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NASA NTRS1997

Comparison of Several Numerical Methods for Simulation of Compressible Shear Layers

An investigation is conducted on several numerical schemes for use in the computation of two-dimensional, spatially evolving, laminar variable-density compressible shear layers. Schemes with various temporal accuracies and arbitrary spatial accuracy for both inviscid and viscous terms are presented and analyzed. All integration schemes use explicit or compact finite-difference derivative operators. Three classes of schemes are considered: an extension of MacCormack's original second-order temporally accurate method, a new third-order variant of the schemes proposed by Rusanov and by Kutier, Lomax, and Warming (RKLW), and third- and fourth-order Runge-Kutta schemes. In each scheme, stability and formal accuracy are considered for the interior operators on the convection-diffusion equation U(sub t) + aU(sub x) = alpha U(sub xx). Accuracy is also verified on the nonlinear problem, U(sub t) + F(sub x) = 0. Numerical treatments of various orders of accuracy are chosen and evaluated for asymptotic stability. Formally accurate boundary conditions are derived for several sixth- and eighth-order central-difference schemes. Damping of high wave-number data is accomplished with explicit filters of arbitrary order. Several schemes are used to compute variable-density compressible shear layers, where regions of large gradients exist.

Kennedy, Christopher A.↗

NASA NTRS2016

Wind Tunnel Model Design for Sonic Boom Studies of Nozzle Jet Flows with Shock Interactions

NASA and the U.S. aerospace industry are performing studies of supersonic aircraft concepts with low sonic boom pressure signatures. The computational analyses of modern aircraft designs have matured to the point where there is confidence in the prediction of the pressure signature from the front of the vehicle, but uncertainty remains in the aft signatures due to boundary layer and nozzle exhaust jet effects. Wind tunnel testing without inlet and nozzle exhaust jet effects at lower Reynolds numbers than in-flight make it difficult to accurately assess the computational solutions of flight vehicles. A wind tunnel test in the NASA Ames 9- by 7-Foot Supersonic Wind Tunnel is planned for February 2016 to address the nozzle jet effects on sonic boom. The experiment will provide pressure signatures of test articles that replicate waveforms from aircraft wings, tails, and aft fuselage (deck) components after passing through cold nozzle jet plumes. The data will provide a variety of nozzle plume and shock interactions for comparison with computational results. A large number of high-fidelity numerical simulations of a variety of shock generators were evaluated to define a reduced collection of suitable test models. The computational results of the candidate wind tunnel test models as they evolved are summarized, and pre-test computations of the final designs are provided.

Wind Tunnel↗

NASA NTRS2000

Estimating the Ocean Flow Field From Combined Sea Surface Temperature and Sea Surface Height Data

The primary focus of this project was on the estimation of the three-dimensional, absolute and time-evolving general circulation of the global ocean from a combined analysis of remotely sensed fields of sea surface temperature (SST) and sea surface height (SSH). The synthesis of those two fields was performed with other relevant physical data, and appropriate dynamical ocean models with emphasis on constraining ocean general circulation models by a combination of both SST and SSH data. This effort is directly related to an attempt to describe the mechanisms which give rise to observed SST and its variability on seasonal and inter-annual timescales, its relation to ocean-atmosphere interaction, and the dynamical coupling between the ocean mixed layer and the deep interior ocean. This is one of the fundamental climate related questions being pursued currently under the CLIVAR Program. Because of the strong turbulent mixing associated with atmospheric fluxes of momentum, heat and freshwater through the sea surface, the ocean forms a shallow surface boundary layer, the mixed layer which is largely homogeneous in its constituents. The relation between the temperature of the remotely sensed "skin" and the bulk of the mixed layer is largely understood (Reynolds and Smith 1994; Emery et al., 1995). However, because the surface mixed layer is effectively decoupled from the underlying ocean dynamics, an interpretation of satellite SST observations in isolation and in direct use for dynamical studies is very difficult. As a result, the impact of SST data on the understanding of ocean variability.

