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At least 199 records · Page 11
All sourcesNASA NTRSDOE OSTI
NASA NTRS1977

Technological development of cylindrical and flat shaped high energy density capacitors

Cylindrical wound metallized film capacitors rated 2 micron F 500 VDC that had an energy density greater than 0.3 J/g, and flat flexible metallized film capacitors rated at 2 micron F 500 VDC that had an energy density greater than 0.1 J/g were developed. Polysulfone, polycarbonate, and polyvinylidene fluoride (PVF2) were investigated as dielectrics for the cylindrical units. PVF2 in 6.0 micron m thickness was employed in the final components of both types. Capacitance and dissipation factor measurements were made over the range 25 C to 100 C, and 10 Hz to 10 kHz. No pre-life-test burning was performed, and six of ten cylindrical units survived a 2500 hour AC plus DC lift test. Three of the four failures were infant mortality. All but two of the flat components survived 400 hours. Finished energy densities were 0.104 J/g at 500 V and 0.200 J/g at 700 V, the energy density being limited by the availability of thin PVF2 films.

Zelik, J. A.↗
NASA NTRS1976

Materials for encapsulation systems for terrestrial photovoltaic arrays

The paper is concerned with glass and polymeric candidate materials and processes for potential encapsulation systems that could be used in low-cost long-life terrestrial photovoltaic arrays. The characteristics of encapsulation systems in use are reviewed, and the properties of proposed materials are examined. These materials include acrylics, epoxies, fluorocarbons, polycarbonates, polyesters, polyimides, polyxylylenes, and silicones. Properties of glass types are also considered. The prospects for glass and polymeric systems are analyzed, and the knowledge gained from a study of existing systems is discussed with attention to weather/aging effects, failures, environments, hazards, costs, development efforts, and materials choices.

Carmichael, D. C.↗
NASA NTRS1977

Effect of heating rate on toxicity of pyrolysis gases from some synthetic polymers

The effect of heating rate on the toxicity of the pyrolysis gases from some synthetic polymers was investigate, using a screening test method. The synthetic polymers were polyethylene, polystyrene, polymethyl methacrylate, polycarbonate, ABS, polyaryl sulfone, polyether sulfone, and polyphenylene sulfide. The toxicants from the sulfur-containing polymers appeared to act more rapidly than the toxicants from the other polymers. It is not known whether this effect is due primarily to differences in concentration or in the nature of the toxicants. The carbon monoxide concentrations found do not account for the observed results.

Hilado, C. J.↗
NASA NTRS1979

High-energy-density cylindrical capacitors

Manufacturing technique produces high quality metalized-film cylindrical capacitors of energy density greater than 0.1 J/g uncased, using either 24-gage polyvinylidene flouride or 14-gage polycarbonate film. Components are wound wrinkle-free on hollow PTFE cores, using winding machine that applies constant dynamically controlled tension to film during winding operation.

Parker, R. D.↗
NASA NTRS1975

Approaches to flame resistant polymeric materials

Four research and development areas are considered for further exploration in the quest of more flame-resistant polymeric materials. It is suggested that improvements in phenolphthalein polycarbonate processability may be gained through linear free energy relationship correlations. Looped functionality in the backbone of a polymer leads to both improved thermal resistance and increased solubility. The guidelines used in the pyrolytic carbon production constitute a good starting point for the development of improved flame-resistant materials. Numerous organic reactions requiring high temperatures and the techniques of protected functionality and latent functionality constitute the third area for exploration. Finally, some well-known organic reactions are suggested for the formation of polymers that were not made before.

Liepins, R.↗
NASA NTRS1978

Characterization of flammability properties of some thermoplastic and thermoset resins

The thermochemical and flammability properties of some thermally stable polymers considered for use in aircraft interiors are described. The properties studied include: (1) thermomechanical properties such as glass transition and melt temperature; (2) dynamic thermogravimetric analysis in anaerobic environment; (3) flammability properties such as oxygen index, flame spread, and smoke evolution; and (4) selected physical properties. The thermoplastic polymers evaluated included polyphenylene sulfide, polyaryl sulfone, 9,9-bis(4-hydroxyphenyl)-fluorene polycarbonate-poly(dimethylsiloxane) and polyether sulfone. The thermoset polymers evaluated included epoxy, bismaleimide, a modified phenolic and polyaromatic melamine resin. These resins were primarily used in the fabrication of glass reinforced prepregs for the construction of experimental panels. Test results and relative rankings of some of the flammability parameters are presented and the relationship of the molecular structure, char yield, and flammability properties of these polymers are discussed.

