Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “HCO”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 217 records · Page 12
All sourcesNASA NTRSDOE OSTI
NASA NTRS1981

The energetics of molecular clouds. III - The S235 molecular cloud

The molecular cloud associated with the S235 H II region has been studied by means of molecular lines and near-infrared observations. The cloud consists of two components, one of which partly surrounds the S235 H II region. The other component contains a dense, hot region of active star formation, marked by self-reversed CO profiles, compact H II regions, masers, and infrared sources. From the molecular line data, the size and mass of the two components are estimated to be 6-8 pc and 3000-4000 solar masses. More detailed studies near the region of active star formation yield estimates of density (approximately 200,000-500,000/cu cm) and the abundances of H2CO, HCO(+), HCN, and (C-13)O. Analysis of the energetics suggests that the cloud is heated by the exciting star of S235 and by the exciting stars of the compact H II regions. Assuming that the gas is heated by collisions with warm dust grains, the far-infrared luminosity has been predicted. The observations of far-infrared emission are in reasonable agreement with predictions.

Evans, N. J., II↗
NASA NTRS1982

Photochemical processes in the inner coma

Models for the inner-coma chemistry of comets are reviewed. The physics relevant to the coma's chemistry is summarized, and the interaction of solar radiation with the coma is described, along with photolytic and chemical processes. The formation and destruction of several observed species are traced through a chemical reaction network, and model results are compared with observations. The species considered include CN, C2, C3, NH2, CH, CO, CO(+), OH, H2O, HCO, C2H4, and C2H3. The models most consistent with observations are shown to indicate that only trace amounts (2% in all) of molecules bearing CN, C2, C3, and NH2 can be present in the nucleus of a comet.

Huebner, W. F.↗
NASA NTRS1982

Loss of CO/+/ ions by reaction with H2 in OMC-1

The temperature dependence of the rate constant for the reaction CO(+)+H2 yields HCO(+) has been measured in the temperature range 100-390 K. The rate constant has no dependence on temperature in this range, indicating that at the temperatures prevalent in OMC-1, the rate of loss of CO(+) by reaction with H2 is much too large to allow for the observed column abundance under steady-state conditions.

Huntress, W. T., Jr.↗
NASA NTRS1982

EUV arcades - Signatures of filament instability

The present investigation is based on the EUV observations from the HCO spectroheliometer aboard Skylab. These observations provide a great deal of information on coronal structures. The investigation is concerned with the EUV corona around active region filaments. One of its goals is to define the geometry and temperature distribution around those filaments which appear to be 'stable' (lifetimes equal to or greater than 2 days). The second goal is to study time changes in structures associated with other filaments which are 'unstable'. It is pointed out that the filaments and associated EUV loops reported in this investigation are not flare-related. The data of primary interest are those of Sept. 5, 1973, for which there exist simultaneous EUV and H-alpha filtergrams for the active region McMath 12510. It is found that active region filaments lie within channels of low emissivity in EUV lines formed above 1.5 x 10 to the 6th K.

Schmahl, E. J.↗
NASA NTRS1983

The molecular cloud complex associated with ON 1

Observations of CO with different resolutions near the compact H II region/maser source ON 1 are presented, as well as new H2CO and HCO(+) observations. ON 1 is part of an extended molecular cloud complex with overall dimensions of 25 x 60 pc at a distance of 1.4 kpc; it appears to be the only site of star formation in at least the western part of the complex. ON 1 coincides with a compact and dense molecular cloud core (size 0.8 pc) that shows little sign of disruption indicating that ON 1 has only recently turned on. The isolation and apparent youth of ON 1 suggest that the very beginning of the star formation phase of a molecular cloud complex is observed here.

