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At least 199 records · Page 11

Cogeneration Technology Alternatives Study (CTAS). Volume 6: Computer data. Part 1: Coal-fired nocogeneration process boiler, section A

Various advanced energy conversion systems (ECS) are compared with each other and with current technology systems for their savings in fuel energy, costs, and emissions in individual plants and on a national level. About fifty industrial processes from the largest energy consuming sectors were used as a basis for matching a similar number of energy conversion systems that are considered as candidates which can be made available by the 1985 to 2000 time period. The sectors considered included food, textiles, lumber, paper, chemicals, petroleum, glass, and primary metals. The energy conversion systems included steam and gas turbines, diesels, thermionics, stirling, closed cycle and steam injected gas turbines, and fuel cells. Fuels considered were coal, both coal and petroleum based residual and distillate liquid fuels, and low Btu gas obtained through the on-site gasification of coal. Computer generated reports of the fuel consumption and savings, capital costs, economics and emissions of the cogeneration energy conversion systems (ECS's) heat and power matched to the individual industrial processes are presented for coal fired process boilers. National fuel and emissions savings are also reported for each ECS assuming it alone is implemented.

Knightly, W. F.↗

The Role of Heat-to-Power Technologies in Building Decarbonization

This paper presents the energy, economic, and environmental benefits associated with different heat-to-power technologies such as Thermoelectrics, Thermophotovoltaics, and Thermionics. Hybrid configurations consisting of heat pumps, heat-to-power systems, and renewable PV in cogeneration and trigeneration modes of operation will be presented. The role of such technologies in lowering the primary energy consumption, carbon dioxide emissions while improving the energy resiliency and serving the needs of underprivileged communities will be discussed. The key barriers of affordability and potential solutions for large scale implementation of these promising technologies are presented.

Cheekatamarla, Praveen↗

Cogeneration Technology Alternatives Study (CTAS). Volume 1: Summary

Various advanced energy conversion systems that can use coal or coal-derived fuels for industrial cogeneration applications were compared to provide information needed by DOE to establish research and development funding priorities for advanced-technology systems that could significantly advance the use of coal or coal-derived fuels in industrial cogeneration. Steam turbines, diesel engines, open-cycle gas turbines, combined cycles, closed-cycle gas turbines, Stirling engines, phosphoric acid fuel cells, molten carbonate fuel cells, and thermionics were studied with technology advancements appropriate for the 1985-2000 time period. The various advanced systems were compared and evaluated for wide diversity of representative industrial plants on the basis of fuel energy savings, annual energy cost savings, emissions savings, and rate of return on investment as compared with purchasing electricity from a utility and providing process heat with an on-site boiler. Also included in the comparisons and evaluations are results extrapolated to the national level.

Barna, G. J.↗

Cogeneration Technology Alternatives Study (CTAS). Volume 2: Comparison and evaluation of results

CTAS compared and evaluated various advanced energy conversion systems that can use coal or coal-derived fuels for industrial cogeneration applications. The principal aim of the study was to provide information needed by DOE to establish research and development (R&D) funding priorities for advanced-technology systems that could significantly advance the use of coal or coal-derived fuels in industrial cogeneration. Steam turbines, diesel engines, open-cycle gas turbines, combined cycles, closed-cycle gas turbines, Stirling engines, phosphoric acid fuel cells, molten carbonate fuel cells, and thermionics were studied with technology advancements appropriate for the 1985-2000 time period. The various advanced systems were compared and evaluated for a wide diversity of representative industrial plants on the basis of fuel energy savings, annual energy cost savings, emissions savings, and rate of return on investment (ROI) as compared with purchasing electricity from a utility and providing process heat with an on-site boiler.

Source record↗

Performance of a Carbon Nanotube Field Emission Electron Gun

A cold cathode field emission electron gun (e-gun) based on a patterned carbon nanotube (CNT) film has been fabricated for use in a miniaturized reflectron time-of-flight mass spectrometer (RTOF MS). Performance of the CNT e-gun has been evaluated. A traditional thermionic electron gun has also been fabricated and evaluated in parallel and its performance is used as a benchmark in the evaluation of our CNT e-gun. Implications for future improvements and integration into the RTOF MS are discussed.

Getty, Stephanie A.↗

Cogeneration Technology Alternatives Study (CTAS). Volume 6: Computer data. Part 1: Coal-fired nocogeneration process boiler, section A

About fifty industrial processes from the largest energy consuming sectors were used as a basis for matching a similar number of energy conversion systems that are considered as candidate which can be made available by the 1985 to 2000 time period. The sectors considered included food, textiles, lumber, paper, chemicals, petroleum, glass, and primary metals. The energy conversion systems included steam and gas turbines, diesels, thermionics, stirling, closed cycle and steam injected gas turbines, and fuel cells. Fuels considered were coal, both coal and petroleum based residual and distillate liquid fuels, and low Btu gas obtained through the on site gasification of coal. Computer generated reports of the fuels consumption and savings, capital costs, economics and emissions of the cogeneration energy conversion systems (ECS's) heat and power matched to the individual industrial processes are presented. National fuel and emissions savings are also reported for each ECS assuming it alone is implemented. Two nocogeneration base cases are included: coal fired and residual fired process boilers.

Knightly, W. F.↗

Cogeneration Technology Alternatives Study (CTAS). Volume 6: Computer data. Part 1: Coal-fired nocogeneration process boiler, section B

About fifty industrial processes from the largest energy consuming sectors were used as a basis for matching a similar number of energy conversion systems that are considered as candidate which can be made available by the 1985 to 2000 time period. The sectors considered included food, textiles, lumber, paper, chemicals, petroleum, glass, and primary metals. The energy conversion systems included steam and gas turbines, diesels, thermionics, stirling, closed cycle and steam injected gas turbines, and fuel cells. Fuels considered were coal, both coal and petroleum based residual and distillate liquid fuels, and low Btu gas obtained through the on site gasification of coal. Computer generated reports of the fuel consumption and savings, capital costs, economics and emissions of the cogeneration energy conversion systems (ECS's) heat and power matched to the individual industrial processes are presented. National fuel and emissions savings are also reported for each ECS assuming it alone is implemented. Two nocogeneration base cases are included: coal fired and residual fired process boilers.

Knightly, W. F.↗

Cogeneration Technology Alternatives Study (CTAS). Volume 6: Computer data. Part 2: Residual-fired nocogeneration process boiler

About fifty industrial processes from the largest energy consuming sectors were used as a basis for matching a similar number of energy conversion systems that are considered as candidate which can be made available by the 1985 to 2000 time period. The sectors considered included food, textiles, lumber, paper, chemicals, petroleum, glass, and primary metals. The energy conversion systems included steam and gas turbines, diesels, thermionics, stirling, closed cycle and steam injected gas turbines, and fuel cells. Fuels considered were coal, both coal and petroleum based residual and distillate liquid fuels, and low Btu gas obtained through the on site gasification of coal. Computer generated reports of the fuel consumption and savings, capital costs, economics and emissions of the cogeneration energy conversion systems (ECS's) heat and power matched to the individual industrial processes are presented. National fuel and emissions savings are also reported for each ECS assuming it alone is implemented. Two nocogeneration base cases are included: coal fired and residual fired process boilers.

Knightly, W. F.↗

High power densities from high-temperature materials interactions

Thermionic energy converters and metallic-fluid heat pipes are well suited to serve together synergistically. The two operating cycles appear as simple and isolated as their material problems seem forebodingly deceptive and complicated. Simplified equations verify material properties and interactions as primary influences on the operational effectiveness of both. Each experiences flow limitations in thermal emission and