Kourtides, D. A.↗
NASA NTRS1979

Thermochemical characterization of some thermally stable thermoplastic and thermoset polymers

The thermochemical and flammability properties of some thermally stable polymers considered for use in aircraft interiors are described. The properties studied include: (1) thermomechanical properties such as glass transition and melt temperature; (2) dynamic thermogravimetric analysis in anaerobic environment; (3) flammability properties such as oxygen index, flame spread, and smoke evolution; and (4) selected physical properties. The thermoplastic polymers evaluated include polyphenylene sulfide, polyaryl sulfone, 9,9-bis(4-hydroxyphenyl)-fluorene polycarbonate-poly(dimethylsiloxane) and polyether sulfone. The thermoset polymers evaluated include epoxy, bismaleimide, a modified phenolic, and polyaromatic melamine resin. These resins were primarily used in the fabrication of glass-reinforced prepregs for the construction of experimental panels. Test results and relative rankings of some of the flammability parameters are presented, and the relationship of the molecular structure, char yield, and flammability properties of these polymers are discussed.

Kourtides, D. A.↗
NASA NTRS1979

Concentration-time data in toxicity tests and resulting relationships

Periodic analyses for carbon monoxide and methane in the animal exposure chamber during pyrolysis of polyethylene at 800 C without forced air flow showed that the concentrations of these compounds increased with exposure time. These observations, and similar observations for polyurethane flexible foam, permitted the calculation of carbon monoxide toxicity in terms of a DP (Death Product Concentration) value, in addition to flammability in terms of HC (Hydro Carbon) value. Observed DP values exceeding the critical DP(CO) value of 47,200 ppm-min for carbon monoxide may indicate that lethal exposures were reached earlier but not immediately manifested because of the time delay involved in physiological processes. On the basis of this DP(CO) value, carbon monoxide could have been the sole toxicant in the case of polyethylene, polypropylene, polyoxymethylene, polystyrene, polycarbonate, ethylene propylene diene rubber, and wood.

Hilado, C. J.↗
NASA NTRS1979

Cosmic ray isotope abundances from chromium to nickel

IRIS, a telescope consisting of a large-area precision Cerenkov detector, scintillators, spark chambers, and a passive stack of Lexan polycarbonate track detectors, was exposed to the primary cosmic radiation for 6.6 sq m sr hr in a balloon flight in 1976. This measurement has yielded the isotopic composition of the iron-group elements Cr, Mn, Fe, and Ni with an average mass resolution of 0.65 amu for the energies 320-500 MeV per amu at the detector. This experiment places the most severe constraints to date on deviation from solar-system composition of the source of the cosmic radiation. Upper limits of 10 percent are placed on the ratios Fe-54/Fe-56 and Fe-58/Fe-56, which are inconsistent with large departures from solar system source composition reported by other workers. The isotopic measurements of Fe and Ni preclude the possibility that these cosmic rays were produced in a single e-process zone. The mean mass of Mn is less than 55, indicating the presence of electron-capture species produced by spallation.

Tarle, G.↗
NASA NTRS1981

Cap protects aircraft nose cone

Inexpensive, easily fabricated cap protects aircraft nose cone from erosion. Made of molded polycarbonate, cap has been flight tested at both subsonic and supesonic speeds. Its strength and erosion characteristics are superior to those of fiberglass cones.

Bryan, C. F., Jr.↗
NASA NTRS1980

Environmental stress cracking of polymers

A two point bending method for use in studying the environmental stress cracking and crazing phenomena is described and demonstrated for a variety of polymer/solvent systems. Critical strain values obtained from these curves are reported for various polymer/solvent systems including a considerable number of systems for which critical strain values have not been previously reported. Polymers studied using this technique include polycarbonate (PC), ABS, high impact styrene (HIS), polyphenylene oxide (PPO), and polymethyl methacrylate (PMMA). Critical strain values obtained using this method compared favorably with available existing data. The major advantage of the technique is the ability to obtain time vs. strain curves over a short period of time. The data obtained suggests that over a short period of time the transition in most of the polymer solvent systems is more gradual than previously believed.