Stammer, Detlef↗

NASA NTRS2011

Current Sheets in the Heliosheath: Voyager 1, 2009

We identified all of the current sheets for which we have relatively complete and accurate magnetic field (B) data from Voyager 1 (V1) from days of year (DOYs) 1 to 331, 2009, which were obtained deep in the heliosheath between 108.5 and 111.8 AU. Three types of current sheets were found: (1) 15 proton boundary layers (PBLs), (2) 10 and 3 magnetic holes and magnetic humps, respectively, and (3) 3 sector boundaries. The magnetic field strength changes across PBL, and the profile B(t) is linearly related to the hyperbolic tangent function, but the direction of B does not change. For each of the three sector boundaries, B rotated in a plane normal to the minimum variance direction, and the component of B along the minimum variance direction was zero within the uncertainties, indicating that the sector boundaries were tangential discontinuities. The structure of the sector boundaries was not as simple as that for PBLs. The average thickness of magnetic holes and humps (approx.30 RL) was twice that of the PBLs (approx.15 RL). The average thickness of the current sheets associated with sector boundaries was close to the thickness of the PBLs. Our observations are consistent with the hypothesis that magnetic holes and humps are solitons, which are initiated by the mirror mode instability, and evolve by nonlinear kinetic plasma processes to pressure balanced structures maintained by magnetization currents and proton drift currents in the gradients of B.

Burlaga, L. F.↗

NASA NTRS2005

Mars Geological Province Designations for the Interpretation of GRS Data

Introduction: An overarching geologic theory, GEOMARS, coherently explains many otherwise anomalous aspects of the geological history of Mars. Premises for a theory of martian geologic evolution include: (1) Mars is a water-rich terrestrial planet, (2) terrestrial planets should evolve through progressive stages of dynamical history (accretion, differentiation, tectonism) and mantle convection (magma ocean, plate tectonism, stagnant lid), and (3) the early history of Earth affords an analogue to the evolution of Mars. The theory describes the following major stages of evolution for Mars (from oldest to youngest): Stage 1 - shortly after accretion, Mars differentiates to a liquid metallic core, a mantle boundary (MBL) of high-pressure silicate mineral phases, upper mantle, magma ocean, thin komatiic crust, and convecting steam atmosphere; Stage 2- Mars cools to condense its steam atmosphere and transform its mode of mantle convection to plate tectonism; subduction of waterrich oceanic crust initiates arc volcanism and transfers water, carbonates and sulfates to the mantle; Stage 3 - the core dynamo initiates, and the associated magnetosphere leads to conditions conducive to the development of near-surface life and photosynthetic production of oxygen; Stage 4 - accretion of thickened, continental crust and subduction of hydrated oceanic crust to the mantle boundary layer and lower mantle of Mars occurs; Stage 5 - the core dynamo stops during Noachian heavy bombardment while plate tectonism continues; Stage 6 - initiation of the Tharsis superplume (approx. between 4.0 and 3.8Ga) occurs, and Stage 7 - the superlume phase (stagnant-lid regime) of martian planetary evolution with episodic phases of volcanism and water outflows continues into the present. The GEOMARS Theory is testable through a multidisciplinary approach, including utilizing GRS-based information. Based on a synthesis of published geologic, paleohydrologic, topographic, geophysical, spectral, and elemental information, we have defined geologic provinces that represent significant windows into the geological evolution of Mars, unfolding the GEOMARS Theory and forming the basis for interpreting GRS data.

Dohm, J. M.↗

DOE OSTI2026

The Role of Subcloud Mesoscale Convergence in Sculpting Convective Updraft Width and Depth

The initiation of deep moist convection is governed in part by the horizontal width of updrafts near cloud base, which limits the deleterious effects of entrainment-driven dilution on buoyant thermals ascending through the free troposphere. However, the factors controlling cloud-base updraft width, which in turn dictates cloud depth, are not well understood. We track the evolving three-dimensional structure of the mesoscale subcloud forcing for vertical motion and near-cloud thermodynamic ingredients within a high-resolution ensemble of simulations of seven realistic daytime orographic convection initiation events to determine their relative roles in controlling cloud width and depth. Statistical analysis of approximately 5000 cloudy updraft samples indicates that the most important contributors to the width of cloudy updrafts across the ensemble are the depth and magnitude of the subcloud mesoscale ascent. However, the depth achieved by clouds is more consistently predicted by the near-cloud ambient relative humidity within the lower to middle free troposphere and convective available potential energy. Therefore, although the width of cloudy updrafts may be partly set at low levels by the mesoscale vertical mass and moisture flux, the likelihood of deep moist convection is governed by the generation of positive buoyancy within cumulus thermals and entrainment-driven dilution that reduces it. The persistence of the low-level mesoscale vertical forcing locally consolidates and vertically transports boundary layer moisture, helping to reduce updraft dilution. However, these factors vary in relative impacts on cloudy updrafts across individual cases, indicating multiple pathways for deep convection initiation.

