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At least 199 records · Page 11
All sourcesNASA NTRSDOE OSTI
NASA NTRS2013

Detection of Propene in Titan's Stratosphere

The Voyager 1 flyby of Titan in 1980 gave a first glimpse of the chemical complexity of Titan's atmosphere, detecting many new molecules with the infrared interferometer spectrometer (IRIS). These included propane (C3H8) and propyne (CH3C2H), while the intermediate-sized C3Hx hydrocarbon (C3H6) was curiously absent. Using spectra from the Composite Infrared Spectrometer on Cassini, we show the first positive detection of propene (C3H6) in Titan's stratosphere (5(sigma) significance), finally filling the three-decade gap in the chemical sequence. We retrieve a vertical abundance profile from 100-250 km, that varies slowly with altitude from 2.0 +/- 0.8 ppbv at 125 km, to4.6 +/- 1.5 ppbv at 200 km. The abundance of C3H6 is less than both C3H8 and CH3C2H, and we remark on an emerging paradigm in Titans hydrocarbon abundances whereby alkanes greater than alkynes greater than alkenes within the C2Hx and C3Hx chemical families in the lower stratosphere. More generally, there appears to be much greater ubiquity and relative abundance of triple-bonded species than double-bonded, likely due to the greater resistance of triple bondsto photolysis and chemical attack.

Titan↗
NASA NTRSDate not supplied

Compositional Analysis of Titan’s Atmosphere Using Spitzer Infrared Spectrograph Data

We present, for the first time, infrared spectra from the Spitzer Space Telescope’s Infrared Spectrograph (IRS) (2004-2008) of Titan in both the short wavelength-low resolution(SL, R=60~127,5.13-14.29 μm) and short wavelength-high resolution channels (SH, R=600, 9.89-19.51 μm) showing the emissions of CH4, C2H4, C2H2, C2H6, HCN, CO2, HC3N, C3H4, C4H2, and C3H8. Spitzer IRS data has been used to measure atmospheric composition of various Solar System bodies, including Neptune [1] and Uranus [2],[3]. Although Spitzer took multiple dedicated observations of Titan, none of the results have been modeled before. We conduct our own investigation of these datasets and search for new results. We retrieve temperature and gas composition profiles and compare the results obtained for Titan to those of the Cassini Composite Infrared Spectrometer (CIRS) and the Infrared Space Observatory Short Wavelength Spectrometer [4], and comment on the effect of spectral resolution on retrieved information content. We conclude by recommending gaps in current spectroscopic knowledge of molecular bands that could be addressed by theoretical and laboratory study to aid future astronomical studies of Titan, for example the James Webb Space Telescope (JWST) and the Stratospheric Observatory for Infrared Astronomy (SOFIA) Acknowledgments: Data analyzed in this project is public available online on the Spitzer Heritage Archive (sha.ipac.caltech.edu). This research has made use of the NASA/IPAC Infrared Science Archive, which is funded by the National Aeronautics and Space Administration and operated by the California Institute of Technology.

Titan↗
NASA NTRS2022

A Numerical Study of the Liquid Motion in Titan’s Subsurface Ocean

An ocean filled with liquid water lies beneath the icy surface of several Jovian and Saturnian moons. In such an ocean, the currents are driven by various phenomena such as the tidal forcing, the deformation of the ice shell lying at its top, the temperature gradient resulting from the surface and bottom heat fluxes…The flow induced by the first two forcings can be modelled by means of a 2D depth-averaged model, while the third one generates horizontal and vertical density variations whose effects can only be captured by a 3D baroclinic model. We study the tides of Titan’s subsurface ocean and the impact of the ice shell on the liquid motion by means of the Second-generation Louvain-la-Neuve Ice–ocean Model, SLIM (https://www.climate.be/slim). The impact of the ice shell lying at the top of the ocean is modelled by a surface friction term and surface pressure terms. The latter are a function of the difference between the ocean elevation and the vertical displacement of the shell and the time derivative of this difference. Because of Titan’s appreciable obliquity (0.306°), the tidal motion expected (and found) is similar to the Europa tidal scenario described by Tyler (2008): the surface elevation consists of two bulges rotating around Titan and the associated depth-averaged velocity field consists of two gyres, separated by an area of high speed flow, whose centre follows a sinusoidal path centred on the equator. The ice shell damps the surface motion, thus slowing down the flow, without significantly modifying the spatial patterns of these fields. The depth of the ocean and the mechanical characteristics of the ice shell being poorly constrained, a sensitivity analysis is conducted. The depth-averaged flow slows down when the depth is increased and a lag appears in the tidal phase but the tidal range remains similar. The ice shell mechanical characteristics influences both the elevation and depth-averaged velocity fields in terms of magnitude but does not modify the spatial patterns of these fields. The influence of the surface heat flux is studied by means of the 3D baroclinic version of SLIM. The heat flux derived from Titan’s topography by Kvorka et al. (2018) is used as surface boundary condition for the temperature equation while a uniform bottom heat flux is implemented. Its value is computed assuming that the heat budget of the ocean is at equilibrium. These boundary conditions cause density variations, which impact the hydrodynamics of the ocean. While the flow velocity induced by these variations is two orders of magnitude smaller than the tidal flow, its orientation is time-independent, hence impacting the orientation of the velocity field. Although the variations of ocean surface elevation and speed with respect to the shell mechanical properties can be larger than those induced by the surface heat flux, taking into account the latter results in large variations of the velocity field global patterns, which was not observed when modifying the shell mechanical properties. Future studies should therefore focus on modelling the surface and bottom heat fluxes while uncertainties about the mechanical characteristics of the shell can be tolerated.

