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At least 217 records · Page 12

Climate, air quality, and equity benefits from hydrogen substitution for fossil fuels used in process heat

Fossil fuel combustion for process heat in heavy industry accounts for ~15% of all United States CO 2 emissions and emits PM 2.5 and its precursors, emissions that have a disproportionate impact on minority populations. Decarbonizing process heat in the U.S. via hydrogen substitution presents an opportunity to reduce emissions of CO 2 and PM 2.5 and mitigate resulting exposure disparity. Here, we show that hydrogen substitution in steelmaking provides a large reduction in CO 2 emissions and air quality-related premature mortality, while hydrogen substitution in petroleum refining substantially benefits disadvantaged communities. When reductions in CO 2 emissions and premature mortality are monetized using standard regulatory values, we find that the sum of air pollution and climate benefits outweighs the difference in private cost associated with hydrogen substitution in steelmaking, regardless of the method of hydrogen production. The approach developed here can support evaluations of equity-focused decarbonization strategies in other industries and for specific sites.

08 HYDROGEN↗

A UNIONS view of the brightest central galaxies of candidate fossil groups

The formation process of fossil groups (FGs) is still under debate, and, because of their relative rarity, large samples of such objects are still missing. The aim of the present paper is to increase the sample of known FGs, to analyse the properties of their brightest group galaxies (BGGs), and to compare them with a control sample of non-FG BGGs. We extracted a sample of 87 FG and 100 non-FG candidates from a large spectroscopic catalogue of haloes and galaxies. For all the objects with data available in UNIONS (initially the Canada France Imaging Survey, CFIS) in the u and r bands, and/or in an extra r-band processed to preserve all low-surface-brightness features (rLSB), we performed a 2D photometric fit of the BGG with GALFIT with one or two Sérsic components. We also analysed how the subtraction of the intracluster light (ICL) contribution modifies the BGG properties. From the SDSS spectra available for the BGGs of 65 FGs and 82 non-FGs, we extracted the properties of their stellar populations with Firefly. To complement our study, and in order to provide a detailed illustration of the possible origin of emission lines in the FG BGGs, involving the presence or absence of an AGN, we investigated the origin of the emission lines in a nearby FG that is dominated by the NGC 4104 galaxy. Morphologically, a single Sérsic profile can fit most objects in the u band, while two Sérsics are needed in the r and rLSB bands, both for FGs and non-FGs. Non-FG BGGs cover a larger range of Sérsic index n. FG BGGs follow the Kormendy relation (mean surface brightness versus effective radius) previously derived for almost 1000 brightest cluster galaxies (BCGs), while the majority of non-FGs BGGs are located below this relation, with fainter mean surface brightnesses. This suggests that FG BGGs have evolved similarly to BCGs, and non-FG BGGs have evolved differently from both FG BGGs and BCGs. All the above properties can be strongly modified by the subtraction of the ICL contribution. Based on spectral fitting, the stellar populations of FG and non-FG BGGs do not differ significantly. FG and non-FG BGGs differ from one another in terms of their morphological properties and Kormendy relation, suggesting they have had different formation histories. However, it is not possible to trace differences in their stellar populations or in their large-scale distributions.

79 ASTRONOMY AND ASTROPHYSICS↗

AGN ACTIVITY AND IGM HEATING IN THE FOSSIL CLUSTER RX J1416.4+2315

We study active galactic nucleus (AGN) activity in the fossil galaxy cluster RX J1416.4+2315. Radio observations were carried out using the Giant Metrewave Radio Telescope at two frequencies, 1420 and 610 MHz. A weak radio lobe that extends from the central nucleus is detected in the 610 MHz map. Assuming the radio lobe originated from the central AGN, we show that the energy injection into the intergalactic medium is only sufficient to heat up the central 50 kpc within the cluster core, while the cooling radius is larger (∼130 kpc). In the hardness ratio map, three low energy cavities have been identified. No radio emission is detected for these regions. We evaluated the power required to inflate the cavities and showed that the total energy budget is sufficient to offset the radiative cooling. We showed that the initial conditions would change the results remarkably. Furthermore, the efficiency of the Bondi accretion in powering the AGN has been estimated.

