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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.
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Chemically reacting stagnation point boundary layers with wall injection of gas, comparing multicomponent solution with binary approximation and chemical simplifications
Gas phase chemical reactions effect on heat transfer to charring ablator, deriving numerical solution for multicomponent stagnation point flow
Multicomponent nonequilibrium air flow past axisymmetric blunt body, calculating flow distribution at various attack angles with time dependent technique
The results of a stagnation-line analysis of the radiative heating of a phenolic-nylon ablator are reported. The analysis includes flowfield coupling with the ablator surface, equilibrium chemistry, multicomponent or binary diffusion and a coupled line and continuum radiation calculations. Users manual and operating instructions for the computer programs listed in the report are included.
Evaluation of interstellar extinction curves over the region from 3600 to 1100 A for 17 stars. The observations were made by the two Wisconsin spectrometers on board the Orbiting Astronomical Observatory 2, with spectral resolutions of 10 and 20 A. The extinction curves generally show a pronounced maximum at 2175 plus or minus 25 A, a broad minimum in the region from 1800 to 1350 A, and finally a rapid rise to the far-ultraviolet. Large extinction variations from star to star are found, especially in the far-ultraviolet; however, with only two possible exceptions in this sample, the wavelength at the maximum of the extinction bump is essentially constant. These data are combined with visual and infrared observations to display the extinction behavior over a range in wavelength of about a factor of 20. The observations appear to require a multicomponent model of the interstellar dust.
Consideration of dissipative processes in anisotropic homogeneous world models, showing that dissipation reduces the anisotropy. The viscosity approximation and its range of applicability is discussed. Examples are presented which have been calculated by the use of a simple approximation to the collision-time method, using the cross section appropriate to weak interaction neutrino scattering. It is found that such dissipation is quite effective except for one particular cosmological model which is axisymmetric and in which the entire expansion of the model is taken up by expansion along the axis. A detailed multicomponent model is developed for dissipative processes in Euclidean homogeneous cosmological models. These processes involve neutrinos which might have long mean free times in interaction with other constituents which are thermalized by electromagnetic interactions, and whose weak interactions produce thermal neutrinos.
Generalized computer methods are developed for inferring details of the formation of cosmochemical systems. Compositions of ideal gas mixtures existing in equilibrium with multicomponent solid and liquid phases are calculated. A comparison of computed results with experimental data is made for the ternary system MgO-FeO-SiO2. While the ideal-solution approximation is shown to be inaccurate in dealing with the silicate melts, the stable phases and compositions can be accurately calculated in a system where there are only solids and gas. A model system containing the elements H, O, Si, Mg, S, C, Cl, and F is investigated over a range of compositions involving the gas and ten solid phases, to show the power of the technique in dealing with complex gas-solid equilibria. Systems close to cosmic composition are next considered, both with and without iron.
A momentum-transfer theory is used to obtain an expression for the drift velocity of an ion in a multicomponent gas mixture. This is combined with an approximate calculation of the partition of the ion energy in the mixture to yield a formula for the drift velocity in terms of the drift velocities in the pure component gases. Positive deviations from Blanc's law at high fields are predicted, of magnitudes that should be easily measured experimentally.
A numerical program was developed to compute transient compressible and incompressible laminar flows in two dimensions with multicomponent mixing and chemical reaction. The algorithm used the Los Alamos Scientific Laboratory ICE (Implicit Continuous-Fluid Eulerian) method as its base. The program can compute both high and low speed compressible flows. The numerical program incorporating the stabilization techniques was quite successful in treating both old and new problems. Detailed calculations of coaxial flow very close to the entry plane were possible. The program treated complex flows such as the formation and downstream growth of a recirculation cell. An implicit solution of the species equation predicted mixing and reaction rates which compared favorably with the literature.
Eighty-two subsamples of Apollo 14 materials have been analyzed by instrumental neutron activation analysis techniques for as many as 25 elements. In many cases, it was necessary to develop new procedures to allow analyses of small specimens. Compositional relationships among Apollo 14 materials indicate that there are small but systematic differences between regolith from the valley terrain and that from Cone Crater ejecta. Fragments from 1-2 mm size fractions of regolith samples may be divided into compositional classes, and the 'soil breccias' among them are very similar to valley soils. Multicomponent linear mixing models have been used as interpretive tools in dealing with data on regolith fractions and subsamples from breccia 14321. These mixing models show systematic compositional variations with inferred age for Apollo 14 clastic materials.
Ambipolar diffusion is discussed for the case of a weakly-ionized, multicomponent plasma. Shortcomings of some of the previous formulations of this problem are pointed out. In particular, it is shown that the polarization electrostatic field acts to couple the motion of the various ions with the result that the diffusion velocity of each ion depends on the density gradients of all the ions.
