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At least 199 records · Page 11

High temperature glass coatings for superalloys and refractory metals

New glasses are used as protective coatings on metals and alloys susceptible to oxidation at high temperatures in oxidizing atmospheres. Glasses are stable and solid at temperatures up to 1000 deg C, adhere well to metal surfaces, and are usable for metals with broad range of expansion coefficients.

Chapman, J. W.↗

Oxidation-resistant coatings for refractory metals used in inert atmospheres

Test conditions and results are reported for various coatings on a 1 percent zirconium columbium alloy at a temperature of 2000 deg F. Molybdenum silicide over molybdenum is most effective coating, tin-aluminum coating is adequately protective, chromium-molybdenum silicides are not protective.

Phillips, W. M.↗

High-temperature strength of refractory-metal wires and consideration for composite applications

Tensile and stress-rupture tests were conducted on wires of W-Hf-C, W-Re-Hf-C, ASTAR 811C (a tantalum alloy), and B-88 (a columbium alloy) at room temperature, 1093 C (2000 F), and 1204 C (2200 F). Metallographic examinations were also made of the wire microstructure after testing. Ultimate tensile strength values up to 2170 meganewtons per square meter (314000 psi) at 1093 C (2000 F) and 1940 meganewtons per square meter (281 000 psi) at 1204 C (2200 F) were obtained for W-Re-Hf-C wire. The best strength values obtained for a 100-hour rupture life were, 1410 meganewtons per square meter (205 000 psi) at 1093 C (2000 F) and 910 meganewtons per square meter (132 000 psi) at 1240 C (2200 F) for W-Re-Hf-C wire. The properties obtained suggested that the wires studied showed promise as potential fiber reinforcement in the 1093 to 1204 C (2000 to 2200 F) temperature range.

Petrasek, D. W.↗

Evaluation of refractory-metal-clad uranium nitride and uranium dioxide fuel pins after irradiation for times up to 10 450 hours at 990 C

The effects of some materials variables on the irradiation performance of fuel pins for a lithium-cooled space power reactor design concept were examined. The variables studied were UN fuel density, fuel composition, and cladding alloy. All pins were irradiated at about 990 C in a thermal neutron environment to the design fuel burnup. An 85-percent dense UN fuel gave the best overall results in meeting the operational goals. The T-111 cladding on all specimens was embrittled, possibly by hydrogen in the case of the UN fuel and by uranium and oxygen in the case of the UO2 fuel. Tests with Cb-1Zr cladding indicate potential use of this cladding material. The UO2 fueled specimens met the operational goals of less than 1 percent cladding strain, but other factors make UO2 less attractive than low-density UN for the contemplated space power reactor use.

Bowles, K. J.↗

Thermal aging effects in refractory metal alloys

The alloys of niobium and tantalum are attractive from a strength and compatibility viewpoint for high operating temperatures required in materials for fuel cladding, liquid metal transfer, and heat pipe applications in space power systems that will supply from 100 kWe to multi-megawatts for advanced space systems. To meet the system requirements, operating temperatures ranging from 1100 to 1600 K have been proposed. Expected lives of these space power systems are from 7 to 10 yr. A program is conducted at NASA Lewis to determine the effects of long-term, high-temperature exposure on the microstructural stability of several commercial tantalum and niobium alloys. Variables studied in the investigation include alloy composition, pre-age annealing temperature, aging time, temperature, and environment (lithium or vacuum), welding, and hydrogen doping. Alloys are investigated by means of cryogenic bend tests and tensile tests. Results show that the combination of tungsten and hafnium or zirconium found in commercial alloys such as T-111 and Cb-752 can lead to aging embrittlement and increased susceptibility to hydrogen embrittlement of ternary and more complex alloys. Modification of alloy composition helps to eliminate the embrittlement problem.

Stephens, J. R.↗

Thermal aging effects in refractory metal alloys

The alloys of niobium and tantalum are attractive from a strength and compatibility viewpoint for high operating temperatures required in materials for fuel cladding, liquid metal transfer, and heat pipe applications in space power systems that will supply from 100 kWe to multi-megawatts for advanced space systems. To meet the system requirements, operating temperatures ranging from 1100 to 1600 K have been proposed. Expected lives of these space power systems are from 7 to 10 yr. A program is conducted at NASA Lewis to determine the effects of long-term, high-temperature exposure on the microstructural stability of several commercial tantalum and niobium alloys. Variables studied in the investigation include alloy composition, pre-age annealing temperature, aging time, temperature, and environment (lithium or vacuum), welding, and hydrogen doping. Alloys are investigated by means of cryogenic bend tests and tensile tests. Results show that the combination of tungsten and hafnium or zirconium found in commercial alloys such as T-111 and Cb-752 can lead to aging embrittlement and increased susceptibility to hydrogen embrittlement of ternary and more complex alloys. Modification of alloy composition helps to eliminate the embrittlement problem.

Stephens, Joseph R.↗

The Role of the Interface in Refractory Metal Alloy Composites

Creep-rupture and tensile tests have been used to evaluate thoriated W-wire reinforced Nb-1 percent Zr alloy matrix composites fabricated via arc-spray monotape technique. A significant creep strength enhancement was observed over the unreinforced matrix alloy while matrix integrity was maintained; the fiber/matrix interface phase is noted to be a strong and ductile W/Nb alloy, which is formed due to the mutual solubility of the constituent metals. High strength, toughness, and thermal stability are demonstrated by this material system, which is also resistant to liquid alkali metal corrosion.

Grobstein, Toni↗