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At least 199 records · Page 11

Flame resistant elastomeric polymer development

Elastomeric products were developed for use in the space shuttle program, and investigations were conducted to improve the properties of elastomers developed in previous programs, and to evaluate the possibility of using lower-cost general purpose polymers. Products were fabricated and processed on conventional processing equipment; these products include: foams based on fluorinated rubber flame-retarded compounds with a density of 20-30 pounds/cubic foot for use as padding and in helmets; foams based on urethane for use in instrument packaging in the space shuttle; flexible and semi-rigid films of fluorinated rubber and neoprene compounds that would not burn in a 70% nitrogen, 30% oxygen atmosphere, and in a 30% nitrogen, 70% oxygen atmosphere, respectively for use in packaging or in laminates; coated fabrics which used both nylon and Kelvar fabric substrates, coated with either fluorinated or neoprene polymer compositions to meet specific levels of flame retardancy; and other flame-resistant materials.

Howarth, J. T.↗

Improved insulation material

Multilayer material consisting of embossed, silver-coated Mylar, nylon net, and silk net is useful for thermal-protection systems and cryogenic containers. Embossing serves two purposes: helps separate radiation barriers and controls radiant energy diffusion. Insulation requires no maintenance after installation.

Source record↗

Non-flammable elastomeric fiber from a fluorinated elastomer and containing an halogenated flame retardant

Flame retardant elastomeric compositions are described comprised of either spandex type polyurethane having incorporated into the polymer chain halogen containing polyols, conventional spandex type polyurethanes in physical admixture with flame retardant additives, or fluoroelastomeric resins in physical admixture with flame retardant additives. Methods are described for preparing fibers of the flame retardant elastomeric materials and articles of manufacture comprised of the flame retardant clastomeric materials and non elastic materials such as polybenzimidazoles, fiberglass, nylons, etc.

Howarth, J. T.↗

Graphite and ablative material response to CO2 laser, carbon-arc, and xenon-arc radiation

The behavior was investigated of graphite and several charring ablators in a variety of high-radiative heat-flux environments. A commercial-grade graphite and nine state-of-the-art charring ablators were subjected to various radiative environments produced by a CO2 laser and a carbon arc. Graphite was also tested in xenon-arc radiation. Heat-flux levels ranged from 10 to 47 MW/sq m. Tests were conducted in air, nitrogen, helium, and a CO2-N2 mixture which simulated the Venus atmosphere. The experimental results were compared with theoretical results obtained with a one-dimensional charring-ablator analysis and a two-dimensional subliming-ablator analysis. Neither the graphite nor the charring ablators showed significant differences in appearance or microstructure after testing in the different radiative environments. The performance of phenolic nylon and graphite was predicted satisfactorily with existing analyses and published material property data. Good agreement between experimental and analytical results was obtained by using sublimation parameters from a chemical nonequilibrium analysis of graphite sublimation. Some charring ablators performed reasonably well and could withstand radiative fluxes of the level encountered in certain planetary entries. Other materials showed excessive surface recession and/or large amounts of cracking and spalling, and appear to be unsuitable for severe radiative environments.

Brewer, W. D.↗

Evaluation of all-parachute and hybrid /parachute-retrorocket/ recovery systems for a one-million-pound booster

Both an all-parachute recovery system and a hybrid parachute-retrorocket recovery system for a one-million-pound booster are evaluated in order to determine what parachute sizes and number in a cluster are required for an all-parachute system to provide impact velocities of less than 100 ft/sec and in order to determine whether the hybrid system permits a weight reduction over an all-parachute system. A minimum-weight hybrid decelerator system using Kevlar materials for a cluster of three parachutes with two stages of reefing is analyzed. Major conclusions are that for an impact velocity of less than 100 ft/sec the hybrid decelerator system is lighter in weight, and that the use of Kevlar rather than Nylon material results in hybrid decelerator system weight savings of over 40% for impact velocities in the range 60-30 ft/sec.