Convective storms↗

NASA NTRS2012

Global Estimates of PBL Depth from Space-Borne LIDAR

The planetary boundary layer (PBL) is responsible for communicating the exchange of energy, moisture, momentum, pollutants, and aerosols between the surface and the free atmosphere and is therefore crucial to many studies of the atmosphere. Unfortunately, there have historically been few observations of this important layer due to the complexity involved in its measurement. However, with the advent of more advanced satellites, global measurements of the PBL are now becoming possible. The PBL is often characterized by a high concentration of aerosols within the layer and low level clouds capping it and these are observable from space. The Cloud-Aerosol Lidar and Infrared Pathfinder Satellite Observations (CALIPSO) satellite was launched in 2006 with the intention of observing aerosols and clouds and was the first space-based LIDAR optimized for this purpose. CALIPSO observations are therefore well suited to observing the depth of the PBL. Since it was launched, CALIPSO has been making nearly continuous measurements enabling a global picture of PBL depth. We plan to present a global PBL depth product and how it evolves throughout the year. The product is able to identify deeper PBL depths in the summer hemisphere over land and deeper depths along the northern hemisphere oceanic storm tracks in winter associated with cold air traveling over warm water. Large seasonal cycles are also evident in the subtropical desert locations among other features. In addition, comparisons will be made between several estimates of PBL depth based on turbulent intensity, meteorology profiles, and aerosol profiles from the GEOS5 model.

McGrath-Spangler, Erica lynn↗

NASA NTRS1981

Numerical Prediction Methods (Reynolds-Averaged Navier-Stokes Simulations of Transonic Separated Flows)

During the past five years, numerous pioneering archival publications have appeared that have presented computer solutions of the mass-weighted, time-averaged Navier-Stokes equations for transonic problems pertinent to the aircraft industry. These solutions have been pathfinders of developments that could evolve into a major new technological capability, namely the computational Navier-Stokes technology, for the aircraft industry. So far these simulations have demonstrated that computational techniques, and computer capabilities have advanced to the point where it is possible to solve forms of the Navier-Stokes equations for transonic research problems. At present there are two major shortcomings of the technology: limited computer speed and memory, and difficulties in turbulence modelling and in computation of complex three-dimensional geometries. These limitations and difficulties are the pacing items of the continuing developments, although the one item that will most likely turn out to be the most crucial to the progress of this technology is turbulence modelling. The objective of this presentation is to discuss the state of the art of this technology and suggest possible future areas of research. We now discuss some of the flow conditions for which the Navier-Stokes equations appear to be required. On an airfoil there are four different types of interaction of a shock wave with a boundary layer: (1) shock-boundary-layer interaction with no separation, (2) shock-induced turbulent separation with immediate reattachment (we refer to this as a shock-induced separation bubble), (3) shock-induced turbulent separation without reattachment, and (4) shock-induced separation bubble with trailing edge separation.

Mehta, Unmeel↗

DOE OSTI2026

Stability and Characteristics of Lower-hybrid Drift Waves: Dependence on Electron Beta and Cross-field Relative Drift

Lower-hybrid drift waves (LHDWs) are frequently observed microinstabilities in both space and laboratory plasmas. Despite decades of study, the relationship between electrostatic (ES-LHDW) and electromagnetic (EM-LHDW) variants and the plasma parameters controlling their stability remains unclear. Here, we systematically examine LHDW behavior by solving the local linear dispersion relation over a wide range of plasma and field conditions. Our results demonstrate that ES-LHDWs and EM-LHDWs are not distinct modes but rather two different regimes of the same drift wave whose character evolves smoothly with electron beta (β e ) and the cross-field electron drift velocity relative to ions, normalized to the ion sound speed (u 0x /C s ). The nature of the waves changes from electrostatic to electromagnetic when β e increases. Growth rates increase with u 0x /C s but decrease with β e , while the most unstable wavelength remains nearly universal, with kρ e ∼ 0.8 (k is the magnitude of the wave vector and ρ e is the electron gyroradius). We further present quasi-linear estimates of nonlinear saturation properties, including energy partition among electric fields, magnetic fields, and particle kinetic responses. We show that ES-LHDWs reach higher electric-field saturation amplitudes, whereas EM-LHDWs generate strong magnetic perturbations and parallel electric fields that may enable efficient particle heating. Comparisons with the classical model reveal that retaining electromagnetic effects is essential for accurate predictions of frequency, growth rate, and the propagation angle. These findings provide a unified framework for understanding LHDWs across diverse collisionless plasma environments, including current sheets of magnetic reconnection, shear layers, collisionless shocks, and boundary regions.

