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NASA NTRS1994

Ion transport and loss in the Earth's quiet ring current. 2: Diffusion and magnetosphere-ionosphere coupling

We have studied the transport and loss of H(+), He(+), and He(++) ions in the Earth's quiet time ring current (1 to 300 keV/e, 3 to 7 R(sub E), Kp less than 2+, absolute value of Dst less than 11, 70 to 110 degs pitchangles, all LT) comparing the standard radial diffusion model developed for the higher-energy radiation belt particles with measurements of the lower energy ring current ions in a previous paper. Large deviations of that model, which fit only 50% of the data to within a factor of 10, suggested that another transport mechanism is operating in the ring current. Here we derive a modified diffusion coefficient corrected for electric field effects on ring current energy ions that fit nearly 80% of the data to within a factor of 2. Thus we infer that electric field fluctuations from the low-latitude to midlatitude ionosphere (ionospheric dynamo) dominated the ring current transport, rather than high-latitude or solar wind fluctuations. Much of the remaining deviation may arise from convective electric field transport of the E less than 30 keV particles. Since convection effects cannot be correctly treated with this azimuthally symmetric model, we defer treatment of the lowest-energy ions to a another paper. We give chi(exp 2) contours for the best fit, showing the dependence of the fit upon the internal/external spectral power of the predicted electric and magnetic field fluctuations.

Sheldon, R. B.↗

DOE OSTI2025

Chelation ion chromatography as an automated, and cost-effective analytical technique for REE determination: method development and applications

Rare earth elements (REEs), as critical minerals, have important uses in modern energy and technologies, yet are vulnerable to potential supply chain disruptions. To establish domestic REE supply chain, efficient REE detection methods for resource characterization and mineral processing will be needed to accelerate innovations for domestic REE recovery. This study developed a rapid, novel, and cost-effective for REE detection method using ion chromatography (IC) for aqueous samples. Various REE-targeted eluent gradients and post-column agent compositions were tested on the chelation ion chromatography (CIC) with UV-vis detector for optimal separation and quantification of REEs within approximately 20 min. The single-channel pump to deliver the post-column solution to UV-vis detector was replaced with a 4-channel gradient pump, to increase operation and maintenance efficiencies. After method optimization, resulting calibration curves for more than ten REEs achieved high coefficients of determination (R2>0.999) and low relatively standard deviations (below 3.24%), demonstrating sub-ppm level detection limits (0.0897 to 0.1149 mg/L). The reliability of the CIC method was validated through comparison with inductively coupled plasma mass spectrometry (ICP-MS), showing strong agreement in REE recovery from certified standards. The impact of metal ions and salts on REE recovery using CIC was also systematically investigated. CIC consistently exhibited reliable performance in the presence of salt solutions such as NaCl and Na₂SO₄ (up to 10,000 mg/L). Our study also found the presence of high concentrations of Al ions (at 10,000 mg/L) significantly influenced REE determination, and elevated concentrations of Ca ions affected the recovery of specific REEs, including La, Ce, and Pr. The CIC method was further tested on REE-containing eluents from solvent extraction tests out of fly ash leachates. REE detection from these real processing fluids were reported to achieve 90% to 100% recovery rate from our IC method, compared to ICP-MS results. This study underscores the potential of CIC as a reliable and efficient alternative for REE determination in complex matrices. It also highlights the importance of minimizing select interfering metal ions in solutions to ensure accurate results. The REE CIC method presents a promising, low-maintenance, salt-tolerant, and cost-effective alternative to traditional analytical methods for REE analysis.

detection of rare earth elements (REE)↗

DOE OSTI2022

Modeling Heterogeneity in UO 2 Nanoparticles Using X‐ray Absorption Spectroscopy

Abstract EXAFS provides the capability to interrogate nanoparticle (NP) structure in atomistic detail without relying on long‐range crystallinity. There is a limitation in that EXAFS provides averaged structural information, making it difficult to separate a small amount of heterogeneous structure from bulk. In this work, models were developed to extract surface‐specific information from conventional EXAFS measurements collected on UO 2 NPs of varying size. Specifically, the surface terminating species of UO 2 NPs was determined from comparison of coordination numbers with geometric models while the origin of static disorder was interrogated from user‐defined simulations. Results show that the degree of oxygenation on the NP surface does not significantly deviate from bulk surface and that static disorder is highly enhanced in NP surface layers but cannot be attributed to surface relaxation effects alone. The approach described herein has the potential to be adapted to a range of inorganic NP systems to interrogate surface structure.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

