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At least 199 records · Page 11
All sourcesNASA NTRSDOE OSTI
NASA NTRS1972

Ultraviolet and charged particle irradiation of proposed solar cell coverslide materials and conductive coatings for the Helios spacecraft

Coverslide materials consisting of Corning 7940 fused silica, multilayers of titanium and manganese oxides (blue reflector), and indium oxide (conductive-coating) were exposed to 16 UVSC up to 800 EUVSH in vacuum. Slight changes in optical transmittance and optical absorptance were found in the (200-360) millimicron regions of the fused silica and conductive coating respectively. Exposure to 4 KeV protons and 4.5 KeV electrons in vacuum, produced decreases of several percent in transmittance, (200-360) millimicron region in the fused silicas after total fluxes less or = 10 to the 14th power particles/sq cm. Sheet resistance of the conductive coating increased above 1.0 kilo-ohm/square after a total flux less or = 10 to the 14th power particles/sq cm. Solar cells with coverglasses utilizing the indium oxide conductive coating were exposed to 1 Mev electrons and 1 Mev protons in air and in vacuum. Total fluxes ranged from 10 to the 11th power particles/sq cm to 10 to the 15th power particle/sq cm. There was no appreciable degradation in the resistance of the conductive coating during or after these tests.

Fry, J.↗
NASA NTRS1972

Experimental observation of Wannier levels in semi-insulating gallium arsenide.

Optical absorption in an electric field has been of increased interest in recent years since Callaway predicted that the Wannier levels may be observable in direct-transition semiconductors such as GaAs. In this work, such levels have been observed for the first time and found to be in substantial agreement with the Callaway theory.

Koss, R. W.↗
NASA NTRS1973

Instrumentation for air quality measurements.

Comparison of the new generation of air quality monitoring instruments with some more traditional methods. The first generation of air quality measurement instruments, based on the use of oxidant coulometric cells, nitrogen oxide colorimetry, carbon monoxide infrared analyzers, and other types of detectors, is compared with new techniques now coming into wide use in the air monitoring field and involving the use of chemiluminescent reactions, optical absorption detectors, a refinement of the carbon monoxide infrared analyzer, electrochemical cells based on solid electrolytes, and laser detectors.

Loewenstein, M.↗
NASA NTRS1973

Ammonium perchlorate gasification and combustion at high heating rates and low pressures.

Mass-spectrometric and linear regression rate characterizations are reported, derived from CO2 laser pyrolyses of pressed NH2ClO4 (AP) at incident heat fluxes ranging from 25 to 4000 cal/sq cm sec. Product evolution-rate histories were obtained in vacuo by time-resolved (5 msec) mass spectrometry during (1) transient heat-up, and (2) subsequent quasi-steady vaporization (QSV). Vaporization induction times were obtained for (1); these, coupled with heat-transfer approximations neglecting thermochemical heat release, indicated that optical absorption at 10.6 microns dominated over conduction for heat fluxes much greater than 300. Conclusions applying in vacuo were: preferential desorption of NH3, with net accumulation of adsorbed HClO4, occurred during transient heat-up and onset of condensed phase decomposition (CPD), but preferential decomposition of adsorbed HClO4 (compared to NH3) occurred during QSV when CPD was significant. CPD was the dominant mode of QSV at moderate heat fluxes.

Pellett, G. L.↗
NASA NTRS1973

Red clouds in reducing atmospheres

A dark reddish-brown high-molecular weight polymer is produced by long wavelength ultraviolet irradiation of abundant gases in reducing planetary atmospheres. The polymer is examined by paper chromatography, mass spectrometry, and infrared, visible, and ultraviolet spectroscopy. High carbon-number straight-chain alkanes with NH2 and, probably, OH and C = O groups are identified, along with amino acids. There are chemical similarities between this polymer and organic compounds recovered from carbonaceous chondrites and precambrian sediments. The visible and near-ultraviolet transmission spectrum of the polymer shows its absorption optical depth to be redder than lambda(-2) and perhaps similar in coloration to the clouds of Jupiter, Saturn, and Titan. The nitrile content is small, and the polymer should be semitransparent in the 5 micrometer atmospheric window. Such polymers may be a common constituent of clouds in the outer solar system and on the early earth.