Solar coronal waves↗

NASA NTRS1993

Atmospheric moisture fields derived by satellite observations over the tropical Pacific Ocean

Values of precipitable water are retrieved over the tropical and subtropical Pacific Ocean from TOVS infrared and microwave channel brightness temperature and OLR observations by means of stepwise linear regression. The most useful temperature and moisture sensing channels are pre-selected from sensitivity tests of a radiative transfer model. Numerous models are developed and tested against collocated radiosonde observations and Nimbus-7 SMMR precipitable water estimates. For RAOB comparisons, the best estimator used 15 TOVS predictors and captured 71.1 deg percent of the variance (+0.62 g/sq cm standard error) for column precipitable water; for precipitable water of 700-500 mb bulk layer, these values were 71.7 percent and +/- 0.17 g/sq cm. Little skill of estimated precipitable water was obtained for moisture above 500 mb. Regressions were less skillful against SMMR, unless collocation parameters were tightly controlled; SMMR was less acceptable than RAOB's because of observational drift and errors. Generally, the most skillful predictors were boundary layer brightness temperatures of TOVS channels and satellite estimated stability indices. 'Moisture channels' were hardly useful except for estimating middle and upper tropospheric moisture. Additional regression models were constructed testing the sensitivity to different observational and meteorological characteristics. Models which used some in situ observations surface observations or stabilities calculated from RAOB, were the most successful. The best of these explained 87.5 percent of the variance but the regression selected almost no TOVS channels, relying instead on conventional RAOB and surface observations. A set of four regression models were developed, stratifying atmospheric characteristics on the basis of collocated OLR values. These models improved the variance explained by 5.0 percent; the model associated with the highest OLR values (275 W/sq m less than or equal to OLR; that is, no cloud) showed only marginal skill. Precipitable water fields were generated from the best TOVS-only model for seven days in January 1983 and compared with SMMR-estimated fields. OLR fields and ECMWF precipitable water analysis. The TOVS regression model compared favorably to the SMMR analysis in amplitudes and features. It revealed more evolving synoptic signal than the ECMWF analysis. In synoptically active regions, it differed with respect to the OLR analysis, primarily because of actual differences in the vertical distribution of water vapor.

Chung, Hyosang↗

NASA NTRS2011

Stereoscopic Planar Laser-Induced Fluorescence Imaging at 500 kHz

A new measurement technique for obtaining time- and spatially-resolved image sequences in hypersonic flows is developed. Nitric-oxide planar laser-induced fluorescence (NO PLIF) has previously been used to investigate transition from laminar to turbulent flow in hypersonic boundary layers using both planar and volumetric imaging capabilities. Low flow rates of NO were typically seeded into the flow, minimally perturbing the flow. The volumetric imaging was performed at a measurement rate of 10 Hz using a thick planar laser sheet that excited NO fluorescence. The fluorescence was captured by a pair of cameras having slightly different views of the flow. Subsequent stereoscopic reconstruction of these images allowed the three-dimensional flow structures to be viewed. In the current paper, this approach has been extended to 50,000 times higher repetition rates. A laser operating at 500 kHz excites the seeded NO molecules, and a camera, synchronized with the laser and fitted with a beam-splitting assembly, acquires two separate images of the flow. The resulting stereoscopic images provide three-dimensional flow visualizations at 500 kHz for the first time. The 200 ns exposure time in each frame is fast enough to freeze the flow while the 500 kHz repetition rate is fast enough to time-resolve changes in the flow being studied. This method is applied to visualize the evolving hypersonic flow structures that propagate downstream of a discrete protuberance attached to a flat plate. The technique was demonstrated in the NASA Langley Research Center s 31-Inch Mach 10 Air Tunnel facility. Different tunnel Reynolds number conditions, NO flow rates and two different cylindrical protuberance heights were investigated. The location of the onset of flow unsteadiness, an indicator of transition, was observed to move downstream during the tunnel runs, coinciding with an increase in the model temperature.

