SEARCH · Engineering Papers
Results for “Critical field”
Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.
Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.
Superconductivity by alloying the topological insulator SnBi 2 Te 4
Alloying indium into the topological insulator SnBi 2 Te 4 induces bulk superconductivity with critical temperatures T c up to 1.85 K and upper critical fields up to about 14 kOe. This is confirmed by electrical resistivity, heat capacity, and magnetic susceptibility measurements. The heat capacity shows a discontinuity at T c and temperature dependence below T c consistent with weak coupling BCS theory, and suggests a superconducting gap near 0.25 meV. The superconductivity is type-II and the topological surface states have been verified by photoemission. Here, a simple picture suggests analogies with the isostructural magnetic topological insulator MnBi 2 Te 4 , in which a natural heterostructure hosts complementary properties on different sublattices, and motivates new interest in this large family of compounds. The existence of both topological surface states and superconductivity in Sn 1-x In x Bi 2 Te 4 identifies these materials as promising candidates for the study of topological superconductivity.
Anisotropic multiband superconductivity in 2 M − WS 2 probed by controlled disorder
The intrinsically superconducting Dirac semimetal 2 M − WS 2 is a promising candidate for realizing proximity-induced topological superconductivity in its protected surface states. A precise characterization of the bulk superconducting state is essential to understand the nature of surface superconductivity in the system. Here, we report a detailed experimental study of the temperature-dependent London penetration depth, λ ( T ) , the upper critical field, H c 2 ( T ) , and the effects of nonmagnetic disorder on these quantities, as well as on the superconducting transition temperature T c in single crystals of 2 M − WS 2 . We observe a power-law variation of λ ( T ) ∝ T 3 at temperatures below 0.35 T c . Nonmagnetic pointlike disorder induced by 2.5 MeV electron irradiation at various doses results in a significant suppression of T c . These observations are markedly different from expectations for a fully gapped isotropic s − wave superconductor. Together with the substantial increase of slope, d H c 2 / d T | T = T c , with increasing disorder, our results suggest a strongly anisotropic s + + multiband superconducting state. These results have direct consequences for the expected proximity-induced superconductivity of the topological surface states. Published by the American Physical Society 2024
Growth of High-Performance 4-5μm Thick Film REBCO Tapes Doped With Hafnium Using Advanced MOCVD
Advanced metal organic chemical vapor deposition technique (A-MOCVD) was used to grow 4-5 µm thick REBa 2 Cu 3 O 7–δ (REBCO, RE = rare earth) films, doped with 5% and 15% Hf. Thick REBCO films doped with 5% Hf exhibit self-field critical current density (J c ) over 1.8 MA/cm 2 at 77 K and 3 MA/cm 2 at 65 K, 1.5 T. Increasing the Hf content to 15% resulted in J c above 9 MA/cm 2 at 20 K, 9 T. The effect of (Ba+Hf)/Cu content in Hf-added (5 and 15 mol.%) REBCO films on the critical current density at 77 K, 0 T, c-axis lattice parameter and out-of- plane texture has been studied. In addition to growth of thick film REBCO tapes with superior performance, the A-MOCVD reactor has been used to quadruple the precursor-to-film conversion efficiency above 45%. Furthermore, this achievement has a first order impact in lowering the cost of REBCO tapes made by A-MOCVD.
Electrical and Thermal Performance of Ga₂O₃–Al₂O₃–Diamond Super-Junction Schottky Barrier Diodes
The design space of Ga 2 O 3 -based devices is severely constrained due to its low thermal conductivity and absence of viable p-type dopants. In this work, we discuss the limits of operation of a novel Ga 2 O 3 –Al 2 O 3 –diamond-based super-junction device concept, which can alleviate the constraints associated with Ga 2 O 3 -based devices. The improvements achieved using the proposed device concept are demonstrated through electrical and thermal simulations of Ga 2 O 3 –Al 2 O 3 –diamond-based super-junction Schottky barrier diodes (SJ-SBDs) and non-punch-through or conventional Schottky barrier diodes (NP-SBDs). The SJ-SBD enables operation below the R ON -breakdown voltage limit of Ga 2 O 3 NP-SBD, enabling >4 kV blocking voltage at R ON of 1–3 mΩ cm 2 . Here, the maximum switching frequency of SJ-SBD may be only a few kHz, as it is limited by the activation energy of acceptors (0.39 eV) in the diamond. Crucially, compared with NP-SBD, the use of diamond also results in ~60% reduction in temperature rise during static power dissipation. Polycrystalline diamond (PCD) properties depend on detailed microstructure and benefits compared to ideal Ga 2 O 3</sub NP-SBD arise for diamond critical fields ≥6 MV/cm and thermal conductivities as low as 50–150 W/(m • K).
