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At least 217 records · Page 12

Two Dimensional Symmetric Correlation Functions of the S Operator and Two Dimensional Fourier Transforms: Considering the Line Coupling for P and R Lines of Linear Molecules

The refinement of the Robert-Bonamy (RB) formalism by considering the line coupling for isotropic Raman Q lines of linear molecules developed in our previous study [Q. Ma, C. Boulet, and R. H. Tipping, J. Chem. Phys. 139, 034305 (2013)] has been extended to infrared P and R lines. In these calculations, the main task is to derive diagonal and off-diagonal matrix elements of the Liouville operator iS1 − S2 introduced in the formalism. When one considers the line coupling for isotropic Raman Q lines where their initial and final rotational quantum numbers are identical, the derivations of off-diagonal elements do not require extra correlation functions of the ^S operator and their Fourier transforms except for those used in deriving diagonal elements. In contrast, the derivations for infrared P and R lines become more difficult because they require a lot of new correlation functions and their Fourier transforms. By introducing two dimensional correlation functions labeled by two tensor ranks and making variable changes to become even functions, the derivations only require the latters' two dimensional Fourier transforms evaluated at two modulation frequencies characterizing the averaged energy gap and the frequency detuning between the two coupled transitions. With the coordinate representation, it is easy to accurately derive these two dimensional correlation functions. Meanwhile, by using the sampling theory one is able to effectively evaluate their two dimensional Fourier transforms. Thus, the obstacles in considering the line coupling for P and R lines have been overcome. Numerical calculations have been carried out for the half-widths of both the isotropic Raman Q lines and the infrared P and R lines of C2H2 broadened by N2. In comparison with values derived from the RB formalism, new calculated values are significantly reduced and become closer to measurements.

infrared radiation↗

Enhanced expression of extracellular calcium sensing receptor in monocyte-differentiated versus undifferentiated HL-60 cells: potential role in regulation of a nonselective cation channel

Human promyelocytic leukemia cells (HL-60) have been used widely as a model for studying the differentiation of hematopoietic progenitor cells in vitro. After treatment with phorbol-12-myristate-13-acetate (PMA) or 1,25-dihydroxyvitamin D(3) [1,25(OH)(2)D(3)], HL-60 cells differentiate into cells with the phenotype of monocytes/macrophages. We previously showed that peripheral blood monocytes and the murine J774 monocytic cell line express the CaR, and myeloid progenitors in the bone marrow and myeloid cells in peripheral blood other than monocytes express lower levels of the CaR. Therefore, we investigated whether undifferentiated HL-60 cells express a functional G protein-coupled, extracellular calcium (Ca(2+)(o))-sensing receptor (CaR) and if the expression of the CaR increases as these cells differentiate along the monocytic lineage. The use of reverse transcription-polymerase chain reaction (RT-PCR) with CaR-specific primers, followed by sequencing of the amplified products, identified an authentic CaR transcript in undifferentiated HL-60 cells. Both immunocytochemistry and Western blot analysis using a CaR-specific antiserum detected low levels of CaR protein expression in undifferentiated HL-60 cells. The levels of CaR protein increased considerably following treatment of the cells with PMA (50 nM) or 1,25(OH)(2)D(3) (100 nM) for 5 days. Northern analysis using a CaR-specific riboprobe identified CaR transcripts in undifferentiated HL-60 cells, but CaR mRNA levels did not change appreciably after treatment with either agent, suggesting that upregulation of CaR protein occurs at a translational level. PMA-treated HL-60 cells expressed a nonselective cation channel (NCC), and the calcimimetic CaR activator, NPS R-467, but not its less active stereoisomer, NPS S-467, as well as the polycationic CaR agonist, neomycin, activated this NCC, demonstrating that the CaR expressed in these cells is functionally active. Therefore, HL-60 cells exhibit an increase in CaR protein expression, occurring at a translational level during their differentiation into cells with a monocyte/macrophage phenotype in response to treatment with PMA or 1, 25(OH)(2)D(3), which is functionally linked to activation of a nonselective cation channel.

