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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.
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Vibrational and valence aloof beam EELS: A potential tool for nondestructive characterization of nanoparticle surfaces
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Contact-based and spheroidal vibrational modes of a hexagonal monolayer of microspheres on a substrate
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What Can Be Learned from Nuclear Resonance Vibrational Spectroscopy: Vibrational Dynamics and Hemes
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Spatially Offset Femtosecond Stimulated Raman Spectroscopy: Observing Exciton Transport through a Vibrational Lens
To design better molecular electronic devices, we need a strong understanding of how charges or excitons propagate, as many efficiency losses arise during transport. Exciton transport has been difficult to study because excitons tend to be short-lived, have short diffusion lengths, and can easily recombine. Here, we debut spatially offset femtosecond stimulated Raman spectroscopy (SO-FSRS), a three-pulse ultrafast microscopy technique. By offsetting the photoexcitation beam, we can monitor Raman spectral changes as a function of both time and position. We used SO-FSRS on 6,13-bis(triisopropylsilylethynyl) pentacene, a well-studied organic semiconductor used in photovoltaics and field-effect transistors. Furthermore, we demonstrated that the fast exciton and free charge carrier transport axes are identical and observed that exciton transport is less anisotropic by a factor of ~3. SO-FSRS is the first technique that directly tracks molecular structural evolution during exciton transport, which can provide roadmaps for tailor-making molecules for specific electronic devices.
Vibrational Dephasing along the Reaction Coordinate of an Electron Transfer Reaction
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Characterization of starch polymorphic structures using vibrational sum frequency generation (SFG) spectroscopy
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Abnormal Elastic and Vibrational Behaviors of Magnetite at High Pressures
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Probing crystal structure and mesoscale assembly of cellulose microfibrils in plant cell walls, tunicate tests, and bacterial films using vibrational Sum Frequency Generation (SFG) spectroscopy
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Chaotic vibrations of the duffing system with fractional damping
We examined the Duffing system with a fractional damping term. Calculating the basins of attraction, we demonstrate a broad spectrum of non-linear behaviour connected with sensitivity to the initial conditions and chaos. To quantify dynamical response of the system, we propose the statistical 0-1 test as well as the maximal Lyapunov exponent; the application of the latter encounter a few difficulties because of the memory effect due to the fractional derivative. The results are confirmed by bifurcation diagrams, phase portraits, and Poincaré sections.
Erratum: “Stochastic many-body perturbation theory for anharmonic molecular vibrations” [J. Chem. Phys. 141, 084105 (2014)]
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Structural, vibrational, and electronic properties of BaReH 9 under pressure
Here we present a study of the high-pressure behavior of BaReH 9 , a novel hydrogen-rich compound, using optical, Raman, and infrared spectroscopy as well as synchrotron x-ray diffraction. The x-ray diffraction measurements demonstrate that BaReH9 retains its hexagonal structure on room temperature compression up to 40 GPa. Optical absorption shows the absence of a gap closure to 80 GPa. Raman and IR spectra reveal the pressure evolution of a newly observed phonon peak, and large peak broadening with increasing pressure. Lastly, these data constrain the disorder present in the material following the P-T paths explored.
Spectroscopic and first principle DFT+eDMFT study of complex structural, electronic, and vibrational properties of M2Mo3O8 ( M=Fe , Mn) polar magnets
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