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The characteristics of photoelectric detector systems for use at visible-light, ultraviolet, and X-ray wavelengths are briefly reviewed in the context of the needs of the Spacelab solar-physics facilities. Photoelectric array detectors for use at XUV wavelengths between 90 and 1500 A are described, and their use in the ESA Grazing-Incidence Solar Telescope (GRIST) facility is discussed.
An examination of the materials concerns for a variety of spacecraft components shows that long-term stability within the space environments is a major issue in the design of large space antenna systems. This survey paper will review some of the more recent work on the effect of space environment on (1) thin films, (2) structural composites, and (3) thermal control materials. Degradation in thermal-mechanical and optical properties associated with atmospheric and trapped particles and ultraviolet light will be highlighted. Finally, the dimensional instability associated with microcracking during thermal cycling will be examined and a methodology for estimating thermal fatigue effects from results of mechanical fatigue tests will be presented.
Compact Luneburg-type lenses of rectangular outline as viewed from above have been made by thermal evaporation of As2S3 glass onto single-mode LiNbO3:Ti waveguides through suitably shaped masks and subsequent exposure of the glass to ultraviolet light. The best lenses had speeds of f/5.5 at an aperture of 10 mm and focal spots at reduced aperture about 1.2 times the diffraction-limited size. These lenses have a field of view of at least 25 degrees inside the waveguide.
Attention is called to the undesirable effects (poor ultraviolet light stability and blooming) sometimes introduced by brominated flame retarders. A brominated polymeric additive (BPA) with little or none of these undesirable side effects is compared with decabromobiphenyl oxide (DBBPO). The additive bears the product name F-2300. It is found to be more easily dispersed than DBBPO. The F-2300 is as effective as the DBBPO in the oxygen index test. The improved efficiency of the F-2300 may be explained by its better dispersion in polybutylene terephthalate (PBT). Glass-filled PBT containing F-2300 is found to be more resistant to UV degradation than DBBPO-containing formulas. Formulations with F-2300 therefore have a longer useful outdoor life. F-2300 is a diglycidyl-type polymer containing 50 percent aromatically bound bromine. Its melting point is 112 C, and it is stable up to 372 C. It is pointed out that since its melts at a relatively low temperature, it can be introduced into the formulation as a large agglomerate and still be dispersed evenly throughout the polymer.
The results of efforts to produce a nonsilver metallization system for silicon photovoltaic cells are given. The system uses a metallization system based on molybdenum, tin, and titanium hydride. The initial work in this system was done using the MIDFILM process. The MIDFILM process attains a line resolution comparable to photoresist methods with a process related to screen printing. The surface to be processed is first coated with a thin layer of photopolymer material. Upon exposure to ultraviolet light through a suitable mask, the polymer in the non-pattern area crosslinks and becomes hard. The unexposed pattern areas remain tacky. The conductor material is then applied in the form of a dry mixture of metal which adheres to the tacky pattern area. The assemblage is then fired to ash the photopolymer and sinter the conductor powder.
Silicone coatings applied to polyimide sheeting for variety of space-related applications. Coatings intended to protect flexible substrates of solar-cell blankets from degradation by oxygen atoms, electrons, plasmas, and ultraviolet light in low Earth orbit and outer space. Since coatings are flexible, generally useful in forming flexible laminates or protective layers on polyimide-sheet products.
A description of the Galileo/Institute for Astronomy charge-coupled device (CCD) imaging system and its initial operation has been presented previously. Originally designed to operate a 500 x 500 backside illuminated three-phase CCD, the system has been modified to allow use of either the 500 x 500 sensor or the TI 800 x 800 virtual phase CCD. The modifications for the operation of the virtual phase CCD and current system performance with each type of sensor are discussed. A description is given of the implementation of various techniques discovered at the Jet Propulsion Laboratory that improve imager performance. These techniques include tri-level clocking of the virtual phase CCD to eliminate spurious charge generation in the serial register, the use of ultraviolet light flood with the backside thinned 500 x 500 three-phase device to dramatically improve the quantum efficiency in the blue, and the practical elimination of deferred charge in the three-phase device. Results of astronomical observations with each sensor are presented.
One aspect of the study of Titan's atmosphere is the elucidation of the chemical and physical nature of the aerosols. In order to facilitate this, a program to produce laboratory synthesized model materials for Titan's aerosol and to study their chemical and physical properties is now in progress. Various processes, including electric discharge, photolysis by ultraviolet light, and irradiation by energetic particles, will be used to produce the materials. A first set of experiments where a nominal Titan mixture (97%N2, 3% CH4, 0.2% H2) was subjected to pulsed high temperature shocks yielded a reddish brown waxy solid. This material was subjected to pyrolysis/gas chromatography, a technique that has been proposed as a method for analysis of the Titan aerosols. Preliminary results show the material to consist of simple hydrocarbons but little else, at least up to temperatures of 600 C. Since the material was colored, compounds other than those mentioned above must be present.
