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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 199 records · Page 11
All sourcesNASA NTRSDOE OSTI
NASA NTRS1993

The reionization of the universe: The feedback of galaxy formation on the intergalactic medium

The thermal and ionization evolution of a uniform intergalactic medium (IGM) composed of H and He, undergoing reionization, including the mean effect of gas clumps embedded in a smoothly distributed ambient gas were calculated. The rate equations for ionization and recombination were solved together with the equations of energy conservation, including the effects of cosmological expansion, radiative and Compton cooling, and the diffuse flux emitted by the gas, and radiative transfer. The contribution to the continuum opacity of the universe due to the observed quasar absorption line clouds (QALC'S) were included. A variety of sources of photoionization, including quasars and primeval galaxies, as well as the possibility that hydrodynamical processes deposit thermal energy in the IGM were considered. Applications of these calculations including the evolution of the Ly-alpha forest clouds are described. A self-consistent treatment of the thermal and ionization history of the intergalactic medium (IGM) must take account of the growth of structure in the universe, since the mean density of the IGM corresponds primarily to the time-varying uncollapsed fraction of the baryon-electron component of the matter, and the collapsed fraction, in turn, can have a feedback effect on this uncollapsed fraction by releasing ionizing radiation and thermal energy and by contributing to the opacity of the universe. The coupled evolution of the IGM and the emerging structure with a special focus on the reionization of the IGM, which is believed to have been completed by some redshift z is approximately greater than 4, as inferred from the absence of the Gunn-Peterson effect in the spectra of high z quasars, are studied. The results and implications of detailed, numerical calculations of the thermal and ionization balance and radiative transfer in a uniform IGM of H and He, including the mean effect of an evolving distribution of gas clumps embedded in a smoothly distributed ambient gas is described.

Shapiro, Paul R.↗
NASA NTRS2002

Laser Induced Aluminum Surface Breakdown Model

Laser powered propulsion systems involve complex fluid dynamics, thermodynamics and radiative transfer processes. Based on an unstructured grid, pressure-based computational aerothermodynamics; platform, several sub-models describing such underlying physics as laser ray tracing and focusing, thermal non-equilibrium, plasma radiation and air spark ignition have been developed. This proposed work shall extend the numerical platform and existing sub-models to include the aluminum wall surface Inverse Bremsstrahlung (IB) effect from which surface ablation and free-electron generation can be initiated without relying on the air spark ignition sub-model. The following tasks will be performed to accomplish the research objectives.

Chen, Yen-Sen↗
NASA NTRS2001

Laser Induced Aluminum Surface Breakdown Model

Laser powered propulsion systems involve complex fluid dynamics, thermodynamics and radiative transfer processes. Based on an unstructured grid., pressure-based computational aerothermodynamics, platform, several sub-nio"'dels describing such underlying physics as laser ray tracing and focusing, thermal non-equilibrium, plasma radiation and air spark ignition have been developed. This proposed work shall extend the numerical platform and existing sub-models to include the aluminum wall surface Inverse Bremsstrahlung (113) effect from which surface ablation and free-electron generation can be initiated without relying on the air spark ignition sub-model. The following tasks will be performed to accomplish the research objectives.

Chen, Yen-Sen↗
NASA NTRS2011

Comparison of DSMC and CFD Solutions of Fire II Including Radiative Heating

The ability to compute rarefied, ionized hypersonic flows is becoming more important as missions such as Earth reentry, landing high mass payloads on Mars, and the exploration of the outer planets and their satellites are being considered. These flows may also contain significant radiative heating. To prepare for these missions, NASA is developing the capability to simulate rarefied, ionized flows and to then calculate the resulting radiative heating to the vehicle's surface. In this study, the DSMC codes DAC and DS2V are used to obtain charge-neutral ionization solutions. NASA s direct simulation Monte Carlo code DAC is currently being updated to include the ability to simulate charge-neutral ionized flows, take advantage of the recently introduced Quantum-Kinetic chemistry model, and to include electronic energy levels as an additional internal energy mode. The Fire II flight test is used in this study to assess these new capabilities. The 1634 second data point was chosen for comparisons to be made in order to include comparisons to computational fluid dynamics solutions. The Knudsen number at this point in time is such that the DSMC simulations are still tractable and the CFD computations are at the edge of what is considered valid. It is shown that there can be quite a bit of variability in the vibrational temperature inferred from DSMC solutions and that, from how radiative heating is computed, the electronic temperature is much better suited for radiative calculations. To include the radiative portion of heating, the flow-field solutions are post-processed by the non-equilibrium radiation code HARA. Acceptable agreement between CFD and DSMC flow field solutions is demonstrated and the progress of the updates to DAC, along with an appropriate radiative heating solution, are discussed. In addition, future plans to generate more high fidelity radiative heat transfer solutions are discussed.

