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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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All sourcesNASA NTRSDOE OSTI
NASA NTRS1995

Polar distribution of annexin-like proteins during phytochrome-mediated initiation and growth of rhizoids in the ferns Dryopteris and Anemia

Although the calcium requirement of phytochrome-mediated fern spore germination and early rhizoid growth is well established, the calcium-binding proteins that serve as transducers for these responses are not known. Here we report the presence of annexin-like proteins in germinating spores of Dryopteris filix-mas (L.) Schott and Anemia phyllitidis (L.) Sw. and evidence that they may be important participants in early photomorphogenic changes in gametophytes. Immunolocalization and immunoblot assays of these proteins were carried out using polyclonal antibodies raised either against a 35-kDa annexin-like protein from pea or against anchorin CII from chicken. Western-blot analysis showed that crude protein extracts obtained from both species after red-light treatment contained two cross-reactive protein bands with molecular weights around 70 kDa. These proteins were annexin-like in that they bound to a phosphatidylserine affinity column in a calcium-dependent fashion. Using this column, two protein bands around 70 kDa, i.e. 67 and 73 kDa, were partially purified together with proteins at 36 kDa and a doublet at 54 kDa. Proteins of these latter molecular weights are suggested to be members of the annexin family, but no cross-reactivity could be found between these and the two antibodies used in our investigations. Immunodetectable levels of these proteins were observed only after light-mediated induction of spore germination. Imaging of the immuno-localization patterns observed with both antibodies showed that the annexin-like proteins are concentrated at the extreme tips of the rhizoids in D. filix-mas and A. phyllitidis during rhizoid initiation and all stages of elongation. We suggest that these proteins may play a major role in the tip-oriented exocytosis events that are critical for the initiation and growth of fern rhizoids.

NASA Discipline Number 40-50↗
NASA NTRS2018

HOMES: Holographic Method for Exoplanet Spectroscopy

The search for habitable exoplanets in the "neighborhood," that is within 10 parsecs (pc),invites new observational techniques, because telescopes available today have significant limitations. For example, gravitational micro-lensing is a deep field method that has little or no utility within 10 pc. Photometry of transits reduces the availability of exoplanets to a probability of approximately a 1%, and fewer than 1 out of 100 earth twins would ever be seen. For the 1% of exoplanets seen in transit, spectra of albedos cannot be taken.Even more limiting, Doppler shift studies are indirect and cannot characterize exoplanets other than by their orbits and masses through stellar radial velocity (RV). Moreover, RV by Doppler shift cannot detect planets in orbits on a plane perpendicular to our line of sight. Astrometry can be used to measure stellar orbital wobble for those exoplanetary systems in the plane perpendicular to our line of sight, as was contemplated for the cancelled NASA SIM mission 1 and rests now with ESA's GAIA2. In either case, the exoplanets detected by stellar RV or astrometry would not be directly observed, so the assumption that the three phases of water could exist does not answer a key question of habitability. Is there water on the exoplanet? Moreover, the discovery of water on an exoplanet in the habitable zone, exciting though it would be, is insufficient to determine just how habitable the exoplanet might possibly be. Like Goldilocks' porridge - there are many other ingredients beyond water alone in a life-sustaining soup.We propose a new species of optical telescope that has as one of its capabilities the high resolution spectrographic characterization of exoplanets on stars within 10 pc of the observatory. To achieve this performance specification, we propose to break with convention by taking advantage of an optical technology unknown until relatively recent times: the hologram. In this Report we show how holograms used in primary and secondary can extract spectrograms from exoplanets at distances reaching 33 light years from our solar system. We describe a notional space telescope using these novel optics that could make its observations in a space deployment scenario.

Ditto, Thomas↗
DOE OSTI2023

A Study of the Gain of Microchannel Plates in the Ionization Profile Monitors at Fermilab

One of the on-going issues with the use of microchannel plates (MCP) in the ionization profile monitors (IPM) at Fermilab is the significant decrease in gain over time. There are several possible issues that can cause this. Historically, the assumption has been that this is aging, where the secondary emission yield (SEY) of the pore surface changes after some amount of extracted charge. Recent literature searches have brought to light the possibility that this is an initial 'scrubbing' effect whereby adsorbed gasses are removed from the MCP pores by the removal of charge from the MCP. This paper discusses the results of studies conducted on the IPMs in the Main Injector at Fermilab.

