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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 199 records · Page 11

Insulating Material for Next-Generation Spacecraft

A report discusses the development of a flexible thermal-insulation material for cryogenic tanks in next-generation spacecraft. This material is denoted Advanced Reusable All-temperature Multimode Insulation System (ARAMIS). The report begins by describing the need for ARAMIS and the technological challenges of developing a single material that is useable throughout the temperature range from storage of liquid hydrogen (20 K) to atmospheric-reentry heating (>2,000 K), has the requisite low thermal conductivity, resists condensation of moisture without need for a gas purge, and withstands reentry heating for a 400-mission lifetime. The report then discusses laboratory apparatuses for testing materials that have been and will be considered as candidates for the development of ARAMIS.

White, Susan↗

Unlocking Synergistic Benefits of Colocation of Data Centers at Airports

This white paper evaluates the potential of a new energy system configuration: Strategic colocation of data centers - on airport property or adjacent to airports - in order to realize significant operational, economic, and environmental benefits to airports, data centers, and the communities they serve. While increasing demand from both airports and data centers requires both parties to make significant infrastructure investments, colocation can mitigate some of the energy, land use, permitting, and connectivity challenges of siting and powering these industries.

24 POWER TRANSMISSION AND DISTRIBUTION↗

A thermal evaporation–trapping strategy to synthesize flexible and robust oxygen electrocatalysts for rechargeable zinc–air batteries

Great efforts have been devoted to the development of bifunctional electrocatalysts to accelerate the sluggish kinetics of cathodic oxygen reduction/evolution reactions (ORR/OER) in zinc–air batteries (ZABs). Here we report a thermal evaporation–trapping synergistic strategy to fabricate a bifunctional electrocatalyst of flexible N-doped carbon fiber cloth loaded with both CoFe-oxide nanoparticles and single-atom Co/Fe–Nx sites, in which the thermal evaporation process functions in both downsizing CoFe-oxide nanoparticles and trapping the evaporated Co/Fe species to generate Co/Fe–Nx sites. The obtained flexible electrocatalyst, directly serving as an oxygen electrode, displays a small potential gap of 0.542 V for the OER/ORR, large peak power densities (liquid-state ZAB: 237.4 mW cm2 ; solid-state ZAB: 141.1 mW cm2 ), and excellent charge–discharge cycling stability without decay after working more than 770 hours. Furthermore, in situ Raman spectroscopy characterization and theoretical calculations reveal that CoFe2O4 species is responsible for the OER while atomic Fe/Co sites play a key role in the ORR

Zhang, Hong-Bo↗

Thermal Performance Of Space Suit Elements With Aerogel Insulation For Moon And Mars Exploration

Flexible fiber-reinforced aerogel composites were studied for use as insulation materials of a future space suit for Moon and Mars exploration. High flexibility and good thermal insulation properties of fiber-reinforced silica aerogel composites at both high and low vacuum conditions make it a promising insulation candidate for the space suit application. This paper first presents the results of a durability (mechanical cycling) study of these aerogels composites in the context of retaining their thermal performance. The study shows that some of these Aerogels materials retained most of their insulation performance after up to 250,000 cycles of mechanical flex cycling. This paper also examines the problem of integrating these flexible aerogel composites into the current space suit elements. Thermal conductivity evaluations are proposed for different types of aerogels space suit elements to identify the lay-up concept that may have the best overall thermal performance for both Moon and Mars environments. Potential solutions in mitigating the silica dusting issue related to the application of these aerogels materials for the space suit elements are also discussed.

Tang, Henry H.↗

An integrated model of the Space Station Freedom active thermal control system

A flexible, generic model of the Space Station Freedom active thermal control system has been developed which is designed to analyze dynamic interactions of the major subsystems of the ATCS. Models are described for the components of the central thermal bus, the radiator external thermal environment, and the internal thermal control system. Two programs are described which facilitate the development of the integrated ATCS model. The first, SIMRAD, simplifies an external thermal environment model given a desired level of accuracy in integrated model performance. The model reduction technique is shown to reduce model execution time significantly while maintaining the desired accuracy. The second, GENFLU, generates SINDA/FLUINT input code for the evaporator and load interface models and automates the integration of load submodels. The component submodels and integration techniques were used to create an integrated model of the thermal control system for an early assembly flight configuration. The results demonstrate the utility of the integrated model in studying dynamic interactions of the ATCS subsystems.

