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At least 199 records · Page 11
All sourcesNASA NTRSDOE OSTI
NASA NTRS1990

Acetylene-chromene terminated resins as high temperature thermosets

A novel phase transfer catalyzed process for the preparation of propargyl ethers has been developed. The propargyl ethers serve as precursors to a new class of thermosetting resins called acetylene-chromene terminated (ACT) resins. Heat treatment of a solution of propargyl ethers with various catalysts, followed by removal of solvent leads to the ACT resins via partial conversion of the propargyl ether groups to chromenes. This process reduces the energy content of the resin systems and reduces the amount of shrinkage found during cure. Due to the presence of the solvent the process is safe and gives rise to low viscosity products suitable for resin transfer molding and filament winding type applications. Due to the high glass transition temperature, high modulus, and low moisture uptake the cured resins display better than 232 C/wet performance. The thermal stability of the ACT resins in air at 204 C is superior to that of conventional bismaleimide resins. The resins also display excellent electrical properties.

Godschalx, J. P.↗
NASA NTRS1991

Pultrusion process characterization

Pultrusion is a process through which high-modulus, lightweight composite structural members such as beams, truss components, stiffeners, etc., are manufactured. The pultrusion process, though a well-developed processing art, lacks a fundamental scientific understanding. The objective here was to determine, both experimentally and analytically, the process parameters most important in characterizing and optimizing the pultrusion of uniaxial fibers. The effects of process parameter interactions were experimentally examined as a function of the pultruded product properties. A numerical description based on these experimental results was developed. An analytical model of the pultrusion process was also developed. The objective of the modeling effort was the formulation of a two-dimensional heat transfer model and development of solutions for the governing differential equations using the finite element method.

Vaughan, James G.↗
NASA NTRS1992

Probabilistic assessment of space trusses subjected to combined mechanical and thermal loads

A three-bay, space, cantilever truss is probabilistically evaluated to quantify the range of uncertainties of buckling loads and member forces due to nonuniform thermal loads, applied loads and moments (mechanical loads), and combination of both. The truss members are assumed to be made from Aluminum tubes or high modulus graphite-fiber/intermediate modulus epoxy-matrix composite tubes. Cumulative distribution function results show that certain combinations of thermal loads with mechanical loads reduce the probabilistic buckling loads and increase the magnitude of the member axial forces for the aluminum truss. The same trend is observed for the composite truss as well, as however, the thermal effects on the probabilistic buckling loads and member axial forces are not as substantial as that for an aluminum truss. This can be attributed to the large differences in the values of coefficient of thermal expansion. Finally, the sensitivities associated with the uncertainties in the structural, material, and load variables (primitive variables) are investigated. They show that buckling loads and member axial forces are most sensitive to the uncertainties in spacial (geometry) variables.

Pai, Shantaram S.↗
NASA NTRS1991

Polymer blends for LDB applications

A series of LCP/PE blends have been studied to determine the potential of such systems to produce a high modulus balloon film material which retains the balloon fabrication and low temperature flight advantages of the current PE films. Blown films of blends of 5 and 15 percent LCP in PE have been produced which show a 28 percent enhancement in modulus over the neat PE matrix. These results are substantially lower than anticipated and are explained in terms of the LCP reinforcement aspect ratio and fibril diameter.

Lichkus, Andrew M.↗
NASA NTRS1992

Sensitivity of the coefficients of thermal expansion of selected graphite reinforced composite laminates to lamina thermoelastic properties

An analytical study of the sensitivity of the laminate coefficient of thermal expansion, CTE, to changes in lamina elastic properties has been made. High modulus graphite/epoxy (P75/934, P100/934, P120/934), graphite/aluminum (P100/Al), and graphite/glass (HMS/Gl) composite materials were considered in quasi-isotropic, low thermal stress, and 'near-zero' thermal expansion laminate configurations. The effects of a positive or negative 10 percent change in lamina properties on laminate CTE is strongly dependent upon both the composite material and the laminate configuration. A 10 percent change in all of the lamina properties had very little effect on the laminate CTE of the HMS/Gl composite laminates investigated. The sensitivity and direction of change in the laminate CTE of Gr/934 depended very strongly on the fiber properties. A 10 percent change in the lamina transverse CTE resulted in changes as large as 0.216 ppm/C in the laminate CTE of a quasi-isotropic Gr/934 laminate. No significant difference was observed in the sensitivity of the laminate CTE of the P100/934 and P120/934 composite materials due to changes in lamina properties. Large changes in laminate CTE can result from measured temperature and radiation effects on lamina properties.