Mahan, K. I.↗
NASA NTRS1980

Shape change of Galileo probe models in free-flight tests

Scale models of the Galileo Probe made of polycarbonate, AXF5Q graphite, carbon-carbon composite, and carbon-phenolic were flown in a free flight range in an ambient gas of air, krypton, or xenon. Mach numbers varied between 14 and 24, Reynolds numbers between 300,000 and 1,000,000, stagnation pressures between 31 and 200 atm, and stagnation point heat transfer rates between 10 and 1,000 kW/sq cm. Shadowgraphs indicate gouging ablation of the aft portion of the frustum; the gouging was moderate in air and severe in the noble gases. The graphite models break in the same region. An explanation of the phenomena is offered in terms of the strong compression and shear caused by the reattachment of a turbulent separated flow. Conditions are calculated for similar tests appropriate for Von Karman Facility of the Arnold Engineering Development Center in which a larger model can be flown in argon.

Park, C.↗
NASA NTRS1980

Thermal diffusivity measurements using a pulsed dual-beam thermal lens technique

A novel pulsed dual-beam thermal lens technique for the determination of thermal diffusivity of liquids and solids was developed. In this technique a transient thermal lens is formed in the test specimen by using a dye laser pulse as a heating source and the thermal lens decay is monitored by means of a CW He-Ne laser. The technique is fast and contactless and avoids some of the major difficulties of conventional methods. Thermal diffusivities for water and a polycarbonate plastic were measured and found to be in agreement with literature values. Considerable simplification and minimization of certain errors was achieved by use of a reference material.

Gupta, M. C.↗
NASA NTRS1981

Super miniaturization of film capacitor dielectrics

The alignment of the stable electrical characteristics of film capacitors in the physical dimensions of ceramic and tantalum capacitors are discussed. The reliability of polycarbonate and mylar capacitors are described with respect to their compatibility with military specifications. Graphic illustrations are presented which show electrical and physical comparisons of film, ceramic, and tantalum capacitors. The major focus is on volumetric efficiency, weight reduction, and electrical stability.

Lavene, B.↗
NASA NTRS1981

Grafting of 2 (2-hydroxy-5-vinylphenyl) 2H-benzotriazole onto polymers with aliphatic groups. Synthesis and polymerization of 2 (2-hydroxy-5-isopropenylphenyl) 2H-benzotriazole and a new synthesis of 2 (2-hydroxy-5-vinylphenyl) 2H-benzotriazole

Successful grafting of 2(2-hydroxy-5-vinylphenyl)2H-benzotriazole onto saturated aliphatic C-H groups of polymers has been accomplished. When the grafting reaction was carried out in chlorobenzene at 150 C = 160 C with di-tertiarybutylperoxide as the grafting initiator, grafts as high as 20 percent - 30 percent at a grafting efficiency of 50 percent and 80 percent have readily been obtained. The grafting reaction was carried out in tubes sealed under high vacuum since trace amounts of oxygen cause complete inhibition of the grafting reaction by the phenolic monomer. On a variety of different polymers including atactic polypropylene, ethylene/vinyl acetate copolymer, poly(methyl methacrylate), poly(butyl acrylate), and polycarbonate were used.

Pradellok, W.↗
NASA NTRS1982

On elastic-plastic analysis of an overloaded breech ring using NASTRAN

The piece-wise linear analysis option of the NASTRAN code was used to analyze a photoplastic model for a sliding breech mechanism. A two dimensional finite element representation for the breech ring was chosen and the material was made of polycarbonate resin. The aluminum block was regarded as rigid and the width of contact was assumed to remain unchanged during loading. The displacements and stresses in the breech ring were obtained for loading in the elastic as well as plastic range. The maximum tensile stresses before and after complete unloading were obtained and compared with numerical and experimental results.

Chen, P. C. T.↗
NASA NTRS1983

Fire resistant films for aircraft applications

Alternative sandwich panel decorative films were investigated as replacements for the polyvinyl fluoride currently used in aircraft interiors. Candidate films were studied for flammability, smoke emission, toxic gas emission, flame spread, and suitability as a printing surface for the decorative acrylic ink system. Several of the candidate films tested were flame modified polyvinyl fluoride, polyvinylidene fluoride, polyimide, polyamide, polysulfone, polyphenylsulfone, polyethersulfone, polybenzimidazole, polycarbonate, polyparabanic acid, polyphosphazene, polyetheretherketon, and polyester. The films were evaluated as pure films only, films silk-screened with an acrylic ink, and films adhered to a phenolic fiberglass substrate. Films which exhibited the highest fire resistant properties included PEEK polyetheretherketon, Aramid polyamide, and ISO-BPE polyester.

Kourtides, D. A.↗