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At least 217 records · Page 12

Simulation of the Genesis of Hurricane Javier (2004) in the Eastern Pacific

NASA is preparing for the Tropical Cloud Systems and Processes (TCSP) field experiment in July 2005, a joint effort with NOAA to study tropical cloud systems and tropical cyclone genesis in the Eastern Pacific. A major thrust of the TCSP program is the improvement of the understanding and prediction of tropical cyclone genesis, intensity, motion, rainfall potential, and landfall impacts using remote sensing and in-situ data, as well as numerical modeling, particularly as they relate to the three phases of water. The Eastern Pacific has the highest frequency of genesis events per unit area of any region worldwide. African easterly waves, mesoscale convective systems (MCSs), and orographic effects are thought to play roles in the genesis of tropical cyclones there. The general consensus is that tropical depressions form in association with one or more mid-level, mesoscale cyclonic vortices that are generated within the stratiform region of the MCS precursors. To create the warm core tropical depression vortex, however, the midlevel cyclonic circulation must somehow extend down to the surface and the tangential winds must attain sufficient strength (-10 m s- ) to enable the wind-induced surface heat exchange to increase the potential energy of the boundary layer air.

Braun, Scott↗

Observations in the vicinity of substorm onset: Implications for the substrom process

Multi-instrument data sets from the ground and satellites at both low and high altitude have provided new results concerning substorm onset and its source region in the magnetosphere. Twenty-six out of 37 substorm onset events showed evidence of azimuthally spaced auroral forms (AAFs) prior to the explosive poleward motion associated with optical substorm onset. AAFs can span 8 hours of local time prior to onset and generally propagate eastward in the morning sector. Onset itself is, however, more localized spanning only about 1 hour local time. AAF onset occur during time periods when the solar wind pressure is relatively high. AAFs brighten in conjunction with substorm onset leading to the conclusion that they are a growth phase activity casually related to substorm onset. Precursor activity associated with these AAFs is also seen near geosynchronous orbit altitude and examples show the relationship between the various instrumental definitions of substorm onset. The implied mode number (30 to 135) derived from this work is inconsistent with cavity mode resonances but is consistent with a modified flute/ballooning instability which requires azimuthal pressure gradients. The extended source region and the distance to the open-closed field line region constrain reconnection theory and local mechanisms for substorm onset. It is demonstrated that multiple onset substorms can exist for which localized dipolarizations and the Pi 2 occur simultaneously with tail stretching existing elsewhere. These pseudobreakups can be initiated by auroral streamers which originate at the most poleward set of arc systems and drift to the more equatorward main UV oval. Observations are presented of these AAFs in conjunction with low- and high-altitutde particle and magnetic field data. These place the activations at the interface between dipolar and taillike field lines probably near the peak in the cross-tail current. These onsets are put in the context of a new scenario for substorm morphology which employs individual modules which operate independently or couple together. This allows particular substorm events to be more accurately described and investigated.

Elphinstone, R. D.↗

Feldspathic Clasts in Yamato 86032: Remnants of the Lunar Crust with Implications for its Formation and Impact History

Yamato (Y)-86032 is a relatively large, feldspathic lunar highlands meteorite composed of a variety of highland lithologies. Low bulk contents of Th and Fe indicated that it came from a region of the moon far distant from the Procellarum KREEP Terrain (PKT) and the Apollo landing sites, perhaps from the farside. A large (5.2 x 3.6 cm) slab was cut from Y-86032 . We report results from coordinated textural, mineralogical-petrological, chemical, and isotopic studies of lithologies identified in the slab, emphasizing the results of Ar-39/Ar-40, Rb-Sr, and Sm-Nd chronological studies as well as Sm-isotopic studies. These studies characterize the history of Y-86032 and its precursors in the farside mega-regolith, leading to inferences about the formation and evolution of the lunar crust. Textural studies establish that the Y-86032 breccia is composed of a variety of highland components including feldspathic breccias, and other components, such as possible VLT mare basalts. Impact melt veins smoothly abut the other lithologies. Thus, Y-86032 experienced at least two impact events. These impacts occurred on a predominantly feldspathic protolith, which formed 4.43+/-0.03 Ga ago as determined from a Sm-Nd isochron for mineral clasts separated from the two dominant lithologies. Initial Nd-143/Nd-144 in the protolith at that time was -0.64+/-0.13 epsilon-units below Nd-143/Nd-144 in reservoirs having chondritic Sm/Nd ratios, consistent with prior fractionation of mafic cumulates from the LMO. Although the mineral chemistry of these clasts differs in detail from that of minerals in Apollo 16 Ferroan Anorthosites (FANs), the Rb-Sr studies establish that the initial Sr-87/Sr-86 in them was the same as in the FANs.