Medford, Taylor L.↗

NASA NTRS1994

Interaction of Oblique Instability Waves with a Nonlinear Plane Wave

This paper is concerned with the downstream evolution of a resonant triad of initially non-interacting linear Instability waves in a boundary layer with a weak adverse pressure gradient. The triad consists of a two-dimensional fundamental mode and a pair of equal-amplitude oblique modes that form a subharmonic standing wave in the spanwise direction. The growth rates are small and there is a well-defined common critical layer for these waves. As in Goldstein & Lee (1992), the wave interaction takes place entirely within this critical layer and is initially of the parametric-resonance type. This enhances the spatial growth rate of the subharmonic but does not affect that of the fundamental. However, in contrast to Goldstein & Lee (1992), the initial subharmonic amplitude is assumed to be small enough so that the fundamental can become nonlinear within its own critical layer before it is affected by the subharmonic. The subharmonic evolution is then dominated by the parametric-resonance effects and occurs on a much shorter streamwise scale than that of the fundamental. The subharmonic amplitude continues to increase during this parametric-resonance stage - even as the growth rate of the fundamental approaches zero - and the subharmonic eventually becomes large enough to influence the fundamental which causes both waves to evolve on the same shorter streamwise scale.

Wundrow, David W.↗

DOE OSTI2022

Non-linear MHD modelling of edge localized modes suppression by resonant magnetic perturbations in ITER

Edge localized modes (ELMs) suppression by resonant magnetic perturbations (RMPs) was studied with the non-linear magneto-hydro-dynamic (MHD) code JOREK for the ITER H-mode scenarios at 15 MA, 12.5 MA, 10 MA/5.3 T. In this study, the main aim was to demonstrate that ELMs can be suppressed by RMPs while the divertor 3D footprints of heat and particle fluxes remain within divertor material limits. The unstable peeling–ballooning modes responsible for ELMs without RMPs were modelled first for each scenario using numerically accessible parameters for ITER. Then the stabilization of ELMs by RMPs was modelled with the same parameters. RMP spectra, optimized by the linear MHD MARS-F code, with main toroidal harmonics N = 2, N = 3, N = 4 have been used as boundary conditions of the computational domain of JOREK, including realistic RMP coils, main plasma, scrape off layer (SOL) divertor and realistic first wall. The model includes all relevant plasma flows: toroidal rotation, two fluid diamagnetic effects and neoclassical poloidal friction. With RMPs, the main toroidal harmonic and the non-linearly coupled harmonics remain dominant at the plasma edge, producing saturated modes and a continuous MHD turbulent transport thereby avoiding ELM crashes in all scenarios considered here. The threshold for ELM suppression was found at a maximum RMP coils current of 45 kAt–60 kAt compared to the coils maximum capability of 90 kAt. In the high beta poloidal steady-state 10 MA/5.3 T scenario, a rotating QH-mode without ELMs was observed even without RMPs. In this scenario with RMPs N = 3, N = 4 at 20 kAt maximum current in RMP coils, similar QH-mode behaviour was observed however with dominant edge harmonic corresponding to the main toroidal number of RMPs. The present MHD modelling was limited in time by few tens of ms after RMPs were switched on until the magnetic energy of the modes saturates. As a consequence the thermal energy was still evolving on this time scale, far from the ITER confinement time scale and hence only the form of 3D footprints on the divertor targets can be indicated within this set-up. Also note, that the divertor physics was missing in this model, so realistic values of fluxes are out of reach in this modelling. However the stationary 3D divertor and particle fluxes could be simply extrapolated from these results to the stationary situation considering that a large power fraction should be radiated in the core and SOL and only about 50 MW power is going to the divertor, which is an arbitrary, but reasonable number used here. The 3D footprints with RMPs show the characteristic splitting with the main RMP toroidal symmetry. The maximum radial extension of the footprints typically was ~20 cm in inner divertor and ~40 cm in outer divertor with stationary heat fluxes decreasing further out from the initial strike point from ~5 MW m ₋2 to ~1 MW m ₋2 assuming a total power in the divertor and walls is 50 MW. The heat fluxes remain within the divertor target and baffle areas, however with rather small margin in the outer divertor which could be an issue for the first wall especially in transient regimes when part of the plasma thermal energy is released due to switching on the RMP coils. This fact should be considered when RMPs are applied with a more favorable application before or soon after the L–H transition, although optimization is required to avoid increasing the L–H power threshold with RMPs.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