79 ASTRONOMY AND ASTROPHYSICS↗

FAST FOSSIL ROTATION OF NEUTRON STAR CORES

It is argued that the superfluid core of a neutron star super-rotates relative to the crust, because stratification prevents the core from responding to the electromagnetic braking torque, until the relevant dissipative (viscous or Eddington-Sweet) timescale, which can exceed {approx}10{sup 3} yr and is much longer than the Ekman timescale, has elapsed. Hence, in some young pulsars, the rotation of the core today is a fossil record of its rotation at birth, provided that magnetic crust-core coupling is inhibited, e.g., by buoyancy, field-line topology, or the presence of uncondensed neutral components in the superfluid. Persistent core super-rotation alters our picture of neutron stars in several ways, allowing for magnetic field generation by ongoing dynamo action and enhanced gravitational wave emission from hydrodynamic instabilities.

79 ASTRONOMY AND ASTROPHYSICS↗

CHANDRA VIEW OF THE ULTRA-STEEP SPECTRUM RADIO SOURCE IN A2443: MERGER SHOCK-INDUCED COMPRESSION OF FOSSIL RADIO PLASMA?

We present a new Chandra X-ray observation of the intracluster medium in the galaxy cluster A2443, hosting an ultra-steep spectrum radio source. The data reveal that the intracluster medium is highly disturbed. The thermal gas in the core is elongated along a northwest to southeast axis and there is a cool tail to the north. We also detect two X-ray surface brightness edges near the cluster core. The edges appear to be consistent with an inner cold front to the northeast of the core and an outer shock front to the southeast of the core. The southeastern edge is coincident with the location of the radio relic as expected for shock (re)acceleration or adiabatic compression of fossil relativistic electrons.

79 ASTRONOMY AND ASTROPHYSICS↗

THE ENTIRE VIRIAL RADIUS OF THE FOSSIL CLUSTER RX J1159+5531. I. GAS PROPERTIES

Previous analysis of the fossil-group/cluster RX J1159+5531 with X-ray observations from a central Chandra pointing and an offset-north Suzaku pointing indicate a radial intracluster medium (ICM) entropy profile at the virial radius (R{sub vir}) consistent with predictions from gravity-only cosmological simulations, in contrast to other cool-core clusters. To examine the generality of these results, we present three new Suzaku observations that, in conjunction with the north pointing, provide complete azimuthal coverage out to R{sub vir}. With two new Chandra ACIS-I observations overlapping the north Suzaku pointing, we have resolved ≳50% of the cosmic X-ray background there. We present radial profiles of the ICM density, temperature, entropy, and pressure obtained for each of the four directions. We measure only modest azimuthal scatter in the ICM properties at R{sub 200} between the Suzaku pointings: 7.6% in temperature and 8.6% in density, while the systematic errors can be significant. The temperature scatter, in particular, is lower than that studied at R{sub 200} for a small number of other clusters observed with Suzaku. These azimuthal measurements verify that RX J1159+5531 is a regular, highly relaxed system. The well-behaved entropy profiles we have measured for RX J1159+5531 disfavor the weakening of the accretion shock as an explanation of the entropy flattening found in other cool-core clusters but is consistent with other explanations such as gas clumping, electron-ion non-equilibrium, non-thermal pressure support, and cosmic-ray acceleration. Finally, we mention that the large-scale galaxy density distribution of RX J1159+5531 seems to have little impact on its gas properties near R{sub vir}.