Nyquist, L.↗

Catalytic consequences of hydrogen addition events and solvent-adsorbate interactions during guaiacol-H 2 reactions at the H 2 O-Ru(0 0 0 1) interface

Catalytic reactions of biomass-derived phenolics and H 2 occur on transition metal surfaces via competitive C–O cleavage and ring saturation pathways, with both requiring multiple hydrogen addition events before forming their respective rate limiting transition states. These events are markedly affected by solvent chemical identity, with polar protic solvents ionizing hydrogen adatoms (H*) to interfacial protons (H + ) and opening up new catalytic routes. Here, we establish the reaction coordinate space for guaiacol-H 2 reactions on Ru(0 0 0 1) using density functional theory and describe the atomic-scale effect of a polar protic solvent, H 2 O. Coupled H + and H* attack leads to quasi-equilibrated enol and keto intermediates as the precursors for C–O cleavage and ring saturation, respectively. For C–O cleavage, H 2 O solvent enables a lower energy pathway via concomitant transfer of the hydroxyl H + to the methoxy oxygen during C–OCH 3 cleavage, forming a charge separated [Ru(s)–(C 6 H 5 O – )…(H + )…OCH 3 ] transition state and reducing the barrier by up to 0.8 eV as compared to unassisted C–OCH 3 cleavage. For ring saturation, H* attack onto an unsaturated meta carbon is rate limiting with no direct solvent participation, suggesting that protic polar solvents selectively promote the C–O cleavage pathway. Taken together, we show that activating guaiacol for either C–O bond cleavage or ring saturation product formation depends on the reactive hydrogen identity (H* or H + ), enol/keto isomerization equilibrium, and accessibility of the proton assisted Car–OCH 3 cleavage transition state. Here, all such factors are tunable via changes to the solvent or metal identity.

09 BIOMASS FUELS↗

Granulatic breccia clasts and feldspathic melt breccia clasts from North Ray crater breccia 67975 - Precursors and petrogenesis

A petrologic study of crystalline lithic clasts from feldspathic breccia 67975, collected on the rim of North Ray crater at the Apollo 16 site, is presented. A light gray group has been identified as granulitic breccias, and a dark gray group has been identified as feldspathic microporphyritic melt breccias. It is suggested that complete homogenization of the minerology of the granulitic breccias may have been prevented by their incorporation into the 67975 fragmental breccia, and that metamorphism of the clasts may have been interrupted by this breccia forming event.

Mcgee, J. J.↗

Highly Siderophile Elements and Osmium Isotope Systematics in Ureilites: Are the Carbonaceous Veins Primary Components?

Ureilites are an enigmatic group of primitive carbon-bearing achondrites of ultramafic composition. The majority of the ~143 ureilite meteorites consist primarily of olivine and pyroxene (and occasionally chromite) [1]. They are coarse-grained, slowly cooled, and depleted in incompatible lithophile elements. Minor amounts of dark interstitial material consisting of carbon, metal, sulfides, and fine-grained silicates occur primarily along silicate grain boundaries, but also intrude the silicates along fractures and cleavage planes. Variable degrees of impact shock features have also been imparted on ureilites. The prevailing two origins proposed for these rocks are either as melting residues of carbonaceous chondritic material [2], [3], or alternatively, derivation as mineral cumulates from such melts [4], [5], [6]. It has recently been proposed that ureilites are the residues of a smelting event, i.e. residues of a partial melting event under highly reducing conditions, where a solid Fe-bearing phase reacts with a melt and carbon to form Fe metal and carbon monoxide [7]. Rapid, localized extraction and loss of the basaltic component into space resulting from high eruption velocities could preserve unequilibrated oxygen isotopes and produce the observed olivine-pyroxene residues via 25-30% partial melting of chondritic-like precursor material.

