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At least 199 records · Page 11
All sourcesNASA NTRSDOE OSTI
DOE OSTI2022

Unveiling four decades of intensifying precipitation from tropical cyclones using satellite measurements

Increases in precipitation rates and volumes from tropical cyclones (TCs) caused by anthropogenic warming are predicted by climate modeling studies and have been identified in several high intensity storms occurring over the last half decade. However, it has been difficult to detect historical trends in TC precipitation at time scales long enough to overcome natural climate variability because of limitations in existing precipitation observations. We introduce an experimental global high-resolution climate data record of precipitation produced using infrared satellite imagery and corrected at the monthly scale by a gauge-derived product that shows generally good performance during two hurricane case studies but estimates higher mean precipitation rates in the tropics than the evaluation datasets. General increases in mean and extreme rainfall rates during the study period of 1980–2019 are identified, culminating in a 12–18%/40-year increase in global rainfall rates. Overall, all basins have experienced intensification in precipitation rates. Increases in rainfall rates have boosted the mean precipitation volume of global TCs by 7–15% over 40 years, with the starkest rises seen in the North Atlantic, South Indian, and South Pacific basins (maximum 59–64% over 40 years). In terms of inland rainfall totals, year-by-year trends are generally positive due to increasing TC frequency, slower decay over land, and more intense rainfall, with an alarming increase of 81–85% seen from the strongest global TCs. As the global trend in precipitation rates follows expectations from warming sea surface temperatures (11.1%/°C), we hypothesize that the observed trends could be a result of anthropogenic warming creating greater concentrations of water vapor in the atmosphere, though retrospective studies of TC dynamics over the period are needed to confirm.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2020

Seasonal representation of extreme precipitation indices over the United States in CMIP6 present-day simulations

Realistically representing the present-day characteristics of extreme precipitation has been a challenge for global climate models, which is due in part to deficiencies in model resolution and physics, but is also due to a lack of consistency in gridded observations. In this study, we use three observation datasets, including gridded rain gauge and satellite data, to assess historical simulations from sixteen Coupled Model Intercomparison Project Phase 6 (CMIP6) models. We separately evaluate summer and winter precipitation over the United States (US) with a comprehensive set of extreme precipitation indices, including an assessment of precipitation frequency, intensity and spatial structure. The observations exhibit significant differences in their estimates of area-average intensity distributions and spatial patterns of the mean and extremes of precipitation over the US. In general, the CMIP6 multi-model mean performs better than most individual models at capturing daily precipitation distributions and extreme precipitation indices, particularly in comparison to gauge-based data. Also, the representation of the extreme precipitation indices by the CMIP6 models is better in the summer than winter. Although the ‘standard’ horizontal-resolution can vary significantly across CMIP6 models, from ~0.7° to ~2.8°, we find that resolution is not a good indicator of model performance. Overall, our results highlight common biases in CMIP6 models and demonstrate that no single model is consistently the most reliable across all indices.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2024

Seasonal variability and predictability of monsoon precipitation in Southern Africa

Rainfed agriculture is the mainstay of economies across Southern Africa (SA), where most precipitation is received during the austral summer monsoon. This study aims to further our understanding of monsoon precipitation predictability over SA. We use three natural climate forcings, El Niño–Southern Oscillation, Indian Ocean Dipole (IOD), and the Indian Ocean Precipitation Dipole (IOPD)—the dominant precipitation variability mode—to construct an empirical model that exhibits significant skill over SA during monsoon in explaining precipitation variability and in forecasting it with a five-month lead. While most explained precipitation variance (50%–75%) comes from contemporaneous IOD and IOPD, preconditioning all three forcings is key in predicting monsoon precipitation with a zero to five-month lead. Seasonal forecasting systems accurately represent the interplay of the three forcings but show varying skills in representing their teleconnection over SA. This makes them less effective at predicting monsoon precipitation than the empirical model.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2023

Contributions to regional precipitation change and its polar-amplified pattern under warming