Tandler, John J.↗

Smart and Efficient Building Envelopes: Thermal Switches and Thermal Storage for Energy Savings and Load Flexibility

The building envelope has traditionally been seen as a static component. Much of the past thermal advancements in building envelopes has consisted of developing higher R/inch insulation. While a suitable approach for static situations, it does not consider the dynamic nature of the ambient environment or the varying needs of the electrical grid. This paper will examine three possible ways that building envelopes can be actively managed: 1. thermal switches, 2. thermal storage, and 3. the coupling of the two. Spurring innovation to make building envelopes smarter will help reduce building energy consumption and peak energy usage and contribute to flexibility in energy demand in the future.

Mumme, Sven↗

Flexible Fully-Decoupled Nuclear Plants with Thermal Energy Storage - Technoeconomic Optimization

New nuclear power plants may be one of the technologies for future zero carbon electricity production. These future systems will however also need significant flexibility to cope with fluctuating demand and large share of intermittent renewable supply, rather than running in conventional baseload generation. The present work explores the use of thermal energy storage (TES) as a buffer between the reactor heat and its conversion to electricity, enabling flexible operation of nuclear plants. The focus is on maximizing flexibility, ideally as full decoupling of the nuclear and power cycle islands, as well as on system efficiency in various modes. A system design presented for a high temperature gas cooled reactor (HTGR) presents a slightly complex solution, as separate high- and low-temperature TES systems are required in order to cover the extended temperature range. Although this configuration imposes certain limitations on the discharge system configuration, it also presents the opportunity to design a more efficient system. For this case in particular, a steam reheat cycle is advantageous. Dynamic models were developed for the decoupled system in order to generate insights into aspects of off design operation and system control. A technoeconomic analysis, furthermore, provides sizing and costing of the component, followed by size and dispatch economic optimization considering energy arbitrage. This optimization shows that in all explored markets, the addition of TES system with the proposed configuration results in positive impact on project net present value. Further sensitivity analyses show impact of multiple inputs and possible technical limitations.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Advanced Coating Compositions and Microstructures to Improve Uptime and Operational Flexibility in Cyclic, Low-Load Thermal Utility Plants

GE, the University of Tennessee, and Oak Ridge National Laboratory collaborated from 2020 to 2023 developing two key technologies for improving the viability of fuel switching and load following in thermal utility plants: a) cost-effective weld overlay compositions for boiler tubing b) cathodic arc coatings that deliver improvements in both erosion resistance and oxidation resistance in high temperature steam for HP turbine blades The team worked through a robust, logical project map to de-risk these two technologies and advance them from TRL 3 to TRL 6. For the cost-effective weld overlay, the team developed a ferritic filler material which was fabricated at a vendor for 18% the average market cost of Inconel 625 wire, had a corrosion rate 3x lower in conditions simulating a biomass-fired superheater and 10x lower in conditions simulating a coal-fired superheater, and was fabricated into prototype overlaid tubing that passed ASME requirements including transverse bending, dye penetrant inspection, and ASTM G-76 evaluation. For the cathodic arc coatings applied to steam turbine blades, the team developed a novel composition that was successfully transferred to a qualified vendor. The vendor was able to produce coated prototypes with 4x the as-deposited erosion resistance and 10.4x the post-steam-exposure erosion resistance of the TiN coating the vendor currently applies on GE steam turbine components, without significantly increasing process cost. These coated prototypes also passed a GE inspection and showed favorable performance in high temperature erosion, nanoindentation, sliding wear, scratch adhesion, and high cycle fatigue testing. If successfully deployed by GE, it is anticipated that the technologies will enable the following: • 25%-50% increase in time between outages for both boilers and HP turbines. • 50% decrease in cost for weld overlay on a per foot basis relative to todays NiCr alloys. • Adequate oxidation resistance and erosion for HP turbine inlet steam at >620°C and >220 bar. • No need for changes in component supply chain or any notable Capital Expenditures. 5 Decreasing component cost, increasing performance, and extending time between outages represent direct value propositions to GE and their customers. For the American consumer, these objectives translate into increased grid reliability (fewer unexpected outages), decreased Levelized Cost of Electricity, and improved environmental health (low-loading/load following to accelerate penetration of renewables). The results also have implications for wear resistant tooling, wire arc additive manufacturing, more durable components for syngas cleanup, and deployment of more efficient thermochemical pathways for carbon negative fuel production

