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At least 199 records · Page 11

On mobile element transport in heated Abee

Abee chondrite samples were heated at 700 C for one week at 0.00001 to 0.001 atm Ne or at 0.00001 atm H2. Samples heated in Ne showed greater loss of Bi and Se and greater retention of Zn than those heated in H2. An inverse relationship between Zn retention and ambient Ne pressure was found. Seven trace elements (Ag, Co, Cs, Ga, In, Te, and Tl) were retained or lost to the same extent regardless of the heating conditions. Variations in the apparent activation energy for C above and below 700 C suggest that diffusive loss from different hosts and/or different mobile transport processes over the temperature range may have been in effect.

Ikramuddin, M.↗

Meteoritic material in lunar highland samples from the Apollo 11 and 12 sites

Radiochemical neutron activation analyses for Ag, Au, Bi, Br, Cd, Cs, Ge, In, Ir, Ni, Os, Pd, Rb, Re, Sb, Te, Tl, U and Zn were carried out on 11 samples from the Apollo 11 and 12 sites (two samples of rock 12013, one granitic and one KREEPy; 4 KREEP fragments from 2-4 mm soil 12033,2; 4 anorthositic fragments from 1-3 mm soil 10085,104; 1 sample of 'Luny' rock-felsite-KREEP breccia 12013 10085,31 LR-1). Most Apollo 12 samples were found to have an Imbrium meteoritic component; others, typified by the Luny breccia, apparently contain a new meteoritic component of low Re content. Components of higher Ir/Au ratio (3L, 5L and 7) were found in Apollo 11 anorthositic samples; the fact that their enrichment in meteoritic siderophiles parallels that of Fe, Mg, REE and other KREEP elements is consistent with progressive contamination of an anorthositic crust. The Luny rock was tentatively classified Group 2, supporting the assignment of this group to Serenitatis.

Janssens, M.-J.↗

Isotopic anomalies of noble gases in meteorites and their origins. IV - C3 /Ornans/ carbonaceous chondrites

The C3O chondrites Kainsaz, Lance, and Ornans were studied by an acid dissolution technique to characterize the noble gas components in 3 mineral fractions: HF, HCl-solubles, chromite and carbon, and 'phase Q', a trace mineral containing Ar, Kr, Xe. For all fractions, gas contents decline in the order Kainsaz, Lance, Ornans; this trend parallels volatile contents but not heterogeneity of olivine composition or degree of metamorphism, and reflects progressively higher condensation temperature from the solar nebula. The Ar/Xe ratios and compositions of the three mineral fractions are discussed, and it is concluded that in all primitive chondrites the amount and the chemical separability of CCFXe parallel the abundance of primordial noble gases and other volatiles, such as C, N, Tl, Bi, and In. The close correlation of CCFXe with properties of local origin, such as volatile content and petrologic type, is more consistent with a local than with an extrasolar origin of the component.

Alaerts, L.↗

On volatile element trends in gas-rich meteorites

Study of 10 volatile elements (and non-volatile Co) in co-existing light and dark portions of 6 gas-rich chondrites indicates patterns of distinct but non-uniform enrichment of volatile elements. Only Cs is enriched in all samples; Bi and Tl enrichments covary. The observed enrichments are inconsistent with prior suggestions of admixture of C1 or C2 chondritic matter, whether pristine or partly devolatilized, but suggest that both light and dark portions of each chondrite represents a compositionally more extended sampling of parental nebular material than hitherto known.

Bart, G.↗

On the chemical composition of L-chondrites

Radiochemical neutron activation analysis of Ag, As, Au, Bi, Co, Cs, Ga, In, Rb, Sb, Te, Tl, and Zn and major element data in 14 L4-6 and 3 LL5 chondrites indicates that the L group is unusually variable and may represent at least 2 subgroups differing in formation history. Chemical trends in the S/Fe rich subgroup support textural evidence indicating late loss of a shock formed Fe-Ni-S melt; the S/Fe poor subgroup seemingly reflects nebular fractionation only. Highly mobile In and Zn apparently reflect shock induced loss from L chondrites. However, contrasting chemical trends in several L chondrite sample sets indicate that these meteorites constitute a more irregular sampling of, or more heterogeneous parent material than do carbonaceous or enstatite chondrites. Data for 15 chondrites suggest higher formation temperatures and/or degrees of shock than for LL5 chondrites.

Neal, C. W.↗

Observations of Cygnus X-3 above 50 keV

Cygnus X-3 was observed in the energy range 50-400 keV using a balloon-borne, actively collimated, NaI(Tl) scintillation detector. The observation was made from phase 0.45-0.91 of the 4.8 hour period. The photon number spectrum was well represented by a power law with index -2.2. The flux increased throughout the observation, consistent with a highly asymmetric light curve with a peak near phase 0.9.

