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Topography and canopy cover influence soil organic carbon composition and distribution across a forested hillslope in the discontinuous permafrost zone

This dataset contains data used for the paper "Topography and canopy cover influence soil organic carbon composition and distribution across a forested hillslope in the discontinuous permafrost zone". The Related References field will be updated with a full citation when available. Topography and canopy cover influence ground temperature in warming permafrost landscapes, yet soil temperature heterogeneity introduced by meso-topographic slope positions, microtopographic differences in vegetation cover, and the subsequent impact of contrasting temperature conditions to soil organic carbon (SOC) dynamics are understudied. Buffering of permafrost-affected soils against warming air temperatures in boreal forests can reflect surface soil characteristics (e.g., thickness of organic material) as well as the degree and type of canopy cover (e.g., open cover vs closed cover). Both landscape and soil properties interact to determine meso- and micro-scale heterogeneity of ground warming. We sampled a hillslope catena transect in a discontinuous permafrost zone near Fairbanks, Alaska to test the small-scale (1 to 3 meter) impacts of slope position and cover type on soil organic matter composition. Mineral active layer samples were collected from backslope, low backslope, and footslope positions at depths spanning 19 to 60 cm. We examined soil mineralogical composition, soil moisture, total carbon and nitrogen content, and organic mat thickness in conjunction with an assessment of SOC composition using Fourier-transform ion Cyclotron Resonance Mass Spectrometry (FT-ICR-MS). Soils in the footslope position had a higher relative contribution of lignin-like compounds while backslope soils had more aliphatic and condensed aromatic compounds as determined by FT-ICR-MS. The effect of open versus closed tree canopy cover varied with slope position. On the backslope, we found higher oxidation of molecules under open cover compared with closed cover, indicating an effect of warmer soil temperature on decomposition. Little to no effect of canopy was observed for soils at the footslope position, which we attributed, in part, to the strong impact of soil moisture content in SOC dynamics in the water-gathering footslope position. The thin organic mat under open cover on the backslope position may have contributed to differences in soil temperature and thus SOC oxidation under open and closed canopy. Here, the thinner organic mat did not appear to buffer the underlying soil against warm season air temperatures and thus increased SOC decomposition as indicated by higher oxidation of SOC molecules and a lower contribution of simple molecules under open cover compared with the closed canopy sites. Our findings suggest that the role of canopy cover in SOC dynamics varies as a function of landscape position and soil properties, namely organic mat thickness and soil moisture. Condition-specific heterogeneity of SOC composition under open and closed canopy cover highlights the protective effect of canopy cover for soils on backslope positions. This dataset contains a compressed (.zip) archive of the data and R scripts used for this manuscript. The dataset includes files in .csv format, which can be accessed and processed using MS Excel or R. This archive can also be accessed on GitHub at https://github.com/Erin-Rooney/Y1_fairbanks (DOI: 10.5281/zenodo.8071247).

54 ENVIRONMENTAL SCIENCES↗

Landscape-scale Characterization of Arctic Tundra Vegetation Composition, Structure, and Function with a Multi-sensor Unoccupied Aerial System: Supporting Data.

