SEARCH · Engineering Papers

Results for “zeolite”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

SourceResearch connectionFrom yearThrough year

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 199 records · Page 11

All sources NASA NTRS DOE OSTI

NASA NTRS2016

Ceres Revealed in a Grain of Salt

Introduction: Zag and Monahans (1998) are H chondrite regolith breccias containing 4.5 giga-year-old halite crystals which contain abundant inclusions of aqueous fluids, solids and organics. These all originated on a cryo-volcanically-active C class asteroid, probably 1 Ceres; the halite was transported to the regolith of the H chondrite parent asteroid, potentially 6 Hebe. Detailed analysis of these solids will thus potentially reveal the mineralogy of Ceres. Mineralogy of solids in the Monahans Halite Solid grains are present in the halites, which were entrained within the mother brines during eruption, including material from the interior and surface of the erupting body. The solids include abundant, widely variable organics that could not have been significantly heated (which would have resulted in the loss of fluids from the halite). Our analyses by Raman microprobe, SEM/EDX, synchrotron X-ray diffraction, UPLC-FD/QToF-MS, C-XANES and TEM reveal that these trapped grains include macromolecular carbon (MMC) similar in structure to CV3 chondrite matrix carbon, aliphatic carbon compounds, olivine (Fo99-59), high- and low-Ca pyroxene, feldspars, phyllosilicates, magnetite, sulfides, metal, lepidocrocite, carbonates, diamond, apatite and zeolites. Conclusions: The halite in Monahans and Zag derive from a water and carbon-rich object that was cryo-volcanically active in the early solar system, probably Ceres. The Dawn spacecraft found that Ceres includes C chondrite materials. Our samples include both protolith and aqueously-altered samples of the body, permitting understanding of alteration conditions. Whatever the halite parent body, it was rich in a wide variety of organics and warm, liquid water at the solar system's dawn.

Zolensky, M. E.↗

NASA NTRS2016

Sorbent Structural Testing on Carbon Dioxide Removal Sorbents for Advanced Exploration Systems

Long term space missions require carbon dioxide removal systems that can function with minimal downtime required for maintenance, low power consumption and maximum efficiency for CO2 removal. A major component of such a system are the sorbents used for the CO2 and desiccant beds. Sorbents must not only have adequate CO2 and H2O removal properties, but they must have the mechanical strength to prevent structural breakdown due to pressure and temperature changes during operation and regeneration, as well as resistance to breakdown due to moisture in the system from cabin air. As part of the studies used to select future CO2 sorbent materials, mechanical tests are performed on various zeolite sorbents to determine mechanical performance while dry and at various humidified states. Tests include single pellet crush, bulk crush and attrition tests. We have established a protocol for testing sorbents under dry and humid conditions, and previously tested the sorbents used on the International Space Station carbon dioxide removal assembly. This paper reports on the testing of a series of commercial sorbents considered as candidates for use on future exploration missions.

Watson, David↗

NASA NTRS2016

Application of the Molecular Adsorber Coating Technology on the Ionospheric Connection Explorer Program

The Molecular Adsorber Coating (MAC) is a zeolite based highly porous coating technology that was developed by NASA Goddard Space Flight Center (GSFC) to capture outgassed contaminants, such as plastics, adhesives, lubricants, silicones, epoxies, potting compounds, and other similar materials. This paper describes the use of the MAC technology to address molecular contamination concerns on NASAs Ionospheric Connection Explorer (ICON) program led by the University of California (UC) Berkeleys Space Sciences Laboratory. The sprayable paint technology was applied onto plates that were installed within the instrument cavity of ICONs Far Ultraviolet Imaging Spectrograph (FUV). However, due to the instruments particulate sensitivity, the coating surface was vibrationally cleaned through simulated acoustics to reduce the risk of particle fall-out contamination. This paper summarizes the coating application efforts on the FUV adsorber plates, the simulated laboratory acoustic level cleaning test methods, particulation characteristics, and future plans for the MAC technology.