Meegan, C. A.↗

Breccias 73215 and 73255 - Siderophile and volatile trace elements

Fifteen siderophile and volatile trace elements (Os, Re, Ir, Pd, Ni, Au, Sb, Ge, Se, Ag, In, Zn, Cd, Bi, Tl) and U were determined by radiochemical neutron activation analysis in a spheroidal aphanitic clast and a clast of coarse-grained anorthositic gabbro from breccia 73215 and in three types of aphanite and two clasts of fine-grained anorthositic gabbro from breccia 73255. In common with most Apollo 17 fragment-laden melt rocks, the aphanites from 73215 and 73255 predominantly contain a Group 2 meteoritic component, which is apparently derived from the Serenitatis impact. All aphanitic lithologies contain the same meteoritic component, and are probably cogenetic. The clasts of fine-grained anorthositic gabbro contain substantial amounts (2% to 6% Cl equivalent based on Au) of a pre-Serenitatis Group 3 component. The clast of coarse-grained anorthositic gabbro is low in siderophile elements (0.4% Cl equivalent), and the meteoritic component (Group 5) is not well-defined. A strong correlation exists between Ir and Au in both the aphanites and the anorthositic gabbro clasts, which argues against the breccias 73215 and 73255 being open systems for Au

Morgan, J. W.↗

Trace element contents of selected Antarctic meteorites. I - Weathering effects and ALH A77005, A77257, A77278 and A 77299

Data is examined for volatile/mobile Ag, As, Au, Bi, Cd, Co, Cs, Cu, Ga, In, Rb, Sb, Se, Te, Tl and Zn in exterior and/or interior samples of four Antarctic meteorites from the Allan Hills (ALH): A77005 (unique achondrite); A77257 (ureilite); A77278 (L3); A77299 (H3). Exterior samples reflect contamination and/or leaching by weathering but trace element (ppm-ppt) contents in interior samples seem reasonable for representatives of these rare meteoritic types. The A77005 achondrite is shown to be related to shergottites; other samples extend compositional ranges previously known for their groups or types. With suitable precautions, Antarctic meteorite finds yield trace element data as reliable as those obtained from previously known falls.

Biswas, S.↗

Thermal metamorphism of primitive meteorites. XI - The enstatite meteorites: Origin and evolution of a parent body

The neutron activation data for Ag, As, Bi, Cd, Co, Cs, Cu, Ga, In, Rb, Se, Te, Tl, and Zn were obtained in samples of Abee heated to 1000-1400 C at low pressures. In addition, these elements were reported in nine enstatite achondrites and in the silicate part of the Mt. Egerton stony-iron. The data show trace element losses above 1000 C by diffusion-controlled processes with apparent activation energies of 8 to 55 kcal/mol; these data together with abundances of aubrites, Mt. Egerton, and E4-6 chondrites, and isotopic results link all enstatite meteorites to a common parent body. The data also indicate that aubrites and the Mt. Egerton material reflect fractional crystallization of a magma produced from enstatite chondrite-like parent material (E6) and the late introduction of chalcophiles and mobile elements transported by an FeS-Fe eutectic from an E4-6 region undergoing open-system metamorphism.

Biswas, S.↗

Chemical studies of L-chondrites. I - A study of possible chemical sub-groups

Radiochemical neutron activation analysis of Ag, As, Au, Bi, Co, Cs, Ga, In, Rb, Sb, Te, Tl and Zn and major element data in 14 L4-6 and 3 LL5 chondrites indicates that the L-group is unusually variable and may represent at least 2 sub-groups differing in formation history. Chemical trends in the S/Fe-rich sub-group support textural evidence indicating late loss of a shock-formed Fe-Ni-S melt; the S/Fe-poor sub-group seemingly reflects nebular fractionation only. Highly mobile In and Zn apparently reflect shock-induced loss from L-chondrites. Data for L5 chondrites suggest higher formation temperatures and/or degrees of shock than for LL5 chondrites.

Neal, C. W.↗

Composition of the earth's upper mantle. I - Siderophile trace elements in ultramafic nodules

The considered investigation is concerned with a reexamination of the question of the distribution of siderophile elements in the earth's upper mantle, taking into account a more unified data base which is now available. A comprehensive suite of ultramafic inclusions was collected as part of the Basaltic Volcanism Study Project and has been analyzed by instrument neutron activation analysis for major, minor, and some lithophile trace elements. In addition, 18 of these rocks and the important sheared garnet lherzolite PHN 1611 have been analyzed by means of radiochemical neutron activation analysis for 7 siderophile elements (Au, Ge, Ir, Ni, Os, Pd, and Re) and 9 volatile elements (Ag, Bi, Cd, In, Sb, Se, Te, Tl, and Zn). The siderophile element data reveal interesting inter-element correlations, which were not apparent from the compiled abundance tables of Ringwood and Kesson (1976) and Chou (1978).

Morgan, J. W.↗

Flaw growth of 7075, 7475, 7050 and 7049 aluminum alloy plate in stress corrosion environments: 4-year marine atmosphere results

After nearly 53 months of exposure to marine atmosphere, crack growth in SL DCB specimens from 7075, 7475, 7050, and 7049-T7X plate has slowed to the arbitrary 10 to the -10 power m/sec used to define threshold stress intensity. Because some specimens appear to be approaching crack arrest, the importance of self-loading from corrosion product wedging as a significant driving force for crack propagation in overaged materials is questioned. Crack length-time data were analyzed using a computer curve fitting program which minimized the effects of normal data scatter, and provided a clearer picture of material performance. Precracked specimen data are supported by the results of smooth specimen tests. Transgranular stress corrosion cracking was observed in TL DCB specimens from all four alloys. This process is extremely slow and is characterized by a striated surface morphology.