Israel, F. P.↗
NASA NTRS1983

Measurement of the J = 0-1 rotational transitions of three isotopes of ArD(+)

The rotational transitions of all three isotopic species of ArD(+) in samples containing the Ar isotopes in their natural abundances have been measured by means of millimeter and submillimeter techniques that employ a magnetically enhanced abnormal glow discharge. All three transition frequency measurements were made from digitally averaged signals detected through a lock-in amplifier with a 10-msec time constant. The Ar-4OD(+) transition was easily visible in real time on an oscilloscope with SNR of about 15. It is noted that the observed transition of Ar-38D(+) is more than five orders of magnitude weaker than that due to HCO(+).

Bowman, W. C.↗
NASA NTRS1983

The young sun and the atmosphere and photochemistry of the early earth

The origin and evolution of the earth's early atmosphere depend crucially on the dissipation time of the primitive solar nebula (SN). Using different theories of turbulence, the dissipation time of an SN of 0.1 solar mass is estimated as 2.5-8.3 Myr. Because accretion times are usually much longer, it is concluded that most planetary accretion must have occurred in a gas-free environment. Using new IUE data, a wavelength-dependent UV flux is constructed for the young sun which is then used to study the photochemistry and concentrations of O, O2, O3, OH, H, HCO and formaldehyde H2CO in the earth's early prebiological atmosphere.

Canuto, V. M.↗
NASA NTRS1982

Millimeter and submillimeter laboratory spectroscopy - Recent results of astrophysical interest

Recent laboratory spectroscopic results on the transient neutral species CCH, NH2, and NaH, the molecular ions HCO(+), N2H(+), and CO(+), and the light asymmetric internal rotor HOOH are reviewed. It is shown that the shorter millimeter and submillimeter spectral region offers a number of advantages, even in the laboratory. Attention is also given to the requirements for theoretical models capable of the accurate spectral predictions required for many astrophysical applications. The results presented here are seen as demonstrating that millimeter and submillimeter microwave spectroscopy provides a sensitive and flexible means of studying short-lived species in the laboratory. It is believed that, in combination with the appropriate theoretical approach, studies of this type are capable of providing accurate spectral maps over wide spectral regions for most species of astrophysical importance.

De Lucia, F. C.↗
NASA NTRS1984

Rate constant for the OH + CO reaction - Pressure dependence and the effect of oxygen

The effect of pressure on the rate constant of the OH + CO reaction has been measured for Ar, N2, and SF6 over the pressure range 200-730 torr. All experiments were at room temperature. The method involved laser-induced fluorescence to measure steady-state OH concentrations in the 184.9 nm photolysis of H2O-CO mixtures in the three carrier gases, combined with supplementary measurements of the CO depletion in these same carrier gases in the presence and absence of competing reference reactants. The effect of O2 on the pressure effect was determined. A pressure enhancement of the rate constant was observed for N2 and SF6, but not for Ar, within an experimental error of about 10 percent. The pressure effect for N2 was somewhat lower than previous literature reports, being about 40 percent at 730 torr. For SF6 a factor of two enhancement was seen at 730 torr. In each case it was found that O2 had no effect on the pressure enhancement. The roles of the radical species HCO and HOCO were evaluated.

Demore, W. B.↗
NASA NTRS1985

Chemistry in dynamically evolving clouds

A unified model of chemical and dynamical evolution of isolated, initially diffuse and quiescent interstellar clouds is presented. The model uses a semiempirically derived dependence of the observed cloud temperatures on the visual extinction and density. Even low-mass, low-density, diffuse clouds can collapse in this model, because the inward pressure gradient force assists gravitational contraction. In contrast, previous isothermal collapse models required the low-mass diffuse clouds to be unrealistically cold before gravitational contraction could start. Theoretically predicted dependences of the column densities of various atoms and molecules, such as C and CO, on visual extinction in diffuse clouds are in accord with observations. Similarly, the predicted dependences of the fractional abundances of various chemical species (e.g., CO, H2CO, HCN, HCO(+)) on the total hydrogen density in the core of the dense clouds also agree with observations reported to date in the literature. Compared with previous models of interstellar chemistry, the present model has the potential to explain the wide spectrum of chemical and physical properties of both diffuse and dense clouds with a common formalism employing only a few simple initial conditions.