79 ASTRONOMY AND ASTROPHYSICS↗

Testing homogeneity with the fossil record of galaxies

The standard Friedmann model of cosmology is based on the Copernican Principle, i.e. the assumption of a homogeneous background on which structure forms via perturbations. Homogeneity underpins both general relativistic and modified gravity models and is central to the way in which we interpret observations of the CMB and the galaxy distribution. It is therefore important to probe homogeneity via observations. We describe a test based on the fossil record of distant galaxies: if we can reconstruct key intrinsic properties of galaxies as functions of proper time along their worldlines, we can compare such properties at the same proper time for our galaxy and others. We achieve this by computing the lookback time using radial Baryon Acoustic Oscillations, and the time along galaxy world line using stellar physics, allowing us to probe homogeneity, in principle anywhere inside the past light cone. Agreement in the results would be an important consistency test — although it would not in itself prove homogeneity. Any significant deviation in the results however would signal a breakdown of homogeneity.

79 ASTRONOMY AND ASTROPHYSICS↗

Inflationary tensor fossils in large-scale structure

Inflation models make specific predictions for a tensor-scalar-scalar three-point correlation, or bispectrum, between one gravitational-wave (tensor) mode and two density-perturbation (scalar) modes. This tensor-scalar-scalar correlation leads to a local power quadrupole, an apparent departure from statistical isotropy in our Universe, as well as characteristic four-point correlations in the current mass distribution in the Universe. So far, the predictions for these observables have been worked out only for single-clock models in which certain consistency conditions between the tensor-scalar-scalar correlation and tensor and scalar power spectra are satisfied. Here we review the requirements on inflation models for these consistency conditions to be satisfied. We then consider several examples of inflation models, such as non-attractor and solid-inflation models, in which these conditions are put to the test. In solid inflation the simplest consistency conditions are already violated whilst in the non-attractor model we find that, contrary to the standard scenario, the tensor-scalar-scalar correlator probes directly relevant model-dependent information. We work out the predictions for observables in these models. For non-attractor inflation we find an apparent local quadrupolar departure from statistical isotropy in large-scale structure but that this power quadrupole decreases very rapidly at smaller scales. The consistency of the CMB quadrupole with statistical isotropy then constrains the distance scale that corresponds to the transition from the non-attractor to attractor phase of inflation to be larger than the currently observable horizon. Solid inflation predicts clustering fossils signatures in the current galaxy distribution that may be large enough to be detectable with forthcoming, and possibly even current, galaxy surveys.

79 ASTRONOMY AND ASTROPHYSICS↗

THE HERSCHEL AND IRAM CHESS SPECTRAL SURVEYS OF THE PROTOSTELLAR SHOCK L1157-B1: FOSSIL DEUTERATION

We present the first study of deuteration toward the protostellar shock L1157-B1, based on spectral surveys performed with the Herschel-HIFI and IRAM 30 m telescopes. The L1157 outflow is driven by a low-mass Class 0 protostar and is considered the prototype of the so-called chemically active outflows. The young (2000 yr), bright blueshifted bow shock, B1, is an ideal laboratory for studying the gas chemically enriched by the release of dust mantles due to the passage of a shock. A total of 12 emission lines (up to E{sub u} = 63 K) of CH{sub 2}DOH, HDCO, and DCN are detected. In addition, two lines of NH{sub 2}D and HDO are tentatively reported. To estimate the deuteration, we also extracted from our spectral survey emission lines of non-deuterated isotopologues ({sup 13}CH{sub 3}OH, H{sub 2} {sup 13}CO, H{sup 13}CN, H{sub 2} {sup 13}CO, and NH{sub 3}). We infer higher deuteration fractions for CH{sub 3}OH (D/H = 0.2-2 Multiplication-Sign 10{sup -2}) and H{sub 2}CO (5-8 Multiplication-Sign 10{sup -3}) than for H{sub 2}O (0.4-2 Multiplication-Sign 10{sup -3}), HCN ({approx}10{sup -3}), and ammonia ({<=}3 Multiplication-Sign 10{sup -2}). The measurement of deuteration of water, formaldehyde, and methanol in L1157-B1 provides a fossil record of the gas before it was shocked by the jet driven by the protostar. A comparison with gas-grain models indicates that the gas passed through a low-density ({<=}10{sup 3} cm{sup -3}) phase, during which the bulk of water ices formed, followed by a phase of increasing density, up to 3 Multiplication-Sign 10{sup 4} cm{sup -3}, during which formaldehyde and methanol ices formed.