outgassing↗

NASA NTRS2016

The Use of the Molecular Adsorber Coating Technology to Mitigate Vacuum Chamber Contamination During Pathfinder Testing for the James Webb Space Telescope

As a coating made of highly porous zeolite materials, the Molecular Adsorber Coating (MAC) was developed to capture outgassed molecular contaminants, such as hydrocarbons and silicones. For spaceflight applications, the adsorptive capabilities of the coating can alleviate on-orbit outgassing concerns on or near sensitive surfaces and instruments within the spacecraft. Similarly, this sprayable paint technology has proven to be significantly beneficial for ground based space applications, in particular, for vacuum chamber environments. This paper describes the recent use of the MAC technology during Pathfinder testing of the Optical Ground Support Equipment (OGSE) for the James Webb Space Telescope (JWST) at NASA Johnson Space Center (JSC). The coating was used as a mitigation tool to entrap persistent outgassed contaminants, specifically silicone based diffusion pump oil, from within JSC's cryogenic optical vacuum chamber test facility called Chamber A. This paper summarizes the sample fabrication, installation, laboratory testing, post-test chemical analysis results, and future plans for the MAC technology, which was effectively used to protect the JWST test equipment from vacuum chamber contamination.

molecular contamination↗

NASA NTRS2017

Investigation of Desiccants and CO2 Sorbents for Exploration Systems 2016-2017

NASA has embarked on the mission to enable humans to explore deep space, including the goal of sending humans to Mars. This journey will require significant developments in a wide range of technical areas as resupply and early return are not possible. Additionally, mass, power, and volume must be minimized for all phases to maximize propulsion availability. Among the critical areas identified for development are life support systems, which will require increases in reliability as well as reduce resource usage. Two primary points for reliability are the mechanical stability of sorbent pellets and recovery of CO2 sorbent productivity after off-nominal events. In this paper, we discuss the present efforts towards screening and characterizing commercially-available sorbents for extended operation in desiccant and CO2 removal beds. With minimized dusting as the primary criteria, a commercial 13X zeolite was selected and tested for performance and risk.

Knox, James C.↗

NASA NTRS2016

Performance of Silica Gel in the Role of Residual Air Drying. Part II.

Removal of carbon dioxide (CO2) is a necessary step in air revitalization and is often accomplished with sorbent materials. Since moisture competes with CO2 in zeolite sorbent materials, it is necessary to remove the water first. This is typically accomplished in two stages: “bulk” removal and “residual” drying. Silica gel is used as the bulk drying material in the Carbon Dioxide Removal Assembly (CDRA) in operation on the ISS (International Space Station). There has been some speculation that silica gel may also be capable of serving as both bulk and residual drying material to reduce system mass and Foreign Object Debris (FOD). Previous research tested silica gel alone as drying material. However, the silica gel volume used was not comparable to the current amount used on the CDRA. Therefore, the tests were repeated with the new silica gel volume. This paper discusses the fabrication and assembly of the modified canister to accommodate the new volume, the testing, and the evaluation of the test results.

Air Revitalization↗

NASA NTRS2019

Organic Compounds in Early Solar System Aqueous Fluids

thermally-metamorphosed ordinary chondrite regolith breccias (Monahans 1998, hereafter simply “Monahans” ( 5) and Zag (H3-6)) contain fluid inclusion-bearing halite (NaCl) crystals dated to be ~4.5 billion years old. Thus, compositional data on fluid inclusions in these halites will reveal unique information regarding the origin and activity of aqueous fluids in the early solar system, and especially their interactions with organic mate- rial. Our initial analyses of solid inclusions in Monahans halite has shown the presence of olivine, high- and low- Ca pyroxene, feldspars, magnetite, sulfides, phyllosilicates, zeolites, metal, phosphates and abundant organics. We age of carbon, carbonates and organics in these residues, and low but significant amino acids concentrations in Monahans and Zag halite.