Airborne remote sensing data collected using the Brookhaven National Laboratory's (BNL) heavy-lift unoccupied aerial system (UAS) octocopter platform, the Osprey, operated by the Terrestrial Ecosystem Science and Technology (TEST) group (https://www.bnl.gov/testgroup). This package includes data from three flights flown over the NGEE-Arctic Council, Kougarok and Teller sites in July, 2018. The Osprey is a multi-sensor UAS platform that simultaneously measures very high spatial resolution optical red/green/blue (RGB) and thermal infrared (TIR) surface 'skin' temperature imagery, as well as surface reflectance at 1 nm intervals in the visible to near-infrared spectral range 350 - 1000 nm measured at regular intervals along each flight path. Derived image products include ortho-mosaiced RGB and TIR images, an RGB-based digital surface model (DSM) using the structure from motion (SfM) technique, digital terrain model (DTM), and a canopy height model (CHM). In addition, a VNIR surface reflectance file is provided for the trigger locations collected during each flight campaign. Ancillary aircraft data, flight mission parameters, and general flight conditions provided by the onboard flight and data collection computers are also included. Unprocessed and processed data products are included in this package (processing levels 0-3). Data and metadata are provided as text (*.txt, *.json, *.kml, *hdr, *.enp), tabular (*.dat, *.csv, *.waypoint, ENVI format (no extension)), point cloud (*.laz) and image (*.jpg, *.tif, *png) formats. This metadata document contains flight campaign, instrument and file metadata, along with a description of data processing levels, data products and file naming scheme.The Next-Generation Ecosystem Experiments: Arctic (NGEE Arctic), a research effort to reduce uncertainty in Earth System Models by developing a predictive understanding of carbon-rich Arctic ecosystems and feedbacks to climate. NGEE Arctic was supported by the Department of Energy?s Office of Biological and Environmental Research.The NGEE Arctic project had two field research sites: 1) located within the Arctic polygonal tundra coastal region on the Barrow Environmental Observatory (BEO) and the North Slope near Utqiagvik (Barrow), Alaska and 2) multiple areas on the discontinuous permafrost region of the Seward Peninsula north of Nome, Alaska.Through observations, experiments, and synthesis with existing datasets, NGEE Arctic provided an enhanced knowledge base for multi-scale modeling and contributed to improved process representation at global pan-Arctic scales within the Department of Energy's Earth system Model (the Energy Exascale Earth System Model, or E3SM), and specifically within the E3SM Land Model component (ELM).

54 ENVIRONMENTAL SCIENCES↗

Energy Surplus and an Atmosphere‐Land‐Surface “Tug of War” Control Future Evapotranspiration

Abstract The 21st century evapotranspiration (ET) trends over the continental U.S. are assessed using innovative, energy‐based principles. Annual ET is projected to increase with high confidence at the rate of 20 mm for every 1℃ of rise in near‐surface air temperature, or 0.45 or 0.98 mm/year/year, depending on the emission scenario. The ET trajectory is dominated (58%) by the increase of land‐surface net radiative energy. An enhancement of the fraction of energy taken up by ET becomes a more important controller (53%) in late 21st century, under the high emission scenario. This increase is explained by the “tug of war” between atmospheric vapor demand and land‐surface ability to supply water. An assessment of future water availability (precipitation minus ET) shows no significant changes at the continental scale. This outcome nevertheless hides strong spatial variability, emphasizing the role of ET in shaping the distribution of water availability among human populations.

Xu, Donghui↗

Representing surface heterogeneity in land–atmosphere coupling in E3SMv1 single-column model over ARM SGP during summertime

Abstract. The Earth's land surface features spatial and temporal heterogeneity over a wide range of scales below those resolved by current Earth system models (ESMs). State-of-the-art land and atmosphere models employ parameterizations to represent their subgrid heterogeneity, but the land–atmosphere coupling in ESMs typically operates on the grid scale. Communicating the information on the land surface heterogeneity with the overlying atmospheric boundary layer (ABL) remains a challenge in modeling land–atmosphere interactions. In order to account for the subgrid-scale heterogeneity in land–atmosphere coupling, we implement a new coupling scheme in the Energy Exascale Earth system model version 1 (E3SMv1) that uses adjusted surface variances and covariance of potential temperature and specific water content as the lower boundary condition for the atmosphere model. The new lower boundary condition accounts for both the variability of individual subgrid land surface patches and the inter-patch variability. The E3SMv1 single-column model (SCM) simulations over the Atmospheric Radiation Measurement (ARM) Southern Great Plain (SGP) site were performed to assess the impacts. We find that the new coupling parameterization increases the magnitude and diurnal cycle of the temperature variance and humidity variance in the lower ABL on non-precipitating days. The impacts are primarily attributed to subgrid inter-patch variability rather than the variability of individual patches. These effects extend vertically from the surface to several levels in the lower ABL on clear days. We also find that accounting for surface heterogeneity increases low cloud cover and liquid water path (LWP). These cloud changes are associated with the change in cloud regime indicated by the skewness of the probability density function (PDF) of the subgrid vertical velocity. In precipitating days, the inter-patch variability reduces significantly so that the impact of accounting for surface heterogeneity vanishes. These results highlight the importance of accounting for subgrid heterogeneity in land–atmosphere coupling in next-generation ESMs.