NASA Discipline Musculoskeletal↗

Assessment of Satellite Sea Surface Salinity Products Using a Coupled ENSO Prediction Model

Much work has gone into revising and updating algorithms for converting satellite-measured radiances to useful ocean variables like sea surface salinity (e.g. SMOS - Boutin et al., 2017, SMAP - Fore et al., 2016 and Aquarius - Meissner et al., 2018). As part of our Ocean Salinity Science Team work, we utilize an intermediate-complexity air/sea coupled model as a transfer function to test if more mature satellite SSS model algorithms actually improve ENSO forecast skill. For initialization of the coupled forecast, we demonstrate that the positive impact of SSS assimilation is brought about by surface freshening near the eastern edge of the western Pacific warm pool and density changes that lead to shallower mixed layer between 10S-5N. In addition, salting near the ITCZ leads to a deepening of the mixed layer and thermocline near 8N. These patterns together provide the background state to amplify equatorial Kelvin waves and improve ENSO hindcasts (Hackert et al., 2019). Here we extend this work to compare the impact of various pairs of original and improved satellite SSS algorithms. For instance we compare SMAP V4.1 with the latest, SMAP V4.2, to see what impact algorithm improvements may have on ENSO forecasts. SSS observations are tested on seasonal to interannual variability of tropical Indo-Pacific Ocean dynamics as well as on dynamical ENSO forecasts by initializing twelve-month forecasts for each month of available data. All experiments assimilate satellite sea level (SL), sea surface temperature (SST), and in situ subsurface temperature and salinity observations (Tz, Sz). Additionally various satellite, blended, and in-situ SSS products are assimilated. We find that including satellite SSS significantly improves Niño3.4 sea surface temperature anomaly validation, more mature SSS model algorithms are generally improving ENSO forecasts over time, and more satellite SSS data coverage helps to extend useful forecasts.

Ocean↗

Finite-field Calculations of Molecular Polarizabilities Using Field-Induced Polarization Functions: Second- and Third-order Perturbation Correlation Corrections to the Coupled Hartree-Fock Polarizability of H2O

Ordinary Rayleigh-Schroudinger perturbation theory with Moller-Plesset (RSMP) partitioning is used to calculate second- and third-order correlation corrections to the CHF polarizability and dipole moment of the water molecule by a finite-field procedure. Pade approximants are found to be useful in accelerating the convergence of the property perturbation expansions. Field-induced polarization functions suitable for polarizability calculations are determined. The average polarizability calculated, neglecting vibrational averaging, with Dunning's (9s5p/4s-4s2p/2s) contracted GTO basis set augmented by field-induced lslp2d/lp polarization functions is within 3 per cent of the experimental result. Correlation corrections to the dipole moment and polarizability of the water molecule calculated by the finite-field RSMP and single + double excitation CI(SDCI) methods for the same basis set are found to be in close agreement. The RSMP approach has the advantages of being size-consistent and of being capable of greater efficiency than the SCDI method. Comparative calculations carried out using Epstein-Nesbet partitioning show that through third order RSEN correlation perturbation expansions for the dipole moment and polarizability are less rapidly convergent than RSMP expansions. However, reasonable accord with RSMP results can be achieved by using Pade approximants to accelerate the convergence of RSEN energy perturbation expansions. The convergence of RSMP property correlation expansions based on the zeroth-order uncoupled-Hartree-Fock (UCHF) and coupled-Hartree-Fock (CHF) approximations are compared through third order. Whereas the CHF + RSMP expansions are for practical purposes fully converged, the UCHF + RSMP expansions are not adequately converged.

Langhoff, S. R.↗

Fatigue failure in metal bellows due to flow-induced vibrations

To prevent fatigue due to flow-induced vibrations in metal bellows connected to ducts carrying liquid hydrogen, a study was made which shows that the flexure lines are in general a function of the vibration coupling between the fluid and bellows structure, and the nature of the external environment.

Daniels, C. M.↗

Interdiffusion behavior of tungsten or rhenium and group 5 and 6 elements and alloys of the periodic table, part 1

Arc cast W, CVD W, CVD Re, and powder metallurgy Re materials were hot isostatically pressure welded to ten different refractory metals and alloys (Cb, Cb-1Zr, Ta, Ta-10W, T-111, ASTAR-811C, W-25Re, Mo-50Re, W-30Re-20Mo, ect.) and thermally aged at 10 to the minus 8th power torr at 1200, 1500, 1630, 1800, and 2000 C for 100 to 2000 hours. Electron beam microprobe analysis was used to characterize the interdiffusion zone width of each couple system as a function of age time and temperature. Extrapolations of interdiffusion zone thickness to 10,000 hours were made. Classic interdiffusion analysis was performed for several of the systems by Boltzmann-Matano analysis. A method of inhibiting Kirkendall voids from forming during thermal ageing of dissimilar metal junctions was devised and experimentally demonstrated. An electron beam weld study of Cb-1Zr to Re and W-25Re demonstrated the limited acceptability of these welds.