Abstract The polar regions are predicted to experience the largest relative change in precipitation in response to increased greenhouse-gas concentrations, where a substantial absolute increase in precipitation coincides with small precipitation rates in the present-day climate. The reasons for this amplification, however, are still debated. Here, we use an atmospheric energy budget to decompose regional precipitation change from climate models under greenhouse-gas forcing into contributions from atmospheric radiative feedbacks, dry-static energy flux divergence changes, and surface sensible heat flux changes. The polar-amplified relative precipitation change is shown to be a consequence of the Planck feedback, which, when combined with larger polar warming, favors substantial atmospheric radiative cooling that balances increases in latent heat release from precipitation. Changes in the dry-static energy flux divergence contribute modestly to the polar-amplified pattern. Additional contributions to the polar-amplified response come, in the Arctic, from the cloud feedback and, in the Antarctic, from both the cloud and water vapor feedbacks. The primary contributor to the intermodel spread in the relative precipitation change in the polar region is also the Planck feedback, with the lapse rate feedback and dry-static energy flux divergence changes playing secondary roles. For all regions, there are strong covariances between radiative feedbacks and changes in the dry-static energy flux divergence that impact the intermodel spread. These results imply that constraining regional precipitation change, particularly in the polar regions, will require constraining not only individual feedbacks but also the covariances between radiative feedbacks and atmospheric energy transport.

Bonan, David B. (ORCID:0000000338676009)↗
DOE OSTI2019

Effect of solute concentration on the spectral induced polarization response of calcite precipitation

SUMMARY Induced calcite precipitation is used in geotechnics to modify the mechanical and hydrological properties of the underground. Laboratory experiments have shown that spectral induced polarization (SIP) measurements can detect calcite precipitation. However, the results of previous studies investigating the SIP response of calcite precipitation were not fully consistent. This study aims to investigate how the SIP response of calcite depends on solute concentration to explain the differences in SIP response observed in previous studies. A four-phase experiment with SIP measurements on a column filled with sand was performed. In phase I, calcite precipitation was generated for a period of 12 d by co-injecting Na2CO3 and CaCl2 solutions through two different ports. This resulted in a well-defined calcite precipitation front, which was associated with an increase in the imaginary part of the conductivity ($\sigma ^{\prime\prime}$). In phase II, diluted solutions were injected into the column. This resulted in a clear decrease in $\sigma ^{\prime\prime}$. In phase III, the injection of the two solutions was stopped while calcite precipitation continued and solute concentrations in the mixing zone decreased. Again, this decreased $\sigma ^{\prime\prime}$. Finally, the injection rate of the Na2CO3 solution was reduced relative to that of the CaCl2 solution in phase IV. This resulted in a shift of the mixing zone away from the calcite precipitation front established in phase I and an associated decrease of $\sigma ^{\prime\prime}$. These results imply that the SIP response of calcite is highly sensitive to the solute concentration near the precipitates, which may explain previously reported conflicting results.

Izumoto, Satoshi↗
DOE OSTI2026

Surface Quantitative Precipitation Estimates (SQUIRE) of Snow Water Equivalent from the Surface Atmospheric Integrated Field Laboratory