Tompkins, S. S.↗
NASA NTRS1992

Nonuniform thermal environmental effects on space truss structural reliability

A three-bay, space, cantilever truss is probabilistically evaluated to quantify the range of uncertainties of buckling loads and member forces due to nonuniform thermal loads, applied loads and moments (mechanical loads), and combination of both. The truss members are assumed to be made from (1) aluminum tubes or (2) high modulus graphite-fiber/intermediate modulus epoxy-matrix composite tubes. Cumulative distribution function results show that certain combinations of thermal loads with mechanical loads reduce the probabilistic buckling loads and increase the magnitude of the member axial forces for aluminum truss. However, the reverse is true for composite truss due to very low coefficient of thermal expansion and higher stiffness of the composite. Finally, the sensitivities associated with the uncertainties in the structural, material, and load variables (primitive variables) are investigated. They show that buckling loads and member axial forces are most sensitive to the uncertainties in spacial (geometry) variables.

Pai, Shantaram S.↗
NASA NTRS1992

Numerical calibration of the stable poisson loaded specimen

An analytical calibration of the Stable Poisson Loaded (SPL) specimen is presented. The specimen configuration is similar to the ASTM E-561 compact-tension specimen with displacement controlled wedge loading used for R-Curve determination. The crack mouth opening displacements (CMOD's) are produced by the diametral expansion of an axially compressed cylindrical pin located in the wake of a machined notch. Due to the unusual loading configuration, a three-dimensional finite element analysis was performed with gap elements simulating the contact between the pin and specimen. In this report, stress intensity factors, CMOD's, and crack displacement profiles are reported for different crack lengths and different contacting conditions. It was concluded that the computed stress intensity factor decreases sharply with increasing crack length, thus making the SPL specimen configuration attractive for fracture testing of brittle, high modulus materials.

Ghosn, Louis J.↗
NASA NTRS1992

Results of ASTM round robin testing for mode 1 interlaminar fracture toughness of composite materials

The results are summarized of several interlaboratory 'round robin' test programs for measuring the mode 1 interlaminar fracture toughness of advanced fiber reinforced composite materials. Double Cantilever Beam (DCB) tests were conducted by participants in ASTM committee D30 on High Modulus Fibers and their Composites and by representatives of the European Group on Fracture (EGF) and the Japanese Industrial Standards Group (JIS). DCB tests were performed on three AS4 carbon fiber reinforced composite materials: AS4/3501-6 with a brittle epoxy matrix; AS4/BP907 with a tough epoxy matrix; and AS4/PEEK with a tough thermoplastic matrix. Difficulties encountered in manufacturing panels, as well as conducting the tests are discussed. Critical issues that developed during the course of the testing are highlighted. Results of the round robin testing used to determine the precision of the ASTM DCB test standard are summarized.

Obrien, T. Kevin↗
NASA NTRS1993

Mechanical properties of composite materials

A composite material incorporates high strength, high modulus fibers in a matrix (polymer, metal, or ceramic). The fibers may be oriented in a manner to give varying in-plane properties (longitudinal, transverse-stress, strain, and modulus of elasticity). The lay-up of the composite laminates is such that a center line of symmetry and no bending moment exist through the thickness. The laminates are tabbed, with either aluminum or fiberglass, and are ready for tensile testing. The determination of the tensile properties of resin matrix composites, reinforced by continuous fibers, is outlined in ASTM standard D 3039, Tensile Properties of Oriented Fiber Composites. The tabbed flat tensile coupons are placed into the grips of a tensile machine and load-deformation curves plotted. The load-deformation data are translated into stress-strain curves for determination of mechanical properties (ultimate tensile strength and modulus of elasticity).

Thornton, H. Richard↗
NASA NTRS1992

Probabilistic structural analysis of space truss structures for nonuniform thermal environmental effects

A three-bay, space, cantilever truss is probabilistically evaluated to quantify the range of uncertainties of vibration frequencies and truss free end vertical displacements due to nonuniform thermal loads, applied loads and moments (mechanical loads), and combination of both. The truss members are assumed to be made from (1) aluminum tubes or (2) high modulus graphite-fiber/intermediate modulus epoxy-matrix composite tubes. Cumulative distribution function results show that certain combination of thermal loads with mechanical loads reduce the probabilistic vibration frequencies and increase the magnitude of the truss free end vertical displacements for the aluminum truss. However, for the composite truss, the thermal effects on the probabilistic vibration frequencies are not as substantial as that for an aluminum truss. This can be attributed to the large differences in the values of coefficient of thermal expansion. Finally, the sensitivities associated with the uncertainties in the structural, material and load variables (primative variables) are investigated. Results indicate that vibration frequencies and truss free end vertical displacements are sensitive to the uncertainties in spacial (geometry) variables as well as member modulus.

