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At least 199 records · Page 11

In Situ Microscopy and Spectroscopy Applied to Surfaces at Work

Here, the present review discusses the current state of the art microscopic and spectroscopic characterization techniques available to study surfaces and interfaces under working conditions. Microscopic techniques such as environmental transmission electron microscopy and in situ transmission electron microscopy are first discussed showing their applications in the field of nanomaterials and catalysis. Next sum frequency generation vibrational spectroscopy is discussed, giving probing examples of surface studies in gaseous conditions. Synchrotron based X-ray techniques are also examined with a specific focus on ambient pressure X-ray photoelectron and absorption techniques such as near and extended X-ray absorption fine structure. Each of the techniques is evaluated, whilst the pros and cons are discussed in term of surface sensitivity, spatial resolution and/or time resolution. The second part of the articles is articulated around the future of in situ characterization, giving examples of the probable development of the discussed techniques as well as an introduction of emerging tools such as scanning transmission X-ray microscopy, ptychography, and X-ray photon correlation spectroscopy.

36 MATERIALS SCIENCE↗

Black carbon aerosol number and mass concentration measurements by picosecond short-range elastic backscatter lidar

Abstract Black carbon aerosol emissions are recognized as contributors to global warming and air pollution. There remains, however, a lack of techniques to remotely measure black carbon aerosol particles with high range and time resolution. This article presents a direct and contact-free remote technique to estimate the black carbon aerosol number and mass concentration at a few meters from the emission source. This is done using the Colibri instrument based on a novel technique, referred to here as Picosecond Short-Range Elastic Backscatter Lidar (PSR-EBL). To address the complexity of retrieving lidar products at short measurement ranges, we apply a forward inversion method featuring radiometric lidar calibration. Our method is based on an extension of a well-established light-scattering model, the Rayleigh–Debye–Gans for Fractal-Aggregates (RDG-FA) theory, which computes an analytical expression of lidar parameters. These parameters are the backscattering cross-sections and the lidar ratio for black carbon fractal aggregates. Using a small-scale Jet A-1 kerosene pool fire, we demonstrate the ability of the technique to quantify the aerosol number and mass concentration with centimetre range-resolution and millisecond time-resolution.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Organic Aerosol Component (OACOMP) Value-Added Product

Organic aerosol (OA, i.e., the organic fraction of particles) accounts for 10–90% of the fine aerosol mass globally and is a key determinant of aerosol radiative forcing. But atmospheric OA is poorly characterized and its life cycle insufficiently represented in models. As a result, current models are unable to simulate OA concentrations and properties accurately. This deficiency represents a large source of uncertainty in quantification of aerosol effects and prediction of future climate change. Evaluation and development of aerosol models require data products generated from field observations. Real-time, quantitative data acquired with aerosol mass spectrometers (AMS) (Canagaratna et al. 2007) are critical to this need. The AMS determines size-resolved concentrations of non-refractory (NR) species in submicrometer particles (PM1) with fast time resolution suitable for both ground-based and aircraft deployments. The high-resolution AMS (HR-AMS), which is equipped with a high mass resolution time-of-flight mass spectrometer, can be used to determine the elemental composition and oxidation degrees of OA (DeCarlo et al. 2006).

Fast, J↗

Green Ocean Amazon (GoAmazon) 2014/15. Semi-Volatile Thermal Desorption Aerosol Gas Chromatograph (SVTAG) Field Campaign Report

In areas where biogenic emissions are oxidized in the presence of anthropogenic pollutants such as SO2, NOx, and black carbon, it has become increasingly apparent that secondary organic aerosol (SOA) formation from biogenic volatile organic compounds (VOCs) is substantially enhanced. Research is urgently needed to elucidate fundamental processes of natural and anthropogenically influenced VOC oxidation and the contribution of these processes to SOA formation. GoAmazon 2014/15 afforded study of the chemical transformations in the region downwind of Manaus, Brazil, where local biogenic VOC emissions are high, and their chemical oxidation can be studied both inside and outside of the urban plume to differentiate the role of anthropogenic influence on secondary aerosol formation during oxidation of these natural VOC emissions. To understand the connection between primary biogenic VOC emissions and their secondary products that form aerosols, we made time-resolved molecular level measurements by deploying a Semi-Volatile Thermal Desorption Aerosol Gas Chromatograph (SV-TAG) and a sequential filter sampler during two intensive operational periods (IOPs) of the GoAmazon 2014/15 field campaign. The SV-TAG measured semi-volatile organic compounds in both the gas and particle phases and the sequential filter sampler collected aerosols on quartz fiber filters in four-hour increments used for offline analysis. SV-TAG employed novel online derivatization that provided chemical speciation of highly oxygenated or functionalized compounds that comprise a substantial fraction of secondary organic aerosols, yet are poorly characterized. It also provided partitioning of these compounds between the vapor and particle phases at sufficient time resolution to define the importance of competing atmospheric processes. These measurements were supported by offline analysis of the filters using two-dimensional gas chromatography (GC x GC) with high-resolution time-of-flight mass spectrometry (HR-TOF-MS) using both electron impact (EI) and soft vacuum ultraviolet (VUV) ionization with derivatization. Speciated chemical data from SV-TAG and filter measurements were used to elucidate the relative importance of potential oxidation pathways by providing detailed information on the product distribution from atmospheric reactions and the quantification of known tracers for various oxidation pathways. Together, these techniques provided unequivocal molecular identification of a wide range of atmospheric organic compounds spanning the volatile, semi-volatile, and non-volatile phases. This level of chemical characterization provided insight into the chemical and physical processes that control the atmospheric oxidation of biogenic VOC and subsequent formation of SOA.