Liechty, Derek S.↗
NASA NTRS2006

Electrostatic Properties of PE and PTFE Subjected to Atmospheric Pressure Plasma Treatment; Correlation of Experimental Results with Atomistic Modeling

The use of an atmospheric pressure glow discharge (APGD) plasma was used at KSC to increase the hydrophilicity of spaceport materials to enhance their surface charge dissipation and prevent possible ESD in spaceport operations. Significant decreases in charge decay times were observed after tribocharging the materials using the standard KSC tribocharging test. The polarity and amount of charge transferred was dependent upon the effective work function differences between the respective materials. In this study, polyethylene (PE) and polytetrafluoroethylene (PTFE) were exposed to a He+O2 APGD. The pre and post treatment surface chemistry was analyzed by X-ray photoelectron spectroscopy and contact angle measurements. Semi-empirical and ab initio calculations were performed to correlate the experimental results with some plausible molecular and electronic structure features of the oxidation process. For the PE, significant surface oxidation was observed, as indicated by XPS showing C-O, C=O, and O-C=O bonding, and a decrease in the surface contact angle from 98.9 deg to 61.2 deg. For the PTFE, no C-O bonding appeared and the surface contact angle increased indicating the APGD only succeeded in cleaning the PTFE surface without affecting the surface structure. The calculations using the PM3 and DFT methods were performed on single and multiple oligomers to simulate a wide variety of oxidation scenarios. Calculated work function results suggest that regardless of oxidation mechanism, e.g. -OH, =0 or a combination thereof, the experimentally observed levels of surface oxidation are unlikely to lead to a significant change in the electronic structure of PE and that its increased hydrophilic properties are the primary reason for the observed changes in its electrostatic behavior. The calculations for PTFE argue strongly against significant oxidation of that material, as confirmed by the XPS results.

Trigwell, Steve↗
NASA NTRS2022

Quantifying Structural Relationships of Metal-Binding Sites Suggests Origins of Biological Electron Transfer

Biological redox reactions drive planetary biogeochemical cycles. Using a novel, structure-guided sequence analysis of proteins, we explored the patterns of evolution of enzymes responsible for these reactions. Our analysis reveals that the folds that bind transition metal–containing ligands have similar structural geometry and amino acid sequences across the full diversity of proteins. Similarity across folds reflects the availability of key transition metals over geological time and strongly suggests that transition metal–ligand binding had a small number of common peptide origins. We observe that structures central to our similarity network come primarily from oxidoreductases, suggesting that ancestral peptides may have also facilitated electron transfer reactions. Last, our results reveal that the earliest biologically functional peptides were likely available before the assembly of fully functional protein domains over 3.8 billion years ago. Thus, life is a special, very complex form of motion of matter, but this form did not always exist, and it is not separated from inorganic nature by an impassable abyss; rather, it arose from inorganic nature as a new property in the process of evolution of the world. We must study the history of this evolution if we want to solve the problem of the origin of life.

Yana Bromberg↗
NASA NTRS1974

Vibrational relaxation in expanding N2 and air

New N2 vibrational temperature data, obtained in expanding N2 and air using the electron beam technique, are analyzed permitting the vibrational relaxation times to be determined as a function of temperature. In addition, the effects on N2 vibrational relaxation times of direct vibrational energy transfer between N2 and H2O, between N2 and O2, and between N2 and free electrons introduced from arc contaminants are analyzed. The vibrational relaxation times determined from the present measurements agree with those measured in the expanding flows of shock tunnels and impact tubes. These expanding data also agree with relaxation times observed in acoustical resonant cavities where alternating compressions and expansions take place. The relaxation times in expanding flows (vib-tran exchange process) are found to be approximately 50 times faster than those measured in the compressing flow of shock tubes (tran-vib exchange process). This evidence strongly supports the concept that one relaxation time distribution cannot be applied to both exchange processes.

