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At least 199 records · Page 11

Evidence-Based Recommendations for Optimizing Light in Day-to-Day Spaceflight Operations

NASA Behavioral Health and Performance Element (BHP) personnel have previously reported on efforts to transition evidence‐based recommendations for a flexible lighting system on the International Space Station (ISS). Based on these recommendations, beginning in 2016 the ISS will replace the current fluorescent‐based lights with an LED‐based system to optimize visual performance, facilitate circadian alignment, promote sleep, and hasten schedule shifting. Additional efforts related to lighting countermeasures in spaceflight operations have also been underway. As an example, a recent BHP research study led by investigators at Harvard Medical School and Brigham and Women's Hospital, evaluated the acceptability, feasibility, and effectiveness of blue‐enriched light exposure during exercise breaks for flight controllers working the overnight shift in the Mission Control Center (MCC) at NASA Johnson Space Center. This effort, along with published laboratory studies that have demonstrated the effectiveness of appropriately timed light for promoting alertness, served as an impetus for new light options, and educational protocols for flight controllers. In addition, a separate set of guidelines related to the light emitted from electronic devices, were provided to the Astronaut Office this past year. These guidelines were based on an assessment led by NASA's Lighting Environment Test Facility that included measuring the spectral power distribution, irradiance, and radiance of light emitted from ISS‐grade laptops and I‐Pads, as well as Android devices. Evaluations were conducted with and without the use of off‐the‐shelf screen filters as well as a software application that touts minimizing the short‐wave length of the visible light spectrum. This presentation will focus on the transition for operations process related to lighting countermeasures in the MCC, as well as the evidence to support recommendations for optimal use of laptops, I‐Pads, and Android devices during all phases of spaceflight operations.

Whitmire, Alexandra↗

Hidden role of Bi incorporation in nonradiative recombination in methylammonium lead iodide

Bismuth incorporation has been shown to significantly decrease the performance of perovskite solar cells, which has led to the common belief that Bi Pb is a strong nonradiative recombination center in hybrid perovskites. Using rigorous first-principles calculations, we demonstrate that Bi Pb is not an efficient recombination center. However, Bi acts as a donor, and pushes the Fermi level closer to the conduction band; this shift promotes the formation of iodine interstitials, which are the actual nonradiative recombination centers. Here, these insights explain why Bi incorporation is detrimental for the photovoltaic performance. More generally, it draws attention to the detrimental role unintentionally incorporated impurities can play, not by acting as nonradiative recombination centers themselves, but by shifting the Fermi level and thereby promoting the formation of efficiency-killing defects.

36 MATERIALS SCIENCE↗

All-optical reconfiguration of single silicon-vacancy centers in diamond for non-volatile memories

Strain engineering is vital for tuning the optical and spin properties of solid-state color centers, enhancing spin coherence and compensating emission wavelength shift. Here, we develop an all-optical approach to directly modify the local strain of color centers at the nanoscale by migrating the nearby defect. High-power pulsed optical irradiation triggers defect migration, which subsequently leads to the redistribution of the local crystal lattice of the host material. This redistribution alters the strain experienced by nearby color centers. Using silicon-vacancy centers in diamond, we validate this method and demonstrate a ground state splitting enhancement of up to 1.8 THz. Unlike conventional methods, our approach requires no external fields or nanostructure modifications, enabling non-volatile strain control and optical memory functionality across wide temperature ranges. Its local, permanent nature offers a scalable path for enhancing spin coherence in large-scale quantum systems and has potential applications in photonic machine learning.

Nanoscale devices↗

Telemetry Boards Interpret Rocket, Airplane Engine Data

For all the data gathered by the space shuttle while in orbit, NASA engineers are just as concerned about the information it generates on the ground. From the moment the shuttle s wheels touch the runway to the break of its electrical umbilical cord at 0.4 seconds before its next launch, sensors feed streams of data about the status of the vehicle and its various systems to Kennedy Space Center s shuttle crews. Even while the shuttle orbiter is refitted in Kennedy s orbiter processing facility, engineers constantly monitor everything from power levels to the testing of the mechanical arm in the orbiter s payload bay. On the launch pad and up until liftoff, the Launch Control Center, attached to the large Vehicle Assembly Building, screens all of the shuttle s vital data. (Once the shuttle clears its launch tower, this responsibility shifts to Mission Control at Johnson Space Center, with Kennedy in a backup role.) Ground systems for satellite launches also generate significant amounts of data. At Cape Canaveral Air Force Station, across the Banana River from Kennedy s location on Merritt Island, Florida, NASA rockets carrying precious satellite payloads into space flood the Launch Vehicle Data Center with sensor information on temperature, speed, trajectory, and vibration. The remote measurement and transmission of systems data called telemetry is essential to ensuring the safe and successful launch of the Agency s space missions. When a launch is unsuccessful, as it was for this year s Orbiting Carbon Observatory satellite, telemetry data also provides valuable clues as to what went wrong and how to remedy any problems for future attempts. All of this information is streamed from sensors in the form of binary code: strings of ones and zeros. One small company has partnered with NASA to provide technology that renders raw telemetry data intelligible not only for Agency engineers, but also for those in the private sector.

