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At least 199 records · Page 11

Detection of Sub-Surface Water on Mars by Controlled and Natural Source Electromagnetic Induction

Detection of subsurface liquid water on Mars is a leading scientific objective for Mars exploration in this decade. We describe electromagnetic induction (EM) methods that are both uniquely well suited for detection of subsurface liquid water on Mars and practical within the context of a Mars exploration program. EM induction methods are ideal for detection of more highly conducting (liquid water bearing) soils and rock beneath a more resistive overburden. A combined natural source and controlled source method offers an efficient and unambiguous characterization of the depth to liquid water and the extent of the aqueous region. The controlled source method employs an ac vertical dipole source (horizontal loop) to probe the depth to the conductor and a natural source method (gradient sounding) to characterize its conductivity-thickness product. These methods are proven in geophysical exploration and can be tailored to cope with any reasonable Mars crustal electrical conductivity. We describe a practical experiment and discuss experiment optimization to address the range of material properties likely encountered in the Mars crust.

Connerney, J. E. P.↗

Design of Advanced Atmospheric Water Vapor Differential Absorption Lidar (DIAL) Detection System

The measurement of atmospheric water vapor is very important for understanding the Earth's climate and water cycle. The lidar atmospheric sensing experiment (LASE) is an instrument designed and operated by the Langley Research Center for high precision water vapor measurements. The design details of a new water vapor lidar detection system that improves the measurement sensitivity of the LASE instrument by a factor of 10 are discussed. The new system consists of an advanced, very low noise, avalanche photodiode (APD) and a state-of-the-art signal processing circuit. The new low-power system is also compact and lightweight so that it would be suitable for space flight and unpiloted atmospheric vehicles (UAV) applications. The whole system is contained on one small printed circuit board (9 x 15 sq cm). The detection system is mounted at the focal plane of a lidar receiver telescope, and the digital output is read by a personal computer with a digital data acquisition card.

Refaat, Tamer F.↗

Framework for Coordinated Efforts in the Exploration of Volatiles in the South Polar Region of the Moon

The exploration of the lunar south polar region and the ground truthing of polar volatiles is one of the top priorities for several space agencies and private partners. Here we use Moon Mineralogy Mapper surficial water ice detections to investigate the location of water ice-bearing permanently shaded regions near the south pole. We extract a variety of parameters such as their temperature regime, slope, hydrogen content, number of ice detections, depth stability for water ice and dry ice, and mobility aspects. We identify 169 water ice-bearing PSRs and use their characteristics to identify sites that allow to access the highest abundances of volatiles, sites that can be visited to characterize the lateral or vertical distribution of volatiles (water ice and dry ice), and sites that allow for the fastest recovery of a scientifically interesting sample. Collectively, 37 PSRs are identified as sites of interest, including 11 that would address more than one mission objective and may be, for that reason, higher priority targets of exploration. These PSRs are found in Shoemaker, Faustini, Cabeus, Malapert, Nobile, Sverdrup, Wiechert J and Haworth craters, as well as 3 unnamed craters (PSRs 57, 120, 89). These sites are all located within 6 degrees of the south pole. We present case studies for a relatively short traverse mission (20 to 50 km) to PSR 89, a medium length traverse (~100 km) to Sverdrup 1, and a longer traverse (~300 km) to Cabeus that can serve as a guide in planning upcoming exploration missions.

Myriam Lemelin↗

An airborne laser fluorosensor for the detection of oil on water

The successful operation of an airborne laser fluorosensor system is reported that makes it possible to detect and map surface oil, either of natural-seepage or spill origin, on large bodies of water. Preliminary results indicate that the sensitivity of the instrument exceeds that of conventional passive remote sensors currently available for oil spill detection.

Kim, H. H.↗

The Relative Importance of Random Error and Observation Frequency in Detecting Trends in Upper Tropospheric Water Vapor

Recent published work assessed the amount of time to detect trends in atmospheric water vapor over the coming century. We address the same question and conclude that under the most optimistic scenarios and assuming perfect data (i.e., observations with no measurement uncertainty) the time to detect trends will be at least 12 years at approximately 200 hPa in the upper troposphere. Our times to detect trends are therefore shorter than those recently reported and this difference is affected by data sources used, method of processing the data, geographic location and pressure level in the atmosphere where the analyses were performed. We then consider the question of how instrumental uncertainty plays into the assessment of time to detect trends. We conclude that due to the high natural variability in atmospheric water vapor, the amount of time to detect trends in the upper troposphere is relatively insensitive to instrumental random uncertainty and that it is much more important to increase the frequency of measurement than to decrease the random error in the measurement. This is put in the context of international networks such as the Global Climate Observing System (GCOS) Reference Upper-Air Network (GRUAN) and the Network for the Detection of Atmospheric Composition Change (NDACC) that are tasked with developing time series of climate quality water vapor data.

