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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 217 records · Page 12

Internal Reaction Mass Taxonomy and Narrow-Down Study

Internal reaction mass (IRM) wave energy converters (WEC) capture wave energy by reacting against a moving mass that is suspended within their hulls. Due to their hermetically sealed Power Take Off (PTO), compact form factor and relatively simple mooring requirements, the National Renewable Energy Laboratory has identified IRM WECs are good candidates for applications such as ocean observation. A literature review of existing IRM mechanisms lead to the classification of IRM WECs based on their principal method of energy capture and principal axes of operation. The IRM categories include sliding mass, pendular and gyroscopic devices. A narrow down study was conducted to ascertain the most promising mechanisms for further investigation; devices were evaluated based on a decision matrix of weighted criteria that included device power output, prototypability and power to mass ratio. The narrow down study identified the issue of achieving resonance with pendulum-based designs, as well as the poor response produced by reaction to long period waves. Chaotic pendula and methods to multiply agitation were identified as a means to increase power output. Alternative methods of power generation, such as triboelectric nanogenerators, were also identified as a technology that would benefit from multiplied agitation and chaotic motion. This work was funded under the U.S. Department of Energy's Water Power Technologies Office's Powering the Blue Economy portfolio.

ENGINEERING,TIDAL AND WAVE POWER↗

Computer-aided design of stability enhanced nicotinamide cofactor biomimetics for cell-free biocatalysis

Cell-free biocatalysis (CFB) is an efficient and environmentally friendly method to synthesize molecules such as pharmaceuticals, biochemicals, and biofuels through the in vitro use of enzyme cascades. These enzymes often require redox cofactors to drive chemical reactions. Natural redox cofactors (NAD(P)H) are expensive to isolate, motivating synthetic nicotinamide cofactor biomimetics (NCBs) as a cost-effective solution. A select handful of NCBs have been identified as potential NAD(P)H alternatives with comparable or improved redox capabilities, however, they display a tendency to degrade in common buffers. In this study, a library of 132 NCB candidates is systematically generated, over 85% of which have not been characterized in the literature, to expand the diversity of currently explored NCBs. The decomposition mechanism of NCBs in phosphate is evaluated using density functional theory (DFT), revealing protonation at the nicotinamide C5 position as a reporter of cofactor stability. Based on this result, we trained a linear regression model on DFT calculated descriptors to predict NCB stability in phosphate buffer, achieving mean absolute error (MAE) and root mean squared error (RMSE) values within computational accuracy. Analysis of key atomic descriptors and qualitative trends in our dataset informed the design of novel NCB candidates we propose with optimized stability. This work enables researchers to predict the relative stability of NCBs before synthesis, thereby streamlining the process to make CFB more affordable and viable at industry scales.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Root Source Analysis/ValuStream[Trade Mark] - A Methodology for Identifying and Managing Risks

Root Source Analysis (RoSA) is a systems engineering methodology that has been developed at NASA over the past five years. It is designed to reduce costs, schedule, and technical risks by systematically examining critical assumptions and the state of the knowledge needed to bring to fruition the products that satisfy mission-driven requirements, as defined for each element of the Work (or Product) Breakdown Structure (WBS or PBS). This methodology is sometimes referred to as the ValuStream method, as inherent in the process is the linking and prioritizing of uncertainties arising from knowledge shortfalls directly to the customer's mission driven requirements. RoSA and ValuStream are synonymous terms. RoSA is not simply an alternate or improved method for identifying risks. It represents a paradigm shift. The emphasis is placed on identifying very specific knowledge shortfalls and assumptions that are the root sources of the risk (the why), rather than on assessing the WBS product(s) themselves (the what). In so doing RoSA looks forward to anticipate, identify, and prioritize knowledge shortfalls and assumptions that are likely to create significant uncertainties/ risks (as compared to Root Cause Analysis, which is most often used to look back to discover what was not known, or was assumed, that caused the failure). Experience indicates that RoSA, with its primary focus on assumptions and the state of the underlying knowledge needed to define, design, build, verify, and operate the products, can identify critical risks that historically have been missed by the usual approaches (i.e., design review process and classical risk identification methods). Further, the methodology answers four critical questions for decision makers and risk managers: 1. What s been included? 2. What's been left out? 3. How has it been validated? 4. Has the real source of the uncertainty/ risk been identified, i.e., is the perceived problem the real problem? Users of the RoSA methodology have characterized it as a true bottoms up risk assessment.