Rankenburg, K.↗

A Review of Recent and Emerging Machine Learning Applications for Climate Variability and Weather Phenomena

Abstract Climate variability and weather phenomena can cause extremes and pose significant risk to society and ecosystems, making continued advances in our physical understanding of such events of utmost importance for regional and global security. Advances in machine learning (ML) have been leveraged for applications in climate variability and weather, empowering scientists to approach questions using big data in new ways. Growing interest across the scientific community in these areas has motivated coordination between the physical and computer science disciplines to further advance the state of the science and tackle pressing challenges. During a recently held workshop that had participants across academia, private industry, and research laboratories, it became clear that a comprehensive review of recent and emerging ML applications for climate variability and weather phenomena that can cause extremes was needed. This article aims to fulfill this need by discussing recent advances, challenges, and research priorities in the following topics: sources of predictability for modes of climate variability, feature detection, extreme weather and climate prediction and precursors, observation–model integration, downscaling, and bias correction. This article provides a review for domain scientists seeking to incorporate ML into their research. It also provides a review for those with some ML experience seeking to broaden their knowledge of ML applications for climate variability and weather.

54 ENVIRONMENTAL SCIENCES↗

Direct Measurement of Small Particle Growth and Aging at the Atmospheric Radiation Measurement Southern Great Plains Observatory Field Campaign Report

Two identical Captive Aerosol Growth and Evolution (CAGE) chambers were operated at the U.S. Department of Energy Atmospheric Radiation Measurement (ARM) user facility’s Southern Great Plains (SGP) observatory in the late summer and fall of 2021. The field study was scheduled to begin in spring, 2020, but was delayed because of the pandemic. CAGE chambers are designed to expose particles to an environment that mirrors that of the surroundings with or without a controlled perturbation designed to assess a sensitivity. The analysis here focuses on roughly the last two months of the overall study period during which measurements were almost continuous and when several perturbation experiments were conducted. Though the utility of a dual-chamber system is the ability to measure the influence of a single change on top of ambient conditions, both chambers were initially operated in the same way, with ambient air pulled through the gas exchange channel in both and ammonium sulfate particles injected into both. The similar time-dependent particle growth observed in the chambers for those periods provides confidence in differences observed during the subsequent perturbation experiments. The growth rate of particles in the reference chamber into which only ammonium sulfate particles were injected and for which only ambient air was pulled through were used to describe time-of-day averages. The average growth rate was highest in the evening and in the morning after sunrise and lowest in the late afternoon. The sensitivity of particle growth to secondary aerosol precursor gases was studied by adding them at a controlled rate to the ambient air flow pulled through one of the two chambers. Addition of 5 ppb of α-pinene resulted in an average particle growth rate of 4.4 nm hr -1 , compared with that of just 0.8 nm hr -1 in the reference chamber. The added α-pinene also triggered one new particle formation (NPF) event in the early evening just before sunset and another in the morning just after sunrise. Similarly, addition of 5 ppb of SO 2 to one chamber led to a pair of NPF events and to increased particle growth rate, though unlike the impact of added α-pinene, growth was enhanced only during the daytime when OH concentration is highest. The influence of aerosol liquid water on secondary aerosol formation and particle growth was investigated by injecting ammonium sulfate seed particles into one chamber and potassium sulfate particles into the other. Particles were injected into the two chambers four times over a 1.5-day period. The chamber relative humidity (RH) history during and following each injection was used to determine whether each particle type was crystalline or aqueous. For the case when both particle types remained crystalline throughout the period, they were tracked and for the case when they remained aqueous, the magnitude and time-dependence of the growth of both were almost exactly the same. For the other two cases the ammonium sulfate particles deliquesced upon injection and remained aqueous, while the potassium sulfate particles remained crystalline. For those two cases, the aqueous particles grew substantially faster than did the crystalline particles, providing evidence of the role of aerosol liquid water on secondary aerosol formation and particle growth.