54 ENVIRONMENTAL SCIENCES↗

Data, scripts, and figures associated with a manuscript studying impact of climate and topography on post-fire vegetation recovery.

This data package is associated with the publication “Impact of Topography and Climate on Post-fire Vegetation Recovery Across Different Burn Severity and Land Cover Types through Machine Learning” submitted to Remote Sensing of Environment (Zahura et al. 2023). In this research, a machine learning algorithm, random forest (RF), was utilized to examine the impact of climate and topography on post-fire vegetation recovery. We used enhanced vegetation index (EVI) to examine varying burn severity and land cover types. The data package includes the input files for RF model training, outputs from model predictions and analysis, and python scripts to run the model, analyze the results to understand model performance and interpretability, and plot manuscript figures. This data package contains three folders (Data, Scripts, and Figures), a file-level metadata (FLMD) csv, and a data dictionary (dd) csv. Please see Postfire_recovery_flmd.csv for a list of all files contained in this data package and descriptions for each. The data dictionary (Postfire_recovery_dd.csv) describes the csv column headers. The “Data” folder provides all the inputs and outputs to train the RF model, evaluate performance, and interpret predictions. The “Scripts” folder contains python scripts and jupyter notebooks for model training and result analysis. The “Figures” folder includes the figures used in the manuscript in “.png” and “.jpg” format.

54 ENVIRONMENTAL SCIENCES↗

Influences of North Pacific Ocean Domain Extent on the Western U.S. Winter Hydroclimatology in Variable-Resolution CESM

Variable-resolution global climate models (VRGCMs) are a dynamical downscaling method that can reach spatiotemporal scales needed for regional climate assessments. Over the years, several users of VRGCMs have assumed where the location and extent of the refinement domain should be based on knowledge of the prevailing storm tracks and resolution dependence of important regional climate processes (e.g., atmospheric rivers [ARs] and orographic uplift), but the effect of high-resolution domain size and extent on the simulation of downstream hydroclimatic phenomena has not been systematically evaluated. Here, we use variable resolution in the Community Earth System Model (VR-CESM) to perform such a test. To do this, three VR-CESM grids were generated that span the entire, two thirds, and one third of the North Pacific and evaluated for a 30-year climatology using Atmospheric Model Intercomparison Project protocols. Simulations are compared with reanalysis products offshore (fifth-generation of the European Centre for Medium-Range Weather Forecasts atmospheric reanalysis [ERA5]) and onshore (Livneh, 2015, https://doi.org/10.1038/sdata.2015.42, and Parameter-elevation Regressions on Independent Slopes Model [PRISM]) of the western United States. The westward expansion of refinement domain influenced integrated vapor transport (IVT), which was generally high biased but minimally impacted AR characteristics. Due to slight differences in landfalling AR counts in the western United States, California winter precipitation generally improved with westward expansion of the refinement domain. Western U.S. mountain snowpack and surface temperatures were insensitive to refinement domain size and were more influenced by changes in topographic resolution and/or land surface model version. Here, given minimal dependence of simulated western U.S. hydroclimate on refinement domain size over the North Pacific, we advise future VR-CESM studies to focus grid resolution on better resolving land surface heterogeneity.

54 ENVIRONMENTAL SCIENCES↗

Processed Surface Imagery & Raster Imagery taken onboard TigerShark (U3) UAS

Land-surface orthomosaic imagery derived from the images collected using the Micasense Altum Imager on board the UAS TigerShark (U3) on March 11th, 2021 at an altitude of 2000 ft. The Altum takes images of the land surface across five visible bands and one long wave infrared thermal band. The photogrametry software Agisoft PhotoScan v 1.4 is used to align and stitch the images into a larger composet image using the technique of structure from motion image capture to construct a dense cloud and 3-D model of the surface, which is used to produce a digital elevation model of the terraine surveyed and orthomosaic imagery. This dataset contains the raster calculated orthomosaics of various vegetative indicies, which are used to indicate plant health and land surface characteristics, including Normalized Difference Vegetation Index (NDVI), Green Normalized Difference Vegetation Index (GNDVI), Normalized Difference Water Index (NDWI), surface temperature, and Enhanced_vegetation_index (EVI). These orthomosaics were collected west of the Starkville, MS, airport, and include natural, agricultural, and industrial land coverage. The images have a resolution of 0.2 m/pix.

