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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 199 records · Page 11
All sourcesNASA NTRSDOE OSTI
DOE OSTI2026

Dynamic Interfacial Design in Adaptive Hybrid Materials Enables Reversible and Tunable Mechano-Optic Smart Responses

Next-generation polymeric materials are shifting toward adaptive and interactive behaviors of living systems; however, designing materials that can reversibly modulate optical properties under mechanical deformation while maintaining mechanical robustness remains a key challenge. Here, we report a mechanically robust vitrimer-based adaptive hybrid material (AHM) that exhibits a stretch-induced reversible transparency-to-opacity transition, enabled by the integration of dynamic interactions at the polymer–silica nanoparticle interface and controlled nanoparticle self-assembly. The AHM combines boronic ester–functionalized polystyrene-b-poly(ethylene-co-butylene)-b-polystyrene (S-Bpin) with diol-functionalized silica nanoparticles (diol-SiNPs) to form a hybrid network hosting both dynamic boronic ester and hydrogen-bonding interactions. These reversible linkages facilitate controlled nanoparticle self-assembly and enable strain-induced nanoparticle alignment/aggregation. Upon stretching, SiNP-rich domains align and aggregate within the polymer matrix, while local modulus mismatch between stiff aggregated SiNP/borylated-styrene-rich regions and the softer elastomeric midblock induces surface microwrinkle formation. These internal aggregates and surface wrinkles cooperatively enhance light scattering, producing the opaque state under strain. Furthermore, the tailored AHM exhibits high toughness, thermomechanical stability, reprocessability, and programmable shape-memory behavior. This work presents a dynamic interfacial design strategy for mechanically robust, optically reconfigurable, and reusable soft materials for adaptive optics, smart windows, sensing, soft robotics, and circular smart-material platforms.

adaptive hybrid materials↗
NASA NTRSDate not supplied

Spacecraft Window Design From A Thermal Perspective

This paper gives a rudimentary introduction to spacecraft window design from a thermal engineering perspective. Windows have always been integral parts of all of NASA’s flown, crewed spacecraft missions and will continue to be included on future crewed vehicles. They are part of the primary structure and require high structural reliability. Often neglected by non-thermal engineers, there are important thermal impacts to including windows on a spacecraft design. Thermal radiation from the sun, planetary bodies, or other vehicles can enter the vehicle and heat the interior. Windows can also be heat leaks to space during cold operations. Windows may also serve as part of the vehicle Thermal Protection System for entry vehicles. Like all other parts of the spacecraft, windows must be included in thermal models to predict temperatures; the transparency of pane materials and the addition of coatings increase modeling complexity. Testing of windows is also more complex than typical spacecraft structure due to the uniqueness of each pane (depending on material), transmittance, and the challenge of physically measuring window material temperature during testing.

Thermal↗
DOE OSTI2019

Continuous-flow synthesis of thermochromic M-phase VO2 particles via rapid one-step hydrothermal reaction – effect of mixers

VO2 particles are promising materials for thermochromic smart windows that reduce building energy loss. Continuous-flow hydrothermal processes showcase advantages for synthesizing VO2 particles compared with traditional batch reaction systems. Mixers play a crucial role in particle fabrication in continuous-flow systems. In this study, a Center T-Mixer and a Collision Cross-Mixer are developed and implemented in a hot water fluidized suspension reaction (HWFSR) system. The influence of the resident time on the particle phase and size was evaluated, and properties of particles derived from systems equipped with differing mixers were compared. The resulting particles were characterized using techniques of X-ray powder diffraction (XRD) analysis, scanning electron microscopy (SEM), and differential scanning calorimetry (DSC). When compared with the Center T-Mixer, results indicate that the Collision Cross-Mixer has better control regarding the morphology and size distribution of resulting particles while improving the transition temperatures of the as-synthesized materials. HWFSR systems containing novel mixer designs are capable of producing pure M-phase VO2 particles in a single step contrary to the current reactor design that use a second postheat treatment step, and they are capable of synthesizing many other nanoparticle species, especially those requiring high temperature and pressure reaction conditions.