Brown, Richard Lee↗

SIM PlanetQuest: Progress Report

SIM PlanetQuest, a micro-arcsecond astrometry space mission, has been impacted by significant changes in NASA priorities over the last two years, resulting in the mission being indefinitely delayed. The SIM team has responded by investigating alternative mission concepts based upon completed SIM technology. Several alternative mission concepts have been identified, ranging from a planets-only concept, to versions of SIM, called SIM-Lite, that still address the full breadth of SIM science envisioned by two previous National Academy Astrophysics Decadal Surveys but with lower precision and reduced throughput. These mission concepts, Planet Hunter and SIM-Lite, are significantly more affordable and may fit into a nearer-term future scenario than the full SIM PlanetQuest would. This paper describes the current state of the SIM project, including its design and technology, and the alternative mission concepts for the use of these designs and technology.

SIM-Lite↗

Growth modeling to evaluate alternative cultivation strategies to enhance national microalgal biomass production

In this paper, we present a model-based assessment of alternative cultivation strategies on algal biomass production within the conterminous United States. Our assessment focuses on two basic cultivation strategies: 1) seasonal rotation of three representative freshwater algal strains that are well suited for warm weather, cold weather, and all-season diverse weather conditions, respectively; and 2) variation between three open pond water depths (15cm, 20cm, and 25cm). The enhanced Biomass Assessment Tool (BAT) is applied on a site-specific, hourly basis at 5,832 North American Land Data Assimilation System Phase 2 1/8° meteorological model grid cells over a 30-year period (1980-2009) to evaluate the operational strategies. Recognizing that resource management decisions may also consider scales beyond the individual site, we also conduct a regional assessment of focused on 7 representative climate zones in the conterminous United States. Results demonstrate that the spatial variability of algal productivity is largely affected by the strain-specific growth response to light and temperature that vary significantly by climate zone and latitude. Therefore, with a limited set of alternative cultivation strategies, the BAT identified the best performing combination of cultivation strategies on a site-specific basis that considerably enhances national annual biomass productivity. Specifically, the appropriate choice of seasonal strain rotation is able to significantly dampen climate-driven seasonal and spatial variability.

59 BASIC BIOLOGICAL SCIENCES↗

Material properties of aqueous potassium acetate solutions for use in liquid desiccant air conditioning

We present thermophysical properties of aqueous potassium acetate solutions relevant to their application as a liquid desiccant in air-conditioning systems. Liquid desiccant air conditioners could provide up to 80% energy savings compared to high-efficiency vapor compression air conditioners. However, the commonly used liquid desiccants, particularly chloride salt solutions, are highly corrosive. This precludes the use of metallic components, necessitating specialized plastics and thereby driving up cost, weight, and limiting operational temperature and pressure ranges. Potassium acetate has been identified as a less corrosive alternative, potentially enabling broader material compatibility in LDAC components. In this study we systematically measured and modelled key thermophysical properties of KAc solutions density, vapor pressure, viscosity, specific heat capacity, phase behavior, and diffusion coefficient across a range of concentrations (10 - 70wt%) and temperatures. For instance, KAc exhibits a vapor pressure of 3.1 kPa at 50wt% and 40degrees C, demonstrating dehumidification capability comparable to chloride salts. By providing an extended dataset and associated models, this work advances the understanding needed to design energy-efficient, corrosion mitigating LDAC system.

36 MATERIALS SCIENCE↗

A Glance of the Layered Transition Metal Oxide Cathodes in Sodium and Lithium-ion Batteries: Difference and Similarities

The fast-growing demand of energy storage devices has prompted diverse battery techniques, while the state-of-the-art Li-ion batteries (LIBs) continue to flourish, Na-ion batteries (SIB) have been identified to be a promising alternative to share the burden with LIBs, particularly for large scale grid storage applications. Both LIBs and SIBs techniques work based on similar fundamental mechanisms, with a heavy focus on intercalation chemistry of layered transition metal (TM) oxides. However, the differences between Li-ion and Na-ion in terms of their size and Lewis acidity induce many different behaviors when crystallizing or diffusing in layered cathode materials. This minireview summarizes some typical cases where Li and Na-ion differ in layered cathode materials and discusses potential approaches to leverage their similarities and dissimilarities for future developments of high-performance Na-ion batteries.

Xiao, Biwei↗

Assessment of the Performance of Hydrofluoroolefins, Hydrochlorofluoroolefins, and Halogen-Free Foam Blowing Agents in Cellular Plastic Foams

Oak Ridge National Laboratory has conducted a literature search to identify relevant information available on alternative materials and technologies that are proposed for foam blowing agents applications. For comparison, similar information was collected for available hydrofluorocarbons (HFC), hydrofluoroolefin (HFO), and hydrochlorofluoroolefins (HCFO) materials. The publicly available literature was analyzed and assessed for technical accuracy for each alternative, and a gap analysis was conducted to understand if additional studies are required to fully assess the viability of an alternative. In assessing these alternatives, this project focused on relevant performance and safety attributes. The performance attributes collected include insulation value per unit thickness, which impacts energy usage of buildings and insulated equipment such as refrigerators. We also assessed the impact of blowing agents on foam mechanical properties and flammability characteristics, and the ability of current processing equipment and techniques to utilize these alternatives. Diffusion of blowing agents through foam cells and its impact on foam aging was also examined. The applications covered in this study are spray foam, boardstock, panels, and appliances. Some of the most relevant findings are summarized below.

