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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 217 records · Page 12

Development of a process for high capacity-arc heater production of silicon

The realization of low cost, electric power from large-area silicon, photovoltaic arrays will depend on the development of new methods for large capacity production of solar grade (SG) silicon with a cost of less than $10 per kilogram by 1986 (established Department of Energy goal). The objective of the program is to develop a method to produce SG silicon in large quantities based on the high temperature-sodium reduction of silicon tetrachloride (SiCl4) to yield molten silicon and the coproduct salt vapor (NaCl). Commercial ac electric arc heaters will be utilized to provide a hyper-heated mixture of argon and hydrogen which will furnish the required process energy. The reactor is designed for a nominal silicon flow rate of 45 kg/hr. Analyses and designs have been conducted to evaluate the process and complete the initial design of the experimental verification unit.

Reed, W. H.↗

Development status of the SP-100 power system

The SP-100 Program, whose goal is to develop 10 to 1000 kW electric space reactor power systems for use in civil and military space missions in the mid 1990s and beyond, is described. The major accomplishments of the SP-100 ground engineering system development project are: (1) completion of the preliminary design of the reactor test facility, and (2) completion of the generic flight system design which meets the technical specifications and is the basis for all the ground engineering system analytical and experimental tasks. The power conditioning, control, and distribution subsystem is indicated schematically.

Mondt, Jack F.↗

Space shuttle aps propellant thermal conditioner study

An analytical and experimental effort was completed to evaluate a baffle type thermal conditioner for superheating O2 and H2 at supercritical pressures. The thermal conditioner consisted of a heat exchanger and an integral reactor (gas generator) operating on O2/H2 propellants. Primary emphasis was placed on the hydrogen conditioner with some effort on the oxygen conditioner and a study completed of alternate concepts for use in conditioning oxygen. A hydrogen conditioner was hot fire tested under a range of conditions to establish ignition, heat exchange and response parameters. A parallel technology task was completed to further evaluate the integral reactor and heat exchanger with the side mounted electrical spark igniter.

Fulton, D. L.↗

An Experimental Flow-Through Assessment of Acidic Fe/Mg Smectite Formation on Early Mars

Orbital observations have detected the phyllosilicate smectite in layered material hundreds of meters thick, intracrater depositional fans, and plains sediments on Mars; however, the detection of carbonate deposits is limited. Instead of neutral/alkaline conditions during the Noachian, early Mars may have experienced mildly acidic conditions derived from volcanic acid-sulfate solutions that allowed Fe/Mg smectite formation but prevented widespread carbonate formation. The detection of acid sulfates (e.g., jarosite) associated with smectite in Mawrth Vallis supports this hypothesis. Previous work demonstrated smectite (saponite) formation in closed hydrologic systems (batch reactor) from basaltic glass at pH 4 and 200°C (Peretyazhko et al., 2016 GCA). This work presents results from alteration of basaltic glass from alkaline to acidic conditions in open hydrologic systems (flow-through reactor). Preliminary experiments exposed basaltic glass to deionized water at 190°C at 0.25 ml/min where solution pH equilibrated to 9.5. These initial high pH experiments were conducted to evaluate the flow-through reactor system before working with lower pHs. Smectite at this pH was not produced and instead X-ray diffraction results consistent with serpentine was detected. Experiments are in progress exposing basaltic glass from pH 8 down to pH 3 to determine what range of pHs could allow for smectite formation in this experimental opensystem. The production of smectite under an experimental open-system at low pHs if successful, would support a significant paradigm shift regarding the geochemical evolution of early Mars: Early Mars geochemical solutions were mildly acidic, not neutral/alkaline. This could have profound implications regarding early martain microbiology where acid conditions instead of neutral/alkaline conditions will require further research in terrestrial analogs to address the potential for biosignature preservation on Mars.