continuous-flow process↗
NASA NTRSDate not supplied

Spacecraft Window Design from a Thermal Perspective

This paper gives a rudimentary introduction to spacecraft window design from a thermal engineering perspective. Windows have always been integral parts of all of NASA’s flown, crewed spacecraft missions and will continue to be included on future crewed vehicles. They are part of the primary structure and require high structural reliability. Often neglected by non-thermal engineers, there are important thermal impacts to including windows on a spacecraft design. Thermal radiation from the sun, planetary bodies, or other vehicles can enter the vehicle and heat the interior. Windows can also be heat leaks to space during cold operations. Windows may also serve as part of the vehicle Thermal Protection System for entry vehicles. Like all other parts of the spacecraft, windows must be included in thermal models to predict temperatures; the transparency of pane materials and the addition of coatings increase modeling complexity. Testing of windows is also more complex than typical spacecraft structure due to the uniqueness of each pane (depending on material), transmittance, and the challenge of physically measuring window material temperature during testing.

Cheyn L Worn↗
DOE OSTI2024

Impurity transport in PISCES-RF

Linear plasma devices (LPD) utilizing a helicon plasma source, a high density light ion source, can generate impurities due to progressive erosion of the radio frequency (RF) transmission window caused by rectified sheath voltage. These source-born impurities can entrain and be transported by the plasma toward a target, affecting plasma-material interaction studies. Earlier work on material testing in Prototype-Materials Plasma Exposure eXperiment at ORNL revealed significant source impurity deposition on downstream targets. However, using a similar RF source, no target impurity deposition is observed in Plasma Interaction Surface Component Experimental Station (PISCES)-RF despite evidence of RF window erosion in the source region, thereby motivating the present work. Experimentally, using various magnetic field configurations upstream of the PISCES-RF plasma source and seeding titanium (Ti) impurities at various axial locations, impurity transport and deposition along the machine axis were investigated. It was found that Ti deposition was localized to the side of the plasma source where the Ti impurity was seeded. In contrast, aluminum (Al) deposition, originating from the sputtering of the helicon window, occurred predominantly upstream of the plasma source, suggesting an asymmetry in the axial transport of eroded RF window material. These observations suggest a stagnation of the parallel plasma flow immediately downstream of the plasma source, with impurity ions remaining unmagnetized near the source upstream. Al deposition in magnetic field-free regions in PISCES-RF indicates that sputtered Al impurities likely remained neutral due to their large ionization mean-free path under PISCES-RF conditions. Plasma modeling and simulation supported this, indicating that Al-neutrals transport toward the helicon source upstream for low electron density cases. It was found that the Larmor radius of the Al ions was greater than the plasma radius towards the source upstream and remained weakly magnetized in PISCES-RF, meaning that plasma source-born impurities are not efficiently entrained in the plasma flow. These findings provide critical insights into impurity transport in helicon plasma-based LPDs.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
NASA NTRS2018

Orion EM-2 TPS Radiometer & Spectrometer

Radiometers and Spectrometers embedded as flight instrumentation in a spacecraft's thermal protection system (TPS) can generate data on shock layer radiation to a spacecraft's surface for high-speed trajectories such as lunar return. Robust and accurate flight measurements of shock layer radiation can validate models and inform TPS selection and sizing, to reduce risk and TPS launch mass. Contamination from soot deposition and ablation products in the boundary layer condensing on a cold sapphire radiometer window or blocking open ports interferes with measurements. This poster describes characterization of the optical properties and performance of relevant materials, components, and contaminated windows, as well as investigation of contamination control strategies for the optics.

Ablation↗
DOE OSTI2020

The Effect of Membrane Casting Irregularities on Initial Fuel Cell Performance

Membrane electrode assemblies (MEA) for polymer electrolyte membrane fuel cells (PEMFC) may possess as-manufactured non-uniformities in any of its constituent components. This article studies casting irregularities located within the PEM to understand their potential impact on MEA initial performance. Membrane material was cast on a lab-scale polymer casting line operating either within or at the boundaries of the process window. The resulting membrane material was either pristine in the former case, or, in the latter case, contained air bubbles, cracks, and other irregularities, ranging in size from about 0.6 to 3 mm. Spatial polarization experiments were conducted using a 121-channel segmented fuel cell system, and thermal imaging was performed subsequently to map hydrogen crossover to spatial performance. While total-cell polarization data was minimally impacted by the irregularities, the spatial diagnostics showed local performance impacts that, in operation over time, could cause degradation in performance or earlier failure of the MEA. Such impacts could lead to these irregularities being classified as defects, i.e., manufacturing variations that should be identified and not included in a fuel cell stack. Classification of irregularities as defects will ultimately assist the industry by contributing to the development of threshold detection limits for in-line quality control diagnostics.