79 ASTRONOMY AND ASTROPHYSICS↗

DISCOVERY OF AN ULTRA-FAINT DWARF GALAXY IN THE INTRACLUSTER FIELD OF THE VIRGO CENTER: A FOSSIL OF THE FIRST GALAXIES?

Ultra-faint dwarf galaxies (UFDs) are newcomers among galaxies, and are the faintest galaxies in the observed universe. To date, they have only been found around the Milky Way Galaxy and M31 in the Local Group. We present the discovery of a UFD in the intracluster field in the core of the Virgo cluster (Virgo UFD1), which is far from any massive galaxies. The color-magnitude diagram of the resolved stars in this galaxy shows a narrow red giant branch, similar to those of metal-poor globular clusters in the Milky Way. We estimate its distance by comparing the red giant branch with isochrones, and we obtain a value 16.4 ± 0.4 Mpc. This shows that it is indeed a member of the Virgo cluster. From the color of the red giants we estimate its mean metallicity to be very low, [Fe/H] =–2.4 ± 0.4. Its absolute V-band magnitude and effective radius are derived to be M{sub V} = –6.5 ± 0.2 and r {sub eff} = 81 ± 7 pc, much fainter and smaller than the classical dwarf spheroidal galaxies. Its central surface brightness is estimated to be as low as μ {sub V,} {sub 0} = 26.37 ± 0.05 mag arcsec{sup –2}. Its properties are similar to those of the Local Group analogs. No evidence of tidal features are found in this galaxy. Considering its narrow red giant branch with no asymptotic giant branch stars, low metallicity, and location, it may be a fossil remnant of the first galaxies.

79 ASTRONOMY AND ASTROPHYSICS↗

SDSS-IV MaNGA : Excavating the fossil record of stellar populations in spiral galaxies

ABSTRACT We perform a ‘fossil record’ analysis for ≈800 low-redshift spiral galaxies, using starlight applied to integral field spectroscopic observations from the SDSS-IV MaNGA survey to obtain fully spatially resolved high-resolution star formation histories (SFHs). From the SFHs, we are able to build maps indicating the present-day distribution of stellar populations of different ages in each galaxy. We find small negative mean age gradients in most spiral galaxies, especially at high stellar mass, which reflects the formation times of stellar populations at different galactocentric radii. We show that the youngest (<108.5 yr) populations exhibit significantly more extended distributions than the oldest (>109.5 yr), again with a strong dependence on stellar mass. By interpreting the radial profiles of ‘time slices’ as indicative of the size of the galaxy at the time those populations had formed, we are able to trace the simultaneous growth in mass and size of the spiral galaxies over the last 10 Gyr. Despite finding that the evolution of the measured light-weighted radius is consistent with inside-out growth in the majority of spiral galaxies, the evolution of an equivalent mass-weighted radius has changed little over the same time period. Since radial migration effects are likely to be small, we conclude that the growth of discs in spiral galaxies has occurred predominantly through an inside-out mode (with the effect greatest in high-mass galaxies), but this has not had anywhere near as much impact on the distribution of mass within spiral galaxies.