Sebacher, D. I.↗
NASA NTRS1984

Containerless high temperature property measurements by atomic fluorescence

Laser induced fluorescence (LIF) techniques for containerless study of high temperature processes and material properties was studied. Gas jet and electromagnetic levitation and electromagnetic and laser heating techniques are used with LIF in earth-based containerless high temperature experiments. Included are the development of an apparatus and its use in the studies of (1) chemical reactions on Al2O3, molybdenum, tungsten and LaB6 specimens, (2) methods for noncontact specimen temperature measurement, (3) levitation jet properties and (4) radiative lifetime and collisional energy transfer rates for electronically excited atoms.

Schiffman, R. A.↗
NASA NTRS1992

Modeling of hypersonic reacting flows

The effect of nonequilibrium thermochemical processes on the aerodynamic and heat transfer characteristics of a hypersonic vehicle is illustrated with examples. It is shown that the conventional method of predicting chemical reactions always predict that the flow is closer to equilibrium than it actually is, leading to incorrect predictions of aerodynamic characteristics of a vehicle. A method is presented for predicting chemical processes using a two-temperature kinetic model, which is developed on the basis of combining conservation equations for vibrational energy and for electron electronic energy, which are also derived. The validity of the two-temperature model is proven using two types of experimental data: radiation and shock shapes.

Park, Chul↗
NASA NTRS1974

Dynamic-scanning-electron-microscope study of friction and wear

A friction and wear apparatus was built into a real time scanning electron microscope (SEM). The apparatus and SEM comprise a system which provides the capability of performing dynamic friction and wear experiments in situ. When the system is used in conjunction with dispersive X-ray analysis, a wide range of information on the wearing process can be obtained. The type of wear and variation with speed, load, and time can be investigated. The source, size, and distribution of wear particles can be determined and metallic transferal observed. Some typical results obtained with aluminum, copper, and iron specimens are given.

Brainard, W. A.↗
NASA NTRS1983

A theoretical study on the mechanism of electronic to vibrational energy transfer in Hg/3P/ + CO

The mechanism of electronic-to-vibrational (E-V) energy transfer in Hg(3P) + CO collisions has been studied theoretically. The configuration interaction (CI) method was employed to calculate potential energy surfaces of the collision system. A simplified theoretical model, based on the reaction coordinate concept and the calculated potential energy characteristics, was used to discuss the mechanism of the singlet-triplet transition and the energy disposal in the collision. The results obtained were that: (a) the quenching process processed via a collision complex mechanism; and that (b) the triplet-singlet transition occurs near the collinear geometry. A model classical trajectory calculation gives a product CO vibrational distribution in good agreement with the experimental result.

Kato, S.↗
NASA NTRS1976

Theory of low transitions in CO discharge lasers

A self consistent theoretical model which couples the electron and heavy particle finite rate kinetics with the optical and fluid dynamic processes has been employed to identify the various parameters and explain the mechanism responsible for producing low lying transitions in slow flowing CO lasers. It is found that lasing on low lying transitions can be achieved at low temperatures for low pressures (or low flow rates) together with high partial pressures of the He and N2. The role of N2 has been identified as an additive responsible for reducing the electron temperature to a range where the transfer of electrical power to the lower vibrational modes of CO is optimum.

Sidney, B. D.↗
NASA NTRS1997

Laboratory Studies of Thermal Energy Charge Transfer of Silicon and Iron Ions in Astrophysical Plasmas

The laser ablation/ion storage facility at the UNLV Physics Department is dedicated to the study of atomic processes in low temperature plasmas. Our current program is directed to the study of charge transfer of multiply charged ions and neutrals that are of importance to astrophysics at energies less than 1 eV (about 10(exp 4) K). Specifically, we measure the charge transfer rate coefficient of ions such as N(2+), Si(3+), Si(3+), with helium and Fe(2+) with molecular and atomic hydrogen. All these ions are found in a variety of astrophysical plasmas. Their electron transfer reactions with neutral atoms can affect the ionization equilibrium of the plasma.

Kwong, Victor H. S.↗
NASA NTRS2002

Solving Problems With SINDA/FLUINT

SINDA/FLUINT, the NASA standard software system for thermohydraulic analysis, provides computational simulation of interacting thermal and fluid effects in designs modeled as heat transfer and fluid flow networks. The product saves time and money by making the user's design process faster and easier, and allowing the user to gain a better understanding of complex systems. The code is completely extensible, allowing the user to choose the features, accuracy and approximation levels, and outputs. Users can also add their own customizations as needed to handle unique design tasks or to automate repetitive tasks. Applications for SINDA/FLUINT include the pharmaceutical, petrochemical, biomedical, electronics, and energy industries. The system has been used to simulate nuclear reactors, windshield wipers, and human windpipes. In the automotive industry, it simulates the transient liquid/vapor flows within air conditioning systems.

