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At least 199 records · Page 11

Fungal hyphae develop where titanomagnetite inclusions reach the surface of basalt grains

Nutrient foraging by fungi weathers rocks by mechanical and biochemical processes. Distinguishing fungal-driven transformation from abiotic mechanisms in soil remains a challenge due to complexities within natural field environments. We examined the role of fungal hyphae in the incipient weathering of granulated basalt from a three-year field experiment in a mixed hardwood-pine forest (S. Carolina) to identify alteration at the nanometer to micron scales based on microscopy-tomography analyses. Investigations of fungal-grain contacts revealed (i) a hypha-biofilm-basaltic glass interface coinciding with titanomagnetite inclusions exposed on the grain surface and embedded in the glass matrix and (ii) native dendritic and subhedral titanomagnetite inclusions in the upper 1–2 µm of the grain surface that spanned the length of the fungal-grain interface. We provide evidence of submicron basaltic glass dissolution occurring at a fungal-grain contact in a soil field setting. An example of how fungal-mediated weathering can be distinguished from abiotic mechanisms in the field was demonstrated by observing hyphal selective occupation and hydrolysis of glass-titanomagnetite surfaces. We hypothesize that the fungi were drawn to basaltic glass-titanomagnetite boundaries given that titanomagnetite exposed on or very near grain surfaces represents a source of iron to microbes. Furthermore, glass is energetically favorable to weathering in the presence of titanomagnetite. Our observations demonstrate that fungi interact with and transform basaltic substrates over a three-year time scale in field environments, which is central to understanding the rates and pathways of biogeochemical reactions related to nuclear waste disposal, geologic carbon storage, nutrient cycling, cultural artifact preservation, and soil-formation processes.

58 GEOSCIENCES↗

Influence of manganese abundances on iron and arsenic solubility in rice paddy soils

Arsenic (As) mobilization in rice paddy soils under fluctuating redox conditions is influenced by the biogeochemical cycling of redox sensitive elements such as iron (Fe) and manganese (Mn). Arsenic mobility in paddy soils is highly variable, and the influence of Mn abundances and Mn/Fe ratios on As mobility in these soils have received little attention. In this contribution, we developed a complementary set of field and laboratory experiments designed to evaluate the impact of Mn on interconnected Fe and As solubilization in rice paddy soils experiencing wetting-drying cycles through controlled irrigation. Porewater monitoring and synchrotron-based imaging and spectroscopy of thin sections prepared from an Arkansas paddy soil confirmed that As release was primarily governed by reductive dissolution of Fe (oxy)hydroxide phases. Experiments with laboratory soil microcosms amended with the synthetic nanocrystalline Mn oxide, δ-MnO 2 , showed that higher initial Mn/Fe inhibited Fe and As mobilization into porewater relative to unamended soil by up to 95% and 45%, respectively. Geochemical modeling suggests that pH increases driven by microbial MnO 2 reduction, in conjunction with microbial Fe- and sulfate-reduction in carbonate-rich porewater, enhanced the precipitation of siderite (FeCO 3(s) ), mackinawite (FeS (s) ), and potentially a Mn(II) arsenate phase. These secondary mineral phases likely played a greater role in controlling As solubilization than the role of Mn as a redox buffer regulating the redox conditions in the flooded soils. Field and laboratory experiments showed that alternate wetting and drying approaches with a single dry-down can be effective at reducing dissolved As concentrations in porewater through the oxidation of Fe. Differences in soil Mn/Fe ratios had no clear impact on the effectiveness of dry-downs as a strategy to reduce As mobilization.

54 ENVIRONMENTAL SCIENCES↗

Soil carbon stocks from soil organic carbon at the Teller 47, Teller 27, and Kougarok 86 field sites, Seward Peninsula, Alaska, 2021 – 2023

Carbon stored in permafrost soils represents the largest terrestrial storage and hence has key significance for the global carbon cycle, yet the site-specific estimates of permafrost soil carbon are limited. To better understand permafrost carbon storage, soil organic content (SOC) was measured from soils collected at the Teller 27, Teller 47, and Kougarok 86 field sites on the Seward Peninsula, Alaska in the summers of 2019 and 2021-2023. Soil samples were collected from locations with and without near-surface permafrost to varied depths within the permafrost, where present. In addition to sample collection for soil organic carbon analysis, bulk density samples were also collected within each soil profile to allow for calculation of carbon stocks. Carbon to nitrogen ratios are also reported. Location data were collected at each observation point using a handheld GPS unit with waypoint averaging to reduce location measurement error to within 3 m. SOC was measured using elemental analysis in the laboratory. This dataset contains a *.csv file of soil carbon stocks, a *.kml file of measurement locations, a *.pdf user guide, a *.csv data dictionary, and a *.csv file level metadata.