09 BIOMASS FUELS↗

Flexible, Multipurpose Laboratory Advances Building and Thermal Energy Systems: Expanding Evaluation and Development of Grid-Interactive Buildings

Robust hardware and controls are necessary to ensure results match their intent before they can be used broadly. However, this often requires multiple field experiments in a variety of climate zones. In the field, it is more difficult to obtain information on other important factors, such as thermal, grid, and occupant interaction. Gaps also exist in understanding the performance degradation and life cycle of thermal energy systems as they relate to buildings. There is a lack of robust, high-quality performance data for projects at scale; this data can be expensive to produce and often remain proprietary.

30 DIRECT ENERGY CONVERSION↗

Soluble Aromatic Polyimides For Film Coating

Because of toughness, flexibility, and remarkable thermal stability, linear all-aromatic polyimides excellent candidate film and coating materials for advanced electronic circuitry and wires. Study determined effects on solubility of changing isomeric points of attachment of phenoxy units in diamine portions of several all-aromatic polyimides. Tough, flexible, transparent films produced by thermally converting polyamic acids to polyimides at 300 degree C in air. Potential for electronic applications excellent.

St. Clair, Anne K.↗

Assessing thermal comfort and participation in residential demand flexibility programs

Residential space-conditioning-based demand flexibility (DF) has become an increasingly sought-after method for demand-side load management to enhance grid reliability and facilitate integration of renewable energy generation. However, predicting the effectiveness and flexibility of residential DF resources is challenging due to the variability in household energy use behaviors. Current estimates show that only 50 % of projected savings from DF resources are actualized due to regulatory, technological, and social barriers. From a household perspective, concerns over thermal comfort during space conditioning-based DF events significantly impact participation decisions. Currently, there is a very limited understanding of how thermal comfort during space-conditioning-based DF events in real-world settings impacts household energy use behaviors and, consequently, the success of DF programs in achieving targeted savings. This paper proposes a method to comprehensively assess the thermal comfort implications of DF strategies and presents results of their impacts on DF event participation decisions and demand savings. Here, the proposed method was applied to a heat pump DF field study in Cordova, Alaska. The study’s key findings are: 1) DF event setpoint offsets that maintain indoor operative temperatures between 18 to 22 °C (65 to 71°F) may be preferred in Cordova, Alaska; 2) Household-level thermal comfort is more sensitive to the duration of the DF event than to the degree of temperature offset from baseline conditions; 3) The delayed impact of changes in indoor operative temperature in response to setpoint offsets, both during and after a DF event, influences occupants’ thermal comfort perceptions and willingness to persistently participate in events. The findings from application of the proposed method can help inform future larger-scale occupant-centric DF programs as it can capture information not readily available through utility and device-level energy use data. Thus, it can supplement these sources and help program administrators develop occupant-centric DF strategies, enabling more accurate predictions of participation rates and savings estimates for space-conditioning-based DF programs.