54 ENVIRONMENTAL SCIENCES↗

IDENTIFICATION OF POTENTIAL SUPERCONDUCTOR QUENCH PRECURSORS USING FREQUENCY DOMAIN FEATURE ANALYSIS

Superconducting magnets are important pieces of technology in the world of particle accelerators, allowing researchers to study atomic and subatomic phenomena, among other things. In some instances, superconductors can lose this non-resistive property in a phenomenon known as quenching, which can cause damage to the magnets. This potential danger prompts the introduction of systems to predict when a quench is imminent; one such implementation is through the use of acoustic sensors that detect vibrations within the magnet. Within these acoustic sensor signals, significantly above-noise disturbances (referred to as ”events”) can be identified. Our research applies the statistical framework of a permutation test to features calculated from the power spectral density (PSD) to distinguish between events far from the quench at the end of the signal to events at the start of the signal. We found that dividing the PSD into frequency bands produced a feature capable of distinguishing between events early in the signal and late in the signal leading up the quench, providing a promising starting place for future quench prediction systems.

Roehrig, Benjamin [Northern Illinois U.]↗

Pregraphitic and poorly graphitised carbons in porous chondritic micrometeorites

Two forms of crystalline carbon in porous chondritic micrometeorites W7029E5, U2011C2, and U2022C7/C8 are mixed layered pregraphitic carbons with C/(C+H+O+N) (at. pct) about 0.45. This bulk composition is inferred from the presence of three groupings of d(002) basal spacings at 0.45 nm, 0.37 nm, and 0.348 nm. Mixed layered carbons represent incomplete carbonization and graphitization of precursor material. In U2022C7/C8, carbonization mostly involved volatile loss. The formation of pregraphitic carbons indicates a sustained thermal regime in parent bodies of these micrometeorities (i.e., short-period comets, outer-belt asteroids, or protocomet nuclei). Temperatures of the sustained thermal regime remain unspecified, but carbon reactions were probably facilitated by catalytic support from layer silicates in these samples. Poorly graphitized carbon in U2022C7/C8 formed during a transient thermal event which is most likely flash-heating during micrometeoroid deceleration in the earth's atmosphere.

Rietmeijer, Frans J. M.↗

Improved Satellite Techniques for Monitoring and Forecasting the Transition of Hurricanes to Extratropical Storms

The Geostationary Operational Environmental Satellites R-Series (GOES-R) and Joint Polar Satellite System (JPSS) Satellite Proving Grounds have introduced multiple proxy and operational products into operations over the last few years. Some of these products have proven to be useful in current operations at various National Weather Service (NWS) offices and national centers as a first look at future satellite capabilities. Forecasters at the National Hurricane Center (NHC), Ocean Prediction Center (OPC), NESDIS Satellite Analysis Branch (SAB) and the NASA Hurricane and Severe Storms Sentinel (HS3) field campaign have had access to a few of these products to assist in monitoring extratropical transitions of hurricanes. The red, green, blue (RGB) Air Mass product provides forecasters with an enhanced view of various air masses in one complete image to help differentiate between possible stratospheric/tropospheric interactions, moist tropical air masses, and cool, continental/maritime air masses. As a compliment to this product, a new Atmospheric Infrared Sounder (AIRS) and Cross-track Infrared Sounder (CrIS) Ozone product was introduced in the past year to assist in diagnosing the dry air intrusions seen in the RGB Air Mass product. Finally, a lightning density product was introduced to forecasters as a precursor to the new Geostationary Lightning Mapper (GLM) that will be housed on GOES-R, to monitor the most active regions of convection, which might indicate a disruption in the tropical environment and even signal the onset of extratropical transition. This presentation will focus on a few case studies that exhibit extratropical transition and point out the usefulness of these new satellite techniques in aiding forecasters forecast these challenging events.