Since the prebiotic atmosphere was anaerobic, if not reducing, a useful function of primordial photosynthesis would have been to photooxidize reduced substrates such as Fe(+2), S(-2) or reduced organic molecules and to emit hydrogen. Experiments have shown that the early biogenic pigments uroporphyrin and coproporphyrin do photooxidize organic compounds and emit hydrogen in the presence of a platinum catalyst. These experiments were carried out in dilute aqueous solution near neutral pH under anaerobic atmosphere, and quantum yields near 10-2 were obtained. Thus relevant prebiotic conditions were maintained. Rather then to further optimize conditions, attempts were made to replace the platinum catalyst by a more prebiotically suitable catalyst. Trials with an Fe4S4(SR)4 cluster, in analogy to the present hydrogenase and nitrogenase, were not successful. However, experiments using cobalt complexes to catalyze the formation of hydrogen are promising. In analogy with biological photosynthetic systems which group pigments, electron transfer molecules and enzymes in clusters for efficiency, it was found that binding the biogenic porphyrins to the polyvinyl alcohol used to support the platinum catalyst did increase the quantum yield of the reaction. It was also found that ultraviolet light can serve to photo-oxidize porphyrinogens to porphyrins under anaerobic conditions. Thus the formation of the colorless porphyriogens by the extraordinarily simple biosynthetic pathway would not be a problem because of the prevalence of UV light in the prebiotic, anoxic atmosphere.
The IUE contribution to studies of galactic novae in quiescence and in outburst are reviewed. A class of novae in which the outburst occurs on an ONeMg white dwarf was identified. Ejected masses, elemental abundances, and ultraviolet light curves for a wide variety of nova outbursts were determined.
Drops of ultraviolet-activated dyes encapsulated in liquid films reveal flow patterns. Method based on visualization material composed of polyaphrons containing photochromic dye. Polyaphrons are droplets of organic liquid encapsulated in thin layer of another liquid, which holds droplets stably by surface tension. Photochromic dye within a polyaphron acquires color temporarily after exposure to strong ultraviolet light.
Experimental containerless process combines two established techniques to make variety of polymeric microspheres. In single step, electrostatically-levitated monomer droplets polymerized by ultraviolet light. Faster than multiple-step emulsion polymerization process used to make microspheres. Droplets suspended in cylindrical quadrupole electrostatic levitator. Alternating electrostatic field produces dynamic potential along axis. Process enables tailoring of microspheres for medical, scientific, and industrial applications.
Surfaces to be bonded tested for cleanliness. Equipment includes commercial photoelectron-emission sensor. Inspected surface irradiated with ultraviolet photons from source in sensor head while anode in sensor head collects photoelectrons ejected from surface by absorbed photons. If intensity and spectrum of ultraviolet light and distance between sensor and surface held constant, then photocurrent varies according to amount and type of contamination.
The labelled-release and the gas-exchange experiments of the 1976 Mars Viking biology experiment program detected, respectively, C-14 labelled gases and O2 gas. A chemical model is proposed here for these experiments in which the reactants are an inorganic nitrate salt which has been partly photolyzed by ultraviolet light and a sparingly soluble metal carbonate such as calcite. The model reproduces the main effects seen, indicating that nitrates are present in the Martian regolith as well as calcite (or some other carbonate with similar solubility).
Usability extended to different environments. Application of thin film of iridium to back surface of back-surface-illuminated charge-coupled device expected to increase and stabilize quantum efficiency at wavelengths less than 4,500 Angstrom. Enhances quantum efficiency according to principle discussed in "Metal Film Increases CCD Output" (NPO-16815). Does not react with hydrogen, so device need not be kept in oxygen: Advantage where high absorption of ultraviolet light by oxygen undesirable; for example, when device used to make astronomical observations from high altitudes.
Airborne photometer measures absorption of ultraviolet. Automatically measures ozone concentrations in atmosphere to accuracy within 10 parts per billion. Air collected outside airplane enters photometer by way of transfer valve. Pressure and temperature of air measured simultaneously with transmissivity of air to ultraviolet light from lamp. Instrument has mass of 20.5 kg and fits in aluminum box measuring 78 by 58 by 25 cm. Compact, lightweight, low-power instrument developed for use on high-altitude research airplane.
Quality of air in laboratory or industrial ventilation airstream enhanced by proposed technique. Source of ultraviolet light placed in airstream to degrade fumes photochemically. If fumes acceptable in degraded form, no further processing needed.
Proposed computerized video system processes images of fluorescent dyes absorbed in flaws in welds. Video camera, held by operator or by remote manipulator, views weld illuminated by visible white and ultraviolet light. Images of penetrating dye in cracks and voids in weld joint appear on video monitor. Fluorescent features enhanced by software to facilitate identification of true flaws and record important data.