54 ENVIRONMENTAL SCIENCES↗

Arctic Soil Patterns Analogous to Fluid Instabilities: Supporting Data

This dataset characterizes solifluction lobe morphology and spatial patterns using pre-existing LiDAR-derived digital elevation models of 25 sites across Norway with accompanying long term climate data for each site. Data were collected as part of an effort to better understand controls on the formation of solifluction patterns and to test the idea that they are analogous to fluid instabilities. We also provide soil velocity profiles and estimates of effective viscosity from across the world, drawn from literature. They were collected to improve our understanding of the rheology of soliflucting soil. See this article for more information on the theoretical motivation behind this dataset see "Arctic soil patterns analogous to fluid instabilities" (Glade et al., 2021). Data files arranged in a hierarchy and include image files *.tif and *.png, GIS shapefiles and geopackages (*.gpkg), *.csv (with same file as *.xlsx), and *.py (Python scripts readable with a text editor). Files also bundled into *.zip files. Note (2021-10-20): unit corrections made on two files: RR.csv and snowfall.csv. The Next-Generation Ecosystem Experiments: Arctic (NGEE Arctic), was a research effort to reduce uncertainty in Earth System Models by developing a predictive understanding of carbon-rich Arctic ecosystems and feedbacks to climate. NGEE Arctic was supported by the Department of Energy's Office of Biological and Environmental Research. The NGEE Arctic project had two field research sites: 1) located within the Arctic polygonal tundra coastal region on the Barrow Environmental Observatory (BEO) and the North Slope near Utqiagvik (Barrow), Alaska and 2) multiple areas on the discontinuous permafrost region of the Seward Peninsula north of Nome, Alaska. Through observations, experiments, and synthesis with existing datasets, NGEE Arctic provided an enhanced knowledge base for multi-scale modeling and contributed to improved process representation at global pan-Arctic scales within the Department of Energy's Earth system Model (the Energy Exascale Earth System Model, or E3SM), and specifically within the E3SM Land Model component (ELM).

54 ENVIRONMENTAL SCIENCES↗

Cross-Scale Land-Atmosphere Experiment (CSLAEX) (Final Report)

It is now well recognized that land-atmosphere interactions play an important role in both weather and climate. These interactions take place over a wide range of spatial and temporal scales. Most of the current formulations of the momentum, heat and moisture transport laws are informed by observations with a limited temporal or spatial scale, and hence may have limited applicability. The objective of this work is to improve the multi-scale representation of the near-surface heat transfer in the ground and in the atmosphere using a combination of modeling and field observations. Our knowledge and predictive capacity in land-atmosphere coupling is limited by our capacity to observe the full-scale spectrum at play. In order to bridge this fundamental gap in our observation capacity I will work to: create the first long-term Integrated Cross-Scale land-Atmosphere Experiment (CSLAEX) since I will work to: measure the components of the surface energy balance at a spatial scale relevant to remote sensing and meteorological applications (5km), along with observations of the nested subscale processes with Distributed Temperature Sensors (DTS). This proposal aims to fill the gaps in modeling and observing land-atmosphere interactions across scales via a novel Cross-Scale Land-Atmosphere Experiment (CSLAEX) to be implemented as part of the Department of Energy (DOE) Atmospheric Radiation Measurement (ARM) Southern Great Plains (SGP) site near Lamont, Oklahoma. The proposed research effort aims at exploring land-atmosphere processes across multiple spatial scales and to investigate the effect of landscape heterogeneity using Distributed Temperature Sensor measurements. The novel instrumentation of the Surface Energy Balance and simultaneous observations of the atmospheric state (boundary layer, cloud, convection) available at the DOE ARM SGP site will be used to create CSLAEX. This dataset will be used to frame and evaluate new transport laws and parameterizations for the boundary layer and the land surface, which can be implemented into the Weather and Research Forecasting (WRF) model and Community Atmospheric Model (CAM). The result of this study should impact multiple fields: meteorology, climate, and hydrology.