Source record↗

Geographic Shift and Environment Change of U.S. Tornado Activities in a Warming Climate

Even with ever-increasing societal interest in tornado activities engendering catastrophes of loss of life and property damage, the long-term change in the geographic location and environment of tornado activity centers over the last six decades (1954–2018), and its relationship with climate warming in the U.S., is still unknown or not robustly proved scientifically. Utilizing discriminant analysis, we show a statistically significant geographic shift of U.S. tornado activity center (i.e., Tornado Alley) under warming conditions, and we identify five major areas of tornado activity in the new Tornado Alley that were not identified previously. By contrasting warm versus cold years, we demonstrate that the shift of relative warm centers is coupled with the shifts in low pressure and tornado activity centers. The warm and moist air carried by low-level flow from the Gulf of Mexico combined with upward motion acts to fuel convection over the tornado activity centers. Employing composite analyses using high resolution reanalysis data, we further demonstrate that high tornado activities in the U.S. are associated with stronger cyclonic circulation and baroclinicity than low tornado activities, and the high tornado activities are coupled with stronger low-level wind shear, stronger upward motion, and higher convective available potential energy (CAPE) than low tornado activities. The composite differences between high-event and low-event years of tornado activity are identified for the first time in terms of wind shear, upward motion, CAPE, cyclonic circulation and baroclinicity, although some of these environmental variables favorable for tornado development have been discussed in previous studies.

54 ENVIRONMENTAL SCIENCES↗

The Aqua-planet Experiment (APE): Response to Changed Meridional SST Profile

This paper explores the sensitivity of Atmospheric General Circulation Model (AGCM) simulations to changes in the meridional distribution of sea surface temperature (SST). The simulations are for an aqua-planet, a water covered Earth with no land, orography or sea- ice and with specified zonally symmetric SST. Simulations from 14 AGCMs developed for Numerical Weather Prediction and climate applications are compared. Four experiments are performed to study the sensitivity to the meridional SST profile. These profiles range from one in which the SST gradient continues to the equator to one which is flat approaching the equator, all with the same maximum SST at the equator. The zonal mean circulation of all models shows strong sensitivity to latitudinal distribution of SST. The Hadley circulation weakens and shifts poleward as the SST profile flattens in the tropics. One question of interest is the formation of a double versus a single ITCZ. There is a large variation between models of the strength of the ITCZ and where in the SST experiment sequence they transition from a single to double ITCZ. The SST profiles are defined such that as the equatorial SST gradient flattens, the maximum gradient increases and moves poleward. This leads to a weakening of the mid-latitude jet accompanied by a poleward shift of the jet core. Also considered are tropical wave activity and tropical precipitation frequency distributions. The details of each vary greatly between models, both with a given SST and in the response to the change in SST. One additional experiment is included to examine the sensitivity to an off-equatorial SST maximum. The upward branch of the Hadley circulation follows the SST maximum off the equator. The models that form a single precipitation maximum when the maximum SST is on the equator shift the precipitation maximum off equator and keep it centered over the SST maximum. Those that form a double with minimum on the equatorial maximum SST shift the double structure off the equator, keeping the minimum over the maximum SST. In both situations only modest changes appear in the shifted profile of zonal average precipitation. When the upward branch of the Hadley circulation moves into the hemisphere with SST maximum, the zonal average zonal, meridional and vertical winds all indicate that the Hadley cell in the other hemisphere dominates.

