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At least 199 records · Page 11

𝐽/𝜓 photoproduction and polarization in 𝑒 + 𝑝 collisions in the improved color evaporation model

We calculate the production and polarization of direct 𝐽/𝜓 in the improved color evaporation model in 𝑒 + 𝑝 photoproduction. We present the production as functions of transverse momentum, mass of the hadronic final state, and inelasticity. We also present the polarization parameters 𝜆 𝜗 , 𝜆 𝜑 , and 𝜆 𝜗⁢𝜑 in the helicity and the Collins-Soper frames, as well as the frame-invariant polarization parameter $\tilde{𝜆}$ as a function of transverse momentum and inelasticity. We find agreement with both 𝐽/𝜓 unpolarized cross sections and the invariant polarization parameters as a function of 𝑝𝑇.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

A novel approach to partitioning evapotranspiration into evaporation and transpiration in flooded ecosystems

Reliable partitioning of micrometeorologically measured evapotranspiration (ET) into evaporation (E) and transpiration (T) would greatly enhance our understanding of the water cycle and its response to climate change related shifts in local-to-regional climate conditions and rising global levels of vapor pressure deficit (VPD). While some methods on ET partitioning have been developed, their underlying assumptions make them difficult to apply more generally, especially in sites with large contributions of E. Here, we report a novel ET partitioning method using artificial neural networks (ANNs) in combination with a range of environmental input variables to predict daytime E from nighttime ET measurements. The study uses eddy covariance data from four restored wetlands in the Sacramento-San Joaquin Delta, California, USA, as well as leaf-level T data for validation. The four wetlands vary in their vegetation make-up and structure, representing a range of ET conditions. The ANNs were built with increasing complexity by adding the input variable that resulted in the next highest average value of model testing R 2 across all sites. The order of variable inclusion (and importance) was: VPD > gap-filled sensible heat flux (H_gf) > air temperature (T air ) > friction velocity (u * ) > other variables. The model using VPD, H_gf, T air , and u * showed the best performance during validation with independent data and had a mean testing R 2 value of 0.853 (averaged across all sites, range from 0.728 to 0.910). In comparison to other methods, our ANN method generated T/ET partitioning results which were more consistent with CO 2 exchange data especially for more heterogeneous sites with large E contributions. Further, our method improves the understanding of T/ET partitioning. While it may be particularly suited to flooded ecosystems, it can also improve T/ET partitioning in other systems, increasing our knowledge of the global water cycle and ecosystem functioning.

59 BASIC BIOLOGICAL SCIENCES↗

Simulating evaporative wet and dry cycles in Gale crater, Mars using thermochemical modeling techniques

The aim of this work is to provide a model‐backed hypothesis for the formation of evaporites—sulfates, borates—in Gale crater using thermochemical modeling to determine constraints on their formation. We test the hypothesis that primary evaporites required multiple wet–dry cycles to form, akin to how evaporite assemblages form on Earth. Starting with a basalt‐equilibrated Mars fluid, Mars‐relevant concentrations of B and Li were added, and then equilibrated with Gale lacustrine bedrock. We simulated the cycles of evaporation followed by groundwater recharge/dilution to establish an approximate minimum number of wet–dry cycles required to form primary evaporites. We determine that a minimum of 250 wet–dry cycles may be required to start forming primary evaporites that consist of borates and Ca‐sulfates. We estimate that ~14,250 annual cycles (~25.6 k Earth years) of wet and dry periods may form primary borates and Ca‐sulfates in Gale crater. These primary evaporites could have been remobilized during secondary diagenesis to form the veins that the Curiosity rover observes in Gale crater. No Li salts form after 14,250 cycles modeled for the Gale‐relevant scenario (approximately 10 6 cycles would be needed) which implies Li may be leftover in a groundwater brine after the time of the lake. No major deposits of borates are observed to date in Gale crater which also implies that B may be leftover in the subsequent groundwater brine that formed after evaporites were remobilized into Ca‐sulfate veins.

58 GEOSCIENCES↗

Kerr black hole evaporation and Page curve

In this paper, we compute the black hole entropy and the entanglement entropy of Hawking radiations due to photons during the evaporation of a 4D asymptotically flat Kerr black hole. The Page curve for the Kerr black hole is obtained in the original way à la Page, and it qualitatively mimics the curve for the Schwarzschild black hole but has some new features.