Bodnar, R. J.↗

NASA NTRS2019

Experimental Configuration and Preliminary Results of Testing a Rapid Cycle Adsorption Pump for Martian CO2 Acquisition

Temperature-swing adsorption pumps have been proposed as a method of acquiring and compressing Martian atmospheric CO2 for downstream processing. Most industrial applications and previous research targeted at space in-situ resource utilization (ISRU) utilize long (~hours) temperature swing periods, typically limited by the ability to transfer heat from a naturally insulating sorbent bed. A rapid cycle adsorption pump (RCAP) would reduce these periods to minutes, in the hope of increasing overall throughput. This paper details the design and preliminary experimental results from testing an RCAP in a simulated Martian environment. The test configuration features a central, liquid-cooled and heated heat transfer plate surrounded by symmetrical rectangular sorbent beds. Various bed thicknesses and commercially available Zeolite 13X sorbent particle sizes are evaluated to both determine performance and provide data for a parallel modeling effort. Discussions of multi-stage configurations and methods of boosting bed conductivity are included.

Berg, Jared↗

NASA NTRS2019

Experimental Design and Preliminary Analysis of a Mars CO2 Rapid Cycle Adsorption Pump

Rapid Cycle Adsorption↗

NASA NTRS2020

NASA Exploration Systems & Habitation (X-Hab)Academic Innovation Challenge 2020: Microgravity Gas/Liquid Separator for the CO2 Revitalization System Final Report

This report outlines the efforts of UNT X-Hab Team on a project titled, Microgravity Gas/Liquid Separator for the CO2 Revitalization System. The project is executed as a senior design project during academic year 2019-2020. The X-Hab 2020 Academic Innovation Challenge has selected eleven senior design teams from colleges across the US to demonstrate working prototypes for exploration systems and habitation. UNT has been tasked with the creation of a gas-liquid separator for an air revitalization system. Air revitalization technology has been used to support spaceflight by removing CO2 from enclosed systems in order to maintain breathable air. Solid sorbents such as zeolites or lithium hydroxide have been used in the past for these systems but are difficult to handle in microgravity environments and require a large amount of energy. This challenge aims to demonstrate vortex phase separator (VPS) technology for removing H2O from a CO2 stream. However, VPS technology also has the capability of using liquid sorbents for removing CO2 from an air stream. Further research could be done on liquid sorbents, such as liquid amine, in use with VPS systems. This would potentially be an alternative technology in replacing use of solid sorbents in CO2 removal systems. In 2019, NASA proposed a design that uses a gas/liquid contactor to allow for efficient contact between the two fluid phase. This was integrated into an overall CO2 removal system. The subsystems for gas-liquid separation and storage in NASA’s previous models for CO2 removal system could be replaced with a VPS. Innovative vortex separator technology is expected to allow for high throughput flow and highly efficient CO2 removal compared to other gas-liquid separation technologies. VPS relies on centripetal driven buoyancy forces to form a gas-liquid vortex within a fixed, right circular cylinder. The gas stream enters the separator through a tangential nozzle and breaks into very small bubbles (<<1 mm) resulting in a very large contact surface area for interaction with the liquid stream via energy and mass exchange. VPS technology can handle mismatches in inlet and outlet flow rates and system volume changes through the range of liquid thickness held in the separator (i.e., buffering and accumulating capability), and requires low pressure differences (<5-10 in H2O in most cases) for operation. The X-Hab 2020 team leverages these characteristics to investigate VPS technology as an alternative CO2 removal technology.

Alyssa Sarvadi↗

NASA NTRS2021

Analytical Methods and Testbeds for Characterizing Adsorbents and Catalysts for Atmosphere Revitalization of Crewed Spacecraft