EARTH SCIENCE > CRYOSPHERE > FROZEN GROUND↗

Investigations of Thematic Mapper data dimensionality and features using field spectrometer data

Landsat-4 TM and MSS data, simulated from field reflectance spectra, are used to determine the dimensionality and structure of TM data (excluding the thermal band), demonstrate the relationships between the two sensors, and derive a Tasseled Cap Transformation for TM data. The simulated TM data are found to primarily occupy three dimensions, and to be concentrated into two adjoining and orthogonal planes and a transition zone between the two. The 'Plane of Vegetation' is shown to be comparable to the MSS Tasseled Cap plane, while the 'Plane of Soils' represents new information. The potential for improved spectral estimation of the relative mix of vegegation and soil in the field of view, and for improved monitoring of soil moisture status, is demonstrated.

Crist, E. P.↗

Using Artificial Soiling to Rank Anti-Soiling Coatings for Arid Climates

A simple method to evaluate (e.g., screen and rank) the performance of coatings that are fully or partially anti-soiling (AS) is lacking within the PV industry. Artificial soiling may be used as a rapid and economical assessment approach, offering an efficient alternative to time-intensive, site-specific field testing. In this study, we present an artificial soiling method to replicate the anti-soiling performance rankings of two groups of coated glass samples supplied by two manufacturers (group C with CA, CP, and CS coatings; group A with AC coating). These are compared to field aging in two climates: semi-arid Lemoore, California over 4 months, and the hot desert in Mesa, Arizona over 7 months. Both field and indoor performance ranking utilize the transmittance ratio, defined as the optical transmittance between a coated sample and an uncoated reference in each group, as an evaluation metric to assess the effectiveness of the artificial soiling approach in replicating field soiling. It is critical to mimic the dominant field meteorological conditions associated with soiling-prone days and vulnerable times of day during the soiling season. Our results reveal that the use of artificial soiling for field performance ranking among coatings strongly depends on the soil type (composition and particle distribution), dust surface density, and prevalent environmental factors (wetting saturation by humidity, dew condensation extent, and prior weathering history of the coating). The similar rank order relative to the field suggests that the artificial soiling approach presented may be used for down-selecting anti-soiling coatings prior to prolonged field validation.

14 SOLAR ENERGY↗

Remote sensing research for agricultural applications

Materials and methods used to characterize selected soil properties and agricultural crops in San Joaquin County, California are described. Results show that: (1) the location and widths of TM bands are suitable for detecting differences in selected soil properties; (2) the number of TM spectral bands allows the quantification of soil spectral curve form and magnitude; and (3) the spatial and geometric quality of TM data allows for the discrimination and quantification of within field variability of soil properties. The design of the LANDSAT based multiple crop acreage estimation experiment for the Idaho Department of Water Resources is described including the use of U.C. Berkeley's Survey Modeling Planning Model. Progress made on Peditor software development on MIDAS, and cooperative computing using local and remote systems is reported as well as development of MIDAS microcomputer systems.

Colwell, R. N.↗

A multi-criteria land suitability assessment of field allocation decisions for switchgrass

With the goal of evaluating biomass resource availability in certain regions in the United States, the Department of Energy, Department of Agriculture, Environmental Protection Agency, national laboratories, and Forest Service research laboratories, together with academic and industry collaborators, performed a resource analysis study, 2016 Billion-Ton Report: Advancing Domestic Resources for a Thriving Bioeconomy, Volume 1: Economic Availability of Feedstocks, using POLYSYS model to estimate biomass potential. The study provided county- and state-level biomass potential projections, with biomass feedstock production estimates and suitability assessment of lands acreage likely to transition to energy crops. For this analysis, we estimate biomass supply by year 2028, more specifically, lands acreage transition to switchgrass in the Midwest of the United States, across 50 counties in 3 states (Nebraska, Kansas, and Colorado). We propose a multi-criteria site suitability framework, to determine the potential acreage and production for switchgrass, at the field level. Site selection criteria span agronomic and ecosystem services such as previous land cover, crop rotation, soil water holding capacity, crop productivity, field efficiency, topography, soil organic matter, soil leaching propensity, distance to surface water bodies, and soil erosivity. Efficient agricultural field selection for dedicated energy crops field allocation is critical to evaluate biomass resource availability, and it is our position that estimation at the field level would provide a more accurate and useful estimation to support an emerging bioeconomy. Using field suitability scores and county-level assessments, we model land allocation decision for energy crop in the future, estimating the spatial distribution of dynamics of energy crop adoption with priority to fields scoring the highest. Additionally, compared with POLYSYS results from the report mentioned above, our method shows good performance overall, with about 2% and 1.2% of difference in switchgrass acreage allocation and crop production, respectively.