Demand side management↗

Advancements in Development and Testing of Thermal Power Dispatch Simulators

Flexible plant operations and generation (FPOG) offer nuclear power plants (NPPs) the chance to leverage alternative, non-electric revenue streams while ensuring their continued role as reliable, clean, and constant sources of baseload electrical power. The excess thermal energy generated from NPPs during periods of low electricity demand can be channeled as raw materials to numerous industrial processes via a thermal power dispatch (TPD) system. Hydrogen production via high-temperature steam electrolysis (HTSE) is an optimal use case based on technical and economic feasibility. Researchers at Idaho National Laboratory (INL) have conducted previous works that developed and implemented TPD system models within the GSE Solutions Generic Pressurized Water Reactor (GPWR) simulator to support human-in-the-loop (HITL) scenario-based evaluations. The first part of this report documents modifications made to the GPWR TPD model and HMI from the previous iteration in line with a new Sargent and Lundy (S&L) TPD design with an automatic control system. The was done in collaboration with Westinghouse using their three-loop pressurizer water reactor (W3LPWR) simulator which contains an industrial grade automatic control system for the TPD. This was installed in the Human Systems Simulation Laboratory (HSSL) at INL. The second part of the report documents findings from an all-hands-on-deck integration and verification workshop that was conducted in the HSSL over several days. The research team comprised INL human factors and TPD experts, a nuclear engineer from GSE Solutions who implemented the revised TPD model for GPWR, the human-machine interface (HMI) prototyping and human factors team from the University of Idaho, and personnel with operations experience with pressurized water reactors. The workshop provided time and expertise to conduct the final activities to bring the operations, HMI, and simulator into a functional state. The goals of the integration and verification workshop were: 1. to install the revised GPWR TPD model into the HSSL 2. verify the TPD HMI prototype was functional 3. integrate the HTSE Simulink model to GPWR. 3. Issues were identified for resolution, but overall the workshop accomplished its goal to integrated and verify the majority of the intended functional. Future work will resolve the identified issues and use the integrated simulation to support an evaluation and demonstration in the next fiscal year.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Gaussian approximation potentials for accurate thermal properties of two-dimensional materials

Two-dimensional materials (2DMs) continue to attract a lot of attention, particularly for their extreme flexibility and superior thermal properties. Molecular dynamics simulations are among the most powerful methods for computing these properties, but their reliability depends on the accuracy of interatomic interactions. While first principles approaches provide the most accurate description of interatomic forces, they are computationally expensive. In contrast, classical force fields are computationally efficient, but have limited accuracy in interatomic force description. Machine learning interatomic potentials, such as Gaussian Approximation Potentials, trained on density functional theory (DFT) calculations offer a compromise by providing both accurate estimation and computational efficiency. Here, in this work, we present a systematic procedure to develop Gaussian approximation potentials for selected 2DMs, graphene, buckled silicene, and h-XN (X = B, Al, and Ga, as binary compounds) structures. We validate our approach through calculations that require various levels of accuracy in interatomic interactions. The calculated phonon dispersion curves and lattice thermal conductivity, obtained through harmonic and anharmonic force constants (including fourth order) are in excellent agreement with DFT results. HIPHIVE calculations, in which the generated GAP potentials were used to compute higher-order force constants instead of DFT, demonstrated the first-principles level accuracy of the potentials for interatomic force description. Molecular dynamics simulations based on phonon density of states calculations, which agree closely with DFT-based calculations, also show the success of the generated potentials in high-temperature simulations.

2D Materials↗

Development and Testing of an Innovative Two-Arm Focal-Plane Thermal Strap (TAFTS)

Maintaining temperature stability in optical focal planes comes with the intrinsic challenge of creating a pathway that is both extremely flexible mechanically and highly conductive thermally. The task is further complicated because science‐caliber optical focal planes are extremely delicate, yet their mechanical resiliency is rarely tested and documented. The mechanical engineer tasked with the thermo‐mechanical design must then create a highly conductive thermal link that minimizes the tensile and shear stresses transmitted to the focal plane without design parameters on an acceptable stiffness. This paper will describe the development and testing of the thermal link developed for the Portable Remote Imaging Spectrometer (PRISM) instrument. It will provide experimentally determined mechanical stiffness plots in the three axes of interest. Analytical and experimental thermal conductance results for the two‐arm focal‐plane thermal strap (TAFTS), from cryogenic to room temperatures, are also presented. The paper also briefly describes some elements of the fabrication process followed in developing a novel design solution, which provides high conductance and symmetrical mechanical loading, while providing enhanced flexibility in all three degrees of freedom.