30 DIRECT ENERGY CONVERSION↗
DOE OSTI2015

Optimization of CdTe thin‐film solar cell efficiency using a sputtered, oxygenated CdS window layer

Abstract A major source of loss in cadmium sulfide/cadmium telluride (CdS/CdTe) solar cells results from light absorbed in the CdS window layer, which is not converted to electrical current. This film can be made more transparent by oxygen incorporation during sputter deposition at ambient temperature. Prior to this work, this material has not produced high‐efficiency devices on tin oxide‐coated soda‐lime‐glass substrates used industrially. Numerous devices were fabricated over a variety of process conditions to produce an optimized device. Although the material does not show a consistent increase in band gap with oxygenation, absorption in this layer can be virtually eliminated over the relevant spectrum, leading to an increase in short‐circuit current. Meanwhile, fill factor is maintained, and open‐circuit voltage increases relative to baseline devices with sublimated CdS. The trend of device parameters with oxygenation and thickness is consistent with an increasing conduction band offset at the window/CdTe interface. Optimization considering both initial efficiency and stability resulted in a National Renewable Energy Laboratory verified 15.2%‐efficient cell on 3.2‐mm soda‐lime glass. This window material was shown to be compatible with SnO 2 ‐based transparent conducting oxide and high resistance transparent coated substrates using in‐line compatible processes. Copyright © 2015 John Wiley & Sons, Ltd

Kephart, Jason M.↗
DOE OSTI2024

Low RF Loss DC Conductive Ceramic for High Power Input Coupler Windows for SRF Cavities

Euclid Techlabs, LLC is developing a low RF loss/DC conductive MgTi ceramics for high power input coupler windows for SRF cavities, under DOE SBIR phase II grant DE-SC0017150. JLab was subcontracted to: fabricate two 500 kW capable pre-stressed coaxial windows; provide an RF testing fixture, and test the window with low power and high power RF. This collaboration helped to develop a better material for high power RF windows, with low RF loss and less prone to arcing, with the potential to improve the state of the art high power RF window performance.

36 MATERIALS SCIENCE↗
DOE OSTI2014

Influence of carbon content on the copper-telluride phase formation and on the resistive switching behavior of carbon alloyed Cu-Te conductive bridge random access memory cells

In this paper, we investigate the influence of the carbon content on the Cu-Te phase formation and on the resistive switching behavior in carbon alloyed Cu{sub 0.6}Te{sub 0.4} based conductive bridge random access memory (CBRAM) cells. Carbon alloying of copper-tellurium inhibits the crystallization, while attractive switching behavior is preserved when using the material as Cu-supply layer in CBRAM cells. The phase formation is first investigated in a combinatorial way. With increasing carbon content, an enlargement of the temperature window in which the material stays amorphous was observed. Moreover, if crystalline phases are formed, subsequent phase transformations are inhibited. The electrical switching behavior of memory cells with different carbon contents is then investigated by implementing them in 580 μm diameter dot TiN/Cu{sub 0.6}Te{sub 0.4}-C/Al{sub 2}O{sub 3}/Si memory cells. Reliable switching behavior is observed for carbon contents up to 40 at. %, with a resistive window of more than 2 orders of magnitude, whereas for 50 at. % carbon, a higher current in the off state and only a small resistive window are present after repeated cycling. This degradation can be ascribed to the higher thermal and lower drift contribution to the reset operation due to a lower Cu affinity towards the supply layer, leading cycle-after-cycle to an increasing amount of Cu in the switching layer, which contributes to the current. The thermal diffusion of Cu into Al{sub 2}O{sub 3} under annealing also gives an indication of the Cu affinity of the source layer. Time of flight secondary ion mass spectroscopy was used to investigate this migration depth in Al{sub 2}O{sub 3} before and after annealing, showing a higher Cu, Te, and C migration for high carbon contents.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
NASA NTRS1979