The upper Colorado River basin is the primary source of water for 40 million people. With declining snowpack in the basin, forecasting hydrological budgets in the Southwest United States is more important than ever. However, due in part, to a lack of reliable observations of precipitation in complex terrain, hydrological models struggle to assess and forecast snowpack snow water equivalent (SWE) in the upper Colorado River basin (UCRB). Therefore, the need for more reliable SWE forecasts in the UCRB motivated the U.S. Department of Energy Atmospheric Radiation Measurement Facility’s Surface Atmospheric Integrated Field Laboratory (SAIL) that occurred from June 2021 to June 2023. During SAIL, the X-band precipitation radar from Colorado State University conducted volume scans sampling the precipitation properties over the UCRB. The ARM facility developed a gridded Surface Quantitative Precipitation Estimates (SQUIRE) product from the radar observations. To do this, various daily SWE estimates from radar using the radar reflectivity factor Z e and specific differential phase K dp were compared against ground-based precipitation gauges. SWE in precipitation calculated from Wolfe and Snider’s S–Z e estimator was in best agreement with the rain gauges for the days when SWE < 12 mm. For days with SWE > 12 mm, the WSR-88D Intermountain West relationship had the best agreement with the precipitation gauges. Airborne snow depth observations show that SQUIRE captures regions of orographic enhancement in the mountains to the west and northwest of the SAIL study area, indicating that the scientific community should focus on understanding and ultimately simulating orographic atmospheric precipitation processes to improve UCRB snowpack SWE assessment and forecasting.

Hydrology↗
DOE OSTI2023

Evaluating Contemporary and Future-Scenario Substantial-Precipitation Events in the Missouri River Basin Using Object-Oriented Analysis

The Missouri River Basin is the largest single river basin in the United States, and, as such, it plays an important role in natural ecosystems as well as the country’s economy, through agriculture, hydroelectric power generation, and transportation. Episodes of heavy precipitation can have a substantial negative impact on all these aspects of the basin, so understanding how well these episodes are simulated and projected to change in the future climate is important. We analyzed contemporary and projected mid-century behavior of heavy-precipitation episodes using an object-oriented analysis to diagnose short-term (≥5-day) and extended-period (≥30-day) events with substantial precipitation, using PRISM gridded, observed precipitation and RegCM4 regional-climate simulations that used outputs from two different GCMs for boundary conditions. The simulations were produced for the North American portion of the CORDEX program. A 25 km grid was used for the simulations and for aggregated PRISM precipitation. Overall, the simulated contemporary-climate events compared favorably with the PRISM events’ frequency and duration. The simulated event areas tended to be larger than the areas in the PRISM events, suggesting that the effective resolution of the simulations is greater than 25 km. Event areas and durations change little going from contemporary to scenario climate. The short-term events increase in frequency by an amount commensurate with the increase in mean precipitation simulated for the basis. However, the extended-term events showed little change in frequency, despite the average precipitation increase. Roughly half the extended-period events overlapped with at least one short-term event in both the observations and the simulations. Extended-period events that overlap a short-term event generally have larger areas and longer durations compared to their counterparts with no overlapping short-term events. Understanding the climate dynamics yielding the two types of extended-period events could be useful for assessing future changes in the Missouri River Basin’s heavy precipitation events and their impact.

Fisel, Brandon J.↗
DOE OSTI2021

The prevalence of precipitation from polar supercooled clouds

Abstract. Supercooled clouds substantially impact polar surface energy budgets, but large-scale models often underestimate their occurrence, which motivates accurately establishing metrics of basic processes. An analysis of long-term measurements at Utqiaġvik, Alaska, and McMurdo Station, Antarctica, combines lidar-validated use of soundings to identify supercooled cloud layers and colocated ground-based profiling radar measurements to quantify cloud base precipitation. We find that more than 85 % (75 %) of sampled supercooled layers are precipitating over the Arctic (Antarctic) site, with more than 75 % (50 %) precipitating continuously to the surface. Such high frequencies can be reconciled with substantially lesser spaceborne estimates by considering differences in radar hydrometeor detection sensitivity. While ice precipitation into supercooled clouds from aloft is common, we also find that the great majority of supercooled cloud layers without ice falling into them are themselves continuously generating precipitation. Such sustained primary ice formation is consistent with continuous activation of immersion-mode ice-nucleating particles (INPs), suggesting that supercooled cloud formation is a principal gateway to ice formation at temperatures greater than ∼-38 ∘C over polar regions. The prevalence of weak precipitation fluxes is also consistent with supercooled cloud longevity and with well-observed and widely simulated case studies. An analysis of colocated microwave radiometer retrievals suggests that weak precipitation fluxes can be nonetheless consequential to moisture budgets for supercooled clouds owing to small liquid water paths. The results here also demonstrate that the observed abundance of mixed-phase clouds can vary substantially with instrument sensitivity and methodology. Finally, we suggest that these ground-based precipitation rate statistics offer valuable guidance for improving the representation of polar cloud processes in large-scale models.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2021