AGCM↗

Effect of strain on the reactivity of graphene films

The effect of strain on the adsorption of atomic species (Cl, H, N, and O) on pristine and nitrogen-doped graphene is studied using density functional theory. Expansive strain increases surface reactivity by destabilizing graphene π orbitals, which is similar to the shift in the d-band center observed on stretched metal surfaces. However, compressive strain leads to the formation of nanoripples that strongly bind atomic species at ridge sites, which is fundamentally different from adsorption on compressed metal surfaces. Furthermore, our findings suggest that strain can be used as an effective means of manipulating graphene’s reactivity, which is explicitly shown here for the oxygen reduction reaction.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

An innovative radial gradient material design using hot isostatic pressing for applications in extreme environments

Functionally graded materials (FGMs) are highly advanced continuous or discontinuous structures whose structural and material properties vary along a singular geometric dimension either in the axial or radial direction. Here, the radial gradient FGM design makes for an optimal structural design to incorporate a bi-metallic structure with a copper-based high entropy alloy (Cu-HEA) with good mechanical properties and high irradiation resistance, and Chromium (Cr) with great corrosion resistance. This study focuses on the experimental design of a metal powder loading mechanism to fabricate a bi-metallic radial gradient structure using Cu-HEA and 99.9 % pure Cr metal powders. The powder loading strategy uses custom-designed concentric cylindrical dividers to separate the individual compositions. Two benchtop trial runs were performed for design optimization. The optimized design was then implemented to eventually load the HEA and Cr powders for consolidation via powder metallurgy hot isostatic pressing (PM-HIP). The electron microscopy analysis reveals the successful fabrication of the radial gradient structure with the chemical mapping analysis, demonstrating the gradual composition shift from the HEA at the center to the pure-Cr at the periphery via a three-step gradient.

High Entropy Alloys (HEAs)↗

Understanding the Influence of Urban Form on the Spatial Pattern of Precipitation

Urban areas are known to modify the spatial pattern of precipitation climatology. Existing observational evidence suggests that precipitation can be enhanced downwind of a city. Among the proposed mechanisms, the thermodynamic and aerodynamic processes in the urban lower atmosphere interact with the meteorological conditions and can play a key role in determining the resulting precipitation patterns. In addition, these processes are influenced by urban form, such as the impervious surface extent. This study aims to unravel how different urban forms impact the spatial patterns of precipitation climatology under different meteorological conditions. We use the Multi-Radar Multi-Sensor quantitative precipitation estimation data products and analyze the hourly precipitation maps for 27 selected cities across the continental United States from the years 2015–2021 summer months. Results show that about 80% of the studied cities exhibit a statistically significant downwind enhancement of precipitation. Additionally, we find that the precipitation pattern tends to be more spatially clustered in intensity under higher wind speed; the location of radial precipitation maxima is located closer to the city center under low background winds but shifts downwind under high wind conditions. The magnitude of downwind precipitation enhancement is highly dependent on wind directions and is positively correlated with the city size for the south, southwest, and west directions. This study presents observational evidence through a cross-city analysis that the urban precipitation pattern can be influenced by the urban modification of atmospheric processes, providing insight into the mechanistic link between future urban land-use change and hydroclimates.

54 ENVIRONMENTAL SCIENCES↗

Sharp-tip enhanced catalytic CO oxidation by atomically dispersed Pt 1 /Pt 2 on a raised graphene oxide platform

Revealing structure–activity relationships of graphene-supported atomically dispersed transition metal catalysts is of key importance in catalysis chemistry and materials science. In this work, we report a first-principles theoretical study on O 2 activation and CO oxidation catalyzed by atomically dispersed Pt 1 /Pt 2 anchored on a raised graphene (Gr) platform. The unique sharp-tip structure of the protuberant graphene platform (carbon-tip) can collect extra polarization electrons on the Pt-tip, promoting electron transfer between the catalyst and adsorbates, and greatly enhancing the chemical activity. Higher carbon-tips on defective graphene oxide with a carbon vacancy (Gr-V) produce more polarization electrons, a more localized electric field, and a larger up-shift of the d-orbital center of the Pt-tip, resulting in better catalytic performance. The carbon-tip enhancement reduces the energy barrier for the CO oxidation on Pt 1 O 2 /Gr-V from 1.19 eV to 0.56 eV compared with Pt 1 on planar Gr. In addition, CO poisoning is significantly alleviated, with the CO poisoning rate Γ θ reduced from 2.00 eV to 0.52 eV. Moreover, a linear relationship between the activation barrier and the binding energy of adsorbates is found for various atomically dispersed Pt-tip catalysts on the raised graphene oxide platform. Importantly, the order of catalytic activity is consistent with the carbon-tip enhancement, i.e., Pt 1 O 2 /Gr-V > Pt 2 O 4 /Gr-V > Pt 1 O 2 /Gr > Pt 2 O 4 /Gr. These findings provide important guidance for rational design of atomically dispersed catalysts.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