DOE OSTI2022

RAPID UNSEPARATED RARE EARTH ELEMENT ANALYSES BY ISOTOPE DILUTION MULTICOLLECTOR INDUCTIVELY COUPLED MASS SPECTROMETRY (ID-MC-ICP-MS)

We present a method for analyzing rare earth elements (REEs) by isotope dilution without separation of individual elements. Utilizing a Nu Plasma 2 multicollector inductively coupled plasma mass spectrometer (MC-ICP-MS) equipped with an Aridus II desolvation nebulizer, sample introduction tuning parameters (torch position, gas flows) were investigated and used to minimize oxide formation (e.g., NdO/Nd <0.05%) and remove the need to analyze the REEs as separated “cuts.” Ratios for spike/sample isotopes in mixed synthetic standards containing varying amounts of Ce, Nd, Sm, Eu, Gd, Dy, Er, and Yb were measured accurately within 1% of IUPAC values. La and Lu in the standards were more than 2% off from expected values due to more demanding interference corrections. A USGS BCR-2 rock standard was also processed with flux fusion, iron coprecipitation and a single column pass bulk separation followed by analysis. The concentrations for Ce, Nd, Sm, Eu, Dy, Er, and Yb fell within 2% of consensus values. A United States Geological Survey (USGS) BIR-1A rock standard was also processed in triplicate by hydrofluoric and nitric acid digestion, yielding rare earth concentrations within 3% of consensus values with 0.3% relative standard deviation (n=3). This demonstrates the ability to produce high quality REE patterns of comparable quality to traditional methods involving labor and time intensive REE separation, with sample preparation and analytical times that are comparable to analyses against isotope dilution by single-collector ICP-MS.

Shen, Steve D.↗

DOE OSTI2020

Reconstruction of Electron and Ion Distribution Functions in a Magnetotail Reconnection Diffusion Region

In the diffusion region of magnetotail reconnection, particle distributions are highly structured, exhibiting triangular shapes and multiple striations that deviate dramatically from the Maxwellian distribution. Fully kinetic simulations have been demonstrated to be capable of producing the essential structures of the observed distribution functions, yet are computationally not feasible for 3D global simulations. The fluid models used for large-scale simulations, on the other hand, do not have the kinetic physics necessary for describing reconnection accurately. Our study aims to bridge fully kinetic and fluid simulations by quantifying the information required to capture the non-Maxwellian features in the distributions underlying the closures used in the fluid code. Here, we compare the results of fully kinetic simulations with observed electron velocity distributions in a magnetotail reconnection diffusion region and use the maximum entropy model to reconstruct electron and ion distributions using various numbers of moments obtained from the simulation. Our results indicate that using only local moments, the maximum entropy model can reproduce many of the features of the distributions: (1) the electron outflow distribution with a tilted triangular structure is reproduced with 21 or more moments in agreement with Ng et al. and (2) counterstreaming distributions can be captured with the 35-moment model when the separation in velocity space between the populations is large.

58 GEOSCIENCES↗

DOE OSTI2022

An Assessment of Nonhydrostatic and Hydrostatic Dynamical Cores at Seasonal Time Scales in the Energy Exascale Earth System Model (E3SM)

Abstract In global atmospheric modeling, the differences between nonhydrostatic (NH) and hydrostatic (H) dynamical cores are negligible in dry simulations when grid spacing is larger than 10 km. However, recent studies suggest that those differences can be significant at far coarser resolution when moisture is included. To better understand how NH and H differences manifest in global fields, we perform and analyze an ensemble of 28 and 13 km seasonal simulations with the NH and H dynamical cores in the Energy Exascale Earth System Model global atmosphere model, where the differences between H and NH configurations are minimized. A set of idealized rising bubble experiments is also conducted to further investigate the differences. Although NH and H differences are not significant in global statistics and zonal averages, significant differences in precipitation amount and patterns are observed in parts of the tropics. The most prominent differences emerge near India and the Western Pacific in the boreal summer, and the central‐southern Indian Ocean and Pacific in the boreal winter. Tropical differences influence surrounding regions through modification of the regional circulation and can propagate to the extratropics, leading to significant temperature and geopotential differences over the middle to high latitudes. While the dry bubble experiments show negligible deviation between H and NH dynamics until grid spacing is below 6.25 km, precipitation amount and vertical velocity are different in the moist case even at 25 km resolution.