Khare, B. N.↗
NASA NTRS1974

Physics of compact nonthermal sources. II Determination of physical parameters

A set of restrictions upon the magnetic field and visible angular size of a canonical nonthermal source (one whose emission is incoherent electron synchrotron) has been obtained in another paper. The degree of electron anisotropy and magnetic field disordering were left as free parameters. In the present paper these restrictions are applied to the variable compact radio sources 3C 84, 3C 120, 3C 273, 3C 279, 3C 454.3, CTA 102, 3C 446, PKS 2134 + 004, VRO 42.22.01, and OJ 287. The theoretically derived angular sizes for these sources are in reasonable agreement with published VLBI sizes, provided that the characteristic pitch angles are not extremely small. The magnetic field strengths determined from the degree of circular polarization are generally compatible with field strengths derived from the self-absorption and synchrotron self-Compton conditions, again provided that the pitch angles are not too small. It is argued that the self-absorption optical depth cannot be much less than unity near the low-frequency turnovers; otherwise, serious discrepancies with observation result.

Jones, T. W.↗
NASA NTRS1975

Interstellar molecular abundances toward omicron Persei

Extensive scanning of the B1 III star omicron Per has been done with the Copernicus telescope-spectrometer in an effort to determine column densities or meaningful upper limits for several molecules expected to be relatively abundant in H I regions of moderate density. The combination of radio H II, OH, and CO emission-line data with the optical absorption measurements indicates that omicron Per is embedded in the near edge of a dense molecular cloud and that the material seen in front of the star must be close to it. Molecules detected in ultraviolet absorption are H2, HD, CO, and possibly OH. The CO rotational temperature is between 2.2 and 3.8 K. The observed column densities and upper limits from Copernicus and ground-based data are compared with recent models for molecular formation in diffuse clouds.

Snow, T. P., Jr.↗
NASA NTRS1976

Characterization of iron-doped lithium niobate for holographic storage applications

A comprehensive characterization of chemical and holographic properties of eight systematically chosen Fe:LiNbO3 crystals is performed in order to determine optimum performance of the crystals in holographic storage and display applications. The discussion covers determination of Fe(2+) and Fe(3+) ion concentrations in Fe:LiNbO3 system from optical absorption and EPR measurements; establishment of the relation between the photorefractive sensitivity of Fe(2+) and Fe(3+) concentrations; study of the spectral dependence, the effect of oxygen annealing, and of other impurities on the photorefractive sensitivity; analysis of the diffraction efficiency curves for different crystals and corresponding sensitivities with the dynamic theory of hologram formation; and determination of the bulk photovoltaic fields as a function of Fe(2+) concentrations. In addition to the absolute Fe(2+) concentration, the relative concentrations of Fe(2+) and Fe(3+) ions are also important in determining the photorefractive sensitivity. There exists an optimal set of crystal characteristics for which the photorefractive sensitivity is most favorable.

Shah, R. R.↗
NASA NTRS1977

The photochemical cycle of bacteriorhodopsin

The reaction cycle of bacteriorhodopsin in the purple membrane isolated from Halobacterium halobium has been studied by optical absorption spectroscopy using low-temperature and flash kinetic techniques. After absorption of light, bacteriorhodopsin passes through at least five distinct intermediates. The temperature and pH dependence of the absorbance changes suggests that branch points and/or reversible steps exist in this cycle. Flash spectroscopy in the presence of a pH-indicating dye shows that the transient release of a proton accompanies the photoreaction cycle. The proton release occurs from the exterior and the uptake is on the cytoplasmic side of the membrane, as required by the function of bacteriorhodopsin as a light-driven proton pump. Proton translocating steps connecting release and uptake are indicated by deuterium isotope effects on the kinetics of the cycle. The rapid decay of a light-induced linear dichroism shows that a chromophore orientation change occurs during the reaction cycle.