54 ENVIRONMENTAL SCIENCES↗

An overview of the Western United States Dynamically Downscaled Dataset (WUS-D3)

Abstract. Predicting future climate change over a region of complex terrain, such as the western United States (US), remains challenging due to the low resolution of global climate models (GCMs). Yet the climate extremes of recent years in this region, such as floods, wildfires, and drought, are likely to intensify further as climate warms, underscoring the need for high-quality and high-resolution predictions. Here, we present an ensemble of dynamically downscaled simulations over the western US from 1980–2100 at 9 km grid spacing, driven by 16 latest-generation GCMs. This dataset is titled the Western US Dynamically Downscaled Dataset (WUS-D3). We describe the challenges of producing WUS-D3, including GCM selection and technical issues, and we evaluate the simulations' realism by comparing historical results to temperature and precipitation observations. The future downscaled climate change signals are shaped in physically credible ways by the regional model's more realistic coastlines and topography. (1) The mean warming signals are heavily influenced by more realistic snowpack. (2) Mean precipitation changes are often consistent with wetting on the windward side of mountain complexes, as warmer, moister air masses are uplifted orographically during precipitation events. (3) There are large fractional precipitation increases on the lee side of mountain complexes, leading to potentially significant changes in water resources and ecology in these arid landscapes. (4) Increases in precipitation extremes are generally larger than in the GCMs, driven by locally intensified atmospheric updrafts tied to sharper, more realistic gradients in topography. (5) Changes in temperature extremes are different from what is expected by a shift in mean temperature and are shaped by local atmospheric dynamics and land surface feedbacks. Because of its high resolution, comprehensiveness, and representation of relevant physical processes, this dataset presents a unique opportunity to evaluate societally relevant future changes in western US climate.

Rahimi, Stefan (ORCID:0000000331884462)↗

Gridded Sub-daily Climate Forcings for North America Based on Daymet and ERA5 (Daymet-ERA5)

To support high spatial and temporal resolution land surface modeling, this dataset provides hourly time step historic weather forcing at 1-km spatial resolution for the entire North America. The latest Daymet V4 data provides gridded historic daily weather observations at 1-km spatial resolution from 1980 to 2024. Using sub-daily temporal information from the ECMWF ERA5 reanalysis, Daymet was further temporally downscaled to hourly time steps and provided in the format required for land surface model simulations. The process of temporal downscaling preserves the relative magnitude in each hourly time step from ERA5 while maintaining the total and average values from Daymet for each day. This results in a blended 1980-2024 Daymet-ERA5 dataset. Available variables include surface air temperature, precipitation, specific humidity, shortwave and longwave radiation, wind speed, and pressure. These data can be used as a high-resolution meteorological forcing dataset to support high-resolution land surface modeling where accurate meteorological forcing datasets built from historic observations and/or reanalysis datasets are desirable.

54 ENVIRONMENTAL SCIENCES↗

SICOPOLIS-AD v1: an open-source adjoint modeling framework for ice sheet simulation enabled by the algorithmic differentiation tool OpenAD