Sutter, Brad↗

Laboratory-scale uranium RF plasma confinement experiments

An experimental investigation was conducted using 80 kW and 1.2 MW RF induction heater facilities to aid in developing the technology necessary for designing a self-critical fissioning uranium plasma core reactor. Pure uranium hexafluoride (UF6) was injected into argon-confined, steady-state, RF-heated plasmas in different uranium plasma confinement tests to investigate the characteristics of plamas core nuclear reactors. The objectives were: (1) to confine as high a density of uranium vapor as possible within the plasma while simultaneously minimizing the uranium compound wall deposition; (2) to develop and test materials and handling techniques suitable for use with high-temperature, high-pressure gaseous UF6; and (3) to develop complementary diagnostic instrumentation and measurement techniques to characterize the uranium plasma and residue deposited on the test chamber components. In all tests, the plasma was a fluid-mechanically-confined vortex-type contained within a fused-silica cylindrical test chamber. The test chamber peripheral wall was 5.7 cm ID by 10 cm long.

Roman, W. C.↗

Multiple Restart Testing of a Stainless Steel Sodium Heat Pipe Module

A heat pipe cooled reactor is one of several candidate reactor cores being considered for space power and propulsion systems to support future space exploration activities. Long life heat pipe modules. with designs verified through a combination of theoretical analysis and experimental evaluations. would be necessary to establish the viability of this option. A hardware-based program was initiated to begin experimental testing of components to verify compliance of proposed designs. To this end, a number of stainless steel/sodium heat pipe modules have been designed and fabricated to support experimental testing of a Safe Affordable Fission Engine (SAFE) project, a 100-kWt core design pursued jointly by the Marshall Space Flight Center and the Los Alamos National Laboratory. One of the SAFE heat pipe modules was successfully subjected to over 200 restarts. examining the behavior of multiple passive freeze/thaw operations. Typical operation included a 1-hour startup to an average evaporator temperature of 1000 K followed by a 15 minute hold at temperature. Nominal maximum input power during the hold period was 1.9 kW. Between heating cycles the module was cooled to less than 325 K, returning the sodium to a frozen state in preparation fop the next startup cycle.

Martin, James↗

A-Priori Tuning of Modified Magnussen Combustion Model

In the application of CFD to turbulent reacting flows, one of the main limitations to predictive accuracy is the chemistry model. Using a full or skeletal kinetics model may provide good predictive ability, however, at considerable computational cost. Adding the ability to account for the interaction between turbulence and chemistry improves the overall fidelity of a simulation but adds to this cost. An alternative is the use of simple models, such as the Magnussen model, which has negligible computational overhead, but lacks general predictive ability except for cases that can be tuned to the flow being solved. In this paper, a technique will be described that allows the tuning of the Magnussen model for an arbitrary fuel and flow geometry without the need to have experimental data for that particular case. The tuning is based on comparing the results of the Magnussen model and full finite-rate chemistry when applied to perfectly and partially stirred reactor simulations. In addition, a modification to the Magnussen model is proposed that allows the upper kinetic limit for the reaction rate to be set, giving better physical agreement with full kinetic mechanisms. This procedure allows a simple reacting model to be used in a predictive manner, and affords significant savings in computational costs for simulations.

Norris, A. T.↗

Kinetics of the reaction OH + HO2 yields H2O + O2 from 254 to 382 K

The discharge-flow resonance fluorescence technique has been used to determine the absolute rate constant for the reaction OH + HO2 yields H2O + O2 from 254 to 382 K at a total pressure of 1 Torr. Pseudo-=first-order conditions were used with HO2 in large excess over OH. The rate constant was obtained directly from observed decays of OH and measured concentrations of HO2. Since the observed rate constant was found to be very sensitive to small background concentrations of O and H atoms, NO2 was used to remove both atom species from the system. With added NO2 the result at 299 K is (1.1 + or - 0.3) x 10 to the -10th cu cm/molecule where the error limits are one standard deviation and include an estimate of overall experimental uncertainty. The temperature dependence expressed in Arrhenius form is (4.8 + or - 0.8) x 10 to the -11th exp (250 + or - 50)/T. The results are independent of the type of reactor surface and the precursor used to produce OH and HO2. The present results agree well with earlier measurements near 1-atm total pressure and suggest that this rate constant exhibits little or no pressure dependence between 1 and 1000 Torr.

