Development and testing of a low-temperature hydraulic system Presentation brochure
Low temperature hydraulic system development and testing for space applications
HYDRAULIC FLUID↗
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Results for “low temperatures”
Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.
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Development of low temperature battery
Self-contained low temperature battery system consisting of a magnesium anode, potassium thiocyanate-ammonia electrolyte and a cathode composed of a mixture of sulfur, carbon, and mercuric sulfate operates for at least seventy-two hours within a discharge temperature range of plus 20 degrees C to minus 90 degrees C.
Armstrong, G. M.↗
Infrared spectra of low-temperature stars.
IR spectra of low temperature stars of type M, N/R/ and S, as well as NML objects in Cygnus and Taurus, noting atmospheric differences
STELLAR SPECTRUM↗
Transitions in glasses at low temperatures.
Transitions in glasses at low temperatures, noting molecular relaxation dependence on copolymer composition
Haldon, R. A.↗
Characteristics of solar cells at low temperatures.
Solar cell characteristics at low temperatures, noting efficiency increase with decreasing temperature
Lambert, R. J.↗
Low-temperature coal desulfurization
Economical, low-temperature chlorinolysis converts sulfur to water-soluble sulfates. Sulfates are removed by washing. Subsequent steps dry coal and remove chlorine. Chlorine and solvents can be reused.
Ganguli, P. S.↗
Preparation, Identification, and Low-Temperature Infrared Spectra of Two Elusive Crystalline Nitrile Ices
Infrared (IR) spectra of the alkyl nitrile ices CH3CN and CH3CH2CN are relevant to the study of the low-temperature chemistry of objects within and beyond the Solar System, but the thermodynamically favored low-temperature crystalline phases of these compounds have not been presented and identified in the planetary-sciences literature. Moreover, there is a large variation in the published IR spectra of these two icy solids, including spectra that are used for the analyses of spacecraft data from the Voyager and Cassini missions. Here the IR spectra of the low-temperature crystalline forms of CH3CN and CH3CH2CN, which are the thermodynamically stable phases at Titan temperatures, are presented for the first time with all samples being made by vapor-phase deposition. Conditions are described for producing these ice phases for both compounds, and new measurements are reported of ice density and refractive index, quantities needed to compute IR absorption coefficients, band strengths, optical constants, and, ultimately, nitrile abundances in extraterrestrial environments. Comparisons are drawn between CH3CN and CH3CH2CN, an earlier prediction on their similar crystallization behaviors is verified, and previous work is examined in light of these new results, including a counter-intuitive observation in which the low-temperature phase of an ice is made by heating a high-temperature phase. Applications and extensions are described.
Reggie L Hudson↗
Preparation, Identification, and Low-Temperature Infrared Spectra of Two Elusive Crystalline Nitrile Ices
Infrared (IR) spectra of the alkyl nitrile ices CH3CN and CH3CH2CN are relevant to the study of the low-temperature chemistry of objects within and beyond the Solar System, but the thermodynamically favored low-temperature crystalline phases of these compounds have not been presented and identified in the planetary-sciences literature. Moreover, there is a large variation in the published IR spectra of these two icy solids, including spectra that are used for the analyses of spacecraft data from the Voyager and Cassini missions. Here the IR spectra of the low-temperature crystalline forms of CH3CN and CH3CH2CN, which are the thermodynamically stable phases at Titan temperatures, are presented for the first time with all samples being made by vapor-phase deposition. Conditions are described for producing these ice phases for both compounds, and new measurements are reported of ice density and refractive index, quantities needed to compute IR absorption coefficients, band strengths, optical constants, and, ultimately, nitrile abundances in extraterrestrial environments. Comparisons are drawn between CH3CN and CH3CH2CN, an earlier prediction on their similar crystallization behaviors is verified, and previous work is examined in light of these new results, including a counter-intuitive observation in which the low-temperature phase of an ice is made by heating a high-temperature phase. Applications and extensions are described.