Peterken, Thomas↗

Characterization of Fossil and Renewable Fuels

The special issue aims to provide contributions from a variety of topics relating to the characterization of properties, structures or molecular compositions of fossil fuels, and biomass, as well as the corresponding derivatives or products through thermal, chemical, and biochemical methods

02 PETROLEUM↗

Small Scale SOFC Demonstration Using Bio-Based and Fossil Fuels

Technology Management, Inc. (TMI) of Cleveland, Ohio, has completed the project entitled Small Scale SOFC Demonstration using Bio-based and Fossil Fuels. Under this program, two 1-kW systems were engineered as technology demonstrators of an advanced technology that can operate on either traditional hydrocarbon fuels or renewable biofuels. The systems were demonstrated at Patterson's Fruit Farm of Chesterland, OH and were open to the public during the first quarter of 2012. As a result of the demonstration, TMI received quantitative feedback on operation of the systems as well as qualitative assessments from customers. Based on the test results, TMI believes that > 30% net electrical efficiency at 1 kW on both traditional and renewable fuels with a reasonable entry price is obtainable. The demonstration and analysis provide the confidence that a 1 kW entry-level system offers a viable value proposition, but additional modifications are warranted to reduce sound and increase reliability before full commercial acceptance.

30 DIRECT ENERGY CONVERSION↗

Development of Metal Oxide Nanostructure-based Optical Sensors for Fossil Fuel Derived Gases Measurement at High Temperature

This final technical report details research works performed supported by a Department of Energy grant (DE-FE0003859), which was awarded under the University Coal Research Program administrated by National Energy Technology Laboratory. This research program studied high temperature fiber sensor for harsh environment applications. It developed two fiber optical sensor platform technology including regenerative fiber Bragg grating sensors and distributed fiber optical sensing based on Rayleigh backscattering optical frequency domain reflectometry. Through the studies of chemical and thermal regenerative techniques for fiber Bragg grating (FBG) fabrication, high-temperature stable FBG sensors were successfully developed and fabricated in air-hole microstructured fibers, high-attenuation fibers, rare-earth doped fibers, and standard telecommunication fibers. By optimizing the laser processing and thermal annealing procedures, fiber grating sensors with stable performance up to 1100°C have been developed. Using these temperature-stable FBG gratings as sensor platform, fiber optical flow, temperature, pressure, and chemical sensors have been developed to operate at high temperatures up to 800°C. Through the integration of on-fiber functional coating, the use of application-specific air-hole microstructural fiber, and application of active fiber sensing scheme, distributed fiber sensor for temperature, pressure, flow, liquid level, and chemical sensing have been demonstrated with high spatial resolution (1-cm or better) with wide temperature ranges. These include the demonstration of 1) liquid level sensing from 77K to the room temperature, pressure/temperature sensing from the room temperature to 800C and from the 15psi to 2000 psi, and hydrogen concentration measurement from 0.2% to 10% with temperature ranges from the room temperature to 700°C. Optical sensors developed by this program has broken several technical records including flow sensors with the highest operation temperature up to 750°C, first distributed chemical measurements at the record high temperature up to 700°C, first distributed pressure measurement at the record high temperature up to 800°C, and the fiber laser sensors with the record high operation temperature up to 700°C. The research performed by this program dramatically expand the functionality, adaptability, and applicability of distributed fiber optical sensors with potential applications in a number of high-temperature energy systems such as fossil-fuel power generation, high-temperature fuel cell applications, and potential for nuclear energy systems.

77 NANOSCIENCE AND NANOTECHNOLOGY↗

Large scale simulations of the mechanical properties of layered transition metal ternary compounds for fossil energy power system applications