Source record↗
NASA NTRSDate not supplied

Transients and Dayside Magnetospheric Interactions

Observations at and deep within the Earth’s dayside magnetosphere provide considerable evidence indicating that the solar wind-magnetosphere interaction is often unsteady. Bursty reconnection resulting in the formation of flux transfer events and transient auroral brightenings is common. Fluctuations in solar wind parameters may trigger some bursts of reconnection, while other bursts may result from intrinsic magnetopause instabilities. Large amplitude solitons often travel along the dayside magnetopause. Deeper within the dayside magnetosphere, quasi-periodic transient compressions energize radiation belt electrons and ring current ions. Most of these perturbations occur behind the quasi-parallel bow shock, indicating that they are driven by density structures generated by kinetic processes within the foreshock. This presentation compares and contrasts the amplitudes and occurrence patterns of density and dynamic pressure perturbations intrinsic to the solar wind with those generated within the foreshock, specifies how they move across the magnetosphere, examines recent global MHD simulation results for their interaction with the bow shock, magnetosheath, and magnetopause. It then outlines new paths toward quantifying the significance of bursty reconnection to the overall interaction, via new imaging and analysis techniques.

D. G. Sibeck↗
NASA NTRS2002

Non-Radiative Shocks in the Cygnus Loop: H2 in HH2 Fluorescence or Collisions?

Far Ultraviolet Spectroscopic Explorer (FUSE) observations at four positions across a faint H-alpha filament in the northern Cygnus Loop were carried out successfully. The O(VI) profiles were measured in the four spectra, and we are in the process of fitting them. We have constructed models for a rippled sheet of emission seen almost edge-on based on non-radiative shock wave models for the time-dependent ionization state of the gas behind the shock. The function that describes the rippled sheet geometry predicts the line-of sight velocity component, and we add thermal broadening for various assumed values of ion-ion and ion-electron equilibration. We then compute the radiative transfer in each of the O(VI) lines along the line of sight. Finally, we multiply by the transmission of the ISM using average O(VI) column densities. So far, it appears that partial thermal equilibration is required. Neither full equilibration nor total lack of equilibration seems to provide a workable model. The HH2 observations have not yet been obtained. FUSE has many targets in this region of the sky. We are hoping to get the observations in the spring if FUSE pointing stability allows.

Raymond, John C.↗
NASA NTRS1975

Theory and experiment of low transitions in CO discharge lasers

A self-consistent model which couples the kinetics of the electrons and heavy particles with the optical and fluid dynamic processes has been employed to identify the various parameters and explain the mechanism responsible for producing low-lying transitions in slow-flowing CO lasers. Both theory and experiment indicate that low-lying transitions can be achieved at low temperatures for low pressures (or low-flow rates) together with high partial pressures of He and N2. The role of N2 has been identified as an additive responsible for reducing the electron temperature to a range where the transfer of electrical power to the lower vibrational modes of CO is optimum.

Sidney, B.↗
NASA NTRS2008

Organic/Inorganic Polymeric Composites for Heat-Transfer Reduction

Organic/inorganic polymeric composite materials have been invented with significant reduction in heat-transfer properties. Measured decreases of 20-50 percent in thermal conductivity versus that of the unmodified polymer matrix have been attained. These novel composite materials also maintain mechanical properties of the unmodified polymer matrix. The present embodiments are applicable, but not limited to: racing applications, aerospace applications, textile industry, electronic applications, military hardware improvements, and even food service industries. One specific application of the polymeric composition is for use in tanks, pipes, valves, structural supports, and components for hot or cold fluid process systems where heat flow through materials is problematic and not desired. With respect to thermal conductivity and physical properties, these materials are superior alternatives to prior composite materials. These materials may prove useful as substitutes for metals in some cryogenic applications. A material of this type can be made from a blend of thermoplastics, elastomers, and appropriate additives and processed on normal polymer processing equipment. The resulting processed organic/inorganic composite can be made into fibers, molded, or otherwise processed into useable articles.

Smith, Trent↗