The partitioning of ion energy among thermal energy, drift energy, and random-field energy is studied by solution of the Boltzmann equation. An expansion in powers of the square of the electric field strength is obtained by Kihara's method. Numerical calculations for several ion-neutral force laws show that Wannier's constant mean-free-time model gives a reasonable first approximation. The formal extension to multicomponent mixtures is also given. The matrix elements obtained are tabulated, and can be used to study the field dependence of other moments of the ion-distribution function.
A new correlation method for binary gaseous diffusion coefficients from very low temperatures to 10,000 K is proposed based on an extended principle of corresponding states, and having greater range and accuracy than previous correlations. There are two correlation parameters that are related to other physical quantities and that are predictable in the absence of diffusion measurements. Quantum effects and composition dependence are included, but high-pressure effects are not. The results are directly applicable to multicomponent mixtures.
There are remarkable similarities in the structure of loop prominences when observed in H alpha and coronal lines, although the lines arise from extremely different excitation conditions. This leads to the consideration of a multicomponent model, where different emission lines come from different elements of the structure. The late phases of a large west limb loop prominence system followed by a surge were recorded at Haleakala Observatory on March 6, 1970. Simultaneous filtergrams in H alpha and 5303-A were obtained, together with spectra at three heights in the prominence over the range from 3850 to 5950 A. The positions of bright knots of emission as seen in the green line are compared with associated H alpha knots. With these relative positions determined, the filtergrams are superimposed to demonstrate the two-dimensional spatial relationship between H alpha and 5303-A structures. The results support a model of cool loops within a closely associated hot-loop system.
Data for the system n-pentane/n-heptane on porous Chromosorb-102 adsorbent were obtained at 150, 175, and 200 C for mixtures containing zero to 100% n-pentane by weight. Prior results showing limitations on superposition of pure component data to predict multicomponent chromatograms were verified. The thermodynamic parameter MR0 was found to be a linear function of sample composition. A nonporous adsorbent failed to separate the system because of large input sample dispersions. A proposed automated data processing scheme involving magnetic tape recording of the detector signals and processing by a minicomputer was rejected because of resolution limitations of the available a/d converters. Preliminary data on porosity and pore size distributions of the adsorbents were obtained.
The mutual diffusion of two reacting gases is examined which takes place in a bath of inert gas atoms. Solutions are obtained between concentric spheres, each sphere acting as a source for one of the reactants. The calculational model is used to illustrate severe number density gradients observed in absorption experiments with alkali vapor. Severe gradients result when sq root k/D R is approximately 5 where k, D, and R are respectively the second order rate constant, the multicomponent diffusion constant, and the geometrical dimension of the experiment.
Major and trace element analyses of over 180 individual chondrules from 12 carbonaceous chondrites are reported, including individual analyses of 60 chondrules from Pueblito de Allende. Siderophile elements in most chondrules are depleted, compared to the whole chondrite. Correlations of Al-Ir and Ir-Sc among chondrules high in Ca and Al were observed. A Cu-Mn correlation was also found for chondrules from some meteorites. No correlation was observed between Au and other siderophile elements (Fe, Ni, Co and Ir). It is suggested that these elemental associations were present in the material from which the chondrules formed. Compositionally, chondrules appear to be a multicomponent mixture of remelted dust. One component displaying an Al-Ir correlation is identified as Allende-type white aggregates. The other components are a material chemically similar to the present matrix and sulfides-plus-metal material. Abundances of the REE (rare earth elements) were measured in ordinary Allende chondrules and were 50% higher than REE abundances in Mokoia chondrules; REE abundances in Ca-Al rich chondrules were similar to REE abundances in Ca-rich white aggregates.
The influence of wall slip and catalytic atom-recombination on the flow field and wall heat flux are calculated for high altitude flight and arc jet flow conditions. Boundary equations, which include velocity slip, temperature jump, and wall catalytic atom recombination, are coupled to the viscous reacting multicomponent Navier-Stokes equations. These equations are solved using a time-dependent finite difference technique applied to spheres in an arc jet flow (Reynolds number of 550) and a high altitude flight case representative of the Space Shuttle Orbiter (Reynolds number of 450). The results indicate that catalysis strongly influences the temperature jump, but not the velocity slip. Slip increases the atom fraction and temperature at both the wall and the flow field. Likewise, the shock stand-off distance, the wall heat flux, and friction coefficient are increased over the nonslip cases. The reacting gas calculations confirm the chemically frozen nature of the shock layer in arc jet flows.