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At least 199 records · Page 11
All sourcesNASA NTRSDOE OSTI
NASA NTRS1986

Manufacture of high-density ceramic sinters

High density ceramic sinters are manufactured by coating premolded or presintered porous ceramics with a sealing material of high SiO2 porous glass or nitride glass and then sintering by hot isostatic pressing. The ceramics have excellent abrasion and corrosion resistances. Thus LC-10 (Si3N2 powder) and Y2O3-Al2O3 type sintering were mixed and molded to give a premolded porous ceramic (porosity 37%, relative bulk density 63%). The ceramic was dipped in a slurry containing high SiO2 porous glass and an alcohol solution of cellulose acetate and dried. The coated ceramic was treated in a nitrogen atmosphere and then sintered by hot isostatic pressing to give a dense ceramic sinter.

Hibata, Y.↗
NASA NTRS1985

Manufacture of sintered silicon nitrides

Sintered silicon nitrides are manufactured by sintering Si3N powder containing 2 to 15% in wt of a powder mixture composed of nitride powder of lanthanide or Y 100 parts and AIN powder less than 100 parts at 1500 to 1900 deg. temperature under a pressure of less than 200 Kg/sq. cm. The sintered Si3N has high mechanical strength in high temperature. Thus, Si3N4 93.0, Y 5.0 and AlN 2.0% in weight were wet mixed in acetone in N atom, molded and sintered at 1750 deg. and 1000 Kg/sq. cm. to give a sintered body having high hardness.

Iwai, T.↗
NASA NTRS1988

A sintering model for SiC(sub)w/Si3N4 composites

Presented is a model which suggests that it should be possible to pressureless sinter a SiC(sub w)/ Si3N4 composite to theoretical density. Prior failure to achieve complete densification by sintering is attributed to the use of compositions which result in a glass deficit. There is one basic premise for this model. The ratio of glass amount to surface area of nonglass constituents must be the same for both composite and sinterable monolithic Si3N4. This model suggests that whisker and grain sizes and whisker loading influence the glass amount necessary for successful sintering of composites. According to the model, a large glass amount will be necessary for successful sintering of these composites. However, grain boundary thicknesses in the composite will be less than those in the analogous monolithic materials. This suggests that good high temperature strength may still be attained. A recent report supports the predictions of the model.

Freedman, Marc R.↗
NASA NTRS1991

Thermochemical analysis of the silicon carbide-alumina reaction with reference to liquid-phase sintering of silicon carbide

The stabilities of different phases in the Si-Al-C-O system are calculated from thermodynamic considerations with the objective of identifying the liquid phases formed during sintering of SiC in the presence of Al2O3. It is shown that a liquid phase can form at the sintering temperatures by the reaction of SiC with Al2O3. Depending on the carbon activity, the liquid can be either of the following: Al2O3 + Al4C3, SiC + Al4C3, or molten aluminum. The stability of the aluminosilicate melts that can form by the reaction of Al2O3 with the surface silica layer on SiC powders is also evaluated. Several factors that influence liquid-phase sintering, such as the solubility of SiC in the melts and the generation of gases during sintering, are discussed. The results of the thermodynamic analysis are compared with the observed sintering behavior for SiC.

Misra, Ajay K.↗
NASA NTRS1993

Powder metallurgy: Solid and liquid phase sintering of copper

Basic powder metallurgy (P/M) principles and techniques are presented in this laboratory experiment. A copper based system is used since it is relatively easy to work with and is commercially important. In addition to standard solid state sintering, small quantities of low melting metals such as tin, zinc, lead, and aluminum can be added to demonstrate liquid phase sintering and alloy formation. The Taguchi Method of experimental design was used to study the effect of particle size, pressing force, sintering temperature, and sintering time. These parameters can be easily changed to incorporate liquid phase sintering effects and some guidelines for such substitutions are presented. The experiment is typically carried out over a period of three weeks.