Spacecraft environmental control and life support systems (ECLSS) include a number of air revitalization (AR) technologies to provide breathable air and a comfortable living environment to the crew. Crew health and comfort is ensured by controlling human produced CO2 (1 kg person-1 day-1) and water vapor (~2 kg person-1 day-1), and by removing trace contaminants (TCs) from cabin air. These life support functions on-board the International Space Station (ISS) are carried out by the Carbon Dioxide Removal Assembly (CDRA), the Water Processor Assembly (WPA), and the trace contaminant control system (TCCS). During the development of the TCCS, new analytical and theoretical methods were developed in the 1970s for characterizing adsorption and desorption characteristics of activated carbons for the purpose of designing suitable AR technologies required for controlling airborne trace contaminants within spacecraft cabins during long exploration missions. The TCCS removes harmful volatile organic compounds and other trace contaminants from the circulating air. It consists of a granular activated carbon (GAC) bed for the removal of high molecular weight contaminants and ammonia followed by a heated catalytic bed for low molecular weight hydrocarbons. The high temperature catalytic oxidizer (HTCO) of the TCCS, which operates at 400°C and requires 120W average power, removes low molecular weight compounds such as carbon monoxide (CO), formaldehyde (CH2O), and methane (CH4), that pass through the GAC bed. The Air Revitalization Laboratory at the Kennedy Space Center (KSC) was established to develop new analytical methods for evaluating emerging ECLSS technologies for use in future AR architectures. General properties of adsorbents and catalysts are required for trace contaminant control system design calculations and vendor-supplied data are seldom available at relevant process conditions of interest to spacecraft cabin applications. To address this shortcoming, appropriate testbeds were developed to measure the desired properties of AR technologies being considered for use in ECLS architectures. Generally, the testbeds developed at KSC challenge the test media (activated carbon, impregnated activated carbon, catalysts, zeolites, solid amines, or pleated filters) with simulated spacecraft gas streams containing representative mixtures of trace contaminants (volatile organic compounds, ammonia, CO, CO2, or siloxanes) at the flow rates, temperatures, and relative humidity that will be encountered within manned spacecraft. Work performed at KSC funded by NASA’s Advanced Exploration (AES) Program has included: Identifying candidate sorbents to replace commercially obsolete impregnated carbons for NH3 control within the TCCS, characterizing their adsorptive capacities using simulated spacecraft gas streams, and ranking their appropriateness in various AR applications; evaluating novel low temperature catalysts for controlling CO and formaldehyde by traditional and photocatalytic methods for trace contaminant control; development of analytical methods to assess regenerable solid amine performance for CO2 control via pressure swing adsorption. The Air Revitalization lab was also funded to study trace contaminant control by other NASA programs. These include: screening of candidate sorbents for the design of new Charcoal HEPA Integrated Particle Scrubber (CHIPS) filters for removing siloxanes from cabin air; characterizing the performance of an impregnated activated carbon at low humidity for use in ORION ECLS; screening of sorbents for protecting the Sabatier 2.0 catalyst from DMSO2, siloxanes, NH3, and solid amine byproducts.

Monje, Oscar↗

NASA NTRS2022

Sub-Scale Adsorption and Compression CO2 Removal System Re-Design

This system is a re-design of NASA’s previously developed Thermally Coupled Temperature Swing Adsorption and Compression (TC-TSAC) systems, providing an air revitalization alternative to assist in the agency’s Moon to Mars exploration objectives. The system consists of two half-cycles whereby packed beds of regenerable bulk sorbents and heat cycles simultaneously adsorb and compress carbon dioxide. The team designed the adsorption and compression beds in a cylindrical shape to maximize airflow. A desiccant bed helps lower humidity and the sorbent Zeolite 13X is used to capture carbon dioxide. Both are monitored by sensors. There is a custom heater within the system that lies in the adsorption bed to regenerate the sorbent, and there is a cooler around the compression bed. The system produced for NASA modeling, experimental test results, and operational results to be able to be scaled up to 4kg CO2 removal per day. The system was found to be 1/16 scale for 1kg of CO2 removal per day. The adsorption and desorption processes were successful, however issues with making the compression bed airtight resulted in an inability to demonstrate full compression. The team provided design suggestions and alternative solutions given these results. This paper describes the final design, fabrication, assembly, and testing of the TC-TSAC re-design.