54 ENVIRONMENTAL SCIENCES↗

Hunting Sub-GeV Dark Matter with Diamonds and Magnetic Microcalorimeters Principle

This project is to study feasibility of a new concept for the sub-GeV dark matter (DM) detection using diamond crystals and magnetic microcalorimeters (MMCs). Diamond crystals are made of low mass carbon constituent that maximize kinetic energy of nuclear recoils from sub-GeV DM scattering due to their relatively similar masses. MMC is employed as a sensitive phonon sensor to measure athermal phonons that are produced by DM scattering in diamond crystals with 100 ns timing resolution and ~10 eV energy resolution. MMC’s fast timing resolution allows high precision phonon pulse shape analysis to separate out unwanted background or noise signals in the low energy region at E < 1 keV. Especially, the low energy excess (LEE) problems have been reported in the dark matter detection community and the proposed diamond-MMC detector might be able to provide important information to understand the origins of LEE signals in DM detectors. In this project a diamond-MMC detector has been built for proof-of-concept experiments and athermal phonon collection efficiencies have been investigated for single crystal and poly-crystal chemical-vapour-diamonds (SC and PC CVDs) as well as reference sapphire crystals are tested in the same geometries to quatify athermal phonon propagation and their collection to the MMC phonon sensors. Athermal phonon collection efficiencies and their lifetime in the diamond and sapphire crystals are successfully measured in the same geometry and experimental setup for comparison. SC CVD crystals exhibit poorer performance than the sapphire reference crystals in athermal phonon collection, while the PC CVD crystal exhibit better result than the sapphire. PC CVD with MMC phonon sensors would be feasible for sub GeV DM detection.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Survey of AC-LGADs for future 4D trackers with a proton beam

We will present the first beam test results with centimeter-scale AC-LGAD strip sensors, using the Fermilab Test Beam Facility, and a study of the performance of AC-LGAD sensors as a function of their thickness. Sensors of this type are envisioned for applications that require large-area precision 4D tracking coverage with economical channel counts, including timing layers for the Electron Ion Collider (EIC), and space-based particle experiments. Long strip sensors with sparse readout offer better cost and performance for applications where channel count or electrical power density is a constraint. Thanks to the excellent signal to noise ratio in AC-LGADs, sparse readout can be exploited without significant degradation of spatial or time resolution, which is demonstrated in our studies. A survey of sensor designs is presented, with the aim of optimizing the electrode geometry for spatial resolution and timing performance. We will present our studies of the sensor geometry optimizatio n to maintain the desirable sensor performance characteristics with increasingly larger electrodes.

43 PARTICLE ACCELERATORS↗

First survey of centimeter-scale AC-LGAD strip sensors with a 120 GeV proton beam

We will present the first beam test results with centimeter-scale AC-LGAD strip sensors, using the Fermilab Test Beam Facility, and a study of the performance of AC-LGAD sensors as a function of their thickness. Sensors of this type are envisioned for applications that require large-area precision 4D tracking coverage with economical channel counts, including timing layers for the Electron Ion Collider (EIC), and space-based particle experiments. Long strip sensors with sparse readout offer better cost and performance for applications where channel count or electrical power density is a constraint. Thanks to the excellent signal to noise ratio in AC-LGADs, sparse readout can be exploited without significant degradation of spatial or time resolution, which is demonstrated in our studies. A survey of sensor designs is presented, with the aim of optimizing the electrode geometry for spatial resolution and timing performance. We will present our studies of the sensor geometry optimization to maintain the desirable sensor performance characteristics with increasingly larger electrodes.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Search for celestial X-ray bursts

Progress in two experimental programs is reported. One program involves the search through satellite data for existing evidence for fast photon intensity bursts with energies exceeding 80 keV. The second program is concerned with the development of very sensitive instrumentation to make possible studies of X-ray and gamma ray bursts in the region from 0.1 to 15 MeV with angular resolution, energy resolution, and time resolution, taking into account the complete dynamic range from several nanoseconds to several hours.