58 GEOSCIENCES↗

DOE OSTI2026

Photoinduced correlations in stochastic dynamics of a solid-state ionic conductor

Photoexcitation by ultrashort laser pulses plays a crucial role in controlling reaction pathways, creating nonequilibrium material properties, and probing complex molecular dynamics. The photoresponse following a laser pulse is generally nonidentical between exposures due to spatiotemporal fluctuations or the stochastic nature of dynamical pathways. However, most ultrafast pump-probe experiments struggle to distinguish intrinsic sample fluctuations from extrinsic apparatus noise, often missing deviations from the averaged response. Leveraging the stability and high photon flux of time-resolved X-ray micro-diffraction at a synchrotron, we characterized stochastic photoinduced dynamics in a solid-state ionic conductor. By analyzing temporal evolutions of the lattice parameter of a single grain, we found that shot-to-shot fluctuations are not independent. Instead, correlations exist between nonequilibrium lattice trajectories following adjacent shots, with a characteristic correlation length of approximately 1500 shots, corresponding to an energy barrier of 0.4 ± 0.1 eV, close to the activation energy of lithium-ion diffusion.

36 MATERIALS SCIENCE↗

DOE OSTI2024

Perturbatively including inhomogeneities in axion inflation

Axion inflation, i.e. an axion-like inflaton coupled to an Abelian gauge field through a Chern-Simons interaction, comes with a rich and testable phenomenology. This is particularly true in the strong backreaction regime, where the gauge field production heavily impacts the axion dynamics. Lattice simulations have recently demonstrated the importance of accounting for inhomogeneities of the axion field in this regime. We propose a perturbative scheme to account for these inhomogeneities while maintaining high computational efficiency. Our goal is to accurately capture deviations from the homogeneous axion field approximation within the perturbative regime as well as self-consistently determine the onset of the nonperturbative regime.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

DOE OSTI2025

Driver Identification Midyear Report

First, we create a profile for each authorized driver based on their existing driving data. We then train a machine learning model on the driving data from this profile, yielding an individualized model for each driver. Finally during a drive, we pass the Controller Area Network (CAN) data to the model and authen ticate the driver’s identity in real-time. This verification or lack thereof could be used to alert supervisors of threats to their drivers or transported materials. Deviations from their normal driving behavior could indicate high-risk situations, medical events, or even insider threats.

98 NUCLEAR DISARMAMENT, SAFEGUARDS, AND PHYSICAL P↗

NASA NTRS1975

Wideband phase modulator works directly on carrier

Multiplier-induced problems related to undesirable effects of the varactor multiplier on the modulation spectrum are eliminated in a modulator circuit which operates directly at the desired output frequency. The principles of operation of the new circuit are discussed and attention is given to requirements for high-Q components and the possibility of linear frequency deviation.

Rippy, R. R.↗

NASA NTRS1977

A model for simulating random atmospheres as a function of latitude, season, and time

An empirical stochastic computer model was developed with the capability of generating random thermodynamic profiles of the atmosphere below an altitude of 99 km which are characteristic of any given season, latitude, and time of day. Samples of temperature, density, and pressure profiles generated by the model are statistically similar to measured profiles in a data base of over 6000 rocket and high-altitude atmospheric soundings; that is, means and standard deviations of modeled profiles and their vertical gradients are in close agreement with data. Model-generated samples can be used for Monte Carlo simulations of aircraft or spacecraft trajectories to predict or account for the effects on a vehicle's performance of atmospheric variability. Other potential uses for the model are in simulating pollutant dispersion patterns, variations in sound propagation, and other phenomena which are dependent on atmospheric properties, and in developing data-reduction software for satellite monitoring systems.

Campbell, J. W.↗

NASA NTRS1977

Use of the optimal control model in the design of motion cue experiments

An experiment is presented in which the effects of roll motions on human operator performance were investigated. The motion cues considered were the result of commanded vehicle motion and vehicle disturbances. An optimal control pilot-vehicle model was used in the design of the experiment and to predict system performance prior to executing the experiment. The model predictions and experimental results are compared. Seventy-eight per cent of the model predictions are within one standard deviation of the means of the experimental results. The high correlation between model predictions and system performance indicate the usefulness of the predictive model for experimental design and for prediction of pilot performance influenced by motion cues.