Joaquin Pesqueira↗

NASA NTRSDate not supplied

Magma-Sediment Interaction Induced Alteration Mineralogy on Mars: Detectability and Analytical Method Comparison Using the Curtis Sandstone as A Terrestrial Analog

Basaltic magmatism is a ubiquitous feature of the Martian crust, and would have interacted with sediments and fluids through the geologic history of Mars to potentially produce higher temperature hydrothermal systems , and contact metamorphic rocks. On Earth, comparable hydrothermal systems represent habitable environments, which can be used as an analog for Mars. Nevertheless, evidence of aforementioned hydrothermal systems on Mars has remained elusive, despite the efforts of both orbital and in-situ analyses. Limited low grade metamorphic minerals typically indicative of hydrothermal systems (prehnite, zeolites, serpentine) have been detected in the Martian crust, though the detections are typically isolated occurrences, and do not necessarily indicate an in-place metamorphic sequence. It is possible that orbital spectroscopy alone is not capable of detecting such an alteration front, with higher resolution in-situ analyses being required to detect the changes in mineralogy and species of alteration minerals associated with magma-sediment interaction. To constrain this, we have investigated a terrestrial analog on the Colorado Plateau, USA, where a mafic dike intrudes a quartz areinite of the Jurassic Curtis Sandstone. The investigation was carried out using Mars relevant instruments: Visible to Near-Infrared (VNIR) spectroscopy analogous to orbital spectroscopy, and X-ray Diffraction (XRD) analogous to CheMin on Mars Sample Laboratory Curiosity. While quartz sandstones have not been, and are unlikely to be, detected on Mars, the relatively mineralogically uniform Curtis Sandstone serves as analog here as it avoids complications of multiple mineral systems or significant element exchange with the surrounding area.

J R Crandall↗

NASA NTRS2023

An evolutionary system of mineralogy, Part VI: Earth’s earliest Hadean crust (> 4370 Ma)

Part VI of the evolutionary system of mineralogy catalogs 262 kinds of minerals, formed by 18 different processes, that we suggest represent the earliest solid phases in Earth’s crust. All of these minerals likely formed during the first tens of millions of years following the global-scale disruption of the Moon-forming impact prior to ~4.4 Ga, though no samples of terrestrial minerals older than ~4.37 Ga are known to have survived on Earth today. Our catalog of the earliest Hadean species includes 80 primary phases associated with ultramafic and mafic igneous rocks, as well as more than 80 minerals deposited from immiscible S-rich fluids and late-stage Si-rich residual melts. Earth’s earliest crustal minerals also included more than 200 secondary phases of these primary minerals that were generated by thermal metamorphism, aqueous alteration, impacts, and other processes. In particular, secondary mineralization related to pervasive near-surface aqueous fluids may have included serpentinization of mafic and ultramafic rocks, hot springs and submarine volcanic vent mineralization, hydrothermal sulfide deposits, zeolite and associated mineral formation in basaltic cavities, marine authigenesis, and hydration of subaerial lithologies. Additional Hadean minerals may have formed by thermal metamorphism of lava xenoliths, sublimation at volcanic fumaroles, impact processes, and volcanic lightning. These minerals would have occurred along with more than 180 additional phases found in the variety of meteorites that continuously fell to Earth’s surface during the early Hadean Eon.

Philosophy of mineralogy↗

NASA NTRS2023

Closed Environment Air Revitalization System Based on Metal Organic Framework Adsorbents