Keyser, Leon F.↗

Nuclear Thermal Propulsion (NTP) Fission Product and Source Term Analysis

Nuclear thermal propulsion (NTP) is an in-space propulsion technology that uses a nuclear reactor to directly heat a propellant to provide high thrust, at higher efficiencies than achievable with conventional chemical propulsion systems. Due to the ability of NTP rockets to efficiently provide high thrust, this technology has been proposed for long duration space missions such as crewed missions to Mars and beyond. A primary hurdle for NTP technology development is the demonstration of an integrated reactor engine system to verify its functionality and performance. This primarily requires the manufacture and testing of candidate reactor and engine technologies to demonstrate the proposed design enables desired performance and exhibits acceptable response under all known operation modes. A major component in this testing is fission product accumulation, since after operation radioactive isotopes can be produced and pose radiological dose concerns. This paper explains the background behind fission product analysis and the methodology used to evaluate current reactor designs and identify the amount of fission products present and their radiological impact. Results of multiple thrust level engines at different time periods are discussed and highlight the need for additional experimental testing to confirm fractional release levels of fission products out of the system. Benchmarking of models and future paths of analysis are also discussed.

Fission↗

Nuclear Thermal Propulsion (NTP) Fission Product and Source Term Analysis

Nuclear thermal propulsion (NTP) is an in-space propulsion technology that uses a nuclear reactor to directly heat a propellant to provide high thrust, at higher efficiencies than achievable with conventional chemical propulsion systems. Due to the ability of NTP rockets to efficiently provide high thrust, this technology has been proposed for long duration space missions such as crewed missions to Mars and beyond. A primary hurdle for NTP technology development is the demonstration of an integrated reactor engine system to verify its functionality and performance. This primarily requires the manufacture and testing of candidate reactor and engine technologies to demonstrate the proposed design enables desired performance and exhibits acceptable response under all known operation modes. A major component in this testing is fission product accumulation, since after operation radioactive isotopes can be produced and pose radiological dose concerns. This paper explains the background behind fission product analysis and the methodology used to evaluate current reactor designs and identify the amount of fission products present and their radiological impact. Results of multiple thrust level engines at different time periods are discussed and highlight the need for additional experimental testing to confirm fractional release levels of fission products out of the system. Benchmarking of models and future paths of analysis are also discussed.

Nuclear Thermal Propulsion↗

Oxidation Resitant HfC-TaC Rocket Thruster for High Performance Propellants

The purpose of this reasearch effort was to develop high temperature, oxidation resistant thrusters which would lessen the thruster cooling requirements, resulting in increased performance and longer life for onboard propulsion systems for spacecraft. This research effort focussed on developing ceramic matrix composites (CMCs) for this application, and specifically investigated the use of HfC stabilized with TaC. This material composition can potentially operate in a stoichiometric oxygen to hydrogen ratio at a temperature of 5000 deg F (2760 deg C) in a radiatively cooled mode. Various compositions of Hafnium Carbide (HfC) and Tantalum Carbide (TaC) were deposited by chemical vapor deposition (CVD) and tested, in an attempt to identify the composition which offered the best oxidation resistance. Although it was identified that small amounts of TaC appeared to offer improved oxidation resistance over HfC alone, an optimal composition was not identified. A 251bf thruster was fabricated from a novel CMC sandwich construction with a HfC-TaC matrix, and survived two test firings, each of 5 seconds before a failure in the injector caused the run to be aborted. It was not possible to control the relative stoichiometry of the HfC and TaC composition throughout the reactor due to the large difference in the thermodynamics of the HfC and TaC formation from their respective chlorides. This also resulted in an inability to infiltrate TaC into the preform under the experimental conditions investigated. Other material compositions were fabricated and tested and two material systems; HfC-SiC functionally graded to C(sub f)/C and Re functionally graded to C(sub f)/C were selected for further testing. These functionally graded composites have use in a number of propulsion applications presently of interest to NASA and the defense industry. Their ability to withstand extremely hostile thermal environments and the light-weight and high-strength exhibited from the C(sub f)/C composite make these materials particularly suited for these applications. In the Phase III which is presently underway, Re functionally graded to C(sub f)/C is being further developed and tested for application in the thrust cells for the Linear Aerospike Engine for the X33 and RLV.

