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NASA NTRS1994

Solventless, curable fluid oligomeric systems for high performance microwave, acoustical and mechanical applications

While establishing the basis for a 'Technology 2000' product plan several years ago we plugged in the usual factors contributing toward product success: price/performance justifiable; profitable, warranting high quality maintenance, enhancement, and specific property improvement; narrow inventory requirements; and raw material integrable backwards with easily variable properties (molecular weight, functionality, and isomer control). We resolved this by selecting radical functional, low molecular weight polybutadiene liquid polymers. Encouraged by the need for solid rocket binders, several companies embarked on various perceptions of binder performance requirements over four decades ago. Initially dominated by progress of liquid polysulfides, soon a few settled primarily upon polybutadiene based binders. Such an approach in a few instances was exploited quite viably with a series of functional group terminated liquid polybutadienes: hydroxyl, mercaptan, carboxyl, vinyl, and amine. Good results are obtained for oligomers, liquid polymers, and their hybrids. The only significant limits on compounded products has been solvent resistance and oxidative sensitivity, unless sufficient proportion of sulfide or nitrile moiety is incorporated. For convenience, they have been grouped under the trademarks Nylane, Seamax, Oligomax, and Castomax.

Lefave, G. M.↗
NASA NTRS1993

Constraints on the Martian cratering rate imposed by the SNC meteorites and Vallis Marineris layered deposits

Following two independent lines of evidence -- estimates of the age and formation time of a portion of the Martian geologic column exposed in the layered deposits and the crystallization and ejection ages of the SNC meteorites -- it appears that the Martian cratering rate must be double the lunar rate or even higher. This means models such as NHII or NHIII (Neukum and Hiller models II and III), which estimate the Martian cratering rate as being several times lunar are probably far closer to reality on Mars than lunar rates. The effect of such a shift is profound: Mars is transformed from a rather Moon-like place into a planet with vigorous dynamics, multiple large impacts, erosion, floods, and volcanism throughout its history. A strong shift upward in cratering rates on Mars apparently solves some glaring problems; however, it creates others. The period of time during which Earth-like atmospheric conditions existed, the liquid water era on Mars, persists in NHIII up to only 0.5 b.y. ago. Scenarios of extended Earth-like conditions on Mars have been discounted in the past because they would have removed many of the craters from the early bombardment era found in the south. It does appear that some process of crater removal was quite vigorous in the north during Mars' past. Evidence exists that the northern plains may have been the home of long-lived seas or perhaps even a paleo-ocean, so models exist for highly localized destruction of craters in the north. However, the question of how the ancient crater population could be preserved in the south under a long liquid-water era found in any high-cratering-rate models is a serious question that must be addressed. It does appear to be a higher-order problem because it involves low-energy dynamics acting in localized areas, i.e., erosion of craters in the south of Mars, whereas the two problems with the low-cratering-rate models involve high-energy events acting over large areas: the formation of the Vallis Marineris, the SNC ejecting impacts, and the global atmospheric pressure and temperature conditions that allow liquid water to exist as a robust entity anywhere on the Martian surface. In any case, it appears Mars is a more complex and dynamic planet than previously supposed. It has canyons dating from the middle to late period of its history that contain apparent lake sediments bedded deeper than most sediments on Earth. Recent multiple, violent impacts on Mars have apparently provided us with multiple random samples of its surface that all crystallized less than 1.5 b.y. ago. These things cannot be accommodated in our present cratering chronologies of Mars, based on 1x lunar cratering rates, without great difficulties. These difficulties suggest that a new chronology, probably based on NHII or even NHIII, should be adopted; this new chronology will provide us with a new view of Mars as a dynamic planet of rich history.