Whiteman, David N.↗

NBC detection in air and water

Participating in a Navy STTR project to develop a system capable of the 'real-time' detection and quanitification of nuclear, biological and chemical (NBC) warfare agents, and of related industrial chemicals including NBC agent synthesis by-products in water and in air immediately above the water's surface. This project uses JPL's Soft Ionization Membrane (SIM) technology which totally ionizes molecules without fragmentation (a process that can markedly improve the sensitivity and specificity of molecule compostition identification), and JPL's Rotating Field Mass Spectrometer (RFMS) technology which has large enough dynamic mass range to enable detection of nuclear materials as well as biological and chemical agents. This Navy project integrates these JPL Environmental Monitoring UnitS (REMUS) an autonomous underwater vehicle (AUV). It is anticipated that the REMUS AUV will be capable of 'real-time' detection and quantification of NBC warefare agents.

molecules↗

Detection efficiency of a water condensation particle counter using electrically neutral sulfuric acid and sulfuric acid-dimethylamine clusters

Recent advances in condensation particle counters (CPCs) have improved the detection of sub-3 nm particles, increasing the accuracy of new particle formation (NPF) measurements. However, the detection efficiencies for neutrally charged, atmospherically relevant, sub-1 nm particles, which are critical for the accurate derivation of atmospheric NPF rates, are currently unknown. Here, this study presents a method to measure the detection efficiency of sulfuric acid and clusters of sulfuric acid and dimethylamine using measured CPC concentrations and modeled cluster distributions at atmospherically relevant concentrations. This study finds that water-based CPCs can measure these clusters at detection efficiencies relevant to NPF studies.

Cheng, Darren [Carnegie Mellon Univ., Pittsburgh, ↗

Hydrogen emission in meteors as a potential marker for the exogenous delivery of organics and water

We detected hydrogen Balmer-alpha (H(alpha)) emission in the spectra of bright meteors and investigated its potential use as a tracer for exogenous delivery of organic matter. We found that it is critical to observe the meteors with high enough spatial resolution to distinguish the 656.46 nm H(alpha) emission from the 657.46 nm intercombination line of neutral calcium, which was bright in the meteor afterglow. The H(alpha) line peak stayed in constant ratio to the atmospheric emissions of nitrogen during descent of the meteoroid. If all of the hydrogen originates in the Earth's atmosphere, the hydrogen atoms are expected to have been excited at T = 4400 K. In that case, we measured an H(2)O abundance in excess of 150 +/- 20 ppm at 80-90 km altitude (assuming local thermodynamic equilibrium in the air plasma). This compares with an expected <20 ppm from H(2)O in the gas phase. Alternatively, meteoric refractory organic matter (and water bound in meteoroid minerals) could have caused the observed H(alpha) emission, but only if the line is excited in a hot T approximately 10000 K plasma component that is unique to meteoric ablation vapor emissions such as Si(+). Assuming that the Si(+) lines of the Leonid spectrum would need the same hot excitation conditions, and a typical [H]/[C] = 1 in cometary refractory organics, we calculated an abundance ratio [C]/[Si] = 3.9 +/- 1.4 for the dust of comet 55P/Tempel-Tuttle. This range agreed with the value of [C]/[Si] = 4.4 measured for comet 1P/Halley dust. Unless there is 10 times more water vapor in the upper atmosphere than expected, we conclude that a significant fraction of the hydrogen atoms in the observed meteor plasma originated in the meteoroid.

Water↗

Copper-Based Two-Dimensional Conductive Metal–Organic Framework Thin Films for Ultrasensitive Detection of Perfluoroalkyls in Drinking Water

Perfluoroalkyls (PFAS) continue to emerge as a global health threat making their effective detection and capture extremely important. Though metal–organic frameworks (MOFs) have stood out as a promising class of porous materials for sensing PFAS, detection limits remain insufficient and a fundamental understanding of detection mechanisms warrants further investigation. Here, in this study, we show the use of a 2D conductive MOF film based on copper hexahydroxy triphenylene (Cu-HHTP) to fabricate chemiresistive sensing devices for detecting PFAS in drinking water. We further show ultrasensitive detection using electrochemical impedance spectroscopy. Owing to excellent electrostatic attractions and electrochemical interactions between the copper-based MOF and PFAS, confirmed by high-resolution spectroscopy and theoretical simulations, the MOF-based sensor reported herein exhibits excellent affinity and sensitivity toward perfluorinated acids at concentrations as low as 0.002 ng/L.