Eckstrom, C. V.↗

Molecular correlations with fracture in fibers and granular-filled composites

Results are presented for an experimental electron spin resonance study of chain-scission kinetics in oriented nylon fibers and in granular-filled elastomer composites. A reaction-rate molecular model is proposed as a tool to predict failure under various loadings. The model assumes a statistical distribution in stress on the polymeric chain structure. Interfacial failure in the filled composites is examined. Failure at the interface between the filler and the matrix may be largely adhesive or cohesive, depending on the magnitude of the interactive forces. It appears that the mechanical behavior of both single-component and filled composites depends on the composite nature of the structure. The electron spin resonance technique is shown to be suitable for experimental observation of phenomena directly related to atomic occurrences.

Devries, K. L.↗

Fabrication and testing of large size nickel-zinc cells

The design and construction of nickel zinc cells, containing sintered nickel electrodes and asbestos coated inorganic separator materials, were outlined. Negative electrodes were prepared by a dry pressing process while various inter-separators were utilized on the positive electrodes, consisting of non-woven nylon, non-woven polypropylene, and asbestos.

Klein, M.↗

Effect of temperature and heating rate on apparent lethal concentrations of pyrolysis products

The apparent lethal concentrations for 50 percent of the test animals of the pyrolysis products from twelve polymeric materials were studied as a function of temperature and heating rate. The materials were polyethylene, nylon 6, ABS, polycarbonate, polyether sulfone, polyaryl sulfone, wool fabric, aromatic polyamide fabric, polychloroprene foam, polyvinyl fluoride film, Douglas fir, and red oak. The apparent lethal concentration values of most materials vary significantly with temperature and heating rate. The apparent lethal concentration values, based on weight of sample charged, appears to effectively integrate the thermophysical, thermochemical, and physiological responses from a known quantity of material under specified imposed conditions.

Hilado, C. J.↗

Studies with the USF/NASA toxicity screening test method - Effect of air flow and effect of fabric dye

One sample each of commercial polyurethane and polychloroprene flexible foams were evaluated using the USF/NASA toxicity screening test method. Air flow rates of 0, 0.16, 16, and 48 ml/sec were used to determine the effect of air flow on relative toxicity. Time to first sign of incapacitation and time to death were substantially reduced with both polyurethane and polychloroprene flexible foams by the introduction of 16 to 48 ml/sec air flow. The relative toxicity rankings of these materials were not altered by changes in air flow. Under these test conditions, the polyurethane foam consistently appeared more toxic than the polychloroprene foam. Samples of six different colors from the same fabric were evaluated separately, using the USF/NASA toxicity screening test method, to determine the effect of fabric dye, if any. The material was an upholstery fabric, consisting of 46 percent cotton, 33 percent wool, and 21 percent nylon. There appeared to be no significant effect of fabric dye on relative toxicity, for this material under these test conditions.

Hilado, C. J.↗

Nonlinear stress waves in a perfectly flexible string

This paper discusses nonlinear stress-wave propagation in a perfectly flexible string obeying a quasilinear (rate-dependent) constitutive equation. Wave speeds and compatibility relations valid along various families of characteristics were determined. It was shown that the compatibility relations associated with the transverse as well as the longitudinal waves readily yield a physical interpretation when they are expressed in suitable variables and in vector form. Coding based on the present information was completed for the machine solution of a class of mixed initial- and boundary-value problems of practical interest. Computer simulation of the stress-wave interaction in the 40-foot lanyard in the Arcas 'Rocoz' system during deployment was carried out using a stress-strain relation for nylon at the strain rate of 30/second. A method for estimating the maximum tension and strain in a string during the initial loading phase is proposed.