Cline, T. L.↗

A two-parameter scintillation spectrometer system for measurement of secondary proton, deuteron, and triton distributions from materials under 558-MeV-proton irradiation

A two-parameter scintillation spectrometer system developed and used to obtain proton, deuteron, and triton double differential cross sections from materials under 558-MeV-proton irradiation is described. The system measures both the time of flight of secondary particles over a 488-cm flight path and the energy deposited in a scintillator, 12.7 cm in diameter and 30.48 cm long. The time resolution of the system is 0.39 nsec. The calculated energy resolution based on this time resolution varies with energy from 1.6 precent to 7.75 percent for 50- and 558-MeV protons. Various systematic and statistical errors are evaluated, and the double differential cross sections for secondary proton and deutron production at 20 deg from a 2.35 g/sq cm thick beryllium target are shown as an example of the results obtainable with this system. The uncertainly in the cross sections for secondary protons varies with particle energy from approximately + or - 9 percent at 50 MeV to approximately + or - 11 percent at 558 MeV.

Beck, S. M.↗

Deriving winds for hurricanes using short interval satellite imagery

Results are presented for a study program designed to develop a better means of obtaining wind data needed by hurricane forecasters and to determine the optimum space and time resolution of satellite data used to obtain such winds. The discussion covers cloud tracking with an image display and manipulation system and analysis of IR imagery of Hurricane Eloise. It is shown that greater resolution in time and space of satellite imagery made it possible to derive up to six times as many low-level winds in a hurricane case, to eliminate 'bad winds' caused by mistaking cloud growth for cloud motion, and to remove ambiguities that would have caused difficulty in tracking clouds using only the imagery taken at 30-min intervals. It is suggested to use short-interval imagery (less than 10 min) for wind determination for future research in areas of tropical cyclones.

Gentry, R. C.↗

A broad look at solar physics adapted from the solar physics study of August 1975

The current status of our knowledge of the basic mechanisms involved in fundamental solar phenomena is reviewed. These include mechanisms responsible for heating the corona, the generation of the solar wind, the particle acceleration in flares, and the dissipation of magnetic energy in field reversal regions, known as current sheets. The discussion covers solar flares and high-energy phenomena, solar active regions; solar interior, convection, and activity; the structure and energetics of the quiet solar atmosphere; the structure of the corona; the solar composition; and solar terrestrial interactions. It also covers a program of solar research, including the special observational requirements for spectral and angular resolution, sensitivity, time resolution, and duration of the techniques employed.

Parker, E.↗

Generic Signatures of the Time Profiles of Cosmic Gamma-Ray Bursts

A new method is proposed which allows the study of the most generic signatures of the time histories of cosmic gamma-ray bursts. We average, with 64 ms time resolution, the time profiles of 275 bright bursts detected by BATSE. The profile of each burst is normalized by the maximum number of counts Cmax at the peak of the primary pulse, and individual pulses and interpulse valleys are selected from the normalized profiles by an identical selection criteria. New temporal parameters are introduced which characterize the duration and equivalent width of each pulse and the duration of each valley.

Mitrofanov, Igor G.↗

Comparison of Ground-Based and Airborne Function Allocation Concepts for NextGen Using Human-In-The-Loop Simulations

Investigation of function allocation for the Next Generation Air Transportation System is being conducted by the National Aeronautics and Space Administration (NASA). To provide insight on comparability of different function allocations for separation assurance, two human-in-the-loop simulation experiments were conducted on homogeneous airborne and ground-based approaches to four-dimensional trajectory-based operations, one referred to as ground-based automated separation assurance (groundbased) and the other as airborne trajectory management with self-separation (airborne). In the coordinated simulations at NASA s Ames and Langley Research Centers, controllers for the ground-based concept at Ames and pilots for the airborne concept at Langley managed the same traffic scenarios using the two different concepts. The common scenarios represented a significant increase in airspace demand over current operations. Using common independent variables, the simulations varied traffic density, scheduling constraints, and the timing of trajectory change events. Common metrics were collected to enable a comparison of relevant results. Where comparisons were possible, no substantial differences in performance or operator acceptability were observed. Mean schedule conformance and flight path deviation were considered adequate for both approaches. Conflict detection warning times and resolution times were mostly adequate, but certain conflict situations were detected too late to be resolved in a timely manner. This led to some situations in which safety was compromised and/or workload was rated as being unacceptable in both experiments. Operators acknowledged these issues in their responses and ratings but gave generally positive assessments of the respective concept and operations they experienced. Future studies will evaluate technical improvements and procedural enhancements to achieve the required level of safety and acceptability and will investigate the integration of airborne and ground-based capabilities within the same airspace to leverage the benefits of each concept.