Arcella, F. G.↗

Interdiffusion behavior of tungsten or rhenium and group 5 and 6 elements and alloys of the periodic table. Part 2A: Appendices A-G

Arc cast W, CVD, W, CVD Re, and powder metallurgy Re materials were hot isostatically pressure welded to ten different refractory metals and alloys and thermally aged at 10 to the minus 8th power torr at 1200 C, 1500 C, 1630 C, 1800 C, and 2000 C for 100 hours to 2000 hours. Electron beam microprobe analysis was used to characterize the interdiffusion zone width of each couple system as a function of age time and temperature. Each system was least squares fitted to the equation: In (delta X sq/t) = B/T + A, where delta X is net interdiffusion zone width, t is age time, and T is age temperature. Detailed descriptions of experimental and analytical procedures utilized in conducting the experimental program are provided. For Vol. 1, see N74-34046.

Arcella, F. G.↗

On aerodynamic coupling between lateral and longitudinal degrees of freedom

An oscillatory technique for routine measurement of all the direct, cross and cross-coupling moment derivatives due to pitching and yawing has been developed and a series of comprehensive results at Mach numbers 0.7 and 0.25 and at angles of attack up to 40 deg has been obtained in a large wind tunnel. It was found that some of the dynamic cross-coupling derivatives, that at low angles of attack were all zero, at higher angles of attack could reach values that rendered the pertinent cross-coupling terms in the equations of motion comparable in magnitude to the well-established damping terms. Large nonlinear variations with angle of attack were observed in many of the measured derivatives including the important damping-in-pitch and damping-in-yaw derivatives. It was concluded that it may be desirable to include some dynamic cross-coupling derivatives, and the functional variation with angle of attack of many derivatives, in the equations of motion, and to consider all these equations simultaneously, rather than in separate longitudinal and lateral groups.

Orlik-Rueckemann, K. J.↗

Experimental determination of the admittances of aluminized propellants by the impedance tube method

The adaptation of the impedance tube concept for the determination of the pressure coupled admittances and response functions of burning solid propellants is discussed. The results obtained in experiments with UTP-3001 and UTP-19360 aluminized propellants are presented. It is shown that the admittance Y remains constant during the quasi-steady burn period of a test, indicating constant driving of the gas phase disturbance by the burning solid propellant. The measured real part of the admittance is positive, indicating that the burning aluminized propellant is driving the gas phase oscillations. In addition, the measured high gas phase damping, provided by the aluminum oxide particles in the gas phase, suggests that the latter can significantly increase the damping in unstable solid rockets over the investigated frequency range. Finally, it is shown that the wave structure obtained by numerically solving the impedance tube wave equations which utilize the determined propellant admittance as an initial condition and the determined value of G to describe the gas phase losses is in excellent agreement with the measured wave structure.

Baum, J. D.↗

An integral analysis of transonic normal shock wave/turbulent boundary layer interactions in internal flow

An approximate integral viscous-inviscid interaction method is presented for calculating the development of a turbulent boundary layer subjected to a normal shock wave induced adverse pressure gradient in an internal axisymmetric flow. The inflow conditions and the downstream pressure are provided for the computation. In the supersonic region of shock pressure rise, the Prandtl-Meyer function is used to couple the viscous and inviscid flows. An analytical model for the coupling process is postulated and appropriate equations are defined. Downstream of the sonic point, one-dimensional inviscid flow is assumed for coupling with the viscous flow. The turbulent boundary layer is calculated using Green's integral lag-entrainment method. Comparisons of the solutions with the experimental data are made for interactions which are unseparated, near separation and separated. For comparison purposes, solutions to the time-dependent, mass-averaged, Navier-Stokes equations incorporating a two-equation, Wilcox-Rubesin turbulence model are also shown. The computed results from the integral method show good agreement with experimental data for unseparated interactions and reasonable agreement with the trend of the viscous effects when the interaction becomes increasingly separated.