Titan↗
NASA NTRSDate not supplied

THUNDER: A New Frontiers-Class Titan Orbiter Mission Concept From the NASA JPL Planetary Science Summer School

Titan’s Hydrocarbons: Uncovering New Dimensions of Evolutionary pRocesses (THUNDER) is a dedicated geology and geophysics mission to trace Titan’s hydrocarbons from the inside out, assessing whether hydrocarbons move through Titan’s water ice bedrock to cycle from the subsurface ocean to the atmosphere. This Titan orbiter will use surface mapping (via radar and spectrometry) and gravity science to advance geophysical expertise for Saturn’s most Earth-like moon.

mission concept↗
NASA NTRSDate not supplied

Aerothermal Analysis of the Dragonfly Titan Entry

Dragonfly is an upcoming NASA New Frontiers mission that will send a rotorcraft lander to Saturn’s moon Titan [1]. This will be the first spacecraft to land on Titan since the Huygens probe’s descent in 2005 and only the second spacecraft overall to enter Titan’s atmosphere. With its dense N 2 atmosphere containing trace amounts of CH 4 , Titan provides a unique entry environment with an unusually long entry sequence and significant radiant heating at relatively low velocities. To address these challenges, the Dragonfly entry capsule design is informed by state-of-the-art aerothermodynamic analysis tools and methodologies that will be laid out in this poster.

EDL↗
DOE OSTI2025

The Photochemistry of Amino Acids Produced on the Polar Cryovolcanic Regions of Titan

The cryovolcanic regions of Titan offer transient opportunities for prebiotic molecules to exist in water–ammonia solutions on the surface of the Saturnian moon. The upcoming NASA’s Dragonfly mission will search for high nitrogen concentrations and amino acids on Titan’s equatorial terrains. Cryovolcanic features, however, are most common on the polar regions. To mitigate the distance, bubble bursting may encapsulate the prebiotic molecules into aerosols, which Titan’s Hadley circulation would subsequently transport to the equator. Here we investigate whether alanine and glycine survive this meridional journey. Despite the unconstrained meridional wind velocities, our results suggest that the amino acids can survive the transport through the mesosphere. Dragonfly may find cryo-volcanogenic amino acids on Titan’s equator. Further, the interaction between the two amino acids increased 10-fold the photodegradation rate of glycine. We justify it based on changes in the environment polarity.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2020

Peritectic phase transition of benzene and acetonitrile into a cocrystal relevant to Titan, Saturn's moon

Benzene and acetonitrile are two of the most commonly used solvents found in almost every chemical laboratory. Titan is one other place in the solar system that has large amounts of these compounds. On Titan, organic molecules are produced in the atmosphere and carried to the surface where they can mineralize. In this work, we report the phase diagram of mixtures of acetonitrile and benzene, and provide an account of the structure and composition of the phases. To mimic the environment on Titan more accurately, we tested the stability of the structure under liquid ethane. The results provide new insights into the structure and stability of potential extraterrestrial minerals. In light of Dragonfly, NASA's upcoming mission to Titan, revisiting the fundamental chemistry of the smallest molecules with modern methods and techniques can have significant contributions to this epochal mission and can open new research directions in chemistry.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2020

