Optical and infrared masers
High resolution studies of atoms and molecules applied to optical and infrared maser experimentation
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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.
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The variation method, 1
Variation method, and binding energy and structure of atoms and molecules
Epstein, S. T.↗
Post-threshold energy dependence of the cross section for endoergic processes - Vibrational excitation and reactive scattering.
The essential features of the translational energy dependence or excitation function for two types of endoergic collisional processes are deduced on the basis of information on the inverse, exoergic processes. Microreversibility is conveniently exploited via the symmetric field function, Y(E), which is uniquely determined at a given total energy, E. In the case of the vibrational excitation of diatomic molecules by atomic or molecular impact, use is made of the abundant data on the temperature dependence of the relaxation time.
Levine, R. D.↗
An ESCA study of lunar and terrestrial materials.
The technique of electron spectroscopy for chemical analysis (ESCA) is used to obtain rapid, nondestructive elemental analyses of selected lunar samples, and the chemical shift of the Fe(2p) line in lunar materials is found characteristic of iron in the Fe(2+) state. A difference in binding energy of approximately 0.5 eV is observed between the 0(1s) levels of the terrestrial minerals fayalite and quartz, and effects due to surface oxidation and absorption are also observed in terrestrial materials. The new ESCA technique is based on energy analysis at high resolution of electrons emitted from the surface of a sample on irradiation with X rays and is valuable for the study of the electronic structure of atoms and molecules.
Huntress, W. T., Jr.↗
Interstellar molecules and dense clouds.
Current knowledge of the interstellar medium is discussed on the basis of recent published studies. The subjects considered include optical identification of interstellar molecules, radio molecular lines, interstellar clouds, isotopic abundances, formation and disappearance of interstellar molecules, and interstellar probing techniques. Diagrams are plotted for the distribution of galactic sources exhibiting molecular lines, for hydrogen molecule, hydrogen atom and electron abundances due to ionization, for the densities, velocities and temperature of NH3 in the direction of Sagitarius B2, for the lower rotational energy levels of H2CO, and for temporal spectral variations in masing H2O clouds of the radio source W49. Future applications of the maser and of molecular microscopy in this field are visualized.
Rank, D. M.↗
An adhesion criterion in the gas solid interface
A theoretical model is developed to establish an adhesion criterion for the interaction of a gas atom or molecule with a nonmetallic surface. As a first approximation a linear lattice mass points of the solid surface is considered and the classical lattice dynamical model is used.
George, M. C.↗
On the measurement of Rayleigh scattering by gases at 6328A
The problem of laboratory measurements of Rayleigh scattering and depolarization ratio for atoms and molecules in the gaseous state is described. It is shown that, if the scattered radiation measurements are made at two angles, the normal depolarization ratio cannot be determined meaningfully. However, from scattering measurements, the Rayleigh scattering cross sections can be determined accurately. The measurements of Raleigh scattering from He, H2, Ar, O2, and N2 for unpolarized radiation at 6328A are reported and compared with similar measurements at 6943 and 1215.7A.
SHARDANAND↗
New kind of ring around Saturn.
It is believed that barring extraordinary circumstances the Saturn satellite Titan must lose its atmosphere at a prodigious rate. The velocity of the atmospheric particles, however, although sufficient to escape from the satellite, does not quite reach Saturnian escape velocity. Consequently, atoms and molecules lost by Titan are forced by the planet's gravitational field to orbit Saturn until ionized or until they are recaptured by Titan, forming a gaseous torus encompassing Titan's orbit.
Mcdonough, T. R.↗
Wall boundary equations with slip and catalysis for multicomponent, nonequilibrium gas flows
Boundary equations obtained for a low Reynolds number, high enthalpy gas flow in regions of velocity slip and temperature jump are presented. The formulation treats, through a first-order distribution function used to include multicomponent diffusion, a multicomponent gas mixture that may be in nonequilibrium with finite-rate catalytic recombination occurring on the wall. In the boundary equations, which are obtained for use in flow-field calculations applicable to low-density flow regimes, a simplified gas/wall interaction is assumed wherein individual atoms or molecules either reflect specularly off the wall or stick and are fully accommodated. Fluxes in terms of evaluated integrals over the distribution function and integrals necessary for determining fluxes are given.
Scott, C. D.↗
A study of stratospheric gases catalytically reacting on alumina
A vacuum system developed to study stratospheric gases reacting on Al2O3. Special attention was given to the reactions of HCl, SO2, and O3. Efforts were made to detect atoms and/or molecules produced by catalytic action of Al2O3 with mass spectrometer.