Hasse, K. R.↗

Composition of the earth's upper mantle. II - Volatile trace elements in ultramafic xenoliths

Radiochemical neutron activation analysis was used to determine the nine volatile elements Ag, Bi, Cd, In, Sb, Se, Te, Tl, and Zn in 19 ultramafic rocks, consisting mainly of spinel and garnet lherzolites. A sheared garnet lherzolite, PHN 1611, may approximate undepleted mantle material and tends to have a higher volatile element content than the depleted mantle material represented by spinel lherzolites. Comparisons of continental basalts with PHN 1611 and of oceanic ridge basalts with spinel lherzolites show similar basalt: source material partition factors for eight of the nine volatile elements, Sb being the exception. The strong depletion of Te and Se in the mantle, relative to lithophile elements of similar volatility, suggests that 97% of the earth's S, Se and Te may be in the outer core.

Morgan, J. W.↗

Observations of a weak gamma ray burst, A0535 plus 26, NP0532 and solar flare events by a balloon-borne detector array

Observations of a cosmic gamma ray burst of about 10 to the -6 erg/sq cm, pulsed emission profiles of A0535 plus 26 and NP0532, and two solar flare events are reported for several energy intervals in 45-500 keV. The measurements were made with a NaI (Tl) detector array flown on a balloon to 4 g/sq cm residual atmosphere from Palestine, Texas Oct. 6-8, 1980 for 28 hours. The detector is a prototype of the Burst and Transient Source Experiment to be flown on the Gamma Ray Observatory.

Wilson, R. B.↗

Low-gravity experiments on Liquid Phase Miscibility Gap (LPMG) alloys: Materials Experiments Assembly (MEA)

Space shuttle experiments which study the massive separation which occurred during sounding rocket Al-In alloy tests are described. The gradient cool experiment studies surface tension driven droplet migration and particle pushing in an LPMG alloy. Isothermal experiments on the Te-Tl alloys test the hypothesis that LPMG systems with low surface energies produce relatively fine, and uniform emulsions and dispersions. It also examines the effect of droplet concentration on phase separation kinetics. Isothermal plunger experiments on Al-In alloys determine whether surface tension driven convection currents originating at a free surface contribute to massive separation. They ascertain whether In-rich droplets migrate under the action of a temperature gradient when they are not influenced by the crucible walls.

Gelles, S. H.↗

Observations of a gamma-ray burst and other sources with a large-area, balloon-borne detector

Observations of a weak cosmic gamma ray burst of integrated intensity 2 x 10 to the -6th erg/sq cm, two solar flare events, and pulsed emission profiles of A0535+26 and NP0532 are reported for several energy intervals in the energy range from 45 to 520 keV. The measurements were made with a NaI(Tl) detector array flown on a balloon to 4 g/sq cm residual atmosphere from Palestine, Texas, on October 6-8, 1980, for 28 hours. The detector is a prototype of the Burst and Transient Source Experiment (BATSE) to be flown on the Gamma-Ray Observatory (GRO).

Wilson, R. B.↗

Nuclear Science Symposium, 29th, and Symposium on Nuclear Power, 14th, Washington, DC, October 20-22, 1982, Proceedings

High-energy radiation detectors suitable for balloon-borne or space-based radiation event studies are described. The employment of NaI(Tl) scintillator bars for gamma ray detection is outlined, and the development of a fluorescent gated gas-filled scintillation proportional counter is reported. A high throughput nondispersive hard X ray spectrograph with angular resolution for cosmic bursts, transients, and sources has been constructed. Features of a sealed high pressure xenon filled imaging proportional counter with a 30 sq cm sensitive area are explored. Finally, the various radiation effects on electronic circuitry in a space environment are defined, and an MOS dosimeter for assaying the cumulative radiation flux in a spacecraft due to ambient conditions is characterized.

Davis, W. D.↗

Gamma ray detection with long NaI/Tl/ scintillator bars

Test measurements with a prototype NaI(Tl) scintillator for energy, position, and timing measurements in gamma ray astronomy are reported. The scintillator bar is 100 x 5 x 5 cu cm in size, and allows detection of the arrival times and pulse heights of signals from two photomultiplier tubes, one at each end of the bar. Data is gathered on the energy loss, linear position, and time-of-flight of gamma ray interactions within the bar over an energy range of 0.5-20 MeV. A mean attenuation coefficient of 0.015/cm has been determined, as have a FWHM resolution of 5 cm, 9.4%, and 10 nsec at an energy of 0.662 MeV. At 1.25 MeV the timing resolution was 6 nsec, and at 6.13 MeV the spatial resolution was 2.2 cm. The instrument is a prototype of a Compton scatter telescope being constructed for two balloon flights, one each in the Northern and Southern Hemispheres, in 1984.

Zych, A. D.↗