Effects of coupling a stochastic convective parameterization with the Zhang–McFarlane scheme on precipitation simulation in the DOE E3SMv1.0 atmosphere model

Abstract. A stochastic deep convection parameterization is implemented into the US Department of Energy (DOE) Energy Exascale Earth System Model (E3SM) Atmosphere Model version 1.0 (EAMv1). This study evaluates its performance in simulating precipitation. Compared to the default model, the probability distribution function (PDF) of rainfall intensity in the new simulation is greatly improved. The well-known problem of “too much light rain and too little heavy rain” is alleviated, especially over the tropics. As a result, the contribution from different rain rates to the total precipitation amount is shifted toward heavier rain. The less frequent occurrence of convection contributes to suppressed light rain, while more intense large-scale and convective precipitation contributes to enhanced heavy total rain. The synoptic and intraseasonal variabilities of precipitation are enhanced as well to be closer to observations. The sensitivity of the rainfall intensity PDF to the model vertical resolution is examined. The relationship between precipitation and dilute convective available potential energy in the stochastic simulation agrees better with that in the Atmospheric Radiation Measurement (ARM) observations compared with the standard model simulation. The annual mean precipitation is largely unchanged with the use of the stochastic scheme except over the tropical western Pacific, where a moderate increase in precipitation represents a slight improvement. The responses of precipitation and its extremes to climate warming are similar with or without the stochastic deep convection scheme.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2022

Impacts of the boreal summer intraseasonal oscillation on precipitation extremes in Indonesia

The relationship between boreal summer intraseasonal oscillation (BSISO) and precipitation extremes over Indonesia is investigated using observational datasets from 30 years (1987–2016) of rain gauge measurements and the gridded Asian Precipitation–Highly Resolved Observational Data Integration Towards Evaluation of Water Resources from 1998 to 2015. The results indicate that the frequency of daily extreme precipitation events in Indonesia (defined as total precipitation above the 95th percentile) during extended boreal summer (May–August) is significantly modulated by BSISO, especially over the western and northern regions. Under the influences of BSISO1, the probability of the precipitation extremes over Sumatra and Borneo increases by 20–120% (relative to the seasonal probability) during phases 1–3 and approximately 50–80% over the eastern part of Borneo and Sulawesi during phase 4. Under BSISO2, the probability of the extremes increases up to 40% over Sumatra during phases 1 and 2 and up to 140% over Borneo and Sulawesi during phases 2 and 3. The increase in the probability of extreme summer precipitation is associated with enhanced large–scale moisture flux convergence and upward moisture transport induced by the active phases of BSISO. Finally, these results provide potential information for medium–to extended–range predictions of summer precipitation extremes in Indonesia.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2024

Stress field and interaction forces between dislocations and precipitate distributions

A computational method is developed for calculation of the stress field and interaction forces between dislocations and precipitates of arbitrary shape and distribution. The internal stress generated by precipitates due to coherency strain is implemented within the discrete dislocation dynamics (DDD) framework. The s-version finite element method (s-FEM), which models a precipitate of arbitrary shape using a local mesh is used to calculate coherency stress fields. The method facilitates meshing precipitate volumes of arbitrary geometry, and multiple local meshes can be superimposed at various positions of the global mesh. Accuracy and convergence conditions of the method are established. For a single precipiate, the method is shown to be 3.5 times faster than a standard FEM calculation for the same accuracy, and the gain in speed increases with the number of precipitates. The CRSS of spherical precipitates is found to be higher than disk-shaped precipitates of the same volume fraction.