Folmer, Michael↗

I-mode pedestal relaxation events in the Alcator C-Mod and ASDEX Upgrade tokamaks

Abstract In some conditions, I-mode plasmas can feature pedestal relaxation events (PREs) that transiently enhance the energy reaching the divertor target plates. To shed light on their appearance, characteristics and energy reaching the divertor targets, a comparative study between two tokamaks — Alcator C-Mod and ASDEX Upgrade — is carried out. It is found that PREs appear only in a subset of I-mode discharges, mainly when the plasma is close to the H-mode transition. Also, a growing oscillating precursor before the PRE onset is observed in the region close to the separatrix in both devices, and a discussion on a possible triggering mechanism is outlined. The PRE relative energy loss from the confined region is found to increase with decreasing pedestal top collisionality ν ped * . Similarly, also the relative electron temperature drop at the pedestal top, which is related to the conductive energy loss, rises with decreasing ν ped * . Based on these relations, the PRE relative energy loss in future devices such as DEMO and ARC is estimated. Finally, the divertor peak energy fluence due to the PRE is measured on each device. Those values are then compared to the model introduced in Eich et al (2017 Nucl. Mater. Energy 12 84–90) for type-I edge localized modes. The model is shown to provide an upper boundary for PRE energy fluence data, while a lower boundary is found by dividing the model by three. These two boundaries are used to make projections of the PRE divertor energy fluence to DEMO and ARC.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Volcano monitoring using short wavelength infrared data from satellites

It is shown that Landsat TM and MSS data provide useful and sometimes unique information on magmatic and fumarolic events at poorly monitored active volcanoes. The digital number data recorded in each spectral band by TM and MSS can be converted into spectral radiance, measured in W/sq m per micron per sr, using calibration data such as those provided by Markham and Barker (1986) and can provide temperature information on the lava fountain, lava lakes, pahoehoe flows, blocky lava, pyroclastic flow, and fumarole. The examples of Landsat data documenting otherwise unobserved precursors and/or activity include the September 1986 eruption of Lascar volcano, Chile; the continued presence of lava lakes at Erta 'Ale, Ethiopia (in the absence of any ground-based observations); and minor eruptions at Mount Erebus, Antarctica.

Rothery, D. A.↗

Impact glasses from the ultrafine fraction of lunar soils

The chemical compositions of microscopic glasses produced during meteoroid impacts on the lunar surface provide information regarding the various fractionation processes which accompany these events. To learn more about these fractionation processes, we studied the compositions of submicrometer glass spheres from two Apollo 17 sampling sites using electron microscopy. The majority of the analyzed glasses show evidence for varying degrees of impact induced chemical fractionation. Among these are HASP glasses (High-Al, Si-Poor) which are believed to represent the refractory residuum left after the loss of volatile elements (e.g. Si, Fe, N) from the precursor material. In addition to HASP-type glasses, we also observed a group of VRAP glasses (volatile-rich, Al-poor) that represent condensates of vaporized volatile constituents and are complementary to the HASP compositions. High-Ti glasses were also found during the course of the study, and are documented here for the first time.

Norris, J. A.↗

Impact glasses from the less than 20-micrometer fraction of Apollo 17 soils 72501 and 78221

The chemical compositions of microscopic glasses produced during meteoroid impacts on the lunar surface provide information regarding the various fractionation processes that accompany these events. To learn more about these fractionation processes, we studied the compositions of submicrometer glass spheres from two Apollo 17 sampling sites using electron microscopy. The majority of the analyzed glasses show evidence for varying degrees of impact-induced chemical fractionation. Among these are HASP glasses (high-Al, Si-poor), which are believed to represent the refractory residuum left after the loss of volatile elements (e.g., Si, Fe, Na) from the precursor material. In addition to HASP-type glasses, we also observed a group of volatile-rich, Al-poor (VRAP) glasses that represent condensates of vaporized volatile constituents, and are complementary to the HASP compositions. High-Ti glasses were also found during the course of this study, and are documented here for the first time.