NASA NTRS2009

Multi-Scale Hydrometeorological Modeling, Land Data Assimilation and Parameter Estimation with the Land Information System

The Land Information System (LIS; http://lis.gsfc.nasa.gov; Kumar et al., 2006; Peters- Lidard et al.,2007) is a flexible land surface modeling framework that has been developed with the goal of integrating satellite- and ground-based observational data products and advanced land surface modeling techniques to produce optimal fields of land surface states and fluxes. As such, LIS represents a step towards the next generation land component of an integrated Earth system model. In recognition of LIS object-oriented software design, use and impact in the land surface and hydrometeorological modeling community, the LIS software was selected ase co-winner of NASA's 2005 Software of the Year award. LIS facilitates the integration of observations from Earth-observing systems and predictions and forecasts from Earth System and Earth science models into the decision-making processes of partnering agency and national organizations. Due to its flexible software design, LIS can serve both as a Problem Solving Environment (PSE) for hydrologic research to enable accurate global water and energy cycle predictions, and as a Decision Support System (DSS) to generate useful information for application areas including disaster management, water resources management, agricultural management, numerical weather prediction, air quality and military mobility assessment. LIS has evolved from two earlier efforts North American Land Data Assimilation System (NLDAS; Mitchell et al. 2004) and Global Land Data Assimilation System (GLDAS; Rodell al. 2004) that focused primarily on improving numerical weather prediction skills by improving the characterization of the land surface conditions. Both of GLDAS and NLDAS now use specific configurations of the LIS software in their current implementations. In addition, LIS was recently transitioned into operations at the US Air Force Weather Agency (AFWA) to ultimately replace their Agricultural Meteorology (AGRMET) system, and is also used routinely by NOAA's National Centers for Environmental Prediction (NCEP)/Environmental Modeling Center (EMC) for their land data assimilation systems to support weather and climate modeling. LIS not only consolidates the capabilities of these two systems, but also enables a much larger variety of configurations with respect to horizontal spatial resolution, input datasets and choice of land surface model through "plugins,". As described in Kumar et al., 2007, and demonstrated in Case et al., 2008, and Santanello et al., 2009, LIS has been coupled to the Weather Research and Forecasting (WRF) model to support studies of land-atmosphere coupling the enabling ensembles of land surface states to be tested against multiple representations of the atmospheric boundary layer. LIS has also been demonstrated for parameter estimation as described in Peters-Lidard et al. (2008) and Santanello et al. (2007), who showed that the use of sequential remotely sensed soil moisture products can be used to derive soil hydraulic and texture properties given a sufficient dynamic range in the soil moisture retrievals and accurate precipitation inputs. LIS has also recently been demonstrated for multi-model data assimilation (Kumar et al., 2008) using an Ensemble Kalman Filter for sequential assimilation of soil moisture, snow, and temperature. Ongoing work has demonstrated the value of bias correction as part of the filter, and also that of joint calibration and assimilation. Examples and case studies demonstrating the capabilities and impacts of LIS for hydrometeoroogical modeling, assimilation and parameter estimation will be presented as advancements towards the next generation of integrated observation and modeling systems.

Peters-Lidard, Christa D.↗

NASA NTRS1998

Prebiotic Polymer Synthesis and the Origin of Glycolytic Metabolism

Our research resulted in several discoveries which contributed to understanding the origin and operation of life. (1) Most importantly, we discovered a new pathway of prebiotic amino acid synthesis in which formaldehyde and glycolaldehyde (formose reaction substrates) react with ammonia to give alanine and homoserine in the presence of thiol catalysts. The thiol-dependent synthesis of amino acids undoubtedly occurs via amino acid thioester intermediates capable of forming peptides. This 'one-pot' reaction system operates under mild aqueous conditions, and like modern amino acid biosynthesis, uses sugar intermediates which are converted to amino acids by energy-yielding redox disproportionation. Preliminary evidence suggests that this type of process can be "evolved" by a serial transfer methods that lead to enrichment of autocatalytic molecules. (2) We established that prebiotic peptide polymers can be made by condensation of amino acid thioesters (homocysteine thiolactone and S-(N-beta-orotidyl- diaminopropionic acid) ethanethiol), and that prebiotic polydisulfide polymers can be generated by oxidation of dithiols with iron(III) in minerals. (3) In our analysis of metabolism we discovered the primary energy source of biosynthesis -- chemical energy made available by the redox disproportionation of substrate carbon groups. We concluded that the energy and reactivity of sugars make them the optimal substrate for the origin and operation of terrestrial (or extraterrestrial) life. (4) Since it is likely that the use of optimal sugar substrates in biosynthesis sets the average oxidation number of functional biocarbon throughout the Universe near 0.0 (the reduction level of formaldehyde), we proposed that a line(s) in the microwave spectrum of formaldehyde could be rationally selected as a frequency for interstellar communication that symbolizes life. (5) Finally, in preparation for the analysis of Martian meteorite samples, we upgraded our HPLC system to one femtomole sensitivity, and developed a new electrophoretic method of sample preparation for HPLC analysis of the meteoritic amino acids. In a sample of the KT boundary layer from Sussex Wyoming, we found about 300 picomoles per gram of meteoritic alpha-aminoisobutyric acid per gram of KT layer.