We present a new capability of the ice sheet model SICOPOLIS that enables flexible adjoint code generation via source transformation using the open-source algorithmic differentiation (AD) tool OpenAD.The adjoint code enables efficient calculation of the sensitivities of a scalar-valued objective function or quantity of interest (QoI) to a range of important, often spatially varying and uncertain model input variables, including initial and boundary conditions, as well as model parameters.Compared to earlier work on the adjoint code generation of SICOPOLIS, our work makes several important advances:(i) it is embedded within the up-to-date trunk of the SICOPOLIS repository – accounting for 1.5 decades of code development and improvements – and is readily available to the wider community;(ii) the AD tool used, OpenAD, is an open-source tool;(iii) the adjoint code developed is applicable to both Greenland and Antarctica, including grounded ice as well as floating ice shelves, with an extended choice of thermodynamical representations.A number of code refactorization steps were required. They are discussed in detail in an Appendix as they hold lessons for the application of AD to legacy codes at large.As an example application, we examine the sensitivity of the total Antarctic Ice Sheet volume to changes in initial ice thickness, austral summer precipitation, and basal and surface temperatures across the ice sheet.Simulations of Antarctica with floating ice shelves show that over 100 years of simulation the sensitivity of total ice sheet volume to the initial ice thickness and precipitation is almost uniformly positive, while the sensitivities to surface and basal temperature are almost uniformly negative. Sensitivity to austral summer precipitation is largest on floating ice shelves from Queen Maud to Queen Mary Land. The largest sensitivity to initial ice thickness is at outlet glaciers around Antarctica. Comparison between total ice sheet volume sensitivities to surface and basal temperature shows that surface temperature sensitivities are higher broadly across the floating ice shelves, while basal temperature sensitivities are highest at the grounding lines of floating ice shelves and outlet glaciers. A uniformly perturbed region of East Antarctica reveals that, among the four control variables tested here, total ice sheet volume is the most sensitive to variations in austral summer precipitation as formulated in SICOPOLIS.Comparison between adjoint- and finite-difference-derived sensitivities shows good agreement, lending confidence that the AD tool is producing correct adjoint code.The new modeling infrastructure is freely available at http://www.sicopolis.net (last access: 2 April 2020) under the development trunk.

58 GEOSCIENCES↗

Effects of groundwater pumping on ground surface temperature: A regional modeling study in the North China Plain

Over-exploitation of groundwater (GW) in the North China Plain (NCP) since the 1960s has many environmental consequences. However, understanding of the dominant mechanisms remains limited, particularly at regional scale. In this study, the coupled ParFlow.CLM model representing subsurface and land-surface processes and their interactions was applied in the NCP at high spatio-temporal resolutions. The model was validated using the water and energy fluxes reported in previous studies and from the JRA-55 reanalysis. Numerical experiments were designed to examine the relative impacts of GW pumping and irrigation on the ground surface temperature (GST). Results show significant effects of GW pumping on GST in the NCP. Generally, the subsurface acts as a buffer to temporal variations in heat fluxes at the land-surface, but long-term pumping can gradually weaken this buffer, resulting in increases in the spatio-temporal variability of GST, as exemplified by hotter summers and colder winters. Considering that changes of water table depth (WTD) can significantly affect land surface heat fluxes when WTD ranges roughly between 0.01–10 m, the 0.5 m/year increase of WTD simulated by the model due to pumping can continue to increase the average WTD and hence, disturb GST, for about 20 years from the pre-pumping WTD in the NCP, before the WTD exceeds 10 m. The variations of GST are expected to be faster initially and gradually slow down due to the nonlinear behaviors of GST with WTD. The findings from this study in the NCP may also have implications for other regions with GW depletion.

Yang, Chen↗

Data for: Patel et al. Carbon flux estimates are sensitive to data source: A comparison of field and lab temperature sensitivity data