Ices, IR spectroscopy, Titan, organic chemistry, i↗
The Effect of Electrolyte Composition on Lithium Plating During Low Temperature Charging of Li-Ion Cells
In the present work, a number of additives have been investigated for their effect on the charge characteristics of cells containing low temperature, high ester content electrolytes (1.0 M LiPF6 in ethylene carbonate (EC) + ethyl methyl carbonate (EMC) + methyl propionate (MP) 20:20:60 vol % + X additive). These experimental three-electrode cells are composed of graphite anodes, LiNiCoAlO2 cathodes, and a lithium metal reference electrode. Cells were first subjected to electrochemical characterization at various temperatures, consisting of performing Electrochemical Impedance Spectroscopy (EIS), linear micropolarization and Tafel polarization measurement to determine the kinetic parameters for both the anodes and cathodes. Following electrochemical characterization, the cells were subjected to charging at decreasing temperatures using C/5 rates to 4.10V, with a constant potential C/50 current taper. Analysis of the C/20 discharge following the charge at low temperature revealed either the presence or absence of a high voltage plateau during the initial stages of the discharge. This plateau has been linked to the presence of lithium metal on the anode previously and was used as a measure for the extent of lithium plating in the cell. Differential analysis (dV/dQ) was applied as well to more clearly visualize the position of the high voltage plateau and use the peak position (x-axis) in the dV/dQ plot as a gauge for the amount of plating which took place in the cell on the prior charge. Most additives investigated increased the resistance of the anode and decreased the resistance of the cathode, thereby leading to an overall increase in plating observed at low temperature. One additive, LiFSI, was found to be beneficial during low temperature charging, however studies of electrode kinetics from the cell containing LiFSI did not reveal significant improvements compared to the baseline.
Jones, John-Paul↗
The Development of the Low Temperature Microgravity Physics Facility
We describe the design and development of the Low Temperature Microgravity Physics Facility, which is intended to provide long duration (4.5 months) low temperature (1.4K) and microgravity conditions for scientists to perform breakthrough investigations on board the International Space Station.
Low Temperature Fundamental Physics Microgravity P↗
Substituted Quaternary Ammonium Salts Improve Low-Temperature Performance of Double-Layer Capacitors
Double-layer capacitors are unique energy storage devices, capable of supporting large current pulses as well as a very high number of charging and discharging cycles. The performance of doublelayer capacitors is highly dependent on the nature of the electrolyte system used. Many applications, including for electric and fuel cell vehicles, back-up diesel generators, wind generator pitch control back-up power systems, environmental and structural distributed sensors, and spacecraft avionics, can potentially benefit from the use of double-layer capacitors with lower equivalent series resistances (ESRs) over wider temperature limits. Higher ESRs result in decreased power output, which is a particular problem at lower temperatures. Commercially available cells are typically rated for operation down to only 40 C. Previous briefs [for example, Low Temperature Supercapacitors (NPO-44386), NASA Tech Briefs, Vol. 32, No. 7 (July 2008), p. 32, and Supercapacitor Electrolyte Solvents With Liquid Range Below 80 C (NPO-44855), NASA Tech Briefs, Vol. 34, No. 1 (January 2010), p. 44] discussed the use of electrolytes that employed low-melting-point co-solvents to depress the freezing point of traditional acetonitrile-based electrolytes. Using these modified electrolyte formulations can extend the low-temperature operational limit of double-layer capacitors beyond that of commercially available cells. This previous work has shown that although the measured capacitance is relatively insensitive to temperature, the ESR can rise rapidly at low temperatures, due to decreased electrolyte conductance within the pores of the high surface- area carbon electrodes. Most of these advanced electrolyte systems featured tetraethylammonium tetrafluoroborate (TEATFB) as the salt. More recent work at JPL indicates the use of the asymmetric quaternary ammonium salt triethylmethylammonium tetrafluoroborate (TEMATFB) or spiro-(l,l')-bipyrrolidium tetrafluoroborate (SBPBF4) in a 1:1 by volume solvent mixture of acetonitrile (AN) and methyl formate (MF) enables double-layer capacitor cells to operate well below -40 C with a relatively low ESR. Typically, a less than twofold increase in ESR is observed at -65 C relative to room-temperature values, when these modified electrolyte blends are used in prototype cells. Double-layer capacitor coin cells filled with these electrolytes have displayed the lowest measured ESR for an organic electrolyte to date at low temperature (based on a wide range of electrolyte screening studies at JPL). The cells featured high-surface-area (approximately equal to 2,500 m/g) carbon electrodes that were 0.50 mm thick and 1.6 cm in diameter, and coated with a thin layer of platinum to reduce cell resistance. A polyethylene separator was used to electrically isolate the electrodes.