36 MATERIALS SCIENCE↗

Estuarine nutrient pollution impact reduction assessment through euphotic zone avoidance/bypass considerations

The feasibility of reducing nutrient pollution impact by redirecting the effluent to depths below the euphotic zone was investigated for the deep estuarine Puget Sound region of the Salish Sea in the Pacific Northwest of America. The hypothesis tested was that the thickness of the outflow layer in deep estuaries may be greater than the euphotic zone depth, allowing a fraction of nutrients to be exported out passively through the layers immediately below. The euphotic zone depth in Puget Sound varies from 8 to 25 m while the depth of the outflow layer can reach up to ≈ 60 m. Outfall relocation strategies were tested on 99% of the anthropogenic nutrient loads currently delivered to Puget Sound. The impact was quantified using the previously established biophysical Salish Sea Model, using gross primary production and exposure to low dissolved oxygen (DO) levels as the metric (< 2 mg/L for hypoxia and < 5 mg/L for impairment). Eliminating nutrient pollution (above natural) from rivers and wastewater reduced hypoxia exposure by 8.1% and 11.2%, respectively. Relocating the outfalls to deeper waters resulted in improvements, but only in the sill-less sub-basins such as Whidbey, where hypoxia and DO impairment exposure decreased (7.9% and 6.8%, respectively). The presence of multiple sills and circulation cells in Puget Sound resulted in increased exposure and rendered nutrient bypass goals unfeasible as originally envisioned. However, an alternate nutrient export pathway was identified through bottom exchange flow out of Puget Sound via Whidbey Basin and Deception Pass. An unexpected reduction in the exchange outflow magnitude (≈ 4%) due additional (22%) freshwater discharged to the estuary bottom was also noted. The potential loss in circulation strength due to rerouting of natural surface freshwater through submerged deep-water outfalls is identified as a new unforeseen anthropogenic impact.

54 ENVIRONMENTAL SCIENCES↗

Identifying Characteristics of Wildfire Towers and Troughs

Wildfire behavior is dictated by the complex interaction of numerous physical phenomena including dynamic ambient and fire-induced winds, heat transfer, aerodynamic drag on the wind by the fuel and combustion. These phenomena create complex feedback effects between the fire and its surroundings. In this study, we aim to study the mechanisms by which buoyant flame dynamics along with vortical motions and instabilities control wildfire propagation. Specifically, this study employs a suite of simulations conducted with the physics-based coupled fire-atmosphere behavior model (FIRETEC). The simulations are initialized with a fire line and the fires are allowed to propagate on a grass bed, where the fuel heights and wind conditions are varied systematically. Flow variables are extracted to identify the characteristics of the alternating counter-rotational vortices, called towers and troughs, that drive convective heat transfer and fire spread. These vortices have previously been observed in wildfires and laboratory fires, and have also been observed to arise spontaneously in FIRETEC due to the fundamental physics incorporated in the model. However, these past observations have been qualitative in nature and no quantitative studies can be found in the literature which connected these coherent structures fundamental to fire behavior with the constitutive flow variables. To that end, a variety of state variables are examined in the context of these coherent structures under various wind profile and grass height conditions. Identification of various correlated signatures and fire-atmosphere feedbacks in simulations provides a hypothesis that can be tested in future observational or experimental efforts, potentially assisting experimental design, and can aid in the interpretation of data from in situ detectors.

54 ENVIRONMENTAL SCIENCES↗

Data catalog of satellite experiments

This catalog is divided into three sections: data description contains descriptions of data available at or through NSSDC as well as descriptions of the experiments and spacecraft from which the data originated; and supporting data contains brief descriptions of space environment models and programs distributed by NSSDC. Section 3 is a series of indexes that contain: (1) a listing of all spacecraft, experiment, and data descriptions presented in Section 1 plus tables indicating the period for which each spacecraft was operational; (2) an index of all spacecraft described here, identified by common names and alternate names; (3) a listing of the original experiment institutions for all experiments described; (4) a listing of the investigators associated with the experiments and their current affiliations; and (5) an index of all experiments sorted by phenomenon measured.