Weber, Arthur L.↗

NASA NTRS1995

Instrument technology for magnetosphere plasma imaging from high Earth orbit. Design of a radio plasma sounder

The use of radio sounding techniques for the study of the ionospheric plasma dates back to G. Briet and M. A. Tuve in 1926. Ground based swept frequency sounders can monitor the electron number density (N(sub e)) as a function of height (the N(sub e) profile). These early instruments evolved into a global network that produced high-resolution displays of echo time delay vs frequency on 35-mm film. These instruments provided the foundation for the success of the International Geophysical Year (1958). The Alouette and International Satellites for Ionospheric Studies (ISIS) programs pioneered the used of spaceborne, swept frequency sounders to obtain N(sub e) profiles of the topside of the ionosphere, from a position above the electron density maximum. Repeated measurements during the orbit produced an orbital plane contour which routinely provided density measurements to within 10%. The Alouette/ISIS experience also showed that even with a high powered transmitter (compared to the low power sounder possible today) a radio sounder can be compatible with other imaging instruments on the same satellite. Digital technology was used on later spacecraft developed by the Japanese (the EXOS C and D) and the Soviets (Intercosmos 19 and Cosmos 1809). However, a full coherent pulse compression and spectral integrating capability, such as exist today for ground-based sounders (Reinisch et al., 1992), has never been put into space. NASA's 1990 Space Physics Strategy Implementation Study "The NASA Space Physics Program from 1995 to 2010" suggested using radio sounders to study the plasmasphere and the magnetopause and its boundary layers (Green and Fung, 1993). Both the magnetopause and plasmasphere, as well as the cusp and boundary layers, can be observed by a radio sounder in a high-inclination polar orbit with an apogee greater than 6 R(sub e) (Reiff et al., 1994; Calvert et al., 1995). Magnetospheric radio sounding from space will provide remote density measurements of unprecedented precision and coverage in the plasmasphere, inner magnetosphere and magnetopause, from which the structure, inter-relationship, and variations of different plasma regions can be determined (Armstrong Johnson, 1995). A space-borne Radio Plasma Imager (RPI) could provide a unique global view of the magnetosphere revealing the underlying structure of remote plasma regions, thereby providing a framework for the interpretation of images obtained by other techniques as identified in the technical areas TA1 to TA4 in the MSFC NRA8-8.

Haines, D. Mark↗

DOE OSTI2022

Parametric dependencies of resonant layer responses across linear, two-fluid, drift-MHD regimes

Non-axisymmetric magnetic fields arising in a tokamak either by external or internal perturbations can induce complex non-ideal MHD responses in their resonant surfaces while remaining ideally evolved elsewhere. This layer response can be characterized in a linear regime by a single parameter called the inner-layer Δ, which enables outer-layer matching and the prediction of torque balance to non-linear island regimes. In this work, we follow strictly one of the most comprehensive analytic treatments including two-fluid and drift MHD effects and keep the fidelity of the formulation by incorporating the numerical method based on the Riccati transformation when quantifying the inner-layer Δ. The proposed scheme reproduces not only the predicted responses in essentially all asymptotic regimes but also with continuous transitions as well as improved accuracies. In particular, the Δ variations across the inertial regimes with viscous or semi-collisional effects have been further resolved, in comparison with additional analytic solutions. The results imply greater shielding of the electromagnetic torque at the layer than what would be expected by earlier work when the viscous or semi-collisional effects can compete against the inertial effects, and also due to the intermediate regulation by kinetic Alfvén wave resonances as rotation slows down. These are important features that can alter the non-axisymmetric plasma responses including the field penetration by external fields or island seeding process in rotating tokamak plasmas.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