43 PARTICLE ACCELERATORS↗
DOE OSTI2020

Operations and Recent Upgrades to a Tritium Recycling Facility - 20375

Nuclear Sources and Services Inc. (NSSI) is a waste handling treatment company that has been operating since 1971. In 2000, NSSI began building a 1,000 m{sup 2} (∼10,000 sqft) tritium recycling facility on the Houston, Texas premises to address a growing need in the waste disposal market. Over the years, the capability of the facility grew to address many different waste streams with the goal of recycling > 99.9% of all tritium activity back into the fusion community. This is achieved by maintaining an effluent stack release well below the 150 GBq/year (C Ci/year) operating limit and maintaining all liquid and solid waste disposal below the low-level radioactive release limit of 0.C MBq/kg (10 μCi/kg). The unique processing systems in the facility attracts many challenging contracts. Within the past two years, NSSI has engaged with customers to treat; organic mixed wastes that simultaneously contain tritium and carbon-14, safely extract tritium from large quantities of exit sign lights, and remove tritium from uncharacterised legacy depleted uranium beds from a superfund site. This paper will outline the initial testing, the system upgrades to treat these varied streams, and the progress in processing the feedstocks provided by these projects. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
NASA NTRS1988

Early quantitative method for measuring germination in non-green spores of Dryopteris paleacea using an epifluorescence-microscope technique

A method is described to determine germination by blue-light excited red fluorescence in the positively photoblastic spores of Dryopteris paleacea Sw. This fluorescence is due to chlorophyll as evidenced from 1) a fluorescence-emission spectrum in vivo, where a bright fluorescence around 675 nm is obtained only in red light (R)-irradiated spores and 2) in vitro measurements with acetone extracts prepared from homogenized spores. Significant amounts of chlorophyll can be found only in R-treated spores; this chlorophyll exhibits an emission band around 668 nm, when irradiated with 430 nm light at 21 degrees C. Compared to other criteria for germination, such as swelling of the cell, coat splitting, greening, and rhizoid formation, which require longer periods after induction for their expression, chlorophyll fluorescence can be used to quantify germination after two days. This result is confirmed by fluence-response curves for R-induced spore germination; the same relationship between applied R and germination is obtained by the evaluation with the epifluorescence method 2 days after the light treatment as compared with the evaluation with bright-field microscopy 5 days after the inducing R. Using this technique we show for the first time that Ca2+ contributes to the signal-transduction chain in phytochrome-mediated chlorophyll synthesis in spores of Dryopteris paleacea.

NASA Discipline Plant Biology↗
DOE OSTI2022

Extraction of low-energy constants of single- and double-β decays from lattice QCD: A sensitivity analysis

Lattice quantum chromodynamics (LQCD) has the promise of constraining low-energy constants (LECs) of nuclear effective field theories (EFTs) from first-principles calculations that incorporate the dynamics of quarks and gluons. Given the Euclidean and finite-volume nature of LQCD outputs, complex mappings are developed in recent years to obtain the Minkowski and infinite-volume counterparts of LQCD observables. In particular, as LQCD is moving toward computing a set of important few-nucleon matrix elements at the physical values of the quark masses, it is important to investigate whether the anticipated precision of LQCD spectra and matrix elements will be sufficient to guarantee tighter constraints on the relevant LECs than those already obtained from phenomenology, considering the nontrivial mappings involved. With a focus on the leading-order LECs of the pionless EFT, L 1,A and $g$$^{NN}_{v}$, which parametrize, respectively, the strength of the isovector axial two-body current in a single-β decay (and other related processes such pp fusion), and of the isotensor contact two-body operator in the neutrinoless double-β decay within the light neutrino exchange scenario, the expected uncertainty on future extractions of L 1,A and $g$$^{NN}_{v}$ are examined using synthetic data at the physical values of the quark masses. It is observed that achieving small uncertainties in L 1,A will be challenging, and (sub)percent-level precision in the two-nucleon spectra and matrix elements is essential in reducing the uncertainty on this LEC compared to the existing constraints. On the other hand, the short-distance coupling of the neutrinoless double-β decay, $g$$^{NN}_{v}$, is shown to be less sensitive to uncertainties on both LQCD energies and the matrix element, and can likely be constrained with percent-level precision in the upcoming LQCD calculations.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
DOE OSTI2022