Window Insulation

A highly reflective insulating material developed to protect NASA spacecraft from intense solar radiation is now being used in a commercially-available window-insulating product which offers significant energy savings. Called Nunsun, it is a thin metallized film adhesively bonded to windows of homes, office buildings, schools, industrial plants and other facilities; the film reflects the sun's heat and glare outward, thereby cutting down on energy costs for cooling. Trained dealer personnel can affix the film to windows of any size in minutes (right), converting ordinary glass to heat-reflective mirror glass at a fraction of the cost. Manufactured by National Metallizing, a division of Standard Packaging Corporation, Cranbury, New Jersey, Nunsun is also available in windowshade form.

Source record↗
NASA NTRS2024

SCIFLI HORIS Windowpane Optical Analysis

This NASA Technical Memorandum summarizes windowpane optical analyses for the OSIRIS-REx (Origins, Spectral Interpretation, Resource Identification and Security Regolith Explorer) mission [1] supported by the SCIFLI (Scientifically Calibrated In-Flight Imagery) team [2] at NASA Langley Research Center (NASA LaRC). The SCIFLI team led a NASA multi-center team in characterization of fused silica (FS) and anti-reflective coated (AR-coated) sapphire materials for use as aircraft windowpanes. These materials were needed for the Hypervelocity OSIRIS-REx Reentry Imaging & Spectroscopy (HORIS) mission and were tested to generate performance parameters relevant to the flight environment. Some of the assessed parameters included optical quality, transmittance, reflectance, color balance, birefringence, transmitted wavefront error, wedge, and haziness of the windows. In order to evaluate the material characteristics in a uniform manner, several criteria were held constant. For example, the physical dimensions of the test articles were held constant (i.e., 17-inch diameter aircraft windowpane and 2-inch diameter witness samples). In this way, the comparison of test results from one material specimen to another was invariant with regard to the manner in which the tests were conducted. This also reduced the variability in how the data were reported. As a result, the results shown in this report, including test data generated by NASA can be used for windowpane material evaluation and future material design trades. Window designers can use the data and the testing method along with the testing matrices to efficiently match material performance to their design and mission objectives and requirements. Standardized testing methodologies and data reduction procedures are described in this report. Unless otherwise noted in the data itself, all the windowpane materials were tested in order to characterize their performance for the HORIS mission. One appendix has been included in this report. These include detailed wavefront interferograms of transmitted wavefront error and optical wedge used in the generation of aggregated material performance.

SCIFLI↗
DOE OSTI2018

Morphological behaviour, electronic bond formation and electrochemical performance study of V2O5-polyaniline composite and its application in asymmetric supercapacitor

Highlights: • Interlinked V{sub 2}O{sub 5}-PANI composites are synthesized by chemical polymerization. • V{sub 2}O{sub 5}-PANI exhibits the highest capacitance of 529.56 F g{sup −1} with wide window of 1.6 V. • Correlation between electrochemical performances with IR peak shifts is studied. • Inorganic-organic synergistic effect plays crucial role for wide working window. • Asymmetric supercapacitor exhibits high energy and power in wide potential windows. - Abstract: To meet the demand of high-energy density supercapacitors, development of suitable electrode material with a wide potential window and high specific capacitance is most important. In this report, we have synthesized V{sub 2}O{sub 5}-PANI nanocomposite through in-situ intercalation and polymerization reaction of aniline with V{sub 2}O{sub 5}, which shows a wide potential window as well as high specific capacitance. XRD, SEM and FTIR have been used to characterize the electrode materials. Their electrochemical activity and pseudocapacitive performances were investigated. The correlation between morphology and electrochemical performances were investigated which is a vital way for the selection of electrode materials. Due to the organic-inorganic compatibility, V{sub 2}O{sub 5}-PANI exhibits good electrochemical charge storage in a wide potential window of 1.6 V (ranging between −0.4 V to 1.2 V) with excellent stability of 84.2% capacitance retention after 5000 GCD cycles. Moreover, asymmetric supercapacitor was assembled V{sub 2}O{sub 5}-PANI composite and NiMn{sub 2}O{sub 4} electrodes which yield remarkable energy and power density.