DOE OSTI2022

On-Demand Designing of Cathode Internal Surface Architecture for Dramatic Enhancement of SOFC Performance and Durability

This project is aimed to design and modify the internal surfaces of porous composite cathode from currently commercially viable Solid Oxide Fuel Cells (SOFCs), using additive manufacturing process of Atomic Layer Deposition (ALD). The material systems being investigated are commercial composite electrodes complex three-dimensional topographies. In term of the chemistry of the ALD layer applied on the internal surface of the porous cathode, this project has employed commercially relevant electrolyte, electrocatalyst and noble metal materials set. Such materials are fully compatible with the commercial fuel cells, and this project has developed special nanostructure on the surface of the commercial composite cathodes. The formation of the designed nanoarchitecture on the surface of SOFC cathode has been achieved through precise control of ALD parameters and their effect on overall cell performance and resultant electrochemical reaction mechanism of cathodes has been investigated through full cell electrochemical performance testing and nanostructure characterization by transmission electron microscopy (TEM). Under the support of this award, following has been achieved: (1). For cathode materials in solid oxide fuel cells (SOFCs), such as perovskite mixed conductor La 0.6 Sr 0.4 Co 0.2 Fe 0.8 O 3-x (LSCF), cation surface segregation and consequently losing conductivity and active sites for the oxygen reduction reaction (ORR) are problematic. To mitigate the cation segregation and enhance SOFC durability, further decorating the internal backbone surface using the desired electrocatalysts could be a promoting approach. Commonly, the cation segregation such as Sr is very volatile, so the effective surface decoration is ideally conformal. Nevertheless, the conformal surface coating would inevitably alter the ORR pathways that initially take place on the surface of the backbone. To reveal the impact of the conformal coating on both the catalytic activity and the conductivity of the cathode, the unary electrocatalyst of Pt or CoO x , was applied to the LSCF/SDC composite electrode of inherently functional SOFCs, respectively. Both ALD coating layers evolve strong interaction with the LSCF composite cathode. Upon operations, the Pt coating layer remains conformal on LSCF grain surfaces but turns into discrete particles on SDC grain surfaces. Meanwhile, CoO x conformal coating grows to be the discrete nanograins on both the LSCF and SDC grains. ALD coating of the cathode alone reduces the ohmic resistance up to 28 % for the entire cells. The increased conductivity induced by the ALD coating of Pt or CoO x is ascribed to different mechanisms. For the inherent functional SOFCs, the present study presents a novel and feasible approach to apply a conformal, dense coating layer on the surface of a mixed conductor, simultaneously increasing the conductivity and durability of the SOFC cathode. (2). High resistance of the oxygen electrode still significantly hinders the state-of-the-art Solid Oxide Fuel Cells (SOFCs). In particular, for an oxygen electrode consisting of mixed electronic and ionic conductors, such as perovskite lanthanum strontium cobalt ferrite (LSCF), it deteriorates due to its low chemical stability of the grain surface. Such degradation is often associated with the segregation of cations. To prevent the cation surface segregation and its resultant perovskite phase decomposition, we demonstrate a conformal ultra-thin (7-10 nm) surface heterogeneous coating layer consisting of subjacent discrete Pt nanoparticles capped with a superjacent fully dense conformal CoO x layer. The performance studies indicate the ALD coating reduces the cell series resistance by up to 40 %. The conformal CoO x layer consists of randomly orientated but single-layered nanograins, with high-density intergranular and surface grain boundaries serving as the electrochemical reaction sites and facilitating mass transport. The conformal coating layer appears to have successfully suppressed the Sr outward diffusion and confined the Sr enriched layer to a ~ 2 nm interface perovskite phase between the coating layer and the LSCF grain surface. Moreover, this ultra-thin Sr enriched perovskite layer presumably possesses high oxygen vacancy and high ionic conductivity and further imposes tensile strain to the LSCF grain surfaces. With the combination of a conformal CoO x nanoionics, Sr enriched layer, and its strained interface, the ALD coating induced surface layer is estimated to have a conductivity of ~ 1.27x10 4 S/cm, which is over two orders magnitude of that from LSCF at 750 ºC.

30 DIRECT ENERGY CONVERSION↗