Sheldon, Rex↗
NASA NTRS1998

Sintering and Creep Behavior of Plasma-Sprayed Zirconia and Hafnia Based Thermal Barrier Coatings

The sintering and creep of plasma-sprayed ceramic thermal barrier coatings under high temperature conditions are complex phenomena. Changes in thermomechanical and thermophysical properties and in the stress response of these coating systems as a result of the sintering and creep processes are detrimental to coating thermal fatigue resistance and performance. In this paper, the sintering characteristics of ZrO2-8wt%y2O3, ZrO2-25wt%CeO2-2.5wt%Y2O3, ZrO2-6w%NiO- 9wt%Y2O3, ZrO2-6wt%Sc2O3-2wt%y2O3 and HfO2-27wt%y2O3 coating materials were investigated using dilatometry. It was found that the HfO2-Y2O3 and baseline ZrO2-Y2O3 exhibited the best sintering resistance, while the NiO-doped ZrO2-Y2O3 showed the highest shrinkage strain rates during the tests. Higher shrinkage strain rates of the coating materials were also observed when the specimens were tested in Ar+5%H2 as compared to in air. This phenomenon was attributed to an enhanced metal cation interstitial diffusion mechanism under the reducing conditions. It is proposed that increased chemical stability of coating materials will improve the material sintering resistance.

Zhu, Dongming↗
NASA NTRS2007

Sintering of Lunar and Simulant Glass

Most oxygen-extraction techniques are temperature-dependent, with higher temperatures resulting in higher oxygen yield. An example is hydrogen reduction, in which the optimum process temperature is 1050 C. However, glass-rich lunar soil begins to show the effects of sintering at temperatures of 900 C or lower. Sintering welds particles together due to viscous relaxation of the glass in the sample. One approach to avoid problems related to sintering, such as difficulty in removing waste material from the reactor, is to keep the soil in motion. One of several methods being studied to accomplish this is fluidized-bed processing techniques, in which the grains are kept in motion by the action of flowing reductant gas. The spent material can be removed from the chamber while still fluidized, or the fluidizing motion can continue until the material has cooled below approx. 500 C. Until end-to-end prototypes are built that can remove the heated soil, the most practical option is to keep the bed fluidized while cooling the waste material. As ISRU technology advances, another option will become valuable, which is to intentionally sinter the material to a great enough extent that it becomes a brick. The free iron in lunar soil is magnetic, and ferromagnetic bricks can be manipulated by robotic systems using electromagnetic end effectors. Finally, if an electromagnetic field is applied to the soil while the brick is being formed, the brick itself will become a magnet. This property can be used to create self-aligning bricks or other building materials that do not require fasteners. Although sintering creates a challenge for early lunar surface systems, knowledge gained during prototype development will be valuable for the advanced lunar outpost.

Cooper, Bonnie L.↗
NASA NTRS2019

Optimization of Aluminum-Tin Ink Composition and Sintering in Atmospheric Conditions

This study will focus on the basics of generating an aluminum-tin ink that can sinter in air and exhibits properties near that of a solid aluminum-tin alloy. Sintering temperatures will also be assessed in this study. Once the optimal aluminum ink composition is determined, the optimal ink thickness for homogeneous sintering must be determined by additional experimentation. Additive manufacturing is a rapidly developing and growing manufacturing process and has proven successful in many different ways. Processes, such as extrusion three-dimensional (3D) printing and selective laser melting (SLM), have proven to work but have limitations, such as material capabilities or density issues. SLM is a revolutionary process for additive manufacturing of metals but cannot be used in outer space due to the need for metallic powder which would diffuse into the atmosphere in a zero-gravity environment. For this reason, metallic ink additive manufacturing is a potential solution. Work is being done on metallic ink additive manufacturing in a vacuum for electrical applications. This project has focused on developing an aluminum-tin metallic ink that can sinter without the need of a vacuum or inert gas-purged atmosphere in order to prevent oxidation of the aluminum by adding flux. Once a potential ink composition has been determined through sintering of small disks and thin layers of ink, the ink may be studied with a multimaterial 3D printer at NASA Marshall Space Flight Center (MSFC) in future experiments. If successful, this aluminum-tin ink will be capable for use on the International Space Station to make replacement parts quickly. Along with its zero-gravity advantages, this ink may also have applications on Earth because it may be extruded on a substrate with precise ceramic tips in a 3D printing process. This would allow the fabrication of precise, complex shapes and may generate a much faster and more efficient printing process as compared with traditional powder bed additive manufacturing processes. The process would not be limited by a small building volume because the system would not require an enclosed chamber.