Detection of Cyclopropenylidene on Titan with ALMA

We report the first detection on Titan of the small cyclic molecule cyclopropenylidene (c-C{sub 3}H{sub 2}) from high-sensitivity spectroscopic observations made with the Atacama Large Millimeter/submillimeter Array. Multiple lines of cyclopropenylidene were detected in two separate data sets: ∼251 GHz in 2016 (Band 6) and ∼352 GHz in 2017 (Band 7). Modeling of these emissions indicates abundances of 0.50 ± 0.14 ppb (2016) and 0.28 ± 0.08 (2017) for a 350 km step model, which may either signify a decrease in abundance, or a mean value of 0.33 ± 0.07 ppb. Inferred column abundances are (3–5) × 10{sup 12} cm{sup −2} in 2016 and (1–2) × 10{sup 12} cm{sup −2} in 2017, similar to photochemical model predictions. Previously the C{sub 3}H{sub 3}{sup +} ion has been measured in Titan’s ionosphere by Cassini’s Ion and Neutral Mass Spectrometer (INMS), but the neutral (unprotonated) species has not been detected until now, and aromatic versus aliphatic structure could not be determined by the INMS. Our work therefore represents the first unambiguous detection of cyclopropenylidene, the second known cyclic molecule in Titan’s atmosphere along with benzene (C{sub 6}H{sub 6}) and the first time this molecule has been detected in a planetary atmosphere. We also searched for the N-heterocycle molecules pyridine and pyrimidine finding nondetections in both cases, and determining 2σ upper limits of 1.15 ppb (c-C{sub 5}H{sub 5}N) and 0.85 ppb (c-C{sub 4}H{sub 4}N{sub 2}) for uniform abundances above 300 km. These new results on cyclic molecules provide fresh constraints on photochemical pathways in Titan’s atmosphere, and will require new modeling and experimental work to fully understand the implications for complex molecule formation.

79 ASTRONOMY AND ASTROPHYSICS↗
NASA NTRS1972

The bulk composition of Titan's atmosphere.

Consideration of the physical constraints for Titan's atmosphere leads to a model which describes the bulk composition of the atmosphere in terms of observable parameters. Intermediate-resolution photometric scans of both Saturn and Titan, including scans of the Q branch of Titan's methane band, constrain these parameters in such a way that the model indicates the presence of another important atmospheric gas, namely, another bulk constituent or a significant thermal opacity. Further progress in determining the composition and state of Titan's atmosphere requires additional observations to eliminate present ambiguities. For this purpose, particular observational targets are suggested.

Trafton, L.↗
NASA NTRS1973

The greenhouse of Titan.

Analysis of non-gray radiative equilibrium and gray convective equilibrium on Titan suggests that a massive molecular-hydrogen greenhouse effect may be responsible for the disagreement between the observed IR temperatures and the equilibrium temperature of an atmosphereless Titan. Calculations of convection indicate a probable minimum optical depth of 14 which corresponds to a molecular hydrogen shell of substantial thickness with total pressures of about 0.1 bar. It is suggested that there is an equilibrium between outgassing and blow-off on the one hand and accretion from the protons trapped in a hypothetical Saturnian magnetic field on the other, in the present atmosphere of Titan. It is believed that an outgassing equivalent to the volatilization of a few kilometers of subsurface ice is required to maintain the present blow-off rate without compensation for all geological time. The presence of an extensive hydrogen corona around Titan is postulated, with surface temperatures up to 200 K.

Sagan, C.↗
NASA NTRS1974

Titan - Unidentified strong absorptions in the photometric infrared

The morphology of Titan's infrared spectral features reveals a pattern of differences with respect to Saturn's bands. Titan's bands exhibit a progressive washing out with increasing wavelength relative to the corresponding bands in Saturn's spectrum. Unidentified absorption features of apparently gaseous origin appear in the long-wavelength wing of Titan's 1-micron CH4 band complex with considerably greater strength. Greater absorption is also observed in the 1.1 micron region. Not all of the phenomena can be explained by enhanced CH4 absorption, so Titan's spectrum implies the existence of another spectroscopically active gas. Several candidates for this gas are briefly considered.

Trafton, L.↗
NASA NTRS1974

Infrared photometry of Titan

A set of observations of Titan at wavelengths from 1.6 through 34 microns shows that Titan has a remarkably low albedo near 1.6 micron. Thermal flux observations for 10 years at 10.6 microns and for 5 years at 21 microns suggest that the thermal properties of Titan remained constant over this period and are independent of phase. Narrowband photometry between 17 and 25 microns does not indicate the presence of a structure characteristic of a hydrogen-rich atmosphere. An atmospheric model consistent with the observations is proposed for Titan.-

Low, F. J.↗
NASA NTRS1974

The atmospheres of Titan and the Galilean satellites

The stability of various atmospheres on Titan and the Galilean satellites is examined relative to escape. One method consists of the comparison of exospheric temperature and a blow-off temperature defined for the various constituents. Another method consists of the evaluation of outflow based on a polytropic model. Hydrogen, methane, nitrogen, and neon atmospheres are examined. It is found that the Jovian satellites require heavier gases if they are to have any but very tenuous atmospheres, since all constituents examined are unstable. Nitrogen is stable on Titan, but methane and neon are marginally stable. Hydrogen is extremely unstable as a major constituent. As a minor constituent it is rapidly lost from Titan's thermosphere and must be replenished by outgassing or dissociation of a hydrogen compound, if the presently observed hydrogen content on Titan is not a transient occurrence. The rate of loss may be limited by diffusion, but could be augmented by vertical convection.