Investigating Local Carrier Dynamics in PERC Patterned CdTe Solar Cells

Remarkable progress has been achieved in CdTe photovoltaics (PVs) to further improve cell performance while reducing manufacturing costs. Researchers optimized the front contact that leads the short-circuit current density (J sc ) over 31mA/cm 2 (e.g., (Zn, Mg)O buffer layer and/or alloying CdTe with Se). Reese et al. reported an open-circuit voltage (V oc ) over 1 V with group-V doped single crystal, showing the feasibility of increasing V oc in CdTe PV that is fixed to less than 900 mV in most cases. Recent studies suggested that the V oc improvement in polycrystalline CdTe PVs requires well-passivated back contact. One possible strategy is to use CdMgTe alloy (E g > 1.8 eV), where the band-gap offset (ΔE CB ≈ 0.2 eV) reflects minority carrier electrons, thereby decreasing surface recombination. Another strategy is to utilize a stable Al 2 O 3 layer as an electron reflector; experimental works confirmed the improved performance with a conformal Al 2 O 3 layer. In this configuration, the precise control of Al 2 O 3 (≈1 nm) over the entire CdTe layer is essential because the J sc greatly depends on the tunneling current. While promising, both CdMgTe and Al 2 O 3 passivation on CdTe introduce unfavorable valence band offset that blocks the hole transport. Kephart et al. proposed a patterned passixc vation layer (≈ 20 nm Al 2 O 3 ) with point contacts (≈ 3 μm in diameter) that extract hole carriers. This configuration is similar to the passive emitter and rear contact (PERC) design that has been extensively studied in Si PVs. While remarkably high carrier lifetime and photoluminescence (> 10 X) were measured, consistent improvement in V oc and efficiency in this CdTe PERC were not yet observed. At this time, it is unclear how the surface potential is distributed in the presence of patterned Al 2 O 3 reflectors and how this additional field impacts the PV performance for Cu-doped and group-V doped CdTe PERC devices. To tackle this challenge, we develop robust nanofabrication and characterization platform to study CdTe PERC devices consisting of a patterned Al 2 O 3 layer on CdSe( 1-x )Te x (Cu-doped, GrV-doped; x = 0 to 1; CST). First Solar supplies high-quality CST materials. The dark and light I-Vs under 1-sun illumination are extracted for a series of each set of devices. We perform quantitative and qualitative PV analysis for a series of Cu-doped and Gr-V doped PERC devices, showing notably different V oc changes for GrV-doped compared to Cu-doped PERC devices. This project attempts to produce individual contacts on single grains and grain boundaries to measure lateral transport. As a model system, we use a CdSe( 1-x )Te x film on glass prepared by a colossal grain growth (CGG) technique at National Renewable Research Laboratories (NREL). Our preliminary results confirm that intergranular transport is hindered by the electrical barrier formed near grain boundaries. The PERC fabrication and the lateral transport measurement platform developed in this project can easily be applied to other types of advanced CdSe( 1-x )Te x architectures to better understand local photocarrier transport, in turn, providing the fundamental knowledge to improve the performance of CdTe PVs.