Junker, A. M.↗

NASA NTRS1982

Spin tests of a single-engine, high-wing light airplane

The airplane has a relatively steep spin mode (low angle of attack) with a high load factor and high velocity. The airplane recovers almost immediately after any deviation from the prospin control positions, except for one maneuver with reduced flexibility in the elevator control system.

Stewart, E. C.↗

NASA NTRS1985

Effect of time span and task load on pilot mental workload

Two sets of experiments were run to examine how the mental workload of a pilot might be measured. The effects of continuous manual control activity versus discrete assigned mental tasks (including the length of time between receiving an assignment and executing it) were examined. The first experiment evaluated the strengths and weaknesses of measuring mental workload with an objective perforamance (altitude deviations) and five subjective ratings (activity level, complexity, difficulty, stress, and workload). The second set of experiments built upon the first set by increasing workload intensities and adding another performance measure: airspeed deviation. The results are discussed for both low and high experience pilots.

Berg, S. L.↗

NASA NTRS1985

Modeling the 3-D flow effects on deviation angle for axial compressor middle stages

A model of the spanwise variation of the three-dimensional flow effects on deviation is proposed for middle-stage rotors and stators. This variation is taken as the difference above or below that predicted by blade element theory at any spanwise location. It was found that the stator variation is strongly affected by the end-wall boundary-layer thickness as well as camber, solidity, and blade channel aspect ratio. Rotor variation was found to depend on end-wall boundary layer thickness and tip clearance normalized by blade span. If these parameters are known or can be calculated, the models provide a reasonable approximation to the spanwise variation of deviation for middle compressor stages operating at low to high subsonic inlet Mach numbers.

Roberts, W. B.↗

NASA NTRS1988

Recent advances in capacitance type of blade tip clearance measurements

Two recent electronic advances at NASA-Lewis that meet the blade tip clearance needs of a wide class of fans, compressors, and turbines are described. The first is a frequency modulated (FM) oscillator that requires only a single low cost ultrahigh frequency operational amplifier. Its carrier frequency is 42.8 MHz when used with a 61 cm long hermetically sealed coaxial cable. The oscillator can be calibrated in the static mode and has a negative peak frequency deviation of 400 kHz for a typical rotor blade. High temperature performance tests of the probe and 13 cm of the adjacent cable show good accuracy up to 600 C, the maximum which produces a clearance error of + or - 10 microns at a clearance of 500 microns. In the second advance, a guarded probe configuration allows a longer cable capacitance. The capacitance of the probe is part of a small time constant feedback in a high speed operational amplifier. The solution of the governing differential equation is applied to a ramp type of input. The results show an amplifier output that contains a term which is proportional to the derivative of the feedback capacitance. The capacitance is obtained by subtracting a balancing reference channel followed by an integration stage.

Barranger, John P.↗

NASA NTRS1988

Recent advances in capacitance type of blade tip clearance measurements

Barranger, John P.↗

NASA NTRS1994

Gravitational collapse of small-scale structure as the origin of the Lyman-alpha forest

If gravitational clustering is a hierarchical process, the present large-scale structure of the galaxy distribution implies that structures on smaller scales must have formed at high redshift. We simulate the formation of small-scale structure (average cell mass: (delta) bar m(sub b) = 10(sup 4.2) solar mass) and the evolution of photoionized gas, in the specific case of the CDM + Lambda model. The photoionized gas has a natural minimal scale of collapse, the Jeans scale (m(sub b,J) is approximately equal to 10(exp 9) solar mass). We find that low column density (N(sub HI) is less than or equal to 10(exp 14)/sq cm) lines originate in regions resembling Zel'dovich pancakes, where gas with overdensities in the range 3-30 is enclosed by two shocks but is typically reexpanding at approximately the Hubble velocity. However, higher column density lines stem from more overdense regions where the shocked gas is cooling. We show that this model can probably account for the observed number of lines, their distribution in column density and b-parameters, as well as the cloud physical sizes as observed in gravitationally lensed quasars. We find a redshift evolution that is too steep; however, this may be due to insufficient dynamical range in the simulation or because the specific model is incorrect. The model predicts that high signal-to-noise observations should find systematic deviations from Voigt profiles, mainly in the form of broad wings in the line profiles, and that a fluctuating Gunn-Peterson effect will be detected, which can be modeled as a superposition of weak lines with a wide range of b-parameters.

Cen, Renyue↗