Norris, John A.↗

Mission Design Analysis for the Martian Moon Phobos: Close Flybys, Missed Thrusts, and Other In-Flight Entertainment

A robotic mission to the Martian moons Phobos and Deimos would offer a wealth of scientific information and serve as a useful precursor to potential human missions. In this paper, we investigate a prospective mission enabled by solar electric propulsion that would explore Phobos via a series of flybys followed by capture into orbit around the moon. Of particular interest are low-cost options for capture and walkdown to the target science orbits aided by multi-body effects due to the mutual gravitational interaction of Phobos and Mars. We also consider contingency operations in the event of missed thrust or maneuver execution errors.

SEP↗

Radioimaging for real-time tracking of high-voltage breakdown

Development of a radioimaging diagnostic for high-voltage component reliability testing and electrical breakdown computational model validation is described. Radioimaging has its roots in radio astronomy, where aperture synthesis (also known as synthesis imaging) has been utilized for decades to image radio sources far from Earth. Radioimaging as described herein, in contrast, seeks to image radio sources in close proximity to its receivers (i.e., in a laboratory environment). Here it is shown that corona discharge, a non-destructive precursor to catastrophic (thermal) arc discharge, electromagnetically radiates strongly within a 250 kHz – 2.5 GHz bandwidth, and is readily detected and located by postprocessing the received radio signals. The ability of radioimaging to detect both corona and arc discharge (grouped together herein as high voltage breakdown or HVB) makes it a valuable tool for 100% HVB detection in materials, components, and devices, and has the ability to indicate electrical weakness (via corona detection) prior to a destructive arc discharge event. Radioimaging enables HVB to be located both internal and external to dielectric components under test in near-real-time, with multiple and/or extended HVB events located simultaneously. In contrast, existing non-destructive diagnostics (at the time of this writing) either indicate electrical breakdown without resolving failure locations (e.g., current, voltage, and chemical measurements), locate external HVB (e.g., high-speed optical and ultraviolet (UV) measurements or photography), or locate both external and internal HVB but with low fidelity (e.g., a single HVB source can be located by existing time-of-arrival (TOA) UHF or acoustic emissions). Radioimaging instead creates a sequence of high-fidelity images similar to an optical high-speed camera but at radiofrequencies (RF), and is not limited to two-dimensions. Moreover, radioimaging has already served one internal and two external industry customers, the results of which are detailed in this report. The radioimaging results described herein were part of a three-year effort funded by the Sandia Lab Directed Research and Development (LDRD) program within the Radiation, Electromagnetic, High Energy Density Science (REHEDS) investment area.

47 OTHER INSTRUMENTATION↗

Mesosphere-Stratosphere Coupling: Implications for Climate Variability and Trends

A key aspect of this project is the establishment of a causal link from circulation anomalies in the lower mesosphere and stratopause region downward through the stratosphere to the troposphere. The observational link for stratospheric sudden warmings and surface climate is fairly clear. However, our understanding of the dynamics is incomplete. We have been making significant progress in the area of dynamical mechanisms by which circulation anomalies in the stratosphere affect the troposphere. We are trying to understand the details and sequence of events that occur when a middle atmosphere (wind) anomaly propagates downward to near the tropopause. The wind anomaly could be caused by a warming or solar variations in the low-latitude stratopause region, or could have other causes. The observations show a picture that is consistent with a circulation anomaly that descends to the tropopause region, and can be detected as low as the mid-troposphere. Processes near the stratopause in the tropics appear to be important precursors to the wintertime development of the northern polar vortex. This may affect significantly our understanding of the process by which low-latitude wind anomalies in the low mesosphere and upper stratosphere evolve through the winter and affect the polar vortex.

Baldwin, Mark P.↗