42 ENGINEERING↗
DOE OSTI2021

Long-term single-column model intercomparison of diurnal cycle of precipitation over midlatitude and tropical land

General Circulation Models (GCMs) have for decades exhibited difficulties in modelling the diurnal cycle of precipitation (DCP). This issue can be related to inappropriate representation of the processes controlling sub-diurnal phenomena like convection. In this study, 11 single-column versions of GCMs are used to investigate the interactions between convection and environmental conditions, processes that control nocturnal convections, and the transition from shallow to deep convection on a diurnal time-scale. Long-term simulations are performed over two continental land sites: the Southern Great Plains (SGP) in the USA for 12 summer months from 2004 to 2015 and the Manacapuru site at the central Amazon (MAO) in Brazil for two full years from 2014 to 2015. The analysis is done on two regimes: afternoon convective regime and nocturnal precipitation regime. Most models produce afternoon precipitation too early, likely due to the missing transition of shallow-to-deep convection in these models. At SGP, the unified convection schemes better simulate the onset time of precipitation. At MAO, models produce the heating peak in a much lower level compared with observation, indicating too shallow convection in the models. For nocturnal precipitation, models that produce most of nocturnal precipitation all allow convection to be triggered above the boundary layer. This indicates the importance of model capability to detect elevated convection for simulating nocturnal precipitation. Sensitivity studies indicate that (a) nudging environmental variables towards observations has a minor impact on DCP, (b) unified treatment of shallow and deep convection and the capability to capture mid-level convection can help models better capture DCP, and (c) the interactions of the atmosphere with other components in the climate system (e.g. land) are also important for DCP simulations in coupled models. Finally, these results provide long-term statistical insights on which physical processes are essential in climate models to simulate DCP.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2021

Projected Changes in Temperature and Precipitation Over the United States, Central America, and the Caribbean in CMIP6 GCMs

The Coupled Model Intercomparison Project Phase 6 (CMIP6) dataset is used to examine projected changes in temperature and precipitation over the United States (U.S.), Central America and the Caribbean. The changes are computed using an ensemble of 31 models for three future time slices (2021–2040, 2041–2060, and 2080–2099) relative to the reference period (1995–2014) under three Shared Socioeconomic Pathways (SSPs; SSP1-2.6, SSP2-4.5, and SSP5-8.5). The CMIP6 ensemble reproduces the observed annual cycle and distribution of mean annual temperature and precipitation with biases between – 0.93 and 1.27 °C and – 37.90 to 58.45%, respectively, for most of the region. However, modeled precipitation is too large over the western and Midwestern U.S. during winter and spring and over the North American monsoon region in summer, while too small over southern Central America. Temperature is projected to increase over the entire domain under all three SSPs, by as much as 6 °C under SSP5-8.5, and with more pronounced increases in the northern latitudes over the regions that receive snow in the present climate. Annual precipitation projections for the end of the twenty-first century have more uncertainty, as expected, and exhibit a meridional dipole-like pattern, with precipitation increasing by 10–30% over much of the U.S. and decreasing by 10–40% over Central America and the Caribbean, especially over the monsoon region. Seasonally, precipitation over the eastern and central subregions is projected to increase during winter and spring and decrease during summer and autumn. Over the monsoon region and Central America, precipitation is projected to decrease in all seasons except autumn. The analysis was repeated on a subset of 9 models with the best performance in the reference period; however, no significant difference was found, suggesting that model bias is not strongly influencing the projections.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2025

MX precipitate behavior in an irradiated advanced Fe-9Cr steel: Helium effects on phase stability