14 SOLAR ENERGY↗
NASA NTRS2022

X-Ray Imaging Observations of the High-Mass γ-Ray Binary HESS J0632+057

The Chandra X-ray Observatory (CXO)imaged the high-massγ-ray binary (HMGB) HESS8J0632+057 with the Advanced CCD Imaging Spectrometer (ACIS). We analyzed the CXO data to-9gether with 967 ks of archival imaging Swift-XRT observations. On arcsecond scales we find a hint10of asymmetric extended emission. On arcminute scales, there is a region of extended emission (“the11blob”) which is located≈5.5′east of the binary. The blob is seen in both the CXO-ACIS and the12Swift-XRT images but it does not have a counterpart in the radio, NIR, IR, or optical images. The13ACIS spectrum of the blob fits either an absorbed power-law model with Γ'2.6, or a thermal plasma14model withkT'3 keV. Since the blob’s NH is significantly larger than that of the binary we conclude15that the blob and binary are not directly related. The somewhat larger very deep XRT image suggests16that the binary may be located within a shell (or cavity). The four ACIS spectra taken within the∼2017day interval near the light curve minimum suggests that the NH is varying on timescales of days, pos-18sibly due to the inhomogenous circumbinary environment. The XRT spectra extracted from the wider19orbital phase intervals support significant changes in NH near the light curve maximum/minimum,20which may be responsible for the substantial systematic residuals seen near 1 keV, and provide tenta-21tive evidence for a Fe line at 6.4 keV. We find no significant periodic signal in the ACIS data up to 0.156 Hz.

O Kargaltsev↗
DOE OSTI2021

Multifunctional Conjugated Ligand Engineering for Stable and Efficient Perovskite Solar Cells

Surface passivation is an effective way to boost the efficiency and stability of perovskite solar cells (PSCs). However, a key challenge faced by most of the passivation strategies is reducing the interface charge recombination without imposing energy barriers to charge extraction. Here, a novel multifunctional semiconducting organic ammonium cationic interface modifier inserted between the light-harvesting perovskite film and the hole-transporting layer is reported. It is shown that the conjugated cations can directly extract holes from perovskite efficiently, and simultaneously reduce interface non-radiative recombination. Together with improved energy level alignment and the stabilized interface in the device, a triple-cation mixed-halide medium-bandgap PSC with an excellent power conversion efficiency of 22.06% (improved from 19.94%) and suppressed ion migration and halide phase segregation, which lead to a long-term operational stability, is demonstrated. Finally, this strategy provides a new practical method of interface engineering in PSCs toward improved efficiency and stability.

36 MATERIALS SCIENCE↗
DOE OSTI2024

Biomolecular budget of persistent, microbial-derived soil organic carbon: The importance of underexplored pools

The details of how soil microorganisms contribute to stable soil organic carbon pools are a pressing knowledge gap with direct implications for soil health and climate mitigation. It is now recognized that microbial necromass contributes substantially to the formation of stable soil carbon. However, the quantification of necromass in soils has largely been limited to model molecules such as aminosugar biomarkers. The abundance and chemical composition of other persistent microbial residues remain unresolved, particularly concerning how these pools may vary with microbial community structure, soil texture, and management practices. We use yearlong soil incubation experiments with an isotopic tracer to quantify the composition of persistent residues derived from microbial communities inhabiting sand or silt dominated soil with annual (corn) or perennial (switchgrass) monocultures. Persistent microbial residues were recovered in diverse soil biomolecular pools including metabolites, proteins, lipids, and mineral-associated organic matter (MAOM). The relative abundances of microbial contributions to necromass pools were consistent across cropping systems and soil textures. The greatest residue accumulation was not recovered in MAOM but in the light density fraction of soil debris that persisted after extraction by chemical fractionation using organic solvents. Necromass abundance was positively correlated with microbial biomass abundance and revealed a possible role of cell wall morphology in enhancing microbial carbon persistence; while gram-negative bacteria accounted for the greatest contribution to microbial-derived carbon by mass at one year, residues from gram-positive Actinobacteria and Firmicutes showed greater durability. Together these results offer a quantitative assessment of the relative importance of diverse molecular classes for generating durable soil carbon.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2022

Effect of proton irradiation temperature on persistent photoconductivity in zinc oxide metal-semiconductor-metal ultraviolet photodetectors