Tarafdar, S. P.↗
NASA NTRS1986

HCNH(+) - A new interstellar molecular ion

The first interstellar detection of HCNH(+) is reported. The J = 1-0, 2-1, and 3-2 rotational transitions of this molecule at 74, 148, and 222 GHz have been observed toward Sgr B2. Using a large velocity gradient model calculation, the column density of HCNH(+) is found to be about 4 x 10 to the 14th/sq cm, about one order of magnitude less than that estimated for HCO(+) and HCN in this source. Such a column density implies a fractional abundance of at least one to several orders of magnitude larger than predicted by numerous ion-molecule models. Coupled with a relatively low abundance of HCN and a small HNC/HCN ratio, this suggests that HCNH(+) is not channeled into HCN or HNC as rapidly as thought.

Ziurys, L. M.↗
NASA NTRS1986

Ion composition results during the International Cometary Explorer encounter with Giacobini-Zinner

The International Cometary Explorer spacecraft passed through the coma of comet Giacobini-Zinner about 7800 kilometers antisunward of the nucleus on September 11, 1985. The ion composition instrument was sensitive to ambient ions with mass-to-charge ratios in the ranges 1.4 to 3 atomic mass units per electron charge (amu/e) and 14 to 33 amu/e. Initial interpretation of the measurements indicates the presence of H2O(+), H3O(+), probably CO(+) and HCO(+), and ions in the mass range 23 to 24; possible candidates are Na(+) and Mg(+) and Mg(+). In addition to these heavy ions, measured over the velocity range 80 to 223 kilometers per second, the instruments measured He(2+) of solar wind origin over the range 237 to 463 kilometers per second. The heavy ions have a velocity distribution which indicates that they have been picked up by the motional electric field, whereas the light ions are steadily decelerated as the comet tail axis is approached. These results are in agreement with the picture of a comet primarily consisting of water ice, together with other material, that sublimes, streams away from the nucleus, becomes ionized, and interacts with the solar wind.

Ogilvie, K. W.↗
NASA NTRS1986

Molecular ions in the circumstellar envelope of IRC + 10216

Assuming a steady and spherically symmetric mass loss, the spatial distribution of the ionization in a C-rich circumstellar envelope (CSE) is calculated, and it is shown that molecular ions dominate the ionization and chemistry of a large part of the CSE. Cosmic ray ionization of molecular hydrogen yields H3(+), and the photoionization of acetylene and neutral carbon yields C2H2(+) and C(+). In the system, the primary ions generate a series of heavier molecular ions by reactions with neutral molecules before being destroyed by dissociative recombination. The most promising candidate for mm-wavelength detection is found to be HCO(+), and IRC + 10216 antenna temperatures are calculated for different telescope sizes. Photoproduced C2H2(+), the most abundant intermediate distance CSE ion, may be responsible for the synthesis of various heavy hydrocarbon molecules at levels observed in IRC + 10216.

Glassgold, A. E.↗
NASA NTRS1986

Effects of stellar outflows on interstellar sulfur oxide chemistry

Interferometer Maps with 2" to 6" resolution of a number of regions with active star formation (Orion A, W49, W51, SGRB2) show that the distribution of the molecule SO is very compact around stellar outflow sources. Both SO and SO2 were studied near three outflows, OrionA/IRc2 and two sources in W49. The two molecules have similar distributions and abundances. More than 95% of the emission comes from regions whose extents are only .05 to .2 pc., being larger around the more energetic sources. Their spectra are broad, 30 km/sec or more, suggesting that the oxide production is associated with the flows. The outflows are identified by water masers and by extended bipolar flows in SiO. Maps in other molecules, such as HCO+ and CS, which have similar collisional excitation requirements, have much greater spatial extent. Thus it appears that the SO and SO2 abundances are truly compact and are closely associated with the outflows.