As part of an ongoing series aimed at optimizing Fe-9Cr reduced activation ferritic/martensitic (RAFM) alloys for fusion energy systems, this study explores MX precipitate behavior under dual-ion irradiations, specifically examining correlations between helium transmutation and irradiation-induced damage. Utilizing single and dual-beam ion irradiation, the research explores the combined effects of helium (10–25 appm He/dpa), temperature (400–600 °C), and damage levels (15–100 dpa) on the microstructural evolution of CNA9 steel, a variant of Castable Nanostructured Alloys (CNAs). The study demonstrates that helium co-implantation hinders radiation-enhanced coarsening of MX-TiC precipitates at 500 and 600 °C, maintaining MX-TiC precipitate stability at moderate damage levels (15 dpa) but failing to prevent complete precipitate dissolution at higher damage levels (≥50 dpa) when irradiated at 500 °C. Here, a generalized precipitate stability model suggests that helium-induced suppression of diffusion alters the balance between recoil resolution and back diffusion for MX-TiC precipitates, enhancing the current understanding of precipitate behavior under damage and transmutation simulated dual-ion irradiation conditions.

Characterization↗
DOE OSTI2022

Using θ' interfaces as templates for planar L1 2 precipitation in AlCuMnZr alloys

Controlled Mn and Zr additions to Al-Cu alloys have allowed for the improved retention of mechanical properties after extended 350°C exposures by stabilizing the main strengthening θ' (Al 2 Cu) phase. Ultimately, θ'/L1 2 (Al 3 Zr) co-precipitate formation stabilizes θ' most effectively; however, Zr diffuses sluggishly and has low solubility in aluminum castings. Increasing the Zr segregation rate would allow for faster and more effective θ'/L1 2 co-precipitation. It is demonstrated that the Zr segregation rate is faster when the Zr matrix content is higher. A much higher Zr matrix content was achieved by rapid cooling during additive manufacturing (AM) that produces θ'/L1 2 co-precipitation faster, which is shown by scanning transmission electron microscopy and atom probe tomography experiments. It was also found that Zr continuously segregates to θ' interfaces up to the most aggressive heat treatment studied such that planar L1 2 precipitates remain after the metastable θ' dissolves. In this manner, we demonstrate that θ' coherent interfaces serve as perfect templates to form stable planar L1 2 precipitates that can provide strength at higher temperatures than traditional θ' strengthened AlCu alloys. This work introduces an alloy design strategy that uses metastable precipitates to quickly nucleate and grow co-precipitates with a desired geometry that contain slow diffusing elements. These ideas can be applied to engineer more heat resistant alloys by taking advantage of high solute matrix contents enabled by rapid cooling during additive manufacturing.

36 MATERIALS SCIENCE↗
DOE OSTI2024

Hydrologic applicability of satellite-based precipitation estimates for irrigation water management in the data-scarce region

Reliable precipitation estimates are crucial for planning and managing water resources, monitoring hydrologic extremes, and fulfilling irrigation water requirements. Accurate precipitation estimates are particularly challenging in complex mountain terrains, where monitoring gauges are often sparsely distributed due to their remote locations, and high installation and long-term operation costs. Recent advances in satellite-based precipitation estimates offer promising opportunities to improve our understanding of hydrologic processes and their applications for irrigation water management. Several datasets are available varying considerably in terms of their data sources, quality control methods, estimation procedure, and spatiotemporal resolutions. Choosing the most suitable dataset for a particular application is a complex task. In this study, we (1) evaluate the performance of six satellite-based precipitation estimates (SPEs): i) CHIRPS v2.0, ii) CMORPH v1.0, iii) ERA5, iv) IMERG v6, v) MSWEP v2.8, and vi) PERSIANN-CDR against the gauge precipitation using continuous statistical and categorical indices, (2) integrate SPEs with a calibrated semi-distributed hydrologic model to predict streamflow, and (3) demonstrate practical implications of improved streamflow prediction for irrigation water management in the central Himalayan region, Nepal. Our results illustrate that satellite-based precipitation estimates have competitive performance in capturing a wide range of rainfall characteristics, with demonstrated variability across river basins and time scales. Further, there are no significant discrepancies observed in satellite-based precipitation estimates for estimating irrigation water requirements for the three major crops (maize, wheat, and paddy) during the cropping period across the selected river basins, showing a greater promise for irrigation water management planning and decision making.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2023