Fan, D.-N.↗

Breather cloth for vacuum curing

Finely-woven nylon cloth that has been treated with Teflon improves vacuum adhesive bonding of coatings to substrates. Cloth is placed over coating; entire assembly, including substrate, coating, and cloth, is placed in plastic vacuum bag for curing. Cloth allows coating to "breathe" when bag is evacuated. Applications include bonding film coatings to solar concentrators and collectors.

Reed, M. W.↗

Process for spinning flame retardant elastomeric compositions

Flame retardant elastomeric compositions comprised of either spandex type polyurethane having halogen containing polyols incorporated into the polymer chain, conventional spandex type polyurethanes in physical admixture with flame retardant additives, or fluoroelastomeric resins in physical admixture with flame retardant additives were developed. Methods are described for preparing fibers of the flame retardant elastomeric materials and manufactured articles as well as nonelastic materials such as polybenzimidazoles, fiberglass, and nylons, for high oxygen environments.

Howarth, J. T.↗

A subcutaneous channeling probe for implanting long leads

The channeling probe described in the present paper was designed to overcome surgical problems of the type that were encountered when a multichannel radio transmitter had to be implanted in a cow. The probe was made of a flexible but sufficiently stiff 9.5-mm-diam nylon rod, consisting of 46-cm sections for convenience in sterilization and surgical handling. Stainless steel sleaves reinforced the threaded connecting joints. At one end, arrowhead-shaped channeling heads could be attached to produce wide channels for large sensors. The other end was tapered for narrow channels. Postoperative problems were not encountered in the use of this probe in cows, sheep, and dogs.

Lund, G. F.↗

Determination of overcharge protection

Nylon separator degradation was examined as a function of temperature. Electrochemically active uncharged excess negative (overcharge protection)was measured by charging a cell venting it until it became fully charged, and continuing to overcharge the vent gas. The gas was analyzed as a function of time. The amount of hydrogen evolved was examined, and the cell voltage was observed as the oxygen and/or hydrogen evolved from the cell.

Scott, W. R.↗

Energy storage cycling tests

Results of cyclic tests on seven 3-cell 100 A-H nickel cadmium batteries on 1.5 hr cycles are presented. The failure of the nylon and polypropylene separators was not analyzed.

Bragg, B. J.↗

Shock isolator for operating a diode laser on a closed-cycle refrigerator

A diode laser mounted within a helium refrigerator is mounted using a braided copper ground strap which provides good impact shock isolation from the refrigerator cold-tip while also providing a good thermal link to the cold-tip. The diode mount also contains a rigid stand-off assembly consisting of alternate sections of nylon and copper which serve as cold stations to improve thermal isolation from the vaccum housing mounting structure. Included in the mount is a Pb-In alloy wafer inserted between the cold-tip and the diode to damp temperature fluctuations occurring at the cold-tip.

Jennings, D. E.↗

Comparison of cells with Pellon 2503 and 2505 separator

Unlike the 2505 nonwoven nylon separator material which has fibers in a random direction, the 2503 material has fibers oriented all in one direction. Properties of the two materials discussed include density, porosity, absorptivity, electrolyte retention, capacity, and charge voltage pressure. With only 1,000 test cycles completed, it is not possible to determine whether 2503 is a suitable substitute.

Halpert, G.↗

Ignition characteristics of some aircraft interior fabrics

Six samples of aircraft interior fabrics were evaluated with regard to resistance to ignition by radiant heat. Five samples were aircraft seat upholstery fabrics and one sample was an aircraft curtain fabric. The aircraft seat fabrics were 100% wool (2 samples), 83% wool/17% nylon, 49% wool/51% polyvinyl chloride, and 100% rayon. The aircraft curtain fabric was 92% modacrylic/8% polyester. The five samples of aircraft seat upholstery fabrics were also evaluated with regard to resistance to ignition by a smoldering cigarette. The four samples of wool-containing aircraft seat fabrics appeared to be superior to the sample of rayon seat fabric in resistance to ignition, both by radiant heat and by a smoldering cigarette.

Hilado, C. J.↗