This dataset contains data and code used for the paper "Carbon flux estimates are sensitive to data source: A comparison of field and lab temperature sensitivity data" [DOI COMING SOON]A large literature exists on mechanisms driving soil production of the greenhouse gases CO2 and CH4. Measurements of these gases’ fluxes are often performed using closed-chamber incubations in the laboratory or in situ, i.e., in the field. Although it is common knowledge that measurements obtained through field studies vs. laboratory incubations can diverge because of the vastly different conditions of these environments, few studies have systematically examined these patterns. It is crucial to understand the magnitude and reasons for any differences, as these data are used to parametrize and benchmark ecosystem- to global-scale models, which are then susceptible to the biases of the source data. Here, we specifically examine how greenhouse gas measurements may be influenced by whether the measurement/incubation was conducted in the field vs. laboratory, focusing on CO2 and CH4 measurements. We use Q10 of greenhouse gas flux (temperature sensitivity) for our analyses, because of the ubiquity of this metric in biological and Earth system sciences and its importance to many modeling frameworks. We predicted that laboratory measurements would be less variable, but also less representative of true field conditions. However, there was greater variability in the Q10 values calculated from lab-based measurements of CO2 fluxes, because lab experiments explore extremes rarely seen in situ, and reflect the physical and chemical disturbances occurring during sampling, transport, and incubation. Overall, respiration Q10 values were significantly greater in laboratory incubations (mean = 4.19) than field measurements (mean = 3.05), with strong influences of incubation temperature and climate region/biome. However, this was in part because field measurements typically represent total respiration (Rs), whereas lab incubations typically represent heterotrophic respiration (Rh), making direct comparisons difficult to interpret. Focusing only on Rh-derived Q10, these values showed almost identical distributions across laboratory (n = 1110) and field (n = 581) experiments, providing strong support for using the former as an experimental proxy for the latter, although we caution that geographic biases in the extant data make this conclusion tentative. Due to a smaller sample size of CH4 Q10 data, we were unable to perform a comparable robust analysis, but we expect similar interactions with soil temperature, moisture, and environmental/climatic variables. Our results here suggest the need for more concerted efforts to document and standardize these data, including sample and site metadata. This dataset contains a compressed (.zip) archive of the data and R scripts used for this manuscript. The dataset includes files in .csv format, which can be accessed and processed using MS Excel or R. This archive can also be accessed on GitHub at https://github.com/kaizadp/field_lab_q10 (DOI: 10.5281/zenodo.7106554).

54 ENVIRONMENTAL SCIENCES↗

Deforestation reshapes land-surface energy-flux partitioning

Land-use and land-cover change significantly modify local land-surface characteristics and water/energy exchanges, which can lead to atmospheric circulation and regional climate changes. In particular, deforestation accounts for a large portion of global land-use changes, which transforms forests into other land cover types, such as croplands and grazing lands. Many previous efforts have focused on observing and modeling land–atmosphere–water/energy fluxes to investigate land–atmosphere coupling induced by deforestation. However, interpreting land–atmosphere–water/energy-flux responses to deforestation is often complicated by the concurrent impacts from shifts in land-surface properties versus background atmospheric forcings. In this study, we used 29 paired FLUXNET sites, to improve understanding of how deforested land surfaces drive changes in surface-energy-flux partitioning. Each paired sites included an intact forested and non-forested site that had similar background climate. We employed transfer entropy, a method based on information theory, to diagnose directional controls between coupling variables, and identify nonlinear cause–effect relationships. Transfer entropy is a powerful tool to detective causal relationships in nonlinear and asynchronous systems. The paired eddy covariance flux measurements showed consistent and strong information flows from vegetation activity (gross primary productivity (GPP)) and physical climate (e.g. shortwave radiation, air temperature) to evaporative fraction (EF) over both non-forested and forested land surfaces. More importantly, the information transfers from radiation, precipitation, and GPP to EF were significantly reduced at non-forested sites, compared to forested sites. We then applied these observationally constrained metrics as benchmarks to evaluate the Energy Exascale Earth System Model (E3SM) land model (ELM). ELM predicted vegetation controls on EF relatively well, but underpredicted climate factors on EF, indicating model deficiencies in describing the relationships between atmospheric state and surface fluxes. Moreover, changes in controls on surface energy flux partitioning due to deforestation were not detected in the model. We highlight the need for benchmarking model simulated surface-energy fluxes and the corresponding causal relationships against those of observations, to improve our understanding of model predictability on how deforestation reshapes land surface energy fluxes.

54 ENVIRONMENTAL SCIENCES↗

Integrating Reanalysis and Satellite Cloud Information to Estimate Surface Downward Long-Wave Radiation