Courtright, Z. S.↗
NASA NTRSDate not supplied

Fabrication and Characterization of A Lunar Simulant-Based Sintered Construction Material

In-situ resource utilization (ISRU) is critical to enable future efforts to have a long-term human presence on the Moon as well as Mars. ISRU technologies are being developed for radiation protection, dust mitigation, thermal insulation, and other applications. One such ISRU technology for creating construction materials out of lunar and Martian regolith is sintering, which is a thermal-based construction process that bonds finely grained material together at temperatures below the melting point. However, the conditions employed during the sintering, such as temperature, atmospheric composition, duration of the process, and pressure, can have a significant impact on the quality and strength of the resulting materials. In parallel, the development of methods for characterizing the quality, porosity, density, and other properties of these materials is critical. X-ray computed tomography (X-ray CT) can image large changes in density within a material, such as the presence of pores throughout an otherwise uniform medium, with relatively high spatial resolution. Similarly, Terahertz time-domain spectroscopic (THz-TDS) imaging is sensitive to density variations within samples, but is restricted to non-conducting materials. Specifically, previous work has shown that the refractive index (n eff ) values obtained through the analysis of THz-TDS images increases with increasing density within plastic samples. Even further, this work showed that it is possible to create a calibration curve for a given material from samples of different, but known density, which can enable one to directly convert n eff to density for samples having the same composition, but unknown density. Here, we report on the fabrication of a lunar simulant-based sintered construction material using vacuum hot pressed (VHP) sintering, then show X-ray CT and THz-TDS imaging results of the sample, which show spatial variations in the material. This has important implications for efforts to improve these types of lunar construction material processes and verify the quality of these materials in terms of consolidation. To the best of our knowledge, there is no previous work utilizing VHP sintering to make lunar simulant-based construction materials or exploring the feasibility of THz imaging to spatially map the density variation through a lunar simulant-based construction material.

Terahertz time-domain spectroscopic imaging↗
DOE OSTI2017

Microstructure studies of U3Si2 fuel pellets sintered in argon vs. vacuum environment

A comparison study on the effects of sintering U3Si2 pellets under vacuum (~1x10-6 Torr) vs in argon has been carried out as part of a pellet fabrication process for potential light water reactor fuel application. A cross section of pellets sintered in each environment was examined using scanning electron microscopy (SEM) equipped with Energy dispersive spectroscopy (EDS). The average density of pellets sintered under vacuum and argon was 11.90 g/cm3 (97.5% theoretical density (TD)) and 11.37 g/cm3 (93.2% TD), respectively. SEM micrographs and EDS revealed the grain structure of pellets sintered under vacuum (vacuum samples) to be angular with a Si rich phase, U5Si4, along the grain boundaries, while grain structure of pellets sintered in argon (argon samples) reveals smaller average grain size and higher porosity with two separate Si rich phase inclusions: U5Si4 and USi. EDS confirmed the main phase in each pellet to be U3Si2 with an O rich phase inclusion. The estimated area percent of U3Si2 and the O rich phase in the samples from SEM image analysis was: argon samples 83.9% and 5.9% and vacuum samples 81.8% and 4.6%, respectively.

fuel fabrication↗
DOE OSTI2018

Failure stress comparison of different pairings of Ag-plating and reflow-oven-processed pressureless-sintered-Ag interconnects