XMM-Newton and TESS observations of the highly variable polar V496 UMa

We studied the temporal and spectral behavior of V496 UMa from the optical to the X-ray regimes. Methods. We used archival XMM-Newton and TESS observations obtained in 2017 and 2019, respectively, to perform a spectral and timing analysis of the highly variable magnetic CV. Results. The light curves of the TESS and XMM-Newton satellites reveal a double-humped pattern modulated with the periodicity of 91.058467 ± 0.00001 min. V496 UMa displays a two-pole accretion geometry in the high accretion state. X-ray spectra from these regions are composed of thermal plasma radiation and soft blackbody components with almost identical temperatures and a total accretion rate of $\dot{M}$ = 1.4(8) × 10 -11 M ⊙ yr -1 . The X-ray centers of the humps show longitudinal shifts of -18° and 4°, and shifts around photometric phase zero of -172° and -186°, for the main hump and second hump, respectively. The long-term ZTF light curves reveal high and low accretions states. Low-state ZTF and SDSS photometric data are consistent with an 0.8 M ⊙ white dwarf at 10 000 K and a main-sequence donor star with a spectral type of M5.0 at a Gaia determined distance of 758 pc. Conclusions. V496 UMa is a very bright polar in X-rays when it is in the high state. Due to its unusual geometric structure, mass accretion onto the second accretion pole is interrupted occasionally. This discontinuous behavior does not follow a certain pattern in time and has been observed so far only in the high state. The X-ray light curves display clear evidence of an accretion stream at the photometric phase of φ = 0.81, which does not show up in optical light curves. An accurate period was derived using the combined TESS and XMM-Newton data, which differs by 3.8 σ from published results.

79 ASTRONOMY AND ASTROPHYSICS↗

Enhanced low-energy magnetic excitations evidencing the Cu-induced localization in the Fe-based superconductor Fe 0.98 Te 0.5 Se 0.5

Here, we have performed inelastic neutron scattering measurements on optimally doped Fe 0.98 Te 0.5 Se 0.5 and 10% Cu-doped Fe 0.88 Cu 0.1 Te 0.5 Se 0.5 to investigate the substitution effects on the spin excitations in the whole energy range up to 300 meV. It is found that substitution of Cu for Fe enhances the low-energy spin excitations (≤100 meV), especially around the (0.5, 0.5) point, and leaves the high-energy magnetic excitations intact. In contrast to the expectation that Cu with spin 1/2 will dilute the magnetic moments contributed by Fe with a larger spin, we find that the 10% Cu doping enlarges the effective fluctuating moment from 2.85 to 3.13 μB/Fe, although there is no long- or short-range magnetic order around (0.5, 0.5) and (0.5, 0). The presence of enhanced magnetic excitations in the 10% Cu doped sample which is in the insulating state indicates that the magnetic excitations must have some contributions from the local moments, reflecting the dual nature of the magnetism in iron-based superconductors. We attribute the substitution effects to the localization of the itinerant electrons induced by Cu dopants. Furthermore, these results indicate that the Cu doping does not act as electron donor as in a rigid-band shift model, but more as scattering centers that localize the system.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Measurements of mass flow in the transition region and inner corona

A solar rocket experiment launched on June 5, 1979 is described which provides high spectral resolution line profiles across the solar disk. The instrument consists of a small telescope with moderate spatial resolution and a spectrograph with stability and high spectroscopic resolution (about 0.028 A at 600 A). The detector system uses a microchannel plate array to provide 1,024 simultaneous measurements spanning approximately 30 A of the solar spectrum. The spectrograph uses a 3600 l/mm grating, and the spectral range 609-634 A is recorded in second order overlapping 1218-1268 A in first order. The position of the emission lines is determined by a center-of-mass routine and velocity shifts are evident. The qualitative results are in general agreement with the results of Cushman and Rense (1976).