The estimation of downward long-wave radiation (DLR) at the surface is very important for the understanding of the Earth’s radiative budget with implications in surface–atmosphere exchanges, climate variability, and global warming. Theoretical radiative transfer and observationally based studies identify the crucial role of clouds in modulating the temporal and spatial variability of DLR. In this study, a new machine learning algorithm that uses multivariate adaptive regression splines (MARS) and the combination of near-surface meteorological data with satellite cloud information is proposed. The new algorithm is compared with the current operational formulation used by the European Organization for the Exploitation of Meteorological Satellites (EUMETSAT) Satellite Application Facility on Land Surface Analysis (LSA-SAF). Both algorithms use near-surface temperature and dewpoint temperature along with total column water vapor from the latest European Centre for Medium-range Weather Forecasts (ECMWF) reanalysis ERA5 and satellite cloud information from the Meteosat Second Generation. The algorithms are trained and validated using both ECMWF-ERA5 and DLR acquired from 23 ground stations as part of the Baseline Surface Radiation Network (BSRN) and the Atmospheric Radiation Measurement (ARM) user facility. Results show that the MARS algorithm generally improves DLR estimation in comparison with other model estimates, particularly when trained with observations. When considering all the validation data, root mean square errors (RMSEs) of 18.76, 23.55, and 22.08 W·m –2 are obtained for MARS, operational LSA-SAF, and ERA5, respectively. The added value of using the satellite cloud information is accessed by comparing with estimates driven by ERA5 total cloud cover, showing an increase of 17% of the RMSE. The consistency of MARS estimate is also tested against an independent dataset of 52 ground stations (from FLUXNET2015), further supporting the good performance of the proposed model.

54 ENVIRONMENTAL SCIENCES↗

Atmospheric Gases as Quantitative Indicators of Urbanization Across Land-Use Gradients

The urban heat island (UHI) effect is a significant phenomenon characterized by higher surface temperatures in cities compared to surrounding rural areas. This change in the Earth's energy balance presents considerable challenges for urban populations, increasing heat exposure, straining energy infrastructure, and exacerbating health vulnerabilities. Quantifying UHI intensity is challenging due to blurred distinctions between urban and rural areas as land-use patterns evolve. To address this challenge, the present study builds on the framework established by Salvador et al. (2025) and investigates the use of atmospheric constituents, specifically volatile organic compounds (VOCs) and inorganic gases, as tracers of urbanization levels. A key improvement in this approach is the inclusion of a designated true rural site for comparison. Field measurements were conducted at two locations in the Southeastern United States during the summer of 2025. Inorganic gases were monitored continuously, while VOC samples were collected biweekly and analyzed using a proton transfer reaction time-of-flight mass spectrometer. The urban site exhibited elevated concentrations of anthropogenic inorganic gases, with carbon monoxide and nitrogen dioxide averaging 878 ppb and 17.99 ppb, respectively. In contrast, the rural site showed lower levels of these pollutants, 796 ppb for carbon monoxide and 12.46 ppb for nitrogen dioxide, while displaying higher concentrations of biogenic VOCs, including isoprene and monoterpenes at 1.24 ppb and 0.08 ppb, respectively. Extended mass spectral analyses revealed distinct chemical differences between the two sites, supporting the observed variability of major gases. Overall, these findings are consistent with our previous research and highlight the value of atmospheric constituents as effective indicators of urbanization, thereby improving our understanding of UHI dynamics.

54 ENVIRONMENTAL SCIENCES↗

Soil temperature mitigation due to vegetation biophysical feedbacks

Understanding the interactions between temperature regimes and vegetation cover is one of the key scientific topics in global environmental change and land surface process research. Recently, the prominent global greening trend has inspired considerable interest in examining climate feedbacks to vegetation changes. However, the impacts of recent widespread vegetation cover changes on soil temperature have been less documented and have received insufficient attention. Here, a high-resolution regional climate model was used to examine the potential impact of vegetation cover changes over the past 37 years, obtained as satellite observational data, on regional air and soil temperatures across the Heilong-Amur River Basin. Our sensitivity experiments indicated that the 1.85% increase in the regional fractional vegetation cover (FVC) from 1982 to 2018 cooled the air temperature by 0.045°C and the soil temperature by 0.19°C and that this cooling effect would continue in the near future, from 2016-2018 to 2051-2053. We found that soil temperatures were more sensitive to vegetation cover changes than air temperatures, particularly in mid-high latitude forest ecosystems; this finding helps to explain the nonsignificant decrease in soil temperatures in forest ecosystems over the past 40 years detected in the ERA5-Land reanalysis. Further, our results also suggest that vegetation restoration in forest ecosystems could mitigate the effects of climate change on permafrost environments by increasing the number of soil freezing days.

54 ENVIRONMENTAL SCIENCES↗