The electrical and structural characteristics of 50-nm-thick zinc oxide (ZnO) metal-semiconductor-metal ultraviolet (UV) photodetectors subjected to proton irradiation at different temperatures are reported and compared. The devices were irradiated with 200 keV protons to a fluence of 1016 cm−2. Examination of the x-ray diffraction (XRD) rocking curves indicates a preferred (100) orientation prior to irradiation, with decrease in crystal quality afterward. Additionally, peak shifts in XRD and Raman spectra of the control sample relative to well-known theoretical positions are indicative of tensile strain in the as-deposited ZnO films. Shifts toward theoretical unstrained positions are observed in the irradiated films, which indicates partial relaxation. Raman spectra also indicate increase in oxygen vacancies (VO) and zinc interstitial defects (Zni) compared to the control sample. Additionally, transient photocurrent measurements performed on each sample at different temperatures showed up to 2× increase in photocurrent decay time constants for irradiated samples vs the control. This persistent photoconductive behavior is linked to the activation of electron and hole traps near the surface, and to the desorption and reabsorption of O2 molecules on the ZnO surface under the influence of UV light. Using an Arrhenius model, trap activation energies were extracted and, by comparing with known energies from the literature, the dominant defects contributing to persistent photoconductivity for each irradiation condition were identified. The persistence of differences in photocurrent transients between different samples months after irradiation indicates that the defects introduced by the suppression of thermally activated dynamic annealing processes have a long-term deleterious effect on device performance.

Heuser, Thomas A. (ORCID:0000000225642400)↗
NASA NTRS1995

The stellar wind of an O8.5 I(f) star in M 31

We rediscuss the UV spectrum of OB 78#231, an O8.5 I(f) star in the Andromeda galaxy M 31, which has been obtained with the Faint Object Spectrograph on the Hubble Space Telescope by Hutchings et al. (1992). The spectrum has been re-extracted with better knowledge of background, calibration, and scattered light. The empirical analysis of the stellar wind lines results in a terminal velocity and mass loss rate similar to those typically found in comparable galactic objects. Furthermore, a comparison with an FOS spectrum of an O7 supergiant in the Small Magellanic Cloud and IUE spectra of galactic objects implies a metallicity close to galactic counterparts. These results are confirmed quantitatively by spectrum synthesis calculations using a theoretical description of O-star winds.

Haser, S. M.↗
NASA NTRS2009

The Evolution and Development of the Lunar Regolith and Implications for Lunar Surface Operations and Construction

The lunar regolith consists of about 90% submillimeter particles traditionally termed lunar soil. The remainder consists of larger particles ranging up to boulder size rocks. At the lower size end, soil particles in the 10s of nanometer sizes are present in all soil samples. Lunar regolith overlies bedrock which consists of either lava flows in mare regions or impact-produced megaregolith in highland regions. Lunar regolith has been produced over billions of years by a combination of breaking and communition of bedrock by meteorite bombardment coupled with a variety of complex space weathering processes including solar wind implantation, solar flare and cosmic ray bombardment with attendant radiation damage, melting, vaporization, and vapor condensation driven by impact, and gardening and turnover of the resultant soil. Lunar regolith is poorly sorted compared to most terrestrial soils, and has interesting engineering properties including strong grain adhesion, over-compacted soil density, an abundance of agglutinates with sharp corners, and a variety of properties related to soil maturity. The NASA program has supported a variety of engineering test research projects, the production of bricks by solar or microwave sintering, the production of concrete, the in situ sintering and glazing of regolith by microwave, and the extraction of useful resources such as oxygen, hydrogen, iron, aluminum, silicon and other products. Future requirements for a lunar surface base or outpost will include construction of protective berms, construction of paved roadways, construction of shelters, movement and emplacement of regolith for radiation shielding and thermal control, and extraction of useful products. One early need is for light weight but powerful digging, trenching, and regolith-moving equipment.