Wing, David J.↗

THE CRAB PULSAR AT CENTIMETER WAVELENGTHS. I. ENSEMBLE CHARACTERISTICS

We have observed the pulsar in the Crab Nebula at high radio frequencies and high time resolution. We present continuously sampled data at 640 ns time resolution and individual bright pulses recorded at down to 0.25 ns time resolution. Combining our new data with previous data from our group and from the literature shows the dramatic changes in the pulsar’s radio emission between low and high radio frequencies. Below about 5 GHz the mean profile is dominated by the bright Main Pulse and Low-Frequency Interpulse. Everything changes, however, above about 5 GHz; the Main Pulse disappears and the mean profile of the Crab pulsar is dominated by the High-Frequency Interpulse (which is quite different from its low-frequency counterpart) and the two High-Frequency Components. We present detailed observational characteristics of these different components which future models of the pulsar’s magnetosphere must explain.

79 ASTRONOMY AND ASTROPHYSICS↗

Spatial heterodyne spectroscopy for fast local magnetic field measurements of magnetized fusion plasmas

A novel spectroscopy diagnostic for measuring internal magnetic fields in high temperature magnetized plasmas has been developed. It involves spectrally resolving the Balmer- α (656 nm) neutral beam radiation split by the motional Stark effect with a spatial heterodyne spectrometer (SHS). The unique combination of high optical throughput (3.7 mm 2 sr) and spectral resolution (δλ ~ 0.1 nm) allows these measurements to be made with time resolution $\ll$1 ms. The high throughput is effectively utilized by incorporating a novel geometric Doppler broadening compensation technique in the spectrometer. The technique significantly reduces the spectral resolution penalty inherent to using large area, high-throughput optics while still collecting the large photon flux provided by such optics. In this work, fluxes of order 10 10 s –1 support the measurement of deviations of <5 mT (Δ λ Stark ~ 10 –4 nm) in the local magnetic field with 50 µs time resolution. Example high time resolution measurements of the pedestal magnetic field throughout the ELM cycle of a DIII-D tokamak plasma are presented. Local magnetic field measurements give access to the dynamics of the edge current density, which is essential to understanding stability limits, edge localized mode generation and suppression, and predicting performance of H-mode tokamaks.

47 OTHER INSTRUMENTATION↗

Beam Test Results of the GlueX Forward Calorimeter

GlueX is an experiment to begin running in the near future at Jefferson Lab. Our research group is responsible for the forward calorimeter (FCAL) that is designed to measure the energy of photons produced from the decays of mesons. Recently, we conducted a beam test at Jefferson Lab using a prototype of the FCAL. Its goal was to experimentally verify the energy resolution of the FCAL as a function of beam energy. The prototype was tested with recoil electrons ranging in energy from 113MeV to 277MeV. We obtained the resolution by comparing the reconstructed energy to the known energy. In addition, we corrected our measured resolution for multiple scattering and energy loss based on a GEANT4 simulation of the prototype. Another important goal of the beam test was to measure the timing resolution of the channels on our flash analog to digital converters (fADCs). For GlueX, we need to require the timing resolution to be much less than the bunch spacing (2ns). The results of our studies indicate that the energy resolution of the FCAL is consistent with our predictions. We also found the timing resolution as a function of signal size and the results agreed with a similar study. For signals of about at least 75mV, the timing resolution achieved was significantly lower than 2ns.

Bauer, Kevin↗

Tests of Scintillator+WLS Strips for Muon System at Future Colliders

Prototype scintilator+WLS strips with SiPM readout for muon system at future colliders were tested for light yield, time resolution and position resolution. Depending on the configuration, light yield of up to 36 photoelectrons per muon per SiPM has been achieved, as well as time resolution of 0.5 ns and position resolution of ~ 7 cm.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Electric field vector measurements via nanosecond electric-field-induced second-harmonic generation

Electric-field-induced second-harmonic generation, or E-FISH, has received renewed interest as a nonintrusive tool for probing electric fields in gas discharges and plasmas using ultrashort laser pulses. An important contribution of this work lies in establishing that the E-FISH method works effectively in the nanosecond regime, yielding field sensitivities of about a kV/cm at atmospheric pressure from a 16 ns pulse. Here, this is expected to broaden its applicability within the plasma community, given the wider access to conventional nanosecond laser sources. A Pockels-cell-based pulse-slicing scheme, which may be readily integrated with such nanosecond laser systems, is shown to be a complementary and cost-effective option for improving the time resolution of the electric field measurement. Using this scheme, a time resolution of ~3 ns is achieved, without any detriment to the signal sensitivity. This could prove invaluable for nonequilibrium plasma applications, where time resolution of a few nanoseconds or less is often critical. Finally, we take advantage of the field vector sensitivity of the E-FISH signal to demonstrate simultaneous measurements of both the horizontal and vertical components of the electric field.

42 ENGINEERING↗