Astronomy & Astrophysics↗

Droplet Growth or Evaporation Does Not Buffer the Variability in Supersaturation in Clean Clouds

Abstract Water vapor supersaturation in clouds is a random variable that drives activation and growth of cloud droplets. The Pi Convection–Cloud Chamber generates a turbulent cloud with a microphysical steady state that can be varied from clean to polluted by adjusting the aerosol injection rate. The supersaturation distribution and its moments, e.g., mean and variance, are investigated for varying cloud microphysical conditions. High-speed and collocated Eulerian measurements of temperature and water vapor concentration are combined to obtain the temporally resolved supersaturation distribution. This allows quantification of the contributions of variances and covariances between water vapor and temperature. Results are consistent with expectations for a convection chamber, with strong correlation between water vapor and temperature; departures from ideal behavior can be explained as resulting from dry regions on the warm boundary, analogous to entrainment. The saturation ratio distribution is measured under conditions that show monotonic increase of liquid water content and decrease of mean droplet diameter with increasing aerosol injection rate. The change in liquid water content is proportional to the change in water vapor concentration between no-cloud and cloudy conditions. Variability in the supersaturation remains even after cloud droplets are formed, and no significant buffering is observed. Results are interpreted in terms of a cloud microphysical Damköhler number (Da), under conditions corresponding to , i.e., the slow-microphysics regime. This implies that clouds with very clean regions, such that is satisfied, will experience supersaturation fluctuations without them being buffered by cloud droplet growth. Significance Statement The saturation ratio (humidity) in clouds controls the growth rate and formation of cloud droplets. When air in a turbulent cloud mixes, the humidity varies in space and time throughout the cloud. This is important because it means cloud droplets experience different growth histories, thereby resulting in broader size distributions. It is often assumed that growth and evaporation of cloud droplets buffers out some of the humidity variations. Measuring these variations has been difficult, especially in the field. The purpose of this study is to measure the saturation ratio distribution in clouds with a range of conditions. We measure the in-cloud saturation ratio using a convection cloud chamber with clean to polluted cloud properties. We found in clouds with low concentrations of droplets that the variations in the saturation ratio are not suppressed.

54 ENVIRONMENTAL SCIENCES↗

Evaporation Sub-model Development for Volume of Fluid (eVOF) Method Applicable to Spray-Wall Interaction Including Film Characteristics with Validation at High Pressure and Temperature Conditions (Final Report)

Internal combustion engines have seen a great evolution over the last several decades through application of high pressure direct injection, multiple injections, and other technologies to reduced fuel consumption, NOx, and PM. Although combustion systems with advanced injection strategies have been studied extensively, there exists a significant fundamental knowledge gap on the fuel-spray interactions with the piston surface and chamber walls. Advanced computational codes validated with experimental techniques have to be developed for accurate representation of the drop impingement, fuel film formation, and vaporization. Current engine CFD spray models utilize a Lagrangian framework for modeling which lacks critical considerations of the physics pertaining to these interactions and thus requiring extensive parameterization, tuning and validation. The team from Michigan Technological University, University of Massachusetts Dartmouth, and Argonne National Laboratory is composed of experts in sprays, combustion, engines and CFD with a wide spectrum of knowledge including specific expertise in the area under consideration. In the proposed work, a VOF modeling approach has been adopted for the spray-wall interaction, film formation and spreading, and vaporization. With the inclusion of a vaporization submodel, a more predictive and accurate simulation of the spray-film was performed without extensive need of parameterization and tuning. Extensive experimentation of the spray-wall interaction under the range of conditions matching the thermodynamic and surface temperatures that occur in diesel and gasoline engines were conducted to validate the SWI submodels and for development of the evaporation sub-model, which has been implemented in the Converge software.

42 ENGINEERING↗

Evaporation Submodel Development for Volume of Fluid (eVOF) Method Applicable to Spray-Wall Interaction Including Film Characteristics with Validation at High Pressure and Temperature Conditions

Internal combustion engines have seen a great evolution over the last several decades through application of high pressure direct injection, multiple injections, and other technologies to reduced fuel consumption, NOx, and PM. Although combustion systems with advanced injection strategies have been studied extensively, there exists a significant fundamental knowledge gap on the fuel-spray interactions with the piston surface and chamber walls. Advanced computational codes validated with experimental techniques have to be developed for accurate representation of the drop impingement, fuel film formation, and vaporization. Current engine CFD (Computational Fluid Dynamics) spray models utilize a Lagrangian framework for modeling which lacks critical considerations of the physics pertaining to these interactions and thus requiring extensive parameterization, tuning and validation. The team from Michigan Technological University, University of Massachusetts Dartmouth, and Argonne National Laboratory is composed of experts in sprays, combustion, engines and CFD with a wide spectrum of knowledge including specific expertise in the area under consideration. In the proposed work, a VOF (Volume of Fluid) modeling approach has been adopted for the spray-wall interaction, film formation and spreading, and vaporization. With the inclusion of a vaporization submodel, a more predictive and accurate simulation of the spray-film was performed without extensive need of parameterization and tuning. Extensive experimentation of the spray-wall interaction under the range of conditions matching the thermodynamic and surface temperatures that occur in diesel and gasoline engines were conducted to validate the SWI submodels and for development of the evaporation submodel, which has been implemented in the flow solver.