Lozier, R. H.↗
NASA NTRS1977

Measurements of copper ground-state and metastable level population densities in a copper-chloride laser

The population densities of both the ground and the 2D(5/2) metastable states of copper atoms in a double-pulsed copper-chloride laser are correlated with laser energy as a function of time after the dissociation current pulse. Time-resolved density variations of the ground and excited copper atoms were derived from measurements of optical absorption at 324.7 and 510.6 nm, respectively, over a wide range of operating conditions in laser tubes with diameters of 4 to 40 mm. The minimum delay between the two current pulses at which lasing was observed is shown to be a function of the initial density and subsequent decay of the metastable state. Similarly, the maximum delay is shown to be a function of the initial density and decay of the ground state.

Nerheim, N. M.↗
NASA NTRS1978

Formulation of electrically conductive thermal-control coatings

The development and formulation of electrically conductive thermal control coating was undertaken for use on the International Sun Earth Explorer spacecraft. The primary effort was to develop a coating with a bulk resistivity of less than 100,000 ohm/sqm, an optical absorptance of approximately 0.55, and a normal emittance of 0.90. The required stability in space called for a bulk resistivity of less than 100,000 ohm/sq m, an absorptance of less than 0.67, and a normal emittance of 0.90 after exposure to approximately 4 x 10 to the 16th proton/sq cm of solar-wind particles and 5300 equivalent sun-hours. These exposures represent 2 years of ISEE flight conditions. Both the unsuccessful formulation efforts and the successful use of oxide pigments fired at 1448 K are described. Problems relative to the reactivity of specific coating vehicles exposed to high humidity are discussed.

Shai, M. C.↗
NASA NTRS1976

Studies on color-center formation in glass utilizing measurements made during 1 to 3 MeV electron irradiation

The coloring of NBS 710 glass was studied using a facility for making optical absorption measurements during and after electron irradiation. The induced absorption contains three Gaussian shaped bands. The color center growth curves contain two saturating exponential and one linear components. After irradiation the coloring decays can be described by three decreasing exponentials. At room temperature both the coloring curve plateau and coloring rate increases with increasing dose rate. Coloring measurements made at fixed dose rate but at increasing temperature indicate: (1) The coloring curve plateau decreases with increasing temperature and coloring is barely measurable near 400 C. (2) The plateau is reached more rapidly as the temperature increases. (3) The decay occurring after irradiation cannot be described by Arrhenius kinetics. At each temperature the coloring can be explained by simple kinetics. The temperature dependence of the decay can be explained if it is assumed that the thermal untrapping is controlled by a distribution of activation energies.

Swyler, K. J.↗
NASA NTRS1977

Electron-impact excitation of the low-lying electronic states of HCN

The first study of the low-energy electron-impact excitation of low-lying electronic transitions in the HCN molecule is reported. Measurements were made at incident electron energies of 11.6 and 21.6 eV in the energy-loss range of 3-10 eV, and at scattering angles of 20-130 deg. Inelastic scattering spectra were placed on the absolute cross-section scale by determining first the ratio of inelastic-to-elastic scattering cross sections, and then separately measuring the absolute elastic scattering cross section. Several new electronic transitions are observed which are intrinsically overlapped in the molecule itself. Assignments of these electronic transitions are suggested. These assignments are based on present spectroscopic and cross-sections measurements, high-energy electron scattering spectra, optical absorption spectra, and ab initio molecular orbital calculations.