54 ENVIRONMENTAL SCIENCES↗

Comparing field and lab quantitative stable isotope probing for nitrogen assimilation in soil microbes

ABSTRACT Soil microbial communities play crucial roles in nutrient cycling and can help retain nitrogen in agricultural soils. Quantitative stable isotope probing (qSIP) is a useful method for investigating taxon-specific microbial growth and utilization of specific nutrients, such as nitrogen (N). Typically, qSIP is performed in a highly controlled lab setting, so the field relevance of lab qSIP studies remains unknown. We conducted and compared tandem lab and field qSIP to quantify the assimilation of 15 N by maize-associated soil prokaryotic communities at two agricultural sites. Here, we show that field qSIP with 15 N can be used to measure taxon-specific microbial N assimilation. Relative 15 N assimilation rates were generally lower in the field, and the magnitude of this difference varied by site. Rates differed by method (lab vs field) for 19% of the top N assimilating genera. The field and lab measures were more comparable when relative assimilation rates were weighted by relative abundance to estimate the proportion of N assimilated by each genus with only ~10% of taxa differing by method. Of those that differed, the taxa consistently higher in the lab were inclined to have opportunistic lifestyle strategies, whereas those higher in the field had niches reliant on plant roots or in-tact soil structure (biofilms, mycelia). This study demonstrates that 15 N-qSIP can be successfully performed using field-incubated soils to identify microbial allies in N retention and highlights the strengths and limitations of field and lab qSIP approaches. IMPORTANCE Soil microbes are responsible for critical biogeochemical processes in natural and agricultural ecosystems. Despite their importance, the functional traits of most soil organisms remain woefully under-characterized, limiting our ability to understand how microbial populations influence the transformation of elements such as nitrogen (N) in soil. Quantitative stable isotope probing (qSIP) is a powerful tool to measure the traits of individual taxa. This method has rarely been applied in the field or with 15 N to measure nitrogen assimilation. In this study, we measured genus-specific microbial nitrogen assimilation in two agricultural soils and compared field and lab 15 N qSIP methods. Our results identify taxa important for nitrogen assimilation in agricultural soils, shed light on the field relevance of lab qSIP studies, and provide guidance for the future application of qSIP to measure microbial traits in the field.

Reed, Kinsey (ORCID:0000000155178664)↗

CONSERVB: A numerical method to compute soil water content and temperature profiles under a bare surface

A comprehensive, yet fairly simple model of water disposition in a bare soil profile under the sequential impact of rain storms and other atmospheric influences, as they occur from hour to hour is presented. This model is intended mostly to support field studies of soil moisture dynamics by our current team, to serve as a background for the microwave measurements, and, eventually, to serve as a point of departure for soil moisture predictions for estimates based in part upon airborne measurements. The main distinction of the current model is that it accounts not only for the moisture flow in the soil-atmosphere system, but also for the energy flow and, hence, calculates system temperatures. Also, the model is of a dynamic nature, capable of supporting any required degree of resolution in time and space. Much critical testing of the sample is needed before the complexities of the hydrology of a vegetated surface can be related meaningfully to microwave observations.

Vanbavel, C. H. M.↗

Influence of Soil Heterogeneity on Mesoscale Land Surface Fluxes During Washita '92

The influence of soil heterogeneity on the partitioning of mesoscale land surface energy fluxes at diurnal time scales is investigated over a 10(exp 6) sq km domain centered on the Little Washita Basin, Oklahoma, for the period June 10 - 18, 1992. The sensitivity study is carried out using MM5/PLACE, the Penn State/NCAR MM5 model enhanced with the Parameterization for Land-Atmosphere-Cloud Exchange or PLACE. PLACE is a one-dimensional land surface model possessing detailed plant and soil water physics algorithms, multiple soil layers, and the capacity to model subgrid heterogeneity. A series of 12-hour simulations were conducted with identical atmospheric initialization and land surface characterization but with different initial soil moisture and texture. A comparison then was made of the simulated land surface energy flux fields, the partitioning of net radiation into latent and sensible heat, and the soil moisture fields. Results indicate that heterogeneity in both soil moisture and texture affects the spatial distribution and partitioning of mesoscale energy balance. Spatial averaging results in an overprediction of latent heat flux, and an underestimation of sensible heat flux. In addition to the primary focus on the partitioning of the land surface energy, the modeling effort provided an opportunity to examine the issue of initializing the soil moisture fields for coupled three-dimensional models. For the present case, the initial soil moisture and temperature were determined from off-line modeling using PLACE at each grid box, driven with a combination of observed and assimilated data fields.