Cox, J. L., Jr.↗
Comet Kohoutek
A compilation of scientific observations (workshop) is presented. Topics discussed are: (1) tail form, structure, and evolution; (2) hydroxyl related observations; (3) molecules and atoms in the coma and tail; (4) photometry and radiometry; and (5) spacecraft and ground based observation data. Color photographs are shown.
Gary, Gilmer A.↗
Enhanced effects of starlight on the interstellar medium
The photodesorption of molecules and atoms from the surfaces of interstellar grains can be an important source of heating for the interstellar medium and the origin of instabilities which may separate grains and gas. For low densities, the force exerted on the grains is proportional to the gas density and independent of the radiation intensity; for high densities, it is proportional to the radiative flux and independent of the gas density. This force may act differently on grains of different sizes. The photoelectric effect may also be an efficient mechanism for the separation of gas and dust in diffuse clouds.
Gerola, H.↗
Enhanced effects of starlight on the interstellar medium
The photodesorption of molecules and atoms from the surfaces of interstellar grains can be an important source of heating for the interstellar medium and the origin of instabilities which may separate grains and gas. For low densities, the force exerted on the grains is proportional to the gas density and independent of the radiation intensity; for high densities, it is proportional to the radiative flux and independent of the gas density. This force may act differently on grains of different sizes. The photoelectric effect may also be an efficient mechanism for the separation of gas and dust in diffuse clouds.
Gerola, H.↗
Photoelectron spectroscopy by electron attachment
Technique detects threshold photoelectrons for atoms and molecules with high resolution, yet requires no electron optics setup.
Ajello, J. M.↗
Photon scattering cross sections of H2 and He measured with synchrotron radiation
Total (elastic + inelastic) differential photon scattering cross sections have been measured for H2 gas and He, using an X-ray beam. Absolute measured cross sections agree with theory within the probable errors. Relative cross sections (normalized to theory at large S) agree to better than one percent with theoretical values calculated from wave functions that include the effect of electron-electron Coulomb correlation, but the data deviate significantly from theoretical independent-particle (e.g., Hartree-Fock) results. The ratios of measured absolute He cross sections to those of H2, at any given S, also agree to better than one percent with theoretical He-to-H2 cross-section ratios computed from correlated wave functions. It appears that photon scattering constitutes a very promising tool for probing electron correlation in light atoms and molecules.
Ice, G. E.↗
Use of rate equations to describe laser excitation in flames
The region of validity of conventional rate equation formulations used to describe the excitation of flame gases for spectroscopic diagnostic purposes is examined by direct comparison with the density matrix formulation. The density matrix equations are formulated for an ensemble of atoms or molecules in the gas state. These equations are reduced to the steady-state limit for a two-level system under the effect of single-mode and multimode optical fields. The steady-state equations are shown to be valid only when the laser pulse rises slowly with respect to the collisional dephasing rate for single-mode excitation, and for certain special cases under multimode excitation.
Daily, J. W.↗
On the representation matrices of the spin permutation group
A method is presented for the determination of the representation matrices of the spin permutation group (symmetric group), a detailed knowledge of these matrices being required in the study of the electronic structure of atoms and molecules. The method is characterized by the use of two different coupling schemes. Unlike the Yamanouchi spin algebraic scheme, the method is not recursive. The matrices for the fundamental transpositions can be written down directly in one of the two bases. The method results in a computationally significant reduction in the number of matrix elements that have to be stored when compared with, say, the standard Young tableaux group theoretical approach.
Wilson, S.↗
Photon-scattering cross sections of H2 and He measured with synchrotron radiation
Total (elastic + inelastic) differential photon-scattering cross sections have been measured for H2 gas and for He, using an X-ray beam. Absolute measured cross sections agree with theory within the probable errors. Relative cross sections (normalized to theory at large S) agree to better than 1% with theoretical values calculated from wave functions that include the effect of electron-electron Coulomb correlation, but the data deviate significantly from theoretical independent-particle (e.g., Hartree-Fock) results. The ratios of measured absolute He cross sections to those of H2, at any given S, also agree to better than 1% with theoretical He-to-H2 cross-section ratios computed from correlated wave functions. It appears that photon scattering constitutes a very promising tool for probing electron correlation in light atoms and molecules. The degree of polarization of the synchrotron radiation beam has been measured by rotating the scattering plane about the beam axis; results are compared with theory.
Ice, G. E.↗