flexible thermal strap↗

Active Dust Mitigation Technology for Thermal Radiators for Lunar Exploration

Dust accumulation on thermal radiator surfaces planned for lunar exploration will significantly reduce their efficiency. Evidence from the Apollo missions shows that an insulating layer of dust accumulated on radiator surfaces could not be removed and caused serious thermal control problems. Temperatures measured at different locations in the magnetometer on Apollo 12 were 38 C warmer than expected due to lunar dust accumulation. In this paper, we report on the application of the Electrodynamic Dust Shield (EDS) technology being developed in our NASA laboratory and applied to thermal radiator surfaces. The EDS uses electrostatic and dielectrophoretic forces generated by a grid of electrodes running a 2 micro A electric current to remove dust particles from surfaces. Working prototypes of EDS systems on solar panels and on thermal radiators have been successfully developed and tested at vacuum with clearing efficiencies above 92%. For this work EDS prototypes on flexible and rigid thermal radiators were developed and tested at vacuum.

Calle, C. I.↗

Design of a Meso-Scale Test of a Fracture Thermal Energy Storage (FTES) System

This paper will present the characterization, scaling, and design of an intermediate-scale field test of a fracture thermal energy storage system (FTES). Seasonal storage of thermal energy has the potential to both significantly reduce the total energy requirements for heating and cooling of buildings, but also allow for the flexibility to store thermal energy from intermittent sources. With approximately half of global energy consumption currently being used for heating and cooling, this represents an important path to reducing greenhouse gas (GHG) emissions. The concept of FTES is to drill two or more wells into a low permeability formation, generally at a depth of less than a few hundred meters, and then generate hydraulic fractures to create flow paths for water to circulate between the wells. Hot or cold thermal energy can then be stored in the surrounding rock mass by circulating hot or cold water through the fractures, which will heat or cool the rock mass. To recover the stored energy, ambient temperature water can be then circulated through the fractures, which will then be heated or cooled by the rock mass. Fractures inherently have a very large ratio of surface area to volume. This allows for very high heat fluxes to and from the rock mass to be achieved despite the relatively low thermal conductivity of most geologic formations. Because large fractures can be made with low-cost equipment and with only inexpensive and environmentally safe materials such as water and sand, the cost to construct even large FTES systems is expected to be quite low. This paper will present what the performance requirements, size, and operating conditions of a full-scale system to operate a commercial building. The paper will describe how these full-scale system characteristics will be used as a design basis for an intermediate-scale FTES test to be conducted at the Sanford Underground Research Facility (SURF) in Lead, SD.

Burghardt, Jeffrey A.↗

How Will We Keep Warm on the Red Planet?

Among the many challenges that the Mars environment poses for EVA (extravehicular activity) space suit designers, development of an appropriate thermal insulation is one of the most important. The latest in thermal insulation technologies that could be applied or modified for planetary exploration have been reviewed. These include porous and hollow structures, phase change materials, soluble gas elements, as well as vacuum enclosures and fibrous materials. Using current technology, none of these structures offers all of the features needed for Mars exploration, namely lightweight, low bulk, high flexibility, and low thermal insulation. Nonwoven fibrous materials are still the prime design candidates because they are more flexible than other structures while having good resiliency. They are usually safe to use. They are also available in many types of materials, fiber shapes, as well as fabric densities and constructions. However, a recent study conducted at the NASA Johnson Space Center shows clearly that these structures alone are not sufficient to provide effective thermal insulation in the harsh Mars environment. A more promising solution is being developed using aerogel fillers in the nonwoven structures.

Orndoff, Evelyne↗