2D metal−organic frameworks↗

A tentative detection of the 183-GHz water vapor line in the martian atmosphere: Constraints upon the H2O abundance and vertical distribution

The 183-GHz water vapor line was tentatively detected on Mars in January 1991, with the IRAM 30-m millimeter antenna, under extremely dry atmospheric conditions. The measurement refers to the whole disk. The spectral line, although marginally detected, can be fit with a constant H2O mixing ratio of 1.0 x 10(exp -5), which corresponds to a water abundance of 1 pr-microns; in any case, an upper limit of 3 pr-microns is inferred. This value is comparable to the very small abundances measured by Clancy (1992) 5 weeks before our observation and seems to imply both seasonal and long-term variations in the martian water cycle.

Encrenaz, TH.↗

Colloquium on Water in Planetary Regoliths, Hanover, N.H., October 5-7, 1976, Proceedings

The papers abstracted in this volume deal with the occurrence, detection, and measurement of water on planetary bodies in the solar system; relevant aspects of the terrestrial water balance; the most probable status of water on other planetary bodies; and the methods of water detection and measurement available for consideration in designing planetary exploration missions. Topics include the water inventory for earth, high-energy protons as an early source of regolith water, the evolution of water on Mars, the chemical evolution of the Martian atmosphere by surface weathering, some geochemical aspects of excess volatiles on Mars, fluvial erosion on Mars, water in the outer solar system, and the stability of water on the Galilean satellites. Other papers discuss gamma-ray attenuation methods for determining the water content of soil, Viking biology-experiment results relevant to water on Mars, IR detection of water ice on satellite surfaces during the Mariner Jupiter/Saturn mission, electrical sounding of the lunar regolith, the detection of water on the moon and Mars by orbital gamma-ray spectroscopy, and the Viking Martian soil-water analyzer.

Bowen, S.L.↗

In-situ determination of moisture- and temperature-driven deflection of an encapsulated Si photovoltaic cell

Module reliability and service lifetime are critical factors in improving photovoltaic system performance and reducing the levelized cost of electricity (LCOE). Soldering and lamination of the cell impart residual stresses that persist over time and superimpose additional loads during operation. This paper demonstrates the use of X-ray Topography (XRT) to image in-situ the dynamic response of a glass/backsheet mini-module upon drying at elevated temperature after saturation at humidity levels compatible with accelerated testing. The local water content in the encapsulant is also determined in-situ over time via Water Reflectometric Detection (WaRD), with diffusion of water in the front (glass side) and rear (backsheet side) resolved. As water diffuses out from the back of the glass/backsheet module, the cell curves towards the backsheet concomitantly. Here we find that the cell edges deflect 40μm out-of-plane with respect to its center while the encapsulant dries, compared to ~100 μm deflection when heating from 25°C to 85°C. The local cell deflections (changes in cell orientation) are correlated with the dynamic loss of water in the backside encapsulant. We conclude that the observed cell deflections are the result of hygroscopic stress induced by the encapsulant upon moisture outdiffusion. Therefore, the cell experiences a continually changing stress state and curvature dependent on local humidity and temperature. Depending on cell architecture and interconnection, this “breathing” mode of the cell may induce wear out and fatigue of the interconnects, affect the electrical connection of cracked pieces or cause failure near the interconnected edges of two cells.

14 SOLAR ENERGY↗

Water Vapor in Titan's Stratosphere from Cassini/CIRS Far-infrared Spectra

Since the first detection of water vapor in Titan's stratosphere by disk-average observations from the Infrared Space Observatory (Coustenis et al. 1998) we report here the successful detection of stratospheric water vapor using the Cassini Composite Infrared Spectrometer (CIRS, Flasar et al. 2004). CIRS senses water emissions in the far infrared spectral region near 50 microns, which we have modeled using two independent radiative transfer codes (NEMESIS, Irwin et al 2008 and ART, Coustenis et al. 2007, 2010). From the analysis of nadir spectra we have derived a mixing ratio of (0.14 0.05) ppb at an altitude of 97 kilometers, which corresponds to an integrated (from 0 to 600 kilometers) surface normalized column abundance of (3.7 plus or minus 1.3) x 10(exp 14) molecules per square centimeter. In the latitude range 80 S to 30 N we see no evidence for latitudinal variations in these abundances within the error bars. Using limb observations, we obtained mixing ratios of (0.13 plus or minus 0.04) ppb at an altitude of 115 kilometers and (0.45 plus or minus 0.15) ppb at an altitude of 230 kilometers, confirming that the water abundance has a positive vertical gradient as predicted by photochemical models (e.g. Lara et al. 1996, Wilson and Atreya 2004, Horst et al. 2008); retrieved scaling factors (from approximately 0.1 to approximately 0.6) to the water profile suggested by these models show that water vapor is present in Titan stratosphere with less abundance than predicted.