42 ENGINEERING↗

Modeling the Destruction of Glycolate in the Defense Waste Processing Facility (DWPF) Recycle Stream and Concentration Factors for Glycolate in the 2H Evaporator

Two models were developed to predict maximum glycolate concentrations in the Savannah River Site (SRS) Concentration, Storage, and Transfer Facility (CSTF) from implementation of the Nitric-Glycolic flowsheet at the Defense Waste Processing Facility (DWPF). One model describes the kinetics of glycolate destruction via chemical oxidation with sodium permanganate. This model conservatively predicts glycolate concentration delivered to the CSTF with a high probability the actual glycolate concentration is lower than predicted. The second model describes the potential concentration of said residual glycolate within the 242-16H (i.e., “2H”) Evaporator system.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Additional Analysis of the 2H-Evaporator Wall Scale Sample HTF-17-57

Savannah River National Laboratory previously analyzed scale samples from both the wall and cone sections of the 242-16H Evaporator prior to chemical cleaning. The samples were analyzed for uranium and plutonium isotopes required for a Nuclear Criticality Safety Assessment of the scale removal process. The analysis of the scale samples found the material to contain crystalline nitrated cancrinite and clarkeite and significant amounts of mercury. Savannah River Remediation subsequently requested additional analyses on the samples. Inspection of the sample bottles revealed that no sample remained of the cone scale (HTF-17-56) while approximately 4 g of the wall scale sample (HTF-17-57) remained. The wall sample was subsequently ground with a mortar and pestle, at which time it was discovered that the sample contained a significant amount of liquid, metallic mercury. The portion of the sample that was not mercury was approximately 3 g. This portion of the sample was analyzed to determine the concentrations of selected radionuclides. The following radionuclide concentrations were measured: <9.6E+02 dpm/g H-3, 2.9E+02 dpm/g C-14, 5.6E+03 dpm/g Tc-99, and 1.6E+02 dpm/g I-129. Blank samples were also analyzed to evaluate sample contamination from the Shielded Cells environment. All blank sample results were below detectable limits. Due to the limited sample size and the anticipated low levels of the target radionuclides, no replicate sample analysis was conducted.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

White Paper to Justify the Use of Strip Effluent in the Defense Waste Processing Facility During Slurry Mix Evaporator Processing

At the request of Savannah River Remediation (SRR), a white paper was written to assess whether it would be acceptable to process Strip Effluent (SE) in both the Sludge Receipt and Adjustment Tank (SRAT) and Slurry Mix Evaporator (SME) in the Defense Waste Processing Facility (DWPF) for the nitric-glycolic acid flowsheet. Savannah River National Laboratory (SRNL) experimental data and DWPF Sludge Batch 9 (SB9) process data was reviewed, looking at batches which included Precipitate Reactor Feed Tank (PRFT) and/or Strip Effluent Feed Tank (SEFT) feeds that led to long processing times. These batches were reviewed looking for processing problems such as melter feed trips, foamovers, heating rod or steam coil fouling, missed Reduction/Oxidation (REDOX) targets, and other process anomalies.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Potential for Evaporation and In Situ Reaction of Organic Compounds in Hanford Supplemental LAW

The presence of regulated organic species in Hanford nuclear tank waste is assessed in this report, along with fate of the organics and possible evaporative treatment. A narrowed list of regulated organic species of concern is developed based upon published analyses, chemical properties like aqueous solubility, and chemical reactivity under alkaline conditions. Published analyses include tank headspace and liquid samples, review of chemical reagents formerly used at Hanford, and the Tank Waste Information Network System (TWINS). This work supports possible stabilization of Hanford Supplemental Low Activity Waste (SLAW) by grouting.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Potential for Evaporation and In Situ Reaction of Organic Compounds in Hanford Supplemental LAW