Gross, S. H.↗
NASA NTRS1977

Thermal radiation from Titan's atmosphere

The temperature-inversion model of Titan's atmosphere is modified to include the thermal emission from a plausible amount of C2H2. Infrared photometry of Titan from 8 to 14 microns agrees with model calculations for 0.5 cm-atm C2H6 and 1.0 cm-atm C2H2 and an optically thin dust layer in a temperature-inversion region at 160 K. The random band approximation used to calculate C2H6 opacity has been verified by laboratory transmission measurements. Measurements of the C2H2 emission at 13.7 microns may provide an indirect check on the presence of H2 on Titan. Existing observations of Titan appear to be fully consistent with the inversion model if the surface radius equals 2700 km, the atmospheric radius equals 2900 km, and the surface temperature equals 78 K. The energy balance depends sensitively on these three parameters.

Caldwell, J.↗
NASA NTRS1978

The albedo of Titan

It is shown that a two-layer model of Titan's atmosphere is required in order to match laboratory data on methane absorption to ground-based IR observations of Titan. An excellent fit to the observations is obtained with a model where the dust in Titan's atmosphere is confined to a region containing 50 m-am of methane and located above an atmosphere with 1.95 km-am of methane, with the amount of dust being the value required for an extinction optical depth of 5 at 0.5 micron. The surface reflectivity required by this model is about 40% to 50%, which is typical for both dirty snow and clouds. The possibility is discussed of distinguishing between two scenarios for the observed surface of Titan (a true surface or just cloud tops) on the basis of limb-darkening curves obtained at many wavelengths with an orbiting telescope or a flyby mission.

Podolak, M.↗
NASA NTRS1980

Titan aerosols - Optical properties and vertical distribution

An analysis of Titan's solar phase variation as a function of wavelength together with the continuum geometric albedo makes it possible to set limits on the real part of the refractive index and on the average particle size of the aerosol component of Titan's atmosphere of between about 1.5 and 2.0 and between 0.20 microns and about 0.35 microns, respectively. If the real part of the refractive index is known the average particle size can be determined to within a few percent, and varies inversely with the real part of the refractive index. Using this information in a two-layer model of a methane-aerosol atmosphere and comparing the result with Titan's visible and near-infrared methane spectrum leads to the conclusion that the top layer of Titan's atmosphere contains 0.01 km atm of methane and 2.5 extinction optical depths of aerosol, while the data are consistent with a bottom layer containing 2.2 km atm of methane and about 7.5 aerosol optical depths for a real part of the refractive index equal to 1.7 and an average particle size of 0.25 microns.

Rages, K.↗
NASA NTRS1980

A possible magnetic wake of Titan - Pioneer 11 observations

The paper deals with measurements of the magnetic field along the outbound leg of Pioneer's trajectory at Saturn, which suggest that the spacecraft may have passed through the magnetic wake of Titan at a distance of 145 Titan radii downstream from Titan. The data obtained over a period of several hours around the crossing of Titan's L shell exhibit a number of characteristics which are qualitatively consistent with predictions based on theories of the interaction between a supersonic magnetized plasma and a conducting or magnetized planetary body. In addition, values of the plasma mass density derived from the interaction geometry are consistent with an upper limit inferred from in situ plasma measurements obtained during the outbound leg of Pioneer's trajectory.

Jones, D. E.↗
NASA NTRS1981

Observations of Uranus, Neptune, and Titan by the International Ultraviolet Explorer

The ultraviolet spectra of Uranus, Neptune, and Titan do not reveal absorption features at 7-A resolution from 2100 to 3200 A. Upper limits of from 1 to 3 A are set for the equivalent widths of narrow absorptions, which corresponds to a CO/H2 mixing ratio less than 2 x 10 to the -4th in the case of Uranus. The slopes of the continuum reflectivities of Uranus and Neptune are consistent with the semi-infinite Rayleigh-Raman scattering model of Cochran, while the absolute levels are matched only if solar photometry is modified within acceptable limits. An alternative, but less satisfactory explanation of the new data is that the UV reflectivities of both Uranus and Neptune are depressed uniformly by a continuum absorber. The suggestion by Savage et al (1980) that the albedo of Uranus decreases by approximately 20% from 2200 to 1800 A is not confirmed. For Titan, the albedo decreases monotonically toward shorter wavelengths down to 2300 A. New limits are set for the pressure level in the atmosphere of Titan up to which the real, but presently unidentified, UV absorber there must extend, and for the fraction of Titan that must be covered by this absorber

Caldwell, J.↗