77 NANOSCIENCE AND NANOTECHNOLOGY↗
DOE OSTI2025

The role of sample–window coupling in shock temperature experiments

Radiometric studies of opaque materials under shock compression probe a sample–window interface that may be very different than the bulk state. Subtle experimental details, particularly an initial sample–window gap vs an adhesively bonded stack, have tremendous influence on measured temperature. This work experimentally tests gapped vs bonded targets and theoretically investigates observed differences in the measured temperature. The results indicate that perturbations created by a thin adhesive are smaller than those suggested by a previous work, whereas sample–window gaps alter the measured state more significantly than that previously realized.

Adhesives↗
DOE OSTI2021

Electrochromic Properties of Perovskite NdNiO 3 Thin Films for Smart Windows

Semiconductors with electrically tunable band gaps are of great interest in controlling transparency to electromagnetic radiation. Thin films of perovskite nickelate NdNiO 3 (NNO), a class of correlated oxides, were deposited on single-crystal (LaAlO 3 (LAO)) and polycrystalline (fluorine-doped tin oxide-coated glass (FTO)) substrates by magnetron sputtering, chemical solution deposition (CSD), and atomic layer deposition (ALD). Their electrochromic behaviors were investigated using a three-electrode setup in basic (KOH solution, pH = 12) electrolyte. During bleaching/coloration process, the proton intercalation/deintercalation and simultaneous electron compensation in the NNO lattice under electrical bias led to crossover of the material between the pristine-conducting phase (Ni 3+ ) and the strongly correlated insulating phase (Ni 2+ ), which serves as the working principle for electrochromic (tunable opacity in the visible range) behavior. Cyclic voltammetry (CV) scans demonstrate that NNO films are electrochemically stable in basic solutions for all three film deposition methods explored here. CV scans at varying rates enabled the extraction of diffusion coefficient of protons in thin film NNO, which is similar to 10 –7 cm 2 s –1 among all films studied. Large light transmittance modulation by bleaching and coloration was observed on films grown on both LAO and FTO substrates, suggesting its potential as an electrochromic material candidate for smart windows and optical shutter applications. Here, porous NNO films obtained by chemical solution deposition tend to demonstrate stronger electrochromic activity than dense films grown by sputtering or ALD.

36 MATERIALS SCIENCE↗
NASA NTRS1979

Acoustic response of thin film windows in the environment of an Atlas-Centaur launch

An exhaustive design development study was performed to correlate the survivability of thin film to various parameters. Film material properties, film thicknesses, unsupported window areas, window aspect ratios, film/frame transitions, film reinforcing techniques, and material grain orientations were all considered. Several thin films were tested to acoustical loads which are expected during an Atlas-Centaur launch of the High Energy Astronomy Observatory Satellites (HEAO)

Mastronardi, R.↗
DOE OSTI2019

Phonon-polaritonics: enabling powerful capabilities for infrared photonics

Abstract Here, we review the progress and most recent advances in phonon-polaritonics, an emerging and growing field that has brought about a range of powerful possibilities for mid- to far-infrared (IR) light. These extraordinary capabilities are enabled by the resonant coupling between the impinging light and the vibrations of the material lattice, known as phonon-polaritons (PhPs). These PhPs yield a characteristic optical response in certain materials, occurring within an IR spectral window known as the reststrahlen band. In particular, these materials transition in the reststrahlen band from a high-refractive-index behavior, to a near-perfect metal behavior, to a plasmonic behavior – typical of metals at optical frequencies. When anisotropic they may also possess unconventional photonic constitutive properties thought of as possible only with metamaterials. The recent surge in two-dimensional (2D) material research has also enabled PhP responses with atomically-thin materials. Such vast and extraordinary photonic responses can be utilized for a plethora of unusual effects for IR light. Examples include sub-diffraction surface wave guiding, artificial magnetism, exotic photonic dispersions, thermal emission enhancement, perfect absorption and enhanced near-field heat transfer. Finally, we discuss the tremendous potential impact of these IR functionalities for the advancement of IR sources and sensors, as well as for thermal management and THz-diagnostic imaging.

Foteinopoulou, Stavroula (ORCID:0000000344055209)↗