Jasinski, Michael F.↗

Evaluation of the effects of varying moisture contents on microwave thermal emissions from agriculture fields

Three tasks related to soil moisture sensing at microwave wavelengths were undertaken: (1) analysis of data at L, X and K sub 21 band wavelengths over bare and vegetated fields from the 1975 NASA sponsored flight experiment over Phoenix, Arizona; (2) modeling of vegetation canopy at microwave wavelengths taking into consideration both absorption and volume scattering effects; and (3) investigation of overall atmospheric effects at microwave wavelengths that can affect soil moisture retrieval. Data for both bare and vegetated fields are found to agree well with theoretical estimates. It is observed that the retrieval of surface and near surface soil moisture information is feasible through multi-spectral and multi-temporal analysis. It is also established that at long wavelengths, which are optimal for surface sensing, atmospheric effects are generally minimal. At shorter wavelengths, which are optimal for atmosheric retrieval, the background surface properties are also established.

Burke, H. H. K.↗

Using IKONOS Imagery to Estimate Surface Soil Property Variability in Two Alabama Physiographies

Knowledge of surface soil properties is used to assess past erosion and predict erodibility, determine nutrient requirements, and assess surface texture for soil survey applications. This study was designed to evaluate high resolution IKONOS multispectral data as a soil- mapping tool. Imagery was acquired over conventionally tilled fields in the Coastal Plain and Tennessee Valley physiographic regions of Alabama. Acquisitions were designed to assess the impact of surface crusting, roughness and tillage on our ability to depict soil property variability. Soils consisted mostly of fine-loamy, kaolinitic, thermic Plinthic Kandiudults at the Coastal Plain site and fine, kaolinitic, thermic Rhodic Paleudults at the Tennessee Valley site. Soils were sampled in 0.20 ha grids to a depth of 15 cm and analyzed for % sand (0.05 - 2 mm), silt (0.002 -0.05 mm), clay (less than 0.002 mm), citrate dithionite extractable iron (Fe(sub d)) and soil organic carbon (SOC). Four methods of evaluating variability in soil attributes were evaluated: 1) kriging of soil attributes, 2) co-kriging with soil attributes and reflectance data, 3) multivariate regression based on the relationship between reflectance and soil properties, and 4) fuzzy c-means clustering of reflectance data. Results indicate that co-kriging with remotely sensed data improved field scale estimates of surface SOC and clay content compared to kriging and regression methods. Fuzzy c-means worked best using RS data acquired over freshly tilled fields, reducing soil property variability within soil zones compared to field scale soil property variability.

Sullivan, Dana↗

Effects of Water Table Fluctuation on Greenhouse Gas Emissions from Wetland Soils in the Peruvian Amazon

Amazonian swamp forests remove large amounts of carbon dioxide (CO 2 ) but produce methane (CH 4 ). Both are important greenhouse gases (GHG). Drought and cultivation cut the CH 4 emissions but may release CO 2 . Varying oxygen content in nitrogen-rich soil produces nitrous oxide (N 2 O), which is the third most important GHG. Despite the potentially tremendous changes, GHG emissions from wetland soils under different land uses and environmental conditions have rarely been compared in the Amazon. We measured environmental characteristics, and CO 2 , CH 4 and N 2 O emissions from the soil surface with manual opaque chambers in three sites near Iquitos, Peru from September 2019 to March 2020: a pristine peat swamp forest, a young forest and a slash-and-burn manioc field. The manioc field showed moderate soil respiration and N 2 O emission. The peat swamp forests under slight water table drawdown emitted large amounts of CO 2 and CH 4 . A heavy post-drought shower created a hot moment of N 2 O in the pristine swamp forest, likely produced by nitrifiers. All in all, even small changes in soil moisture can create hot moments of GHG emissions from Amazonian wetland soils, and should therefore be carefully monitored.