Pai, Shantaram S.↗
NASA NTRS1993

Analysis and sizing of Mars aerobrake structure

A cone-sphere aeroshell structure for aerobraking into Martian atmosphere is studied. Using this structural configuration, a space frame load-bearing structure is proposed. To generate this structure efficiently and to perform a variety of studies of several configurations, a mesh generator that utilizes only a few configurational parameters is developed. A finite element analysis program that analyzes space frame structures was developed. A sizing algorithm that arrives at a minimum mass configuration was developed and integrated into the finite element analysis program. A typical 135-ft-diam aerobrake configuration was analyzed and sized. The minimum mass obtained in this study using high modulus graphite/epoxy composite material members is compared with the masses obtained from two other aerobrake structures using lightweight erectable tetrahedral truss and part-spherical truss configurations. Excellent agreement for the minimum mass was obtained with the three different aerobrake structures. Also, the minimum mass using the present structure was obtained when the supports were not at the base but at about 75 percent of the base diameter.

Raju, I. S.↗
NASA NTRS1992

Intercalated graphite fiber composites as EMI shields in aerospace structures

The requirements for electromagnetic interference (EMI) shielding in aerospace structures are more complicated than those for ground structures because of their weight limitations. As a result, the best EMI shielding materials must combine low density, high strength, and high elastic modulus with high shielding ability. EMI shielding characteristics were calculated for shields formed from pristine and intercalated graphite fiber/epoxy composites and compare to preliminary experimental results for these materials and to the characteristics of shields made from aluminum. Calculations indicate that effective EMI shields could be fabricated from intercalated graphite composites which would have less than 12 percent of the mass of conventional aluminum shields, based on mechanical properties and shielding characteristics alone.

Gaier, James R.↗
NASA NTRS1992

Structural considerations in the design of a Mars mission aerobrake

A design for a Mars mission aerobrake with rib-stringer construction coupled with a generic shell using composite materials, which is shown to produce a feasible alternative to propulsive braking, is presented. For the case of a spherical shell subjected to a uniform pressure loading the membrane stress state is isotropic and independent of material properties. The stresses due to bending are significant and dominate only near the attachment points. The addition of meridional stiffeners increased the buckling load and absorbed a large portion of the stresses near the attachment points. The final design employed a high modulus graphite/epoxy composite material. The final weight of the structure when subjected to a 2.0 psi stagnation pressure loading was about 42,000 pounds. This constituted 9 percent of the total spacecraft weight, well below the 15 percent upper limit. It is concluded that aerobraking is a feasible alternative to a propulsive braking system. A rib-stringer shell composition coupled with composite materials is a viable configuration for an aerobrake structure.

Hairr, John↗
NASA NTRS1993

Analytical stress intensity solution for the Stable Poisson Loaded specimen

An analytical calibration of the Stable Poisson Loaded (SPL) specimen is presented. The specimen configuration is similar to the ASTM E-561 compact-tension specimen with displacement controlled wedge loading used for R-curve determination. The crack mouth opening displacements (CMODs) are produced by the diametral expansion of an axially compressed cylindrical pin located in the wake of a machined notch. Due to the unusual loading configuration, a three-dimensional finite element analysis was performed with gap elements simulating the contact between the pin and specimen. In this report, stress intensity factors, CMODs, and crack displacement profiles, are reported for different crack lengths and different contacting conditions. It was concluded that the computed stress intensity factor decreases sharply with increasing crack length thus making the SPL specimen configuration attractive for fracture testing of brittle, high modulus materials.

Ghosn, Louis J.↗
NASA NTRS1993

New textile composite materials development, production, application

New textile composite materials development, production, and application are discussed. Topics covered include: super-high-strength, super-high-modulus fibers, filaments, and materials manufactured on their basis; heat-resistant and nonflammable fibers, filaments, and textile fabrics; fibers and textile fabrics based on fluorocarbon poylmers; antifriction textile fabrics based on polyfen filaments; development of new types of textile combines and composite materials; and carbon filament-based fabrics.