Here, sintered-silver is a candidate material to supplant solders for interconnects in power electronic packaging for many reasons including its desirably high electrical and thermal conductivities and compliance to Restriction of Hazardous Substances (RoHS) guidelines. The shear failure stress of interconnects though is limited by whatever constituent is the weakest, and that includes any employed plating. In the present study, silver-platings were processed electrolytically, electrolessly, and through sputter deposition and their influence on the entire “interconnect system” shear strength was examined. Test sets employing gold plating and no plating were included for comparison and to aid interpretation. Ambient-air, reflow-oven-processed, pressureless-sintered-silver interconnects were identically fabricated with all plating test sets. It was found that all considered silver-plating methods produced consistently strong (characteristic failure stresses > 55 MPa) sintered-silver interconnects. Because failures tended to be adhesive in all six sets, differences in failure stress among the silver-plated sets and the gold-plated or unplated sets were likely due to differences in the adhesive strength of the sintered silver with silver-plating, gold-plating, or direct bonding with copper.

36 MATERIALS SCIENCE↗
DOE OSTI2017

Onset conditions for flash sintering of UO 2

In this paper, flash sintering was demonstrated on stoichiometric and non-stoichiometric uranium dioxide pellets at temperatures ranging from room temperature (26°C) up to 600°C. The onset conditions for flash sintering were determined for three stoichiometries (UO 2.00 , UO 2.08 , and UO 2.16 ) and analyzed against an established thermal runaway model. The presence of excess oxygen was found to enhance the flash sintering onset behavior of uranium dioxide, lowering the field required to flash and shortening the time required for a flash to occur. Finally, the results from this study highlight the effect of stoichiometry on the flash sintering behavior of uranium dioxide and will serve as the foundation for future studies on this material.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗
DOE OSTI2021

A Double-side Cooled SiC MOSFET Power Module with Sintered-silver Interposers: I. Design, Simulation, Fabrication, and Performance Characterization

Planar, double-side cooled power modules are emerging in electric-drive inverters because of their low profile, better heat extraction, and lower package parasitic inductances. However, there is still concern about their reliability due to the rigid interconnection between the device chips and two substrates of the power module. In this paper, a porous interposer made of low-temperature sintered silver is introduced to reduce the thermo-mechanical stresses in the module. A double-side cooled half-bridge module consisting of two 1200 V, 149 A SiC MOSFETs was designed, fabricated, and characterized. By using the sintered-Ag instead of solid copper interposers, our simulation results showed that at a total power loss of 200 W, the thermo-mechanical stress at the most vulnerable interfaces (interposer-attach layer) was reduced by 42 % and in the SiC MOSFET by 50 % with a trade-off of only 3.6 % increase in junction temperature. The sintered-Ag interposers were readily fabricated into desired dimensions without post-machining and did not require any surface finishing for die-bonding and substrate interconnection by silver sintering. Here, the porous interposers were also deformable under a low force or pressure, which helped to accommodate chip thickness and/or substrate-to-substrate gap variations in the planar module structure, thus simplifying module fabrication. Experimental results on the electrical performance of the fabricated SiC modules validated the success of using the porous silver interposers for fabricating planar, double-side cooled power modules.

42 ENGINEERING↗
DOE OSTI2018

Structural, Magnetic, and Dielectric Properties of Conventional- and Microwave-Sintered Ni{sub 0.6}Zn{sub 0.4−x}Cu{sub x}Fe{sub 2}O{sub 4}

In the present work, structural, magnetic, and dielectric properties of conventional- and microwave-sintered Ni{sub 0.6}Zn{sub 0.4-x}Cu{sub x}Fe{sub 2}O{sub 4} (x = 0.0 to 0.4 in steps of 0.1) are studied. X-ray diffraction measurements confirm the formation of a single spinel phase. Crystallite size estimated from Scherrer’s method found between 30–41 nm and 36–28.5 nm in conventional- and microwave-sintered samples respectively. The lattice constant decreases with Cu substitution, suggesting the incorporation of Cu into the spinel lattice. SEM images reveal that microwave sintering results in larger grains with intragranular pores. Saturation magnetization was found to decrease with Cu content. Cation distribution estimated from the magnetization data supports the observed changes in magnetic parameters. A significant influence on microstructure and cation redistribution on dielectric properties are observed for microwave-sintered samples.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2018