The presence of regulated organic species in Hanford nuclear tank waste is assessed in this report, along with fate of the organics and possible evaporative treatment. A narrowed list of regulated organic species of concern is developed based upon published analyses, chemical properties like aqueous solubility, and chemical reactivity under alkaline conditions. Published analyses include tank headspace and liquid samples, review of chemical reagents formerly used at Hanford, and the Tank Waste Information Network System (TWINS). This work supports possible stabilization of Hanford Supplemental Low Activity Waste (SLAW) by grouting.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Analysis of Defense Waste Processing Facility Sample: Slurry Mix Evaporator Condensate Tank Sample Batch 4638

The Savannah River National Laboratory (SRNL) was requested by Savannah River Remediation (SRR, now Savannah River Mission Completion (SRMC)), through a Technical Task Request, to characterization the “as-received” Slurry Mix Evaporator Condensate Tank (SMECT) sample identified as sample batch 4638, which was delivered to SRNL Shielded Cells on March 19, 2021. The SMECT characterization data will be used as input to the Defense Waste Processing Facility (DWPF) Recycle Diversion Project. This SMECT report is the second of three sample characterization reports that will be used for this DWPF Project. The other two DWPF characterization reports involve the characterization of the Recycle Collection Tank (RCT) sample and the future Off-Gas Condensate Tank (OGCT) characterization report.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Creation of Multiple Effect Evaporator and Combined Cycle Modelica Modules, and Optimization of Potable Water Generation from Saltwater Sources (Final Technical Report)

Modelica models for a Heat Recovery Steam Generator (HRSG) and Multiple Effect Evaporator have been developed. These models have been validated against results from literature and from an actual cogeneration system on the campus of NC State University. The models are capable of connecting to other components to create multi-input, multi-output energy systems with storage, also known as integrated energy systems. An existing 35 MW gas turbine model is connected to the HRSG model created for this project to produce 9 bar steam. The high pressure steam feeds a backpressure steam turbine from the library to generate additional electric power. 2 bar steam leaves the turbine to supply an 8 effect MEE to generate water for a community. As part of the effort, three research papers were submitted (two published in ANS Proceedings and one submitted to Applied Energy).

20 FOSSIL-FUELED POWER PLANTS↗

Calendar Year 2022 Annual Monitoring Report for Technical Area IV, Evaporation Lagoons Permit DP-530 at Sandia National Laboratories/New Mexico

Pursuant to Section 20.6.2.3104 of the New Mexico Administrative Code (NMAC), the U.S. Department of Energy/National Nuclear Security Administration/Sandia Field Office (DOE/NNSA/SFO) as owner and National Technology & Engineering Solutions of Sandia, LLC (NTESS) as operator are submitting this annual monitoring and discharge report for calendar year (CY) 2022 as required in Discharge Permit 530 (DP-530), issued by the New Mexico Environment Department (NMED) for the Pulsed Power Development Facilities Evaporation Lagoons located at Sandia National Laboratories/New Mexico (SNL/NM) Technical Area IV (TA-IV).

54 ENVIRONMENTAL SCIENCES↗

Additive Manufacturing Evaporative Casting

Traditional lost foam casting has been around for decades. The process uses foam forms blown by an injection molding like process or CNC milled into the desired shape, then pouring molten metal over the foam pattern to create a metallic object. Additive Manufacturing Evaporative Casting (AMEC) is a new process that eliminates foam forms by using additive manufacturing to 3D print the desired cast geometry. This not only saves time and money but allows for more advanced and complex designs that can’t be achieved by carving foam. Additionally, AMEC doesn’t require molds and tooling like other casting and foundry options. Because the AMEC process is new, extensive testing is needed to develop a better understanding of the process to minimize defects, quantify material properties, and start computer modeling for the process. This CRADA (collaborative research and development agreement) between ORNL and Skuld seeks to improve the process, develop a computational model, characterize material properties, and explore new applications.

36 MATERIALS SCIENCE↗

Development of a high fidelity CFD model for solvent evaporation and transport in porous structure during battery electrode drying

An efficient battery manufacturing process is the key to the mass production of Electric Vehicles (EV), in which drying is one of the most energy-intensive steps significantly influencing the battery cell performance. An accurate 3D CFD model for drying is essential for predicting the drying mechanism and optimizing its parameters. By optimizing the drying process, it is possible to reduce energy consumption and cost during battery manufacturing, minimize binder loading and maximize active material loading to achieve superior electrochemical performances and facilitate wider and faster public adoption of EV. This project aims to optimize the drying process during electrode manufacturing by leveraging high-fidelity, porous electrode simulations for solvent evaporation. By optimizing this process, we seek to reduce energy consumption during battery manufacturing, while minimizing binder loading and maximizing active material loading, with the overall goal of enhancing electrical vehicle performance.

Horner, Jeffrey Scott [Sandia National Laboratorie↗