Mikhailov, Petr Y.↗
NASA NTRS1993

Production and application of chemical fibers with special properties for manufacturing composite materials and goods of different usage

The development of modern technologies demands the creation of new nonmetallic, fibrous materials with specific properties. The fibers and materials developed by NII 'Chimvolokno', St. Petersburg, can be divided into two groups. The first group includes heat-resistant fibers, fire-resistant fibers, thermotropic fibers, fibers for medical application, and textile structures. The second group contains refractory fibers, chemoresistant and antifriction fibers, fibers on the basis of polyvinyl alcohol, microfiltering films, and paperlike and nonwoven materials. In cooperation with NPO 'Chimvolokno' MYTITSHI, we developed and started producing heat-resistant high-strength fibers on the base of polyhetarearilin and aromatic polyimides (SVM and terlon); heat-resistant fibers on the base of polyemede (aramid); fire-retardant fibers (togilen); chemoresistant and antifriction fibers on the basis of homo and copolymers of polytetrafluoroethylene (polyfen and ftorin); and water soluble, acetylated, and high-modulus fibers from polyvinyl alcohol (vylen). Separate reports will deal with textile structures and thermotropic fibers, as well as with medical fibers. One of the groups of refractory fibers carbon fibers (CF) and the corresponding paperlike nonwoven materials are discussed in detail. Also, composite materials (CM) and their base, which is the subject of the author's research since 1968, is discussed.

Levit, R.↗
NASA NTRS1994

Formation and chemical reactivity of carbon fibers prepared by defluorination of graphite fluoride

Defluorination of graphite fluoride (CFX) by heating to temperatures of 250 to 450 C in chemically reactive environments was studied. This is a new and possibly inexpensive process to produce new carbon-based materials. For example, CF 0.68 fibers, made from P-100 carbon fibers, can be defluorinated in BrH2C-CH = CH-CH2Br (1,4-dibromo-2butene) heated to 370 C, and graphitized to produce fibers with an unusually high modulus and a graphite layer structure that is healed and cross-linked. Conversely, a sulfur-doped, visibly soft carbon fiber was produced by defluorinating CF 0.9 fibers, made from P-25, in sulfur (S) vapor at 370 C and then heating to 660 C in nitrogen (N2). Furthermore, defluorination of the CF 0.68 fibers in bromine (Br2) produced fragile, structurally damaged carbon fibers. Heating these fragile fibers to 1100 C in N2 caused further structural damage, whereas heating to 150 C in bromoform (CHBr3) and then to 1100 C in N2 healed the structural defects. The defluorination product of CFX, tentatively called activated graphite, has the composition and molecular structure of graphite, but is chemically more reactive. Activated graphite is a scavenger of manganese (Mn), and can be intercalated with magnesium (Mg). Also, it can easily collect large amounts of an alloy made from copper (Cu) and type 304 stainless steel to form a composite. Finally, there are indications that activated graphite can wet metals or ceramics, thereby forming stronger composites with them than the pristine carbon fibers can form.

Hung, Ching-Cheh↗
NASA NTRS1994

Damage Mechanisms and Controlled Crack Propagation in a Hot Pressed Silicon Nitride Ceramic

The subcritical growth of cracks from pre-existing flaws in ceramics can severely affect the structural reliability of a material. The ability to directly observe subcritical crack growth and rigorously analyze its influence on fracture behavior is important for an accurate assessment of material performance. A Mode I fracture specimen and loading method has been developed which permits the observation of stable, subcritical crack extension in monolithic and toughened ceramics. The test specimen and procedure has demonstrated its ability to generate and stably propagate sharp, through-thickness cracks in brittle high modulus materials. Crack growth for an aluminum oxide ceramic was observed to be continuously stable throughout testing. Conversely, the fracture behavior of a silicon nitride ceramic exhibited crack growth as a series of subcritical extensions which are interrupted by dynamic propagation. Dynamic initiation and arrest fracture resistance measurements for the silicon nitride averaged 67 and 48 J/sq m, respectively. The dynamic initiation event was observed to be sudden and explosive. Increments of subcritical crack growth contributed to a 40 percent increase in fracture resistance before dynamic initiation. Subcritical crack growth visibly marked the fracture surface with an increase in surface roughness. Increments of subcritical crack growth loosen ceramic material near the fracture surface and the fracture debris is easily removed by a replication technique. Fracture debris is viewed as evidence that both crack bridging and subsurface microcracking may be some of the mechanisms contributing to the increase in fracture resistance. A Statistical Fracture Mechanics model specifically developed to address subcritical crack growth and fracture reliability is used together with a damaged zone of material at the crack tip to model experimental results. A Monte Carlo simulation of the actual experiments was used to establish a set of modeling input parameters. It was demonstrated that a single critical parameter does not characterize the conditions required for dynamic initiation. Experimental measurements for critical crack lengths, and the energy release rates exhibit significant scatter. The resulting output of the model produces good agreement with both the average values and scatter of experimental measurements.

Calomino, Anthony Martin↗