McKay, David↗
DOE OSTI2023

An exploration of machine learning models for the determination of reaction coordinates associated with conformational transitions

Determining collective variables (CVs) for conformational transitions is crucial to understanding their dynamics and targeting them in enhanced sampling simulations. Often, CVs are proposed based on intuition or prior knowledge of a system. However, the problem of systematically determining a proper reaction coordinate (RC) for a specific process in terms of a set of putative CVs can be achieved using committor analysis (CA). Identifying essential degrees of freedom that govern such transitions using CA remains elusive because of the high dimensionality of the conformational space. Various schemes exist to leverage the power of machine learning (ML) to extract an RC from CA. Here, we extend these studies and compare the ability of 17 different ML schemes to identify accurate RCs associated with conformational transitions. We tested these methods on an alanine dipeptide in vacuum and on a sarcosine dipeptoid in an implicit solvent. Our comparison revealed that the light gradient boosting machine method outperforms other methods. In order to extract key features from the models, we employed Shapley Additive exPlanations analysis and compared its interpretation with the “feature importance” approach. For the alanine dipeptide, our methodology identifies ϕ and θ dihedrals as essential degrees of freedom in the C7ax to C7eq transition. For the sarcosine dipeptoid system, the dihedrals ψ and ω are the most important for the cisαD to transαD transition. We further argue that analysis of the full dynamical pathway, and not just endpoint states, is essential for identifying key degrees of freedom governing transitions.

Chemistry↗
NASA NTRS1979

Flight test evaluation of predicted light aircraft drag, performance, and stability

A technique was developed which permits simultaneous extraction of complete lift, drag, and thrust power curves from time histories of a single aircraft maneuver such as a pullup (from V sub max to V sub stall) and pushover (to sub V max for level flight.) The technique is an extension to non-linear equations of motion of the parameter identification methods of lliff and Taylor and includes provisions for internal data compatibility improvement as well. The technique was show to be capable of correcting random errors in the most sensitive data channel and yielding highly accurate results. This technique was applied to flight data taken on the ATLIT aircraft. The drag and power values obtained from the initial least squares estimate are about 15% less than the 'true' values. If one takes into account the rather dirty wing and fuselage existing at the time of the tests, however, the predictions are reasonably accurate. The steady state lift measurements agree well with the extracted values only for small values of alpha. The predicted value of the lift at alpha = 0 is about 33% below that found in steady state tests while the predicted lift slope is 13% below the steady state value.

Smetana, F. O.↗
NASA NTRS1979

Flight test evaluation of predicted light aircraft drag, performance, and stability

A technique was developed which permits simultaneous extraction of complete lift, drag, and thrust power curves from time histories of a single aircraft maneuver such as a pull up (from V max to V stall) and pushover (to V max for level flight). The technique, which is an extension of nonlinear equations of motion of the parameter identification methods of Iliff and Taylor and includes provisions for internal data compatibility improvement as well, was shown to be capable of correcting random errors in the most sensitive data channel and yielding highly accurate results. Flow charts, listings, sample inputs and outputs for the relevant routines are provided as appendices. This technique was applied to flight data taken on the ATLIT aircraft. Lack of adequate knowledge of the correct full throttle thrust horsepower true airspeed variation and considerable internal data inconsistency made it impossible to apply the trajectory matching features of the technique.

Smetana, F. O.↗
DOE OSTI2020

Ultrafast spin-nematic and ferroelectric phase transitions induced by femtosecond light pulses

We report, optically induced phase transitions of the manganite Pr 1/3 Ca 2/3 MnO 3 have been simulated by using a model Hamiltonian that captures the dynamics of strongly correlated charge, orbital, lattice, and spin degrees of freedom. Its parameters have been extracted from first-principles calculations. Beyond a critical intensity of a femtosecond light pulse, the material undergoes an ultrafast and nonthermal magnetic phase transition from a noncollinear to collinear antiferromagnetic phase. The light-pulse excites selectively either a spin-nematic or a ferroelectric phase, depending on the light polarization. The behavior can be traced to an optically induced ferromagnetic coupling between Mn trimers, i.e., polarons which are delocalized over three Mn sites. The polarization guides the polymerization of the polaronic crystal into distinct patterns of ferromagnetic chains determining the target phase.

36 MATERIALS SCIENCE↗