Advanced materials with applications in extreme conditions such as high temperature, high pressure, and corrosive environments play a critical role in the development of new technologies to significantly improve the performance of different types of power plants. Materials that are currently employed in fossil energy conversion systems are typically the Ni-based alloys and stainless steels that have already reached their ultimate performance limits. Incremental improvements are unlikely to meet the more stringent requirements aimed at increased efficiency and reduce risks while addressing environmental concerns and keeping costs low. Computational studies can lead the way in the search for novel materials or for significant improvements in existing materials that can meet such requirements. Detailed computational studies with sufficient predictive power can provide an atomistic level understanding of the key characteristics that lead to desirable properties. This project focuses on the comprehensive study of a new class of materials called MAX phases, or M n+1 AX n (M = a transition metal, A = Al or other group III, IV, and V elements, X = C or N). The MAX phases are layered transition metal carbides or nitrides with a rare combination of metallic and ceramic properties. Due to their unique structural arrangements and special types of bonding, these thermodynamically stable alloys possess some of the most outstanding properties. We used a genomic approach in screening a large number of potential MAX phases and established a database for 665 viable MAX compounds on the structure, mechanical and electronic properties and investigated the correlations between them. This database if then used as a tool for materials informatics for further exploration of this class of intermetallic compounds.

36 MATERIALS SCIENCE↗

Novel Modified Optical Fibers for High Temperature In-Situ Miniaturized Gas Sensors in Advanced Fossil Energy Systems

This report covers the technical progress on the program “Novel Modified Optical Fibers for High Temperature In-Situ Miniaturized Gas Sensors in Advanced Fossil Energy Systems”, funded by the National Energy Technology Laboratory of the U.S. Department of Energy, and performed by the Materials Science & Engineering and Electrical & Computer Engineering Departments at Virginia Tech, and summarizes technical progress from July 1st, 2005 –June 30th, 2014. The objective of this program was to develop novel fiber materials for high temperature gas sensors based on evanescent wave absorption in optical fibers. This project focused on two primary areas: the study of a sapphire photonic crystal fiber (SPCF) for operation at high temperature and long wavelengths, and a porous glass based fiber optic sensor for gas detection. The sapphire component of the project focused on the development of a sapphire photonic crystal fiber, modeling of the new structures, fabrication of the optimal structure, development of a long wavelength interrogation system, testing of the optical properties, and gas and temperature testing of the final sensor. The fabrication of the 6 rod SPCF gap bundle (diameter of 70μm) with a hollow core was successfully constructed with lead-in and lead-out 50μm diameter fiber along with transmission and gas detection testing. Testing of the sapphire photonic crystal fiber sensor capabilities with the developed long wavelength optical system showed the ability to detect CO 2 at or below 1000ppm at temperatures up to 1000°C. Work on the porous glass sensor focused on the development of a porous clad solid core optical fiber, a hollow core waveguide, gas detection capabilities at room and high temperature, simultaneous gas species detection, suitable joining technologies for the lead-in and lead-out fibers and the porous sensor, sensor system sensitivity improvement, signal processing improvement, relationship between pore structure and fiber geometry to optical properties, and the development of a sensor packaging prototype for laboratory testing. Analysis and experiments determined that a bonding technique using a CO 2 laser is the most suitable joining technique. Pore morphology alteration showed that transmission improved with increasing annealing temperature (producing smaller pores), while the sensor response time increased and the mechanical strength decreased with increasing annealing temperature. Software was developed for data acquisition and signal processing to collect and interpret spectral gas absorption data. Gas detection on porous glass sensors was completed and the detection limit was evaluated using acetylene and was found to be around 1- 200ppm. A complete materials package for porous glass sensors was manufactured for testing.

36 MATERIALS SCIENCE↗

US-UK Collaboration on Fossil Energy Advanced Materials: Task 1—Steam Oxidation

This presentation goes over the following from the US-UK collaboration on Fossil Energy Advanced Materials: Task 1, Steam Oxidation: US-led or co-led deliverables, Phase II products (US), 2011-present, Phase III products, Phase III Plan, an explanation of sCO 2 compared with sH 2 O, an explanation of Ni-base Alloys, an explanation of 300 Series (18Cr-8Ni)/E-Brite, an explanation of the typical Microchannel HX Fabrication process, and an explanation of diffusion bonded Ni-base superalloys.

02 PETROLEUM↗