare soils - Magnet requirements

Magnetic beneficiation of immature highland soil 67511 recovered 22 wt pct of the sample with an iron oxide content of 0.6 pct. Magnetic isolates of immature highland soils are candidates for the manufacture of silicon, aluminum, and other metals. Fifty-seven percent of the ilmenite in immature mare soil 71061 was recovered in magnetic processing. Ilmenite can be recovered by magnetic separation but may be difficult to 'high'grade'. A parametric description is given of magnetic separators suitable for supplying ilmenite for the production of 22.7 metric tons per year oxygen.

Oder, R. R.↗

NASA NTRS1991

Program and Abstracts for Clay Minerals Society 28th Annual Meeting

This volume contains abstracts that were accepted for presentation at the annual meeting. Some of the main topics covered include: (1) fundamental properties of minerals and methods of mineral analysis; (2) surface chemistry; (3) extraterrestrial clay minerals; (4) geothermometers and geochronometers; (5) smectite, vermiculite, illite, and related reactions; (6) soils and clays in environmental research; (7) kaolinite, halloysite, iron oxides, and mineral transformations; and (8) clays in lakes, basins, and reservoirs.

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