This project utilized a systems engineering methodology to develop a vacuum swing adsorption system with full Labview automated control. The project was successful and provided students with an introduction to systems engineering and air revitalization. Specifically, two stainless steel adsorption beds were custom designed and manufactured and a sequence of computer controlled valves were used to deliver CO 2 laden, humid air, to the adsorbent where the CO 2 was removed from the air stream. Runs were completed using 13X zeolite and bed timing and switching was controlled by the computer based on the data output of a CO 2 detector. Adsorption runs using the MOF have not been completed upon the writing of this report; however, the MOF material is currently being synthesized and the runs will be completed upon receipt of the material. A follow up meeting with NASA has been tentatively planned to discuss the output of these experiments. Consistent with systems engineering practice, an end of project assessment of the class was conducted with the students and several items were realized. Specifically, the short period of performance of this grant makes it necessary to maintain a narrowly focused scope on the project such that multiple experiments after systems development (T&E) need to be limited to ensure timely completion of the proposed tasks. Also, procurement of parts may need to be moved forward in time to allow for delivery delays, and it may be necessary to request SDR, PDR, and CDR dates from NASA that are ahead of the NASA anticipated schedule. These types of lessons provided valuable to both the PI and the students and ultimately illustrate the necessity of proper systems engineering schedule risk assessment. The class met the objectives of the project and provided an introduction to systems engineering to undergraduate students. As a metric of that success, the lead engineer of the undergraduate design team acquired a job with an aerospace defense contractor, which he attributed to his knowledge of systems engineering concepts that were acquired via the X-Hab class.

T. Grant Glover↗

NASA NTRS2015

MARS - Multi-component Adsorption Recirculation System

Goals - Measure carbon dioxide adsorption isotherms on 13X zeolite - Measured using a volumetric method - Injected CO2 is adsorbed and measured using the pressure loss and the ideal gas law to attribute the pressure loss to moles of adsorbed CO2.

Jack Cunningham↗

NASA NTRSDate not supplied

Using Mineralogy to Interpret Martian Geologic History

The surface mineralogy of Mars is key to interpreting the planet’s geologic history and constraining when and where Mars may have been habitable to microbial life. Orbital mineralogical data from infrared spectrometers collected over the last two decades have demonstrated that Mars is more than a basaltic planet. Thermal infrared (TIR) emission spectrometers have identified regional variations in igneous minerals, iron oxides, and chloride salts, showing evidence for magmatic evolution and aqueous alteration. Orbital visible/shortwave infrared reflectance spectra provide detailed information about the aqueous history of Mars through the identification of clay minerals, sulfates, carbonates, zeolites, and amorphous materials in ancient ~3-4-billion-year-old terrains. Mineralogical data from rovers allow us to better characterize mineral formation mechanisms by identifying mineral assemblages and placing them in geologic context using outcrop- to grain-scale images. TIR and Mössbauer data from the Mars Exploration Rovers helped identify an ancient dune-interdune playa environment with multiple episodes of groundwater at Meridiani Planum and volcanism-induced hydrothermalism at Gusev crater. The CheMin X-ray diffractometer on the Mars Science Laboratory Curiosity rover in Gale crater is the first fully quantitative mineralogical instrument sent to another planetary surface. CheMin data allow the quantification of minerals and X-ray amorphous materials with a mineral detection limit of <1 wt.% and provide crystal chemistry of major phases from refined unit-cell parameters. CheMin has revealed local mineralogical changes in ancient sedimentary rocks not seen from orbit and helped identify habitable environments. Throughout the 600+ m of vertical stratigraphy studied so far, changes in clay mineralogy, Fe-oxides/oxyhydroxides, sulfates, and carbonates demonstrate a long history of surface and groundwater at Gale crater with variable salinity, pH, Eh, and temperature. Recent CheMin data document a decrease in clay minerals and an increase in sulfate minerals in younger strata that corresponds with a change from fluvio-lacustrine to eolian depositional environments, potentially documenting a change to a drier climate across the planet.

E. B. Rampe↗

NASA NTRSDate not supplied

Measuring Titanium Heat Pipe Thermal Conductivity for CO2 Adsorption Systems

Current models of the Air-Cooled Temperature Swing Adsorption Compressor (AC-TSAC) being developed for long duration space exploration utilize cooling chambers and heat plates to adsorb and desorb contaminants -13 . To reduce resources required and lower the equivalent system mass (ESM), the study focuses on determining the applications of titanium heat pipe systems to operate both phases, allowing for future research into the development of a heat pipe chamber to hold the zeolite formulations.

multifunctional sorbent↗