Patterson, Mark↗

Application of transport techniques to the analysis of NERVA shadow shields

A radiation shield internal to the NERVA nuclear rocket reactor required to limit the neutron and photon radiation levels at critical components located external to the reactor was evaluated. Two significantly different shield mockups were analyzed: BATH, a composite mixture of boron carbide, aluminum and titanium hydride, and a borated steel-liquid hydrogen system. Based on the comparisons between experimental and calculated neutron and photon radiation levels, the following conclusions were noted: (1) The ability of two-dimensional discrete ordinates code to predict the radiation levels internal to and at the surface of the shield mockups was clearly demonstrated. (2) Internal to the BATH shield mockups, the one-dimensional technique predicted the axial variation of neutron fluxes and photon dose rates; however, the magnitude of the neutron fluxes was about a factor of 1.8 lower than the two-dimensional analysis and the photon dose rate was a factor of 1.3 lower.

Capo, M. A.↗

Optimization of the parameters for a rotating, mixed-phase reactor

The motion of small, monodisperse particles in fluid was studied in a horizontal, cylindrical container rotating about its axis. One instigation for the study was the common requirement for mixed-phase, chemical or biological reactors to maintain particles in suspension for extended periods. A cylindrical, rotating reactor can allow long-term particle suspension without particle collisions and resulting agglomeration. The purpose of this study was to verify parametric effects and optimize the time of particle suspension. The theoretical and experimental results were obtained for inert, constant-diameter particles of nearly neutral buoyancy. The centrifugal buoyancy and gravitation terms were both included in the equations of motion. Laser illumination, photography and computer imaging were used to measure experimental particle concentration.

Cleland, J. G.↗

Influence of the Gas Pressure on Single-wall Carbon Nanotubes Formation

Experiments and modeling have been performed to predict the effect of gas pressure on species distribution and nanotube growth rate under specific conditions of synthesis of singlewall carbon nanotubes (SWCNTs) by arc discharge. Numerical results were compared with experiments in order to find a consistent correlation between the nanotube growth and the pressure. We used argon and helium as buffer gases with a total pressure varied between 0.1 and 1 bar. We experimentally observed that both the anode erosion rate and the Brunauer-Emmett-Teller (BET) surface area of the as produced nanotube soot material are very sensitive to the total gas pressure in the reactor

Hinkov, I.↗

Multiphysics Modeling of an Annular Linear Induction Pump With Applications to Space Nuclear Power Systems

An annular linear induction pump (ALIP) that could be used for circulating liquid-metal coolant in a fission surface power reactor system is modeled in the present work using the computational COMSOL Multiphysics package. The pump is modeled using a two-dimensional, axisymmetric geometry and solved under conditions similar to those used during experimental pump testing. Real, nonlinear, temperature-dependent material properties can be incorporated into the model for both the electrically-conducting working fluid in the pump (NaK-78) and structural components of the pump. The intricate three-phase coil configuration of the pump is implemented in the model to produce an axially-traveling magnetic wave that is qualitatively similar to the measured magnetic wave. The model qualitatively captures the expected feature of a peak in efficiency as a function of flow rate.

Kilbane, J.↗

Selection and use of TLDS for high precision NERVA shielding measurements

An experimental evaluation of thermoluminescent dosimeters was performed in order to select high precision dosimeters for a study whose purpose is to measure gamma streaming through the coolant passages of a simulated flight type internal NERVA reactor shield. Based on this study, the CaF2 chip TLDs are the most reproducible dosimeters with reproducibility generally within a few percent, but none of the TLDs tested met the reproducibility criterion of plus or minus 2%.

Woodsum, H. C.↗

Control of H2S emissions using an ozone oxidation process: Preliminary results

The problem of eliminating industrial emission odors does not have a simple solution, and consequently has not been researched extensively. Therefore, an experimental research program regarding oxidation of H2S through ozone was undertaken to verify the applicable limits of the procedure and, in addition, was designed to supply a useful analytical means of rationalizing the design of reactors employed in the sector.

Defaveri, D.↗