Role of Fe in long-range ordered Ni 2 Cr precipitates in Ni-Cr-Fe model alloys during isothermal aging

The precipitation of new phases during long-term service at elevated temperatures is a concern for the thermal stability of engineering alloys. In Ni-Cr-based alloys, e.g., Alloy 690, the formation of long-range ordered Ni 2 Cr causes embrittlement and may impact the lifetime of nuclear power plant components. In this work, we quantify the formation and evolution of Ni 2 Cr precipitation in eleven Ni-Cr-Fe model alloys with 0, 5, 7, and 10wt % Fe contents, and with Ni/Cr atomic ratios of 1.8, 2.0, 2.2, 2.4. These alloys were isothermally aged up to 10,000h at temperatures between 330 and 475°C. The alloys were characterized by synchrotron-based x-ray diffraction and Vickers hardness testing to quantify Ni 2 Cr precipitate size, and the impact of precipitate size on the mechanical properties as a function of Fe content. After 10,000 h of aging at 475°C and 418°C, the formation of Ni 2 Cr was observed in all alloys with 0 and 5wt % Fe. After 10,000h of aging at 418°C, Ni 2 Cr precipitates were also observed in the 7wt % Fe containing Ni/Cr=2.0 sample. Further, no clear evidence of Ni 2 Cr was observed in any of the 10wt % Fe samples at any time and temperature combination. We find that the face-centered cubic matrix lattice contraction and Vickers hardness are correlated with the Ni 2 Cr formation. The greatest change in hardness and lattice contraction occurs in stoichiometric alloys (Ni/Cr=2.0) with 0wt % Fe at 475°C. The rate of change in the material properties for the 5wt % Fe alloys is reduced, however the magnitude of changes is similar to 0wt % Fe alloys. A precipitation hardening model developed for Ni-Cr alloys based on critical resolved shear stress with weakly coupled dislocations shows a clear link between Ni 2 Cr precipitate size and hardness. This trend held across all alloys with Ni 2 Cr formation regardless of Fe concentration. This important structure-property relationship can potentially help define Ni-Cr-Fe-based component lifetimes directly through an understanding of how Ni 2 Cr formation impacts mechanical properties as a function of Fe content.

36 MATERIALS SCIENCE↗
DOE OSTI2026

Ion-Specific Precipitation of Extractants Enables Rare-Earth Separation and Wastewater Remediation from Solvent Extraction of Critical Elements

The increasing demand for rare-earth elements (REEs) necessitates sustainable recovery strategies, particularly from secondary sources, such as electronic waste. Solvent extraction is the primary industrial method for REE separation; however, the unintentional dissolution of extractants into wastewater poses serious environmental risks, leading to organic contamination and process inefficiencies. Existing wastewater treatment methods struggle to remove these persistent pollutants, underscoring the need for innovative recovery approaches. Herein, we present a ligand-mediated precipitation strategy that simultaneously recovers REEs and removes dissolved extractants from solvent extraction wastewater. We show that residual extractants in the aqueous phase can selectively bind REEs, inducing their precipitation while leaving transition metals in solution. By integrating FTIR spectroscopy, EDS, XPS, EXAFS, and SAXS, we elucidate the mechanism of ion-specific precipitation and the local coordination environment of metal ions in the precipitate. Importantly, we demonstrate that the precipitated extractants can be efficiently recovered and reused, providing a closed-loop solution that enhances sustainability. Applying this method to leachates from samarium–cobalt (Sm–Co) and neodymium–iron–boron (NdFeB) mixed magnets, we achieve highly selective REE precipitation under mild conditions, demonstrating a scalable and cost-effective pathway for REE recovery, wastewater purification, and extractant recycling. In conclusion, by integrating element-specific ligand-mediated precipitation with extractant reuse, this work offers a transformative approach to REE separation that reduces the environmental impact while improving resource efficiency.

E-waste↗