Chutjian, A.↗
NASA NTRS1978

Coronal gas in the Galaxy. I - A new survey of interstellar O VI

Ultraviolet spectra of 40 O- and B-type stars have been intensively scanned in the vicinity of the O VI transitions at 1032 and 1038 A with the Copernicus satellite. This survey of the high-temperature (log T about 5.5) phase of interstellar gas is an extension of the earlier observations of interstellar O VI by Jenkins and Meloy (1974), bringing the total coverage up to 72 stars. Except for a few distant stars, the overall quality of the present data surpasses that of the earlier work. Plots of absorption optical depths versus radial velocity are presented for both transitions in each star. Total column densities (or their upper limits), velocity centroids, and velocity widths have been extracted from the profiles and tabulated, with the results of Jenkins and Meloy (1974) included. Qualitatively, the highly variable O VI densities and velocities seem to exhibit no systematic patterns or regional trends; there is no recognizable correlation in the behavior of coronal gas with pronounced features of galactic structure.

Jenkins, E. B.↗
NASA NTRS1978

Inversion of the resonance line of Sr/+/ produced by optically pumping Sr atoms

A description is presented of an experiment which demonstrates the selective production of excited-state ions by an optical absorption from neutrals. An inversion on the resonance line of Sr(+) was produced by laser excitation of a two-electron transition, followed by ionization of one of the excited electrons by the same laser. A pulsed, mode-locked laser operating at 2680 A was used to excite atoms from the Sr ground level. The same laser then ionized the excited atoms. The 2680-A pump beam was generated by frequency doubling the output of a synchronously pumped mode-locked dye laser in a KDP crystal. It is pointed out that the reported results are significant for the construction of vacuum-ultraviolet and X-ray lasers. Many of the proposed methods for making such lasers depend on the selective production of excited-state ions.

Green, W. R.↗
NASA NTRS1979

Molecules of significance in planetary aeronomy

This monograph is basically devoted to spectroscopic information of the molecules of planetary interest. Only those molecules have been dealt with which have been confirmed spectroscopically to be present in the atmosphere of major planets of our solar system and play an important role in the aeronomy of the respective planets. An introduction giving the general conditions of planets and their atmospheres including the gaseous molecules is given. Some typical planetary spectra is presented and supported with a discussion on some basic concepts of optical absorption and molecular parameters that are important to the study of planetary atmospheres. Quantities like dipole moments, transition probabilities, Einstein coefficients and line strengths, radiative life times, absorption cross sections, oscillator strengths, line widths and profiles, equivalent widths, growth curves, bond strengths, electronic transition moments, Franck-Condon factors and r-centroids, etc., are discussed. Spectroscopic information and relevant data of 6 diatomic (HF, HCL, CO, H2, O2, N2) and 6 polyatomic (CO2, N2), O3, HeO, NH3, CH4) molecules are presented.

Mohan, H.↗
NASA NTRS1981

Improved LEEM ranges over four decades

Low-energy electron magnetometer is suitable for terrestrial and aerial applications. Electron beam strikes tantalum collector plates in device, amplifying current and converting it to frequency. Current difference increases with beam deflection, providing measure of local field strength. LEEM operation requires no liquid helium unlike superconducting quantum interference device. LEEM sensitivity compares favorably with that of optical absorption magnetometers, and microsecond response range makes analyzing fast magnetic transients and signatures possible.

Singh, J. J.↗
NASA NTRS1979

Ultraviolet observations of interstellar molecules and grains from Spacelab

The paper presents observational results obtained on interstellar grains and molecules and suggests promising areas for Spacelab research. Regarding grains, useful data can be expected on the shape of the ultraviolet extinction curve for new interstellar regions, on the nature of UV extinction at short wavelengths, the presence of structure in the UV extinction curve comparable to the visible-wavelength diffuse bands, and the polarization properties of grains in UV wavelengths. The advances in observations of molecules will include the ability to prove more heavily-obscured regions, coverage of wavelength regions inadequately studied with previous instruments, and the capability of observing in optical absorption species detected in the same line of sight in radio emission.

Snow, T. P., Jr.↗