Source record↗

Data catalog of satellite experiments

The availability of space science data, a description of the data, and a description of the services supplied by the National Space Science Data Center (NSSDC) is presented. A series of cumulative indexes that reference the data descriptions contain: (1) a chronological listing of all spacecraft, experiments, and data descriptions; (2) an index of all spacecraft described, identified by common names and alternate names; (3) a listing of the original experiment institutions for experiments described; (4) a listing of the investigators associated with the experiments and their current affiliations; and (5) two displays of information about experiment data coverage for fields and particle data and a listing of all experiments sorted by phenomenon measured.

Source record↗

Maneuver strategy for a possible Pioneer 11 extended mission

The Jupiter-bound Pioneer 11 spacecraft was launched in April 1973, eight months before the Jupiter encounter of the front-running twin spacecraft, Pioneer 10. Depending on the content of the Pioneer 10 science, the Pioneer 11 mission objectives may be modified to explore different regions about Jupiter, including an aimpoint region providing for an extended trajectory to Saturn. Following launch, early maneuver aiming strategies were designed to retain a later retargeting maneuver capability to repeat Pioneer 10 or to encounter alternate Jupiter aimpoints. This paper identifies the ground rules and information required for the adaptive design of these strategies, considering a variety of mission objectives and Project constraints for later retargeting maneuvers.

Frauenholz, R. B.↗

Digital system identification and its application to digital flight control

On-line system identification of linear discrete systems for implementation in a digital adaptive flight controller is considered by the conventional extended Kalman filter and a decoupling process in which the linear state estimation problem and the linear parameter identification problem are each treated separately and alternately. Input requirements for parameter identifiability are established using the standard conditions of observability for a time variant system. Experimental results for simulated linearized lateral aircraft motion are included along with the effect of different initialization and updating procedures for the priming trajectory used by the filter.

Kotob, S.↗

Power processor design considerations for a solar electric propulsion spacecraft

Propulsion power processor design options are described. The propulsion power processor generated the regulated dc voltages and currents from a solar array source of a solar electric propelled spacecraft. The power processor consisted of 12 power supplies that provide the regulated voltages and currents necessary to power a 30-cm mercury ion thruster. The design options for processing unregulated solar array power and for generating the regulated power required by each supply are studied. The technical approaches utilized in the developed design and the technological limitation of the identified design options are discussed. Alternate approaches for delivering power to a number of mercury ion thrusters and methods of optimizing are described. It was concluded that this power processor design should be considered for application in solar electric propulsion missions of the future.

Costogue, E. N.↗

Hydrogen detection study

The effectiveness was assessed of a hydrogen (H2) detection concept for regenerative environmental control life support systems (EC/LSS). The concept evaluated was that utilized for the electrochemical depolarized concentrator (EDC) design, constructed, and tested for the EC/LSS space station prototype program. The EDC contains combustible gas detectors (CGDs) which were evaluated with H2. The CGDs were evaluated for linearity, position sensitivity, reproducibility, ambient effects, repeatability, speed of response, recovery time, and interchangeability. The effectiveness of CGDs located within the EDC for sensing H2 leaks at various line replaceable units in the subsystem was determined. The effects of H2 leak rate, H2 concentration of leaking gas and air currents in the vicinity of the EDC were determined. Proposed improvements for the H2 detection concept were documented and alternative H2 detection approaches were identified and analyzed.

Shumar, J. W.↗

The next 25 years: Industrialization of space: Rationale for planning

The goals of NASA's space industralization program include contributing to increased productivity on earth without taxing the environment, generating new values through extraterrestrial productivity, and providing new growth options for the future which include the permanent settlement of space and long-range colonization and exploration projects. In planning the long-range space program based on essentially utilitarian aspects, without losing sight of the more humanistically significant long term, and to forecast associated technology requirements, a realistic approach is obtained by combining extrapolative and normative planning modes so that common stepping stones can be identified. In the extrapolative view, alternative futures are projected on the basis of past and current trends and tendencies. In the normative view, some ideal state in the far future is envisioned or postulated, and policies and decisions are directed toward its attainment.

Vonputtkamer, J.↗

Ion Propulsion Module design and mission performance

This paper describes the design options, processes and tradeoffs that occur during the establishment of viable Ion Drive vehicle and mission designs. The options identify those internal vehicle design alternatives which are being considered for future Ion Drive missions, such as sunlight concentrating arrays and direct drive thrust subsystems, and their effect on mission performance. Also, the highly interactive nature of the Ion Drive design process, which occurs between the spacecraft and mission designers, is described. The results of design tradeoffs, performed for three Ion Drive comet rendezvous missions, are presented. These results include the following: (1) the power profile is determined primarily by the trajectory while second order effects include the solar cell characteristics and array concentration factor and degradation; and (2) the dominant parameter in mission performance determination, Ion Propulsion Module (IPM) mass, and IPM design, is the total cell power evaluated without concentration, at the beginning of life and at 1 AU.

Graf, J. E.↗