Simulation and Modeling of Time-Resolved X-Ray Detector for the Saturn Accelerator
In this work, we present the technology-aided computer design (TCAD) device simulation and modeling of a silicon p-i-n diode for detecting time-dependent X-ray radiation. We show that the simulated forward and reverse breakdown current–voltage characteristics agree well with the measured data under nonradiation environment by only calibrating carrier lifetimes for the forward bias case and avalanche model critical fields for the reverse bias condition. Using the calibrated parameters and other nominal material properties, we simulated the radiation responses of the p-i-n diode and compared with experimental data when the diode was exposed to X-ray radiation at Sandia’s Saturn facility and the Idaho State University (ISU) TriMeV facility. For Saturn’s Gaussian dose-rate pulses, we show three findings from TCAD simulations. First, the simulated photocurrents are in excellent agreement with the measured data for two dose-rate pulses with peak values of 1.16×10 10 and 1.88×10 10 rad(Si)/s. Second, the simulation results of high dose-rate pulses predict increased delayed photocurrents with longer time tails in the diode electrical responses due to excess carrier generation. Third, simulated peak values of diode radiation responses versus peak dose rates at different bias conditions provide useful guidance to determine the dose-rate range that the p-i-n diode can reliably detect in experiment. For TriMeV’s non-Gaussian dose-rate pulse, our simulated diode response is in decent agreement with the measured data without further calibration. We also studied the effects of device geometry, recombination process, and dose-rate enhancement via TCAD simulations to understand the higher measured response in the time after the peak dose-rate radiation for the p-i-n diode exposed to TriMeV irradiation.
Superconducting Nd 1- x Eu x NiO 2 thin films using in situ synthesis
We report on superconductivity in Nd 1-x Eu x NiO 2 using Eu as a 4f dopant of the parent NdNiO 2 infinite-layer compound. We use an all–in situ molecular beam epitaxy reduction process to achieve the superconducting phase, providing an alternate method to the ex situ CaH 2 reduction process to induce superconductivity in the infinite-layer nickelates. The Nd 1-x Eu x NiO 2 samples exhibit a step-terrace structure on their surfaces, have a T c onset of 21 K at x = 0.25, and have a large upper critical field that may be related to Eu 4f doping.
Optimal Experimental Design for Inverse Problems in the Presence of Observation Correlations
Optimal experimental design (OED) is the general formalism of sensor placement and decisions on the data collection strategy for engineered or natural experiments. This problem is prevalent in many critical fields such as battery design, numerical weather prediction, geosciences, environmental and urban studies. State-of-the-art computational methods for experimental design do not accommodate correlation structure in observational errors produced by many expensive-to-operate devices such as X-ray machines, radars, and satellites. Discarding evident data correlations leads to biased results, higher expenses, and waste of valuable resources. We present a general formulation of the OED formalism for model-constrained large-scale Bayesian linear inverse problems, where measurement errors are generally correlated. The proposed approach utilizes the Hadamard product of matrices to formulate the weighted-likelihood, and is valid for both finite as well as infinite-dimensional Bayesian inverse problems. Extensive numerical experiments are carried out for empirical verification of the proposed approach using an advection-diffusion model, where the objective is to optimally place a small set of sensors, under a limited budget, to predict the concentration of a contaminant in a closed and bounded domain.
Big Advances at the Nano Scale in the Nanocarbons Division
In this issue of ECS Interface, we highlight some exciting success stories for low-dimensional materials in technologically critical fields. These are areas where emergent properties and processes within quantum-confined low-dimensional materials (and heterostructures) enable novel applications beyond what can be achieved in bulk materials.
Topological order of the Rys F-model and its breakdown in realistic square spin ice: Topological sectors of Faraday loops
Both the Rys F-model and antiferromagnetic square ice possess the same ordered, antiferromagnetic ground state, but the ordering transition is of second order in the latter, and of infinite order in the former. To tie this difference to topological properties and their breakdown, we introduce a Faraday lines representation where loops carry the energy and magnetization of the system. Because the F-model does not admit monopoles, its Faraday loops have distinct topological properties, absent in square ice, and which allow for a natural partition of its phase space into topological sectors. Then, the Néel temperature corresponds to a transition from topologically trivial to non-trivial Faraday loops. Because magnetization is a homotopy invariant of the Faraday loops, and it is zero for topologically trivial ones, the susceptibility is zero below a critical field. In square spin ice, instead, monopoles destroy the homotopy invariance and the parity distinction among loops, thus erasing this rich topological structure. Consequently, even trivial loops can be magnetized in square ice, and their susceptibility is never zero.