Rottman, G. J.↗

C IV Doppler shifts observed in active region filaments

The Doppler shift properties of 21 active region filaments were studied using C IV Dopplergram data. Most are associated with corridors of weak magnetic field that separate opposite polarity strong fields seen in photospheric magnetograms. A majority of the filaments are relatively blue shifted, although several lie very close to the dividing lines between blue and red shift. Only one filament in the samples is clearly red shifted. A new calibration procedure for Dopplergrams indicates that sizable zero point offsets are often required. The center-to-limb behavior of the resulting absolute Doppler shifts suggests that filament flows are usually quite small. It is possible that they vanish.

Klimchuk, J. A.↗

Observed redshifts in O V and downflows in the solar transition region

Spectrograms from HRTS are used to find an average net redshift of the O V lines at 1218 and 1371 A at all locations extending from disk center to solar limb. The observed shift in O V is compared with measurements of the O IV line at 1401 A and the Si IV line at 1402 A. Large variations in the shift are found along the instrument slit. Blueshifts are also observed with the sites of the largest upflow located in the sunspot umbrae and in a quiet region close to an active region. The present result could put new constraints on numerical models of flows in the solar transition region and will also be of importance for modeling stellar atmospheres. The spatial variation of line-of-sight velocities in the O V line at 1371A and the SI IV line at 1402 A is illustrated.

Brekke, P.↗

A feasibility study of a microgravity enhancement system for Space Station Freedom

The current low frequency microgravity requirements for Space Station Freedom (SSF) call for a level of less than 1 micro-g over 50 percent of all the laboratory racks for continuous periods of 30 days for at least 180 days per year. While this requirement is attainable for some of the laboratory modules for the Permanently Manned Configuration (PMC), it cannot be met for the Man-Tended Configuration (MTC). To improve the microgravity conditions in the laboratory modules, the Microgravity Enhancement System (MESYS) will apply a continuous thrust to SSF, to negate the disturbing gravity gradient and drag forces. The MESYS consists of a sensor, continuous throttle-able thrusters, and a control system. Both a proof mass system and nano-g accelerometer were evaluated for use as the sensor. The net result of the MESYS will be to shift the microgravity contours from the center of mass to a chosen location. Results indicate the MESYS is not feasible for the MTC since it will require 5073 kg of hydrazine fuel and 7660 watts of electrical power for 30 days of operation during average atmospheric conditions. For the PMC, the MESYS is much more practical, since only 4008 kg of fuel and 5640 watts of electrical power will be required for 30 days of operation during average atmospheric conditions.

Diamond, Preston S.↗

A feasibility study of a microgravity enhancement system for Space Station Freedom

The current low frequency microgravity requirements for Space Station Freedom (SSF) call for a level of less than 1 micro-g over 50 percent of all the laboratory racks for continuous periods of 30 days for at least 180 days per year. While this requirement is attainable for some of the laboratory modules for the Permanently Manned Configuration (PMC), it can not be met for the Man-Tended Configuration (MTC). In addition, many experiments would prefer even lower acceleration levels. To improve the microgravity environment, the Microgravity Enhancement System (MESYS) will apply a continuous thrust to SSF, to negate the disturbing gravity gradient and drag forces. The MESYS consists of a sensor, throttle-able thrusters and a control system. Both a proof mass system and accelerometer were evaluated for use as the sensor. The net result of the MESYS will be to shift the microgravity contours from the center of mass to a chosen location. Results indicate the MESYS is not feasible for MTC since it will require 5,073 kg of hydrazine fuel and 7,660 watts of power for 30 days of operation during average atmospheric conditions. For PMC, the MESYS is much more practical since only 4,008 kg of fuel and 5,640 watts of power are required.

Diamond, Preston S.↗

Multiple flow regimes in the Northern Hemisphere winter. I - Methodology and hemispheric regimes. II - Sectorial regimes and preferred transitions

Multivariate pdfs in the phase space of large-scale atmospheric motions are examined in order to identify recurrent and persistent flow patterns. The extent to which intraseasonal variablity can be described and understood in terms of multiple flow regimes is clarified. It is shown that the synoptically intriguing and statistically significant inhomogeneities exhibited by the 2D phase plane on the periphery of the distribution are due to the existence of persistent and recurrent anomaly patterns. It is argued that these inhomgeneities are obscured when PDFs are examined in a smaller-dimensional subspace than dynamically desired. A synoptic characterization of onsets and breaks for the flow regimes is given by compositing. In situ evolutions of anomaly patterns, slow westward shifts of high-latitude anomaly centers, and successive downstream increase of anomaly magnitudes are the typical signatures of such events.

Kimoto, Masahide↗