Cottini, V.↗

Ultraviolet Observations of Phoebe from the Cassini UVIS

Observations of Saturn's distant moon Phoebe were made at far-ultraviolet (FUV) (1100-1900 A) and extreme-ultraviolet (EUV) (600-1100 A) wavelengths by the Cassini Ultraviolet Imaging Spectrograph (UVIS) during the Cassini spacecraft flyby on June 11, 2004. These are the first UV spectra of Phoebe and the first detection of water ice on a Solar System surface using FUV wavelengths. The characteristics of water ice in the FUV are presented, and Hapke models are used to interpret the spectra in terms of composition and grain size; the use of both areal and intimate mixing models is explored. Non-ice species used in these models include carbon, ice tholin, Triton tholin, poly-HCN and kerogen. Satisfactory disk-integrated fits are obtained for intimate mixtures of approx.10% H2O plus a non-ice species. Spatially resolved regions of higher (approx.20%) and lower (approx.5%) H2O ice concentrations are also detected. Phoebe does not display any evidence of volatile activity. Upper limits on atomic oxygen and carbon are 5 x 10(exp 11) and 2 x 10(exp 12) atoms/sq. cm, respectively, for solar photon scattering. The UVIS detection of water ice on Phoebe, and the ice amounts detected, are consistent with IR measurements and contribute to the evidence for a Phoebe origin in the outer Solar System rather than in the main asteroid belt.

UV spectroscopy↗

The utility of surface temperature measurements for the remote sensing of surface soil water status

Experiments carried out on an Avondale loam soil indicated that the thermal inertia concept of soil water content detection is reasonably sound. The volumetric water contents of surface soil layers between 2 and 4 cm thick were found to be linear functions of the amplitude of the diurnal surface soil temperature wave for clear day-night periods. They were also found to be linear functions of the daily maximum value of the surface soil-air-temperature differential. Tests on three additional soils ranging from sandy loam to clay indicated that the relations determined for Avondale loam could not be accurately applied to these other soil types. When the moisture characteristic curves of each soil were used to transform water contents into pressure potentials, however, it was found that soil water pressure potential could be determined without prior knowledge of soil type, and thus its value as a potential soil water status survey tool was significantly enhanced.

Idso, S. B.↗

Aircraft search for millimeter-wavelength emission by stratospheric ClO

Three millimeter-wavelength transitions of ClO were searched for in the stratospheric emission spectrum during May-August 1977 using aircraft-based instruments. The measurements indicate that if stratospheric ClO has a vertical distribution of the form predicted by present photochemical models, then the ClO volume mixing ratio at the profile peak did not exceed 10 to the -9th at the time and place of the measurements. The observed spectra suggest the presence of ClO in the stratosphere but do not provide a definitive detection.

Waters, J. W.↗

Semiselective Optoelectronic Sensors for Monitoring Microbes

Sensor systems are under development for use in real-time detection and quantitation of microbes in water without need for sampling. These systems include arrays of optical sensors; miniature, portable electronic data-acquisition circuits; and optoelectronic interfaces between the sensor arrays and data-acquisition circuits. These systems are intended for original use in long-term, inline monitoring of waterborne micro-organisms in water-reclamation systems aboard future spacecraft. They could also be adapted to similar terrestrial uses with respect to municipal water supplies, stored drinking water, and swimming water; for detecting low-level biological contamination in biotechnological, semiconductor, and pharmaceutical process streams; and in verifying the safety of foods and beverages. In addition, they could be adapted to monitoring of airborne microbes and of surfaces (e.g., to detect and/or quantitate biofilms). The designs of the sensors in these systems are based partly on those of sensors developed previously for monitoring airborne biological materials. The designs exploit molecular- recognition and fluorescence-spectroscopy techniques, such that in the presence of micro-organisms of interest, fluorescence signals change and the changes can be measured. These systems are characterized as semiselective because they respond to classes of micro-organisms and can be used to discriminate among the classes. This semiselectivity is a major aspect of the design: It is important to distinguish between (1) the principle of detection and quantitation of classes of micro-organisms by use of these sensors and (2) the principle of detection and quantitation of individual microbiological species by means of prior immuno-diagnostic and/or molecular-biology techniques. Detection of classes (in contradistinction to species) is particularly valuable when the exact nature of a contaminant is unknown.

Tabacco, Mary Beth↗