Welch, W. J.↗
NASA NTRS1988

The detection of a discrete outflow from the young stellar object GL 490

A high-resolution (0.059/cm) M-band spectrum has been obtained of the embedded young stellar object GL490. The spectrum shows interstellar absorption in the fundamental vibrational band, v = 1-0, of (C-12)O. Two strong and narrow (10 km/s) velocity components are present. One, at the velocity of GL490 (vLSR = -16 km/s), is likely gas in the molecular cloud within which GL490 is embedded. The other component is blueshifted by 13 km/s relative to GL490. An observation of emission from the J = 3-2 transition of HCO(+) using a 20-arcsec beam supports the view that the blueshifted gas is near the central object. The -29-km/s feature is interpreted as a recently ejected shell. It is conjectured that the extended outflows of cold molecular gas seen by millimeter CO emission observations are driven by sporadic outbursts rather than by continuous flows from the central object.

Mitchell, G. F.↗
NASA NTRS1988

Photochemical and thermal evolution of interstellar/precometary ice analogs

The photochemical and thermal evolution of H2O-, CH3OH-, NH3-, and CO-containing ices whose relative proportions in mixture are consistent with those of interstellar ice are presently studied experimentally. The UV photolysis of these ice analogs invariably generates H2CO, CO2, CO, CH4, and HCO, largely through the photofragmentation of CH3OH. CO and CH4 leave the samples as warmup proceeds to 100 K; most of the parent ice molecules are found to have sublimed upon the reaching of 200 K, with only a mixture of more refractory substances remaining. A residue of CH2 groups remains even after warmup to 300 K.

Allamandola, L. J.↗
NASA NTRS1989

Shock chemistry in the molecular clouds associated with SNR IC 443

Observations of several interstellar molecules toward the highly perturbed B and G clouds associated with SNR IC 443 are reported. The results suggest that hot and dense material is present in the SNR, and that shocks are present in both regions. The HCO(+) abundance is shown to be a few times greater that found in cold quiescent gas, in contradiction with previous results. The SO, CS, CN, and NH3 abundances are similar to those found in cold dark clouds.

Ziurys, L. M.↗
NASA NTRS1990

Laboratory simulation of interstellar grain chemistry and the production of complex organic molecules

During the past 15 years considerable progress in observational techniques has been achieved in the middle infrared (5000 to 500 cm(-1), 2 to 20 microns m), the spectral region most diagnostic of molecular vibrations. Spectra of many different astronomical infrared sources, some deeply embedded in dark molecular clouds, are now available. These spectra provide a powerful probe, not only for the identification of interstellar molecules in both the gas solid phases, but also of the physical and chemical conditions which prevail in these two very different domains. By comparing these astronomical spectra with the spectra of laboratory ices one can determine the composition and abundance of the icy materials frozen on the cold (10K) dust grains present in the interior of molecular clouds. These grains and their ice mantles may well be the building blocks from which comets are made. As an illustration of the processes which can take place as an ice is irradiated and subsequently warmed, researchers present the infrared spectra of the mixture H2O:CH3OH:CO:NH3:C6H14 (100:50:10:10:10). Apart from the last species, the ratio of these compounds is representative of the simplest ices found in interstellar clouds. The last component was incorporated into this particular experiment as a tracer of the behavior of a non-aromatic hydrocarbon. The change in the composition that results from ultraviolet photolysis of this ice mixture using a UV lamp to simulate the interstellar radiation field is shown. Photolysis produces CO, CO2, CH4, HCO, H2CO, as well as a family of moderately volatile hydrocarbons. Less volatile carbonaceous materials are also produced. The evolution of the infrared spectrum of the ice as the sample is warmed up to room temperature is illustrated. Researchers believe that the changes are similar to those which occur as ice is ejected from a comet and warmed up by solar radiation. The warm-up sequence shows that the nitrile or iso-nitrile bearing compound produced during photolysis evaporates between 200 and 250K, suggesting that it is carried by a small molecular species. These molecules could be similar to the source material in Comet Halley that is ejected in grains into the coma, freed by sublimation, and photolyzed by solar radiation to produce the observed jets.

Allamandola, L. J.↗