Preparation of Nb{sub 3}Al Superconducting Tapes by a Powder-in-Tube Method Combined with Hot-Pressed Sintering

The precursors of Nb-Al tape were fabricated by a powder-in-tube (PIT) technique. Supersaturated solid solutions of Nb-Al powder were obtained by high-energy ball milling, followed by a powder-in-tube process to prepare series of Nb{sub 3}Al precursor tapes. Compared with sintering under normal pressure, the hot-pressing sintering greatly increased the critical current density of the tapes. The results showed that the Nb{sub 3}Al tapes prepared via the powder-in-tube method and hot-pressed sintering could significantly improve the J{sub c} performance, and the value of J{sub c} (8 K, 0 T) was higher than 6 × 10{sup 5} A/cm{sup 2}. The Nb{sub 3}Al tapes after pressing under the pressure of 20 MPa and sintering at 950 {sup ∘}C for 3 h had the best magnetic flux pinning performance, and the sample reached the maximum flux pinning force (F{sub p,max}) of 3.28109 N/m{sup 3} in the magnetic field of 2.2 T.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2019

Central Band Structures: New Insights into the Coupling Effects Between the Pores and Minerals of Sinter

It is important to elucidate the coupling effects that exist between the pores and minerals of sinter to establish the relationships that exist among the technological parameters, microstructures, and performance of the sinter. Based on the formation mechanism of the pores within sinter, four types of central band structures (CBSs) were defined to represent the microstructures of the sinter. During reduction, the cracking behavior of each CBS was studied through a series of experiments conducted at a temperature of 873 K.

36 MATERIALS SCIENCE↗
DOE OSTI2019

Neutron Diffraction and Neutron Radiography Investigation into Powder Sintering of Ti/Al and TiH{sub 2}/Al Compacts

Sintering behaviors of two types of powder compact, i.e., Ti/Al and TiH{sub 2}/Al, under vacuum were studied using in situ neutron diffraction, in situ thermal dilatometric measurement, and ex situ neutron radiography. Their densification, microstructure, hydrogen concentration, and phase transformation features were compared. The results indicate that the predominant phase identified in the samples sintered from both compacts is γ-TiAl phase with minor Ti{sub 3}Al phase. Dehydrogenation of TiH{sub 2} plays a decisive role in the sintering behavior and the resultant microstructure. In comparison with the Ti/Al compact, dehydrogenation occurring in the TiH{sub 2}/Al compact leads to a higher level of densification and faster sintering kinetics.

36 MATERIALS SCIENCE↗
DOE OSTI2019

Effect of SiO{sub 2} on the Formation of Acicular Calcium Ferrite in Sinter

SiO{sub 2} greatly influences the formation of acicular calcium ferrite (ACF), which is the main binder phase in sinter, but the mechanism of its influence is not yet clear. Experiments were carried out under air at 1200 °C with different amounts of SiO{sub 2} mixed with Fe{sub 2}O{sub 3} and Ca(OH){sub 2}. X-ray diffraction (XRD), scanning electron microscopy (SEM), energy-dispersive spectroscopy (EDS), and three-dimensional (3D) reconstruction were used to characterize the phase and morphological changes of the sintered samples. The results show that SiO{sub 2} can form silicon-ferrite of calcium (SFC), which is beneficial to the formation of ACF in sinter. The SFC content first increased and then decreased with the increasing SiO{sub 2} content. The sintered sample contained the highest contents of SFC and ACF when w(SiO{sub 2}) was 3 to 4 pct. The morphological changes in calcium ferrite observed with the increasing SiO{sub 2} content followed a sequence of massive → platy → acicular; both platy calcium ferrite and ACF were the longest in one direction in their 3D morphology. The inclusion of Si{sup 4+} in calcium ferrite crystals changes the crystal growth habit from having no obvious orientation to having a preferential orientation along the (040) or (320) surfaces, as determined by the first-principles calculations and XRD analysis of block samples. Viscosity was the main environmental factor influencing the size of ACF in samples with sufficient liquid phase.

36 MATERIALS SCIENCE↗