54 ENVIRONMENTAL SCIENCES↗

Reconstructed Historical Land Cover and Biophysical Parameters for Studies of Land-Atmosphere Interactions within the Eastern United States

The local environment where we live within the Earth's biosphere is often taken for granted. This environment can vary depending on whether the land cover is a forest, grassland, wetland, water body, bare soil, pastureland, agricultural field, village, residential suburb, or an urban complex with concrete, asphalt, and large buildings. In general, the type and characteristics of land cover influence surface temperatures, sunlight exposure and duration, relative humidity, wind speed and direction, soil moisture amount, plant life, birds, and other wildlife in our backyards. The physical and biological properties (biophysical characteristics) of land cover help to determine our surface environment because they directly affect surface radiation, heat, and soil moisture processes, and also feedback to regional weather and climate. Depending on the spatial scale and land use intensity, land cover changes can have profound impacts on our local and regional environment. Over the past 350 years, the eastern half of the United States, an area extending from the grassland prairies of the Great Plains to the Gulf and Atlantic coasts, has experienced extensive land cover and land use changes that began with land clearing in the 1600s, led to extensive deforestation and intensive land use practices by 1920, and then evolved to the present-day landscape. Determining the consequences of such land cover changes on regional and global climate is a major research issue. Such research requires detailed historical land cover data and modeling experiments simulating historical climates. Given the need to understand the effects of historical land cover changes in the eastern United States, some questions include: - What were the most important land cover transformations and how did they alter biophysical characteristics of the land cover at key points in time since the mid-1600s? - How have land cover and land use changes over the past 350 years affected the land surface environment including surface weather, hydrologic, and climatic variability? - How do the potential effects of regional human-induced land cover change on the environment compare to similar changes that are caused by the natural variations of the Earth's climate system? To help answer these questions, we reconstructed a fractional land cover and biophysical parameter dataset for the eastern United States at 1650, 1850, 1920, and 1992 time-slices. Each land cover fraction is associated with a biophysical parameter class, a suite of parameters defining the biophysical characteristics of that kind of land cover. This new dataset is designed for use in computer models of land-atmosphere interactions, to understand and quantify the effects of historical land cover changes on the water, energy, and carbon cycles

Steyaert, Louis T.↗

Soil Moisture Initialization Error and Subgrid Variability of Precipitation in Seasonal Streamflow Forecasting

Offline simulations over the conterminous United States (CONUS) with a land surface model are used to address two issues relevant to the forecasting of large-scale seasonal streamflow: (i) the extent to which errors in soil moisture initialization degrade streamflow forecasts, and (ii) the extent to which a realistic increase in the spatial resolution of forecasted precipitation would improve streamflow forecasts. The addition of error to a soil moisture initialization field is found to lead to a nearly proportional reduction in streamflow forecast skill. The linearity of the response allows the determination of a lower bound for the increase in streamflow forecast skill achievable through improved soil moisture estimation, e.g., through satellite-based soil moisture measurements. An increase in the resolution of precipitation is found to have an impact on large-scale streamflow forecasts only when evaporation variance is significant relative to the precipitation variance. This condition is met only in the western half of the CONUS domain. Taken together, the two studies demonstrate the utility of a continental-scale land surface modeling system as a tool for addressing the science of hydrological prediction.

Streamflow Prediction↗

Design Advancement of an Indoor Soil Deposition Chamber: A Road to Standardization

An indoor soil deposition chamber has been designed and constructed at the Arizona State University Photovoltaic Reliability Lab (ASU-PRL) to simulate photovoltaic (PV) module soiling in the field. This paper discusses the next set of revisions to the design, which are organized into three categories: design improvements, cost reduction, and new features. The design process was carried out with the intention of working toward the development of a national or international soiling standard. The improvements made to the chamber are described in detail to provide a guide for other laboratories or research facilities who wish to study photovoltaic (PV) soiling.

14 SOLAR ENERGY↗

Preliminary Evaluation of TM for Soils Information

The capability of the LANDSAT TM for providing information for soil association maps and for detecting soil properties (variability within vegetated fields) was assessed using TM imagery of fields in Mississippi County, Arkansas that were planted with rice, cotton, and soybeans. Results indicate that the TM bands are providing information that is related to the soil properties within the field. Over large areas, these bands also appear to provide information that is related to the soil properties that are important to plant condition. While these results are only an indication of the information that TM can provide, they do indicate the TM data--especially, the mid-TR and thermal bands--show the capability for separating vegetated soil landscapes on a broad basis. The analysis at the field level with a growing crop also indicates that TM, with its additional and narrower bands and improved spatial and radiometric resolution is influenced by within field variability due to soils that has to be accounted for in the analysis of TM data.

Thompson, D. R.↗