Brandon, Erik J.↗
Evolvable hardware system at extreme low temperatures
This paper describes circuit evolutionary experiments at extreme low temperatures, including the test of all system components at this extreme environment (EE). In addition to hardening-by-process and hardening-by-design, 'hardening-by-reconfiguration ', when applicable, could be used to mitigate drifts, degradation, or damage on electronic devices (chips) in EE, by using re-configurable devices and an adaptive selfreconfiguration of their circuit topology. Conventional circuit design exploits device characteristics within a certain temperature/radiation range; when that is exceeded, the circuit function degrades. On a reconfigurable device, although component parameters change in EE, a new circuit design, suitable for new parameter values, may be mapped into the reconfigurable structure to recover the initial circuit function. This paper demonstrates this technique for circuit evolution and recovery at liquid nitrogen temperatures (-196.6 (deg)C). In addition, preliminary tests are performed to assess the survivability limitations of the evolutionary processor at extreme low temperatures.
evolvable harware↗
The Low Temperature Microgravity Physics Facility: Progress and Status
The Jet Propulsion Laboratory (JPL) is developing the Low Temperature Microgravity Physics Facility (LTMPF). The LTMPF is a multiple user and multiple flight facility that will provide a long duration low temperature environment for performing state of the art experiments at the International Space Station (ISS). During each mission, two distinct primary experiments will be accommodated. Secondary experiments utilizing the hardware built for the primary experiments will also be accommodated during each mission. Over the past year, much progress has occurred on the LTMPF as the flight hardware has started to be built. Also, many changes have occurred. Last summer, the initial flight of the LTMPF was delayed until early 2008 by a 2-year slip in the delivery of the Japanese Experiment Module (KIBO) Exposed Facility of the ISS, where the LTMPF will be attached when it flies. Finally, the experiments that will fly as part of the first mission have been changed so that one Gravitational and Relativistic experiment and one Low Temperature Condensed Matter experiment will fly on each flight of the LTMPF. Therefore, the experiments that will fly on the initial mission of the LTMPF will be DYNAMX and the Superconducting Microwave Oscillator Experiment (SUMO).
Larson, Melora↗
Persistence of Methionine Side Chain Mobility at Low Temperatures in a Nine‐Residue Low Complexity Peptide, as Probed by 2 H Solid‐State NMR
Abstract Methionine side chains are flexible entities which play important roles in defining hydrophobic interfaces. We utilize deuterium static solid‐state NMR to assess rotameric inter‐conversions and other dynamic modes of the methionine in the context of a nine‐residue random‐coil peptide (RC9) with the low‐complexity sequence GGKGMGFGL. The measurements in the temperature range of 313 to 161 K demonstrate that the rotameric interconversions in the hydrated solid powder state persist to temperatures below 200 K. Removal of solvation significantly reduces the rate of the rotameric motions. We employed 2 H NMR line shape analysis, longitudinal and rotation frame relaxation, and chemical exchange saturation transfer methods and found that the combination of multiple techniques creates a significantly more refined model in comparison with a single technique. Further, we compare the most essential features of the dynamics in RC9 to two different methionine‐containing systems, characterized previously. Namely, the M35 of hydrated amyloid‐β 1–40 in the three‐fold symmetric polymorph as well as Fluorenylmethyloxycarbonyl (FMOC)‐methionine amino acid with the bulky hydrophobic group. The comparison suggests that the driving force for the enhanced methionine side chain mobility in RC9 is the thermodynamic factor stemming from distributions of rotameric populations, rather than the increase in the rate constant.
Vugmeyster, Liliya↗
Long Duration Exposure Facility (LDEF) low temperature heat pipe experiment package (HEPP) flight results
The Low Temperature Heat Pipe Flight Experiment (HEPP) is a fairly complicated thermal control experiment that was designed to evaluate the performance of two different low temperature ethan heat pipes. A total of 388 days of continuous operation with an axially grooved aluminum transporter heat pipe and an axially grooved stainless steel heat pipe diode was demonstrated before the EPDS batteries lost power. Preliminary postflight tests showed that the heat pipes are still functioning. A summary of the flight data analysis for the heat pipes and the related support systems is presented.