Om, D.↗

Coupling of the Solar Wind to the Magnetosphere

Solar wind-magnetosphere coupling is considered in the context of four major questions. The first of these questions is concerned with the process of solar wind plasma entry. The processes of energy and momentum transfer from the solar wind to the magnetosphere comprise the focus of the second question. The third question deals with the physics of magnetospheric boundary layers, specifically their role as generators, loads, and plasma transport regions. The final question concerns the global magnetohydrodynamics that characterize the magnetosphere for the various coupling processes and as functions of solar wind parameters.

Source record↗

The flowfield structure of the 3-D shock wave - Boundary layer interaction generated by a 20 deg sharp fin at Mach 3

The three-dimensional oblique shock wave-turbulent boundary layer interaction generated by a sharp fin attached to a flat plate is investigated experimentally and theoretically for Mach 3 and Reynolds number 9 x 10 to the 5th using two different models. Both models employ the three-dimensional compressible Navier-Stokes equations in mass-averaged variables; one model utilizes the algebraic turbulent eddy viscosity model of Baldwin and Lomax (1978), while the other model employs the two-equation turbulence model of Jones and Launder (1972) coupled with the wall function model of Viegas and Rubesin (1985). The computed surface pressure, surface streamlines, pitot pressure, and yaw angle profiles are found to be in good agreement with experimental data. The three-dimensional velocity fields computed by both models are in close agreement, although the eddy viscosity profiles differ significantly within the three-dimensional interaction. This result indicates that the overall structure of this three-dimensional sharp fin interaction is insensitive to the turbulence model.

Knight, D. D.↗

Algal culture studies for CELSS

Microalgae are well-suited as a component of a Closed Environmental Life Support System (CELSS), since they can couple the closely related functions of food production and atmospheric regeneration. The objective was to provide a basis for predicting the response of CELSS algal cultures, and thus the food supply and air regeneration system, to changes in the culture parameters. Scenedesmus growth was measured as a function of light intensity, and the spectral dependence of light absorption by the algae as well as algal respiration in the light were determined as a function of cell concentration. These results were used to test and confirm a mathematical model that describes the productivity of an algal culture in terms of the competing processes of photosynthesis and respiration. The relationship of algal productivity to cell concentration was determined at different carbon dioxide concentrations, temperatures, and light intensities. The maximum productivity achieved by an air-grown culture was found to be within 10% of the computed maximum productivity, indicating that CO2 was very efficiently removed from the gas stream by the algal culture. Measurements of biomass productivity as a function of cell concentration at different light intensities indicated that both the productivity and efficiency of light utilization were greater at higher light intensities.

Radmer, R.↗

Structure of supersonic turbulent flow past a sharp fin

The three-dimensional shock-wave/turbulent-boundary-layer interaction generated by a sharp fin is examined both experimentally and theoretically at Mach 3 for a fin angle 20 deg and Reynolds number 900,000. This study represents an extension of previous research for the sharp fin configuration to stronger interactions. The experimental data include surface pressure profiles, surface streamline patterns, and boundary-layer profiles of pitot pressure and yaw angle. Two separate theoretical approaches or 'models' were employed. Both models utilize the three-dimensional compressible Navier-Stokes equations in mass-averaged variables. The theoretical approach of Knight (1984 and 1985) employs the algebraic turbulent eddy-viscosity model of Baldwin and Lomax (1978), and the theoretical model of Horstman (1984) employs the two-equation turbulence model of Jones and Launder (1972) coupled with the wall function model of Viegas et al. (1985).

Knight, Doyle D.↗

The importance of aerodynamics on dynamics

The effects of aerodynamic phenomena on helicopter structural dynamics are examined, reviewing the results of recent theoretical and experimental investigations. A schematic diagram of a dynamic analysis is presented and discussed, noting the numerous aerodynamic inputs, and numerical data are presented in graphs. Consideration is given to forcing functions, aerodynamic damping, aeroelastic coupling, negative damping, apparent coriolis coupling, periodic coefficients, inverse damping, additional degrees of freedom, flap-lag stability, and dynamic inflow. The need for theoretical models which account for the dynamic loop between blade lift and induced flow (permitting blade motion to dynamically alter the flowfield during transients) is indicated.

Peters, David A.↗