Nb3Sn Coating of Twin Axis Cavity for SRF Applications
The twin axis cavity with two identical accelerating beams has been proposed for Energy recovery linac (ERL) applications. Nb3Sn is a superconducting material with a higher critical temperature and a higher critical field as compared to Nb, which promises a lower operating cost due to higher quality factors. Two niobium twin axis cavities fabricated at JLab and were proposed to be coated with Nb3Sn. Due to their more complex geometry, the typical coating process used for basic elliptical cavities needs to be improved to coat these cavities. This devel-opment advances the current coating system at JLab for coating complex cavities. Two twin axis cavities were coated recently for the first time. This contribution dis-cusses initial results from coating of twin axis cavities, RF testing and witness sample analysis with an overview of the current challenges towards high performance Nb3Sn coated twin axis cavities.
Nb₃Sn Coating of Twin Axis Cavity for SRF Applications
The twin axis cavity with two identical accelerating beams has been proposed for energy recovery linac (ERL) applications. Nb₃Sn is a superconducting material with a higher critical temperature and a higher critical field as compared to Nb, which promises a lower operating cost due to higher quality factors. Two niobium twin axis cavities were fabricated at JLab and were proposed to be coated with Nb₃Sn. Due to their more complex geometry, the typical coating process used for basic elliptical cavi-ties needs to be improved to coat these cavities. This development advances the current coating system at JLab for coating complex cavities. Two twin axis cavities were coated recently for the first time. This contribution dis-cusses initial results from coating of twin axis cavities, RF testing and witness sample analysis with an overview of the current challenges towards high performance Nb₃Sn coated twin axis cavities.
New Environmental-Thermal Barrier Coatings for Ultrahigh Temperature Alloys
Our ARPA-E funded project, New Environmental-Thermal Barrier Coatings for Ultrahigh Temperature Alloys, has made significant strides in advancing the understanding of design and fabrication of novel thermal barriers coatings. Through rigorous research and innovative approaches, our team has explored new frontiers, pushing the boundaries of knowledge in this critical field.
Impact of Annealing on Superconducting Properties of Tantalum Thin Films
The pursuit for higher-coherence superconducting qubits has led to the adoption of new materials and innovative fabrication techniques. Among the commonly used superconducting materials, tantalum-based or tantalum-capped superconducting qubits have demonstrated the longest lifetimes, outperforming niobium devices even in the presence of their native oxides. Given the losses introduced by the surface oxide, one method to further improve performance is to reduce or eliminate the native oxide on tantalum through UHV annealing. In this work, we examine the effect of dissolved oxygen as a function of annealing temperature on the superconducting properties of tantalum thin films. Dissolved oxygen is quantified using atom probe tomography (APT) and secondary ion mass spectrometry (TOF-SIMS) and correlated with electromagnetic transport measurements performed using a Physical Property Measurement System (PPMS). This study observes that annealing decomposes the native oxide and drives oxygen diffusion into the film matrix. Increasing oxygen content decreases the superconducting transition temperature (Tc) and the residual resistivity ratio (RRR). The critical field decreases with the incorporation of oxygen, while the film’s coherence length decreases relatively by 5%. These results, as well as findings from ongoing studies linking fabrication processes to the structural and chemical properties of the superconducting film and Josephson junction, provide insight into effective strategies for improving the performance of superconducting devices.
Effects of Pressure on Superconducting Properties and Vortex Pinning of CaKFe 4 As 4 Single Crystals
Measurements of low field magnetization, trapped flux magnetization and 5 K flux creep in single crystal of CaKFe 4 As 4 under pressure up to 7.5 GPa in a diamond pressure cell are presented. Further, the observed evolution of the temperature dependence of the self-field critical current and slowing down of the base temperature flux creep rate are explained within the two sources of pinning hypothesis involving presence of CaFe 2 As 2 intergrowths suggested in the literature. Above the half collapsed tetragonal structural transition under pressure, where superconductivity is non-bulk or absent, critically diminished or no diamagnetism and flux trapped magnetization were observed.
Investigation of current degradation phenom- enon in superconducting solenoids second quarterly progress report, 15 oct. 1964 - 15 jan. 1965
Critical current density, upper resistive critical field, normal state resistivity, and room temperature resistivity, measurements of titanium-niobium wire samples
Superconducting technetium-tungsten alloys.
Transition temperature, critical fields, electrical resistivities and crystalline structures of technetium-tungsten alloys
Measurements of Magnetization in Superconductive Molybdenum
Magnetization in superconducting Mo measured in He 3 cryostat, noting transition temperatures and critical field