Mcintosh, Roy↗
Long Duration Exposure Facility (LDEF) low-temperature Heat Pipe Experiment Package (HEPP) flight results
The Low Temperature Heat Pipe Flight Experiment (HEPP) is a fairly complicated thermal control experiment that was designed to evaluate the performance of two different low temperature ethane heat pipes and a n-Heptane Phase Change Material (PCM) canister. A total of 388 days of continuous operation with an axially grooved aluminum fixed conductance heat pipe of axially grooved stainless steel heat pipe diode was demonstrated before the EDS batteries lost power. The inability of the HEPP's radiator to cool below 190 K in flight prevented freezing of the PCM and the opportunity to conduct transport tests with the heat pipes. Post flight tests showed that the heat pipes and the PCM are still functioning. This paper presents a summary of the flight data analysis for the HEPP and its related support systems. Pre and post-flight thermal vacuum tests results are presented for the HEPP thermal control system along with individual heat pipe performance and PCM behavior. Appropriate SIG related systems data will also be included along with a 'lessons learned' summary.
Mcintosh, Roy↗
Laboratory studies of low temperature rate coefficients: The atmospheric chemistry of the outer planets
The objectives are to measure laboratory rate coefficients for key reactions of hydrocarbon molecules and radicals at low temperatures, which are relevant to the atmospheric photochemistry of Saturn, Jupiter, and Titan. Upcoming NASA planetary missions, such as Cassini, will probe the atmosphere of Titan in more detail, offering an excellent opportunity to test kinetic models and to establish fiducial standards for using kinetic models to interpret various parameters of the outer planets. Accurate low temperature kinetic data, which are presently lacking, may require crucial revisions to the rates of formation and destruction and are of utmost importance to the success of these efforts. In this program, several key reactions of ethynyl radicals (C2H) with acetylene (C2H2), methane (CH4), and oxygen (O2), down to temperatures of 170 K were successfully investigated. The experimental apparatus developed in our laboratory for measuring reaction kinetics at low temperatures consists of a laser photolysis/infrared probe laser setup. The rate measurements are carried out as a function of (low) temperature with a transverse flow cell designed specifically for these studies. A 193 nm argon fluoride pulsed excimer laser is used to photolyze a suitable precursor molecule, such as acetylene to produce C2H, and a high resolution, tunable infrared F-center laser (2.3-3.35 mu m) probes the transient concentrations of the radical species directly in absorption to extract the kinetic rate coefficients.
Leone, Stephen R.↗
Preliminary Low Temperature Electron Irradiation of Triple Junction Solar Cells
For many years extending solar power missions far from the sun has been a challenge not only due to the rapid falloff in solar intensity (intensity varies as inverse square of solar distance) but also because some of the solar cells in an array may exhibit a LILT (low intensity low temperature) degradation that reduces array performance. Recent LILT tests performed on commercial triple junction solar cells have shown that high performance can be obtained at solar distances as great as approx. 5 AU1. As a result, their use for missions going far from the sun has become very attractive. One additional question that remains is whether the radiation damage experienced by solar cells under low temperature conditions will be more severe than when measured during room temperature radiation tests where thermal annealing may take place. This is especially pertinent to missions such as the New Frontiers mission Juno, which will experience cell irradiation from the trapped electron environment at Jupiter. Recent testing2 has shown that low temperature proton irradiation (10 MeV) produces cell degradation results similar to room temperature irradiations and that thermal annealing does not play a factor. Although it is suggestive to propose the same would be observed for low temperature electron irradiations, this has not been verified. JPL has routinely performed radiation testing on commercial solar cells and has also performed LILT testing to characterize cell performance under far sun operating conditions. This research activity was intended to combine the features of both capabilities to investigate the possibility of any room temperature annealing that might influence the measured radiation damage. Although it was not possible to maintain the test cells at a constant low temperature between irradiation and electrical measurements, it was possible to obtain measurements with the cell temperature kept well below room temperature. A fluence of 1E15 1MeV electrons was selected as representative of a moderately high dose that might be expected for a solar powered mission. Fluences much greater than this would require large increases in array area and mass, compromising the ability of PV to compete with non-solar alternatives.
Stella, Paul M.↗