Brandenburg, J. E.↗
NASA NTRS1994

Mount Rainier active cascade volcano

Mount Rainier is one of about two dozen active or recently active volcanoes in the Cascade Range, an arc of volcanoes in the northwestern United States and Canada. The volcano is located about 35 kilometers southeast of the Seattle-Tacoma metropolitan area, which has a population of more than 2.5 million. This metropolitan area is the high technology industrial center of the Pacific Northwest and one of the commercial aircraft manufacturing centers of the United States. The rivers draining the volcano empty into Puget Sound, which has two major shipping ports, and into the Columbia River, a major shipping lane and home to approximately a million people in southwestern Washington and northwestern Oregon. Mount Rainier is an active volcano. It last erupted approximately 150 years ago, and numerous large floods and debris flows have been generated on its slopes during this century. More than 100,000 people live on the extensive mudflow deposits that have filled the rivers and valleys draining the volcano during the past 10,000 years. A major volcanic eruption or debris flow could kill thousands of residents and cripple the economy of the Pacific Northwest. Despite the potential for such danger, Mount Rainier has received little study. Most of the geologic work on Mount Rainier was done more than two decades ago. Fundamental topics such as the development, history, and stability of the volcano are poorly understood.

Source record↗
NASA NTRS1994

Ar-39-Ar-40 ages of four ureilites

Ureilites Novo Urei, Havero, and Kenna show strong evidence of one or more Ar-40 degassing events in the time period of 3.3-4.1 Ga ago. These ages may be compared to current interpretations of ureilite chronology. These include the suggestion of metasomatic activity on the parent body 3.7 Ga ago that reset some Sm-Nd ages and the suggestion that ureilites have experienced terrestrial contamination of several trace elements (including Pb and LREE), which makes suspect ages younger than approximately 4.5 Ga. Because the K-Ar chronometer can be sensitive to metamorphic events, we made Ar-39-Ar-40 determinations on bulk samples (0.12-0.14 g each) of four ureilites. The Ar-39-Ar-40 age spectra and K/Ca ratios as a function of cumulative Ar release from stepwise temperature extractions for the four ureilites analyzed are shown. Because Ar-39-Ar-40 ages shown by low and high temperature extractions may be suspect, we examined the intermediate temperature extractions. Although interpretation of these spectra is obviously uncertain, we believe that the most recent times of Ar degassing can be roughly inferred. These times are approximately 3.3 Ga for Havero, 3.3-3.7 Ga for Novo Urei, and approximately 4.1 Ga for Kenna, for which Ar degassing may not have been complete. The indication of Ar-39-Ar-40 degassing ages of 3.3-4.1 Ga for three ureilites that also contain an enhanced LREE component and (excepting Havero) produce a 3.74 Ga Sm-Nd age, suggests that both chronometers may have responded to the same parent body event. On the other hand, it is also possible that the Ar data reflect one or more separate events that did not strongly affect the Sm-Nd system, a situation that commonly occurs in eucrites. Thus the existence of reset Ar ages does not require similarly reset Sm-Nd ages.

Bogard, D. D.↗
NASA NTRS1994

Refurbishment of a 39 foot thermal vacuum chamber

The 39' thermal vacuum chamber at Space Systems/Loral has been used to test numerous spacecraft including those of the GOES, Intelsat, Insat, Superbird, N-Star, NATO and other programs. Ten years ago, the aluminum LN2 shroud experienced serious fatigue failures in the field welded jumper tubing, effectively shutting down the chamber for vacuum testing. The problem was repaired at the time, but new failures began to reappear a few months ago and are now occurring at a rate that suggests that the shroud may again become inoperable. Consequently, Space Systems/Loral is spending in excess of $6 million to replace the shroud and the existing LN2 equipment with a new, state of the art cryogenic system. In May, 1994, a contract was awarded to remove the existing shroud and LN2 pumping system and replace it with a gravity fed shroud and distribution system. Included in the contract are eight skid mounted gaseous nitrogen pumping systems capable of controlling shroud zone temperatures between +150 C and -180 C. The project is scheduled to be completed in April 1995.

Edwards, Arthur A.↗
NASA NTRS1994

Evidence signaling the start of enhanced counterjet flow in the symbiotic system R AquarII

The velocity struture of strong far-UV emission lines observed in the symbiotic variable R Aqr suggests the start of new jet activity which will probably culminate in the appearance of a series of intense nebular emission knots within a decade. This is indicated by a systematic redward wavelength drift of emission lines, which we have followed with the International Ultraviolet Explorer (IUE) since the discovery of the brilliant northeast jet emission knots more than 10 years ago. The C IV wavelengths 1548, 1550 resonance lines, which previously showed a prominent blue asymmetric wing that extended to velocities in excess -200 km/s, exhibit red wing asymmetry that extends to speeds of approximately +200 km/s in late 1992. The C IV line profile structure is consistent with the model proposed by Solf (1993), who explains the appearance of the northeast jet knots in terms of a approximately 300-500 km/s collimated wind that collides with slower moving material expelled earlier in a nova outburst that occurred approximately 190 yr ago. Based upon these high-resolution UV spectra, similar emission structues should appear southwest of the central star when the counterwind (or stream) interacts with material in the southwest inner nebula. The apparent change in direction of flow could result from a precessing accretion disk that alters the projection angle of collimated flow from the disk poles. The direction of the collimated wind may be related to the binary orbit, because the velocity shifts associated with emission lines formed in the flow change direction on a timescale which is comparable to the binary period.

Michalitsianos, A. G.↗
NASA NTRS1994

The distribution and nature of star formation regions in NGC 1792

A strong asymmetry with respect to the major axis has been found in the spatial distribution of H II regions in NGC 1792 detected on our H(alpha) image. In the radio continuum, this asymmetry is even stronger than in H(alpha), indicating that supernova activity set in earlier in the northeastern half of the disk than southwest of the nucleus. This suggests that we are viewing spatially propagating star formation (SF) in the disk, which set in about 10(exp 7) yr ago. The most luminous H II regions are distinctly different from the rest of the star-forming regions in NGC 1792, showing up as a peak in the H(alpha) luminosity near L(H(alpha)) approximately equals 3 x 10(exp 39) ergs/s. Around these giant H II regions large amounts of diffuse ionized gas are found, suggesting that this gas is heated by UV radiation escaping these regions. Attributing the radiation coming from the luminous H II regions to a temporarily increased level of SF activity, we estimate that on the order of 1200 OB stars were formed in each of them, with integrated Lyman-continuum luminosites in the range of 6 x 10(exp 51)/s. Although increased significantly near the galactic turnover of rotation, the global SF rate in NGC 1792 is only marginally affected (approximately 20%) by this phenomenon. The most plausible explanation of these results and those obtained for NGC 1808, the interaction partner of NGC 1792, is that the currently on-going SF was triggered by an interaction some 10(exp 8) yr ago.

Dahlem, Michael↗
NASA NTRS1994

Kupier prize lecture: Sources of solar-system carbon

We have tried to deconvolve Solar-System carbon into its sources, on the basis of C-12/C-13 ratios (equivalent to R). Interstellar SiC in meteorites, representing greater than 4.6-Ga-old stardust from carbon stars, is isotopically heavier (bar R = 38 +/- 2) than Solar-System carbon (89), implying that the latter contains an additional, light component. A likely source are massive stars, mainly Type II supernovae and Wolf-Rayet stars, which, being O-rich, eject their C largely as CO rather than carbonaceous dust. The fraction of such light C in the Solar System depends on R(sub light) in the source. For R(sub light) = 180-1025 (as in 'Group 4' meteoritic graphite spherules, which apparently came from massive stars greater than 4.6 Ga ago), the fraction of light C is 0.79-0.61. Similar results are obtained for present-day data on red giants and interstellar gas. Although both have become enriched in C-13 due to galactic evolution (to bar-R = 20 and 57), the fraction of the light component in interstellar gas again is near 0.7. (Here bar R represents the mean of a mixture calculated via atom fractions; it is not identical to the arithmetic mean R). Interstellar graphite, unlike SiC, shows a large peak at R approximately equal 90, near the solar value. Although some of the grains may be of local origin, others show anomalies in other elements and hence are exotic. Microdiamonds, with R = 93, also are exotic on the basis of their Xe and N. Apparently R approximately 90 was a fairly common composition 4.6 Ga ago, of stars as well as the ISM.

Anders, Edward↗
NASA NTRS1995

Blue lobes in the Hydra A cluster central galaxy

We present new U- and I-band images of the centrally dominant galaxy in the Hydra A cluster, obtained with the 2.5 m Isaac Newton Telescope at La Palma. The galaxy is centered in a poor, X-ray-luminous cluster whose gaseous intracluster medium is apparently cooling at a rate of m-dot(sub CF) approximately 3000 solar masses/yr. The galaxy's structure is that of a normal giant elliptical galaxy, apart from the central approximately 8 x 6 arcsec (approximately 12 x 9 kpc) region which contains an unusually blue, lobelike structure that is spatially coincident with a luminous emission-line nebula in rotation about the nucleus. Based on near spatial coincidence of the central continuum structure and the emission-line nebula, we suggest that the blue continuum is due to a warm stellar population in a central disk. In order to isolate and study the structure of the disk, we have subtracted a smooth galactic background model from the U-band image. The disk's surface brightness profiles along its major and minor axes decline roughly exponentially with radius. The disk's axial ratio is consistent with a nearly edge-on thick disk or a thin disk that is inclined with respect to the line of sight. The bluest regions, located a few arcsec on either side of the nucleus (giving the lobelike appearance), may be due to locally enhanced star formation or a seeing-blurred ring of young stars embedded in the disk observed nearly edge-on. If star-formation is occurring with the local initial mass function, the central color, surface brightness, and dynamical mass would be consistent with models for star formation at a rate of less than and approximately 1 solar masses/yr which has persisted for the past approximately 10(exp 9) yr, a short burst (10(exp 7) yr) of star formation at a rate of approximately 30 solar masses/yr which occurred less than and approximately 10(exp 8) yr ago, or an instantaneous burst of star formation which occurred approximately 5 x 10(exp 7) yr ago. While the young population contributes approximately 30%-40% of the central U-band luminosity, its mass would be less than and approximately 1% to less than and approximately 10% (10(exp 8) solar masses - 2 x 10(exp 9) solar masses of the galaxy's central dynamical mass. We consider a number of possible origins for the disk material.

Mcnamara, Brian R.↗
NASA NTRS1998

A Long-Term Space Astrophysics Research Program. An X-Ray Perspective of the Components and Structure of Galaxies

We present optical and archival X-ray data on the disturbed morphology radio elliptical NGC 1316 (Fornax A) that displays numerous low surface brightness shells, loops and tails. An extended (81x27 min or 9x3 kpc) emission line region (EELR) at a projected distance of 35 kpc from the nucleus has been discovered in a approximately 9Ox35 kpc, approximately 3.Ox1O(solar luminosity(B)) tidal tail. The position and extreme size of the EELR suggest it is related to the merger process. We suggest that the ionization mechanism of the EELR is shock excitation, and the gas is remnant from the merger progenitor. X-ray emission is detected near two tidal tails. Hot, approximately 5 x 10(exp 6)K gas is probably the predominant gas component in the tidal tail ISM. However based on the current tidal tail (cold + warm + hot) gas mass, a large fraction of the tidal tail progenitor gas may already reside in the nucleus of NGC 1316. The numerous and varied tidal tail system suggests that a disk-disk or disk-E merger could have taken place greater than or equal to 1 Gyr ago, whilst a low mass, gas rich galaxy started to merge approximately 0.5 Gyr ago.

Fabbiano, G.↗
NASA NTRS1995

Global Stratigraphy of Venus: Analysis of a Random Sample of Thirty-Six Test Areas

The age relations between 36 impact craters with dark paraboloids and other geologic units and structures at these localities have been studied through photogeologic analysis of Magellan SAR images of the surface of Venus. Geologic settings in all 36 sites, about 1000 x 1000 km each, could be characterized using only 10 different terrain units and six types of structures. These units and structures form a major stratigraphic and geologic sequence (from oldest to youngest): (1) tessera terrain; (2) densely fractured terrains associated with coronae and in the form of remnants among plains; (3) fractured and ridged plains and ridge belts; (4) plains with wrinkle ridges; (5) ridges associated with coronae annulae and ridges of arachnoid annulae which are contemporary with wrinkle ridges of the ridged plains; (6) smooth and lobate plains; (7) fractures of coronae annulae, and fractures not related to coronae annulae, which disrupt ridged and smooth plains; (8) rift-associated fractures; and (9) craters with associated dark paraboloids, which represent the youngest 1O% of the Venus impact crater population (Campbell et al.), and are on top of all volcanic and tectonic units except the youngest episodes of rift-associated fracturing and volcanism; surficial streaks and patches are approximately contemporary with dark-paraboloid craters. Mapping of such units and structures in 36 randomly distributed large regions (each approximately 10(exp 6) sq km) shows evidence for a distinctive regional and global stratigraphic and geologic sequence. On the basis of this sequence we have developed a model that illustrates several major themes in the history of Venus. Most of the history of Venus (that of its first 80% or so) is not preserved in the surface geomorphological record. The major deformation associated with tessera formation in the period sometime between 0.5-1.0 b.y. ago (Ivanov and Basilevsky) is the earliest event detected. In the terminal stages of tessera fon-nation, extensive parallel linear graben swarms representing a change in the style of deformation from shortening to extension were formed on the tessera and on some volcanic plains that were emplaced just after, and perhaps also during the latter stages of the major compressional phase of tessera emplacement. Our stratigraphic analyses suggest that following tessera formation, extensive volcanic flooding resurfaced at least 85% of the planet in the form of the presently-ridged and fractured plains. Several lines of evidence favor a high flux in the post-tessera period but we have no independent evidence for the absolute duration of ridged plains emplacement. During this time, the net state of stress in the lithosphere apparently changed from extensional to compressional, first in the form of extensive ridge belt development, followed by the formation of extensive wrinkle ridges on the flow units. Subsequently, there occurred local emplacement of smooth and lobate plains units which are presently essentially undefortned. The major events in the latest 10% of the presently preserved history of Venus (less than 50 m.y. ago) are continued rifting and some associated volcanism, and the redistribution of eolian material largely derived from impact crater deposits.

Basilevsky, Alexander T.↗
NASA NTRS1997

Ice in Channels and Ice-Rock Mixtures in Valleys on Mars: Did They Slide on Deformable Rubble Like Antarctic Ice Streams?

Recent studies of ice streams in Antarctica reveal a mechanism of basal motion that may apply to channels and valleys on Mars. The mechanism is sliding of the ice on deformable water-saturated till under high pore pressures. It has been suggested by Lucchitta that ice was present in outflow channels on Mars and gave them their distinctive morphology. This ice may have slid like Antarctic ice streams but on rubbly weathering products rather than till. However, to generate water under high pore pressures, elevated heatflow is needed to melt the base of the ice. Either volcanism or higher heatflow more than 2 b.y. ago could have raised the basal temperature. Regarding valley networks, higher heatflow 3 b.y. ago could have allowed sliding of ice-saturated overburden at a few hundred meters depth. If the original, pristine valleys were somewhat deeper than they are now, they could have formed by the same mechanism. Recent sounding of the seafloor in front of the Ross Ice Shelf in Antarctica reveals large persistent patterns of longitudinal megaflutes and drumlinoid forms, which bear remarkable resemblance to longitudinal grooves and highly elongated streamlined islands found on the floors of martian outflow channels. The flutes are interpreted to have formed at the base of ice streams during the last glacial advance. Additional similarities of Antarctic ice streams with martian outflow channels are apparent. Antarctic ice streams are 30 to 80 km wide and hundreds of kilometers long. Martian outflow channels have similar dimensions. Ice stream beds are below sea level. Carr determined that most common floor elevations of martian outflow channels lie below martian datum, which may have been close to or below past martian sea levels. The Antarctic ice stream bed gradient is flat and locally may go uphill, and surface slopes are exceptionally. Martian channels also have floor gradients that are shallow or go uphill locally and have low surface gradients. The depth to the bed in ice streams is 1 to 1.5 km. At bankful stage, the depth of the fluid in outflow channels was 1 to 2 km, according to the height of bordering scarps. The similarity between Antarctic ice streams and martian outflow channels suggests that ice may have flowed through and shaped the outflow channels, and that perhaps the mechanism of motion of Antarctic ice streams also operated in outflow channels. In addition, sliding on deformable rubble may explain the formation of small valley networks. The large Siple Coast Antarctic ice streams are thought to slide over longitudinally grooved, deforming till, where much of the movement is within the till. The till is saturated with water at high pore pressures that nearly supports all of the weight of the ice. The small differential between overburden pressure and pore pressure at the bed is more important than the volume of water, but water needs to be supplied to the till interface. For pore pressures to remain high, the ice streams have to act as a seal that blocks the flow of water through them, and the rock underneath has to be of low permeability to prevent the water from draining away.

Lucchitta, B. K.↗
NASA NTRS1998

Conjugate Observations of Optical Aurora with POLAR Satellite and Ground Based Imagers in Antarctica

Operation of the ultraviolet imager on the POLAR satellite permits the observation of Aurora Borealis in daylight during northern summer. With optical imagers in the Automatic Geophysical Observatories (AGO-s) large regions of the oval of Aurora Australis can be observed simultaneously during the southern winter polar night. This opportunity permits conducting a systematic study of the properties of auroras on opposite ends of the same field line. It is expected that simultaneously observed conjugate auroras occurring on closed field lines should be similar to each other in appearance because of the close connection between the two hemispheres through particle scattering and mirroring processes. On open or greatly distorted field lines there is no a priori expectation of similarity between conjugate auroras. To investigate the influence of different IMF conditions on auroral behavior we have examined conjugate data for periods of southward IMF. Sudden brightening and subsequent poleward expansions are observed to occur simultaneously in both hemispheres. The POLAR data show that sudden brightening are initiated at various local time regions. When the local time of this region is in the field of view of the AGO station network then corresponding brightening is also found to occur in the southern hemisphere. Large features such as substorm induced westward propagation and resulting auroral brightening seem to occur simultaneously on conjugate hemispheres. The widely different view scales make it difficult to make unique identification of individual auroral forms in the POLAR and in the ground based data but in a general sense the data is consistent with conjugate behavior.

Mende, S. H.↗
NASA NTRS1998

General Public Space Travel and Tourism: Executive Summary - Volume 1

Travel and tourism is one of the world's largest businesses. Its gross revenues exceed $400 billion per year in the U.S. alone, and it is our second largest employer. U.S. private sector business revenues in the space information area now approximate $10 billion per year, and are increasing rapidly. Not so in the human spaceflight area. After spending $100s of billions (1998 dollars) in public funds thereon, and continuing to spend over $5 billion per year, the government is still the only customer for human spaceflight goods and services. Serious and detailed consideration was first given to the possibility of space being opened up to trips by the general public three decades ago, and some initial attempts to do so were made a dozen years ago. But the difficulties were great and the Challenger disaster put an end to them. In recent years professional space tourism studies have been conducted in the United Kingdom, Germany and, especially, Japan. In the U.S., technological progress has been pronounced; we have had nearly a decade's experience in seeing our astronauts travel to-from low Earth orbit (LEO) safely, and we expect to commence assembly of a LEO space station housing a half-dozen people this year. Too, NASA and our space industry now have new and promising space transportation development programs underway, especially the X-33 and X-34 programs, and some related, further generation, basic technology development programs. And five private companies are also working on the design of new surface - LEO vehicles. The first professional space tourism market studies have been conducted in several countries in the past few years, especially in Japan and here. The U.S. study makes it clear that, conceptually, tens of millions of us would like to take a trip to space if we could do so with reasonable safety, comfort and reliability, and at an acceptable price. Initial businesses will address the desires of those willing to pay a greater price and accept a greater risk. A two-year cooperative Space Act agreement study has been conducted by our National Aeronautics and Space Administration and the Space Transportation Association. It was conducted by NASA and STA study leaders drawing upon the competence, experience and hard-nosed imagination of a national Steering Group and scores of attendees at a multi-day Workshop. The study has involved scores of professionals and business people from various areas: astronauts; space booster technology and operations professionals; a hotel architect and a hotel operator; an airline planner; insurance underwriters; space sickness experts; space theme park designers; space and travel and tourism association and business executives; a space-related financier; university tourism and space policy experts; present and former space-responsible government officials; space entrepreneurs; space writers; This study concludes that serious national attention should now be given to activities that would enable the expansion of today's terrestrial space tourism businesses, and the creation of in-space travel and tourism businesses. Indeed, it concludes that, in time, it should become a very important part of our Country's overall commercial and civil space business-program structure.

ONeil, Daniel↗
NASA NTRS2000

Noble Gases in Iddingsite from the Lafayette Meteorite: Evidence for Liquid Water on Mars in the Last Few Hundred Million Years

We analyzed noble gases from 18 samples of weathering products ("iddingsite") from the Lafayette meteorite. Potassium-argon ages of 12 samples range from near zero to 670 +/- 91 Ma. These ages confirm the martian origin of the iddingsite, but it is not clear whether any or all of the ages represent iddingsite formation as opposed to later alteration or incorporation of martian atmospheric Ar-40. In any case, because iddingsite formation requires liquid water, this data requires the presence of liquid water near the surface of Mars at least as recently as 1300 Ma ago, and probably as recently as 650 Ma ago. Krypton and Xe analysis of a single 34 microg sample indicates the presence of fractionated martian atmosphere within the iddingsite. This also confirms the martian origin of the iddingsite. The mechanism of incorporation could either be through interaction with liquid water during iddingsite formation or a result of shock implantation of adsorbed atmospheric gas.

Swindle, T. D.↗
NASA NTRS1999

Measuring Greenland Ice Mass Variation With Gravity Recovery and the Climate Experiment Gravity and GPS

The response of the Greenland ice sheet to climate change could significantly alter sea level. The ice sheet was much thicker at the last glacial maximum. To gain insight into the global change process and the future trend, it is important to evaluate the ice mass variation as a function of time and space. The Gravity Recovery and Climate Experiment (GRACE) mission to fly in 2001 for 5 years will measure gravity changes associated with the current ice variation and the solid earth's response to past variations. Our objective is to assess the separability of different change sources, accuracy and resolution in the mass variation determination by the new gravity data and possible Global Positioning System (GPS) bedrock uplift measurements. We use a reference parameter state that follows a dynamic ice model for current mass variation and a variant of the Tushingham and Peltier ICE-3G deglaciation model for historical deglaciation. The current linear trend is also assumed to have started 5 kyr ago. The Earth model is fixed as preliminary reference Earth model (PREM) with four viscoelastic layers. A discrete Bayesian inverse algorithm is developed employing an isotropic Gaussian a priori covariance function over the ice sheet and time. We use data noise predicted by the University of Texas and JPL for major GRACE error sources. A 2 mm/yr uplift uncertainty is assumed for GPS occupation time of 5 years. We then carry out covariance analysis and inverse simulation using GRACE geoid coefficients up to degree 180 in conjunction with a number of GPS uplift rates. Present-day ice mass variation and historical deglaciation are solved simultaneously over 146 grids of roughly 110 km x 110 km and with 6 time increments of 3 kyr each, along with a common starting epoch of the current trend. For present-day ice thickness change, the covariance analysis using GRACE geoid data alone results in a root mean square (RMS) posterior root variance of 2.6 cm/yr, with fairly large a priori uncertainties in the parameters and a Gaussian correlation length of 350 km. Simulated inverse can successfully recover most features in the reference present-day change. The RMS difference between them over the grids is 2.8 cm/yr. The RMS difference becomes 1.1 cm/yr when both are averaged with a half Gaussian wavelength of 150 km. With a fixed Earth model, GRACE alone can separate the geoid signals due to past and current load fairly well. Shown are the reference geoid signatures of direct and elastic effects of the current trend, the viscoelastic effect of the same trend starting from 5 kyr ago, the Post Glacial Rebound (PGR), and the predicted GRACE geoid error. The difference between the reference and inverse modeled total viscoelastic signatures is also shown. Although past and current ice mass variations are allowed the same spatial scale, their geoid signals have different spatial patterns. GPS data can contribute to the ice mass determination as well. Additional information is contained in the original.

Wu, Xiao-Ping↗
NASA NTRS2000

Massive Star Formation in NGC4038/4039: HII Regions and Supernova Remnants in "The Antennae"

The nearest merger, NGC4038/4039 ("The Antennae, Arp244), is undergoing a starburst apparently triggered and driven by the ongoing interaction. The system provides an excellent laboratory to study star formation processes because well-studied and nearby (21 Mpc assumed here). Models of the interaction suggest that the interaction's first periapse occurred 200 Myr ago, and that final coalescence will occur in another 100 Myr. Blue and H alpha images show a continuous loop of bright knots around the NGC4038 (northern) nucleus, continuing down through the NGC4039 (southern) nucleus. Recent HST V and I images resolve the star-forming knots into several thousand blue compact clusters, with ages 5Myr for the youngest clusters. Far Ultraviolet (lambda 1500A) observations directly detect O and B stars in regions of low extinction; the total mass of young stars so observed is approximately 8 x 10 (exp 5) solar mass. FIR observations imply a star formation rate of approximately 5 M (sub 0) dot yr (sup -1) or greater. We used the VLA at 6 and 4 cm to obtain high resolution radio images of the star-formation regions in NGC4038/4038. We used high resolution imaging to identify compact radio emitting regions and spectral indices of the compact regions to differentiate between thermal sources such as HII regions (flat spectra) and supernova, remnants (steep spectra). We found that compact radio sources produce approximately 12% and/sim 25 strongest radio emission occurs between the galaxies, at an optically unremarkable location near but not coincident with an extremely red cluster. The radio peak is at a location of intense star formation (as detected in the mid-IR, reference?) and of dense molecular gas. We identify 115 individual compact 6cm radio sources and 63 individual 4 cm sources in the system, to a limiting luminosity of approximately 2 x 10 (exp 1) 8 W Hz (sup -1) (or /sim4x the luminosity of Cas A). Of the strongest sources, for which the h flux densities are large enough to measure spectral indices with reasonable errors, we find that one third have nominally flat radio spectra (presumeable dominated by thermal emission from HII regions) and two thirds have nominally steep spectra (presumeably dominated by synchrotron emission from supernova, remnants). For the thermal sources, we derive typical masses of 10 (exp 4) to 10 (exp 5) solar mass in massive young stars and ionized gas masses of 10 (exp 3) - 10 (exp 4) solar mass. From the steep-spectrum sources, we derive a total system supernova rate of 0.2-0.3 yr (sup -1), about an order of magnitude larger than that expected from the currently observed O-star population. Taken together, these suggest that that a large number of O stars may have formed in the system in a short-lived burst, less than 10 (exp 6) yr in duration and about 3-4 Myr ago.

Neff, S. G.↗
NASA NTRS2000

Lead-Free Double-Base Propellant for the 2.75 Inch Rocket Motor

The current MK 66 2.75 inch Rocket Motor double-base propellant contains the lead-based ballistic modifier LC-12-15 to achieve the desired plateau and mesa burning rate characteristics. The use of lead compounds poses a concern for the environment and for personal safety due to the metal's toxic nature when introduced into the atmosphere by propellant manufacture, rocket motor firing, and disposal. Copper beta-resorcylate (copper 2,4-di-hydroxy-benzoate) was successfully used in propellant as a simple modifier in the mid 1970's. This and other compounds have also been mixed with lead salts to obtain more beneficial ballistic results. Synthesized complexes of lead and copper compounds soon replaced the mixtures. The complexes incorporate the lead, copper lack of organic liquids, which allows for easier propellant processing. About ten years ago, the Indian Head Division, Naval Surface Warfare Center (NSWC), initiated an effort to develop a lead-free propellant for use in missile systems. Several lead-free propellant candidate formulations were developed. About five years ago, NSWC, in conjunction with Alliant Techsystems, Radford Army Ammunition Plant, continued ballistic modifier investigations. A four component ballistic modifier system without lead for double-base propellants that provide adequate plateau and mesa burn rate characteristics was developed and patented. The ballistic modifier's system contains bismuth subsalicylate, 1.5 percent; copper salicylate, 1.0 percent, copper stannate, 0.77 percent; and carbon black, 0.1 percent. Action time and impulse data obtained through multiple static firings indicate that the new lead-free double-base propellant, while not a match for NOSIH-AA-2, will be a very suitable replacement in the 2.75 inch Rocket Motor. Accelerated aging of the double-base propellant containing the lead-free ballistic modifier showed that it had a much higher rate of stabilizer depletion than the AA-2. A comprehensive study showed that an increased rate of stabilizer depletion occurred in propellants containing monobasic copper salicylate. The study also showed that propellants containing a mixture of bismuth subsalicylate and copper salicylate, had only about one-half the stabilizer depletion rate than those with copper salicylate alone. The copper salicylate catalyzes the decomposition of nitroglycerin, which triggers a chain of events leading to the increased rate of stabilizer depletion. A program has been initiated to coat the ballistic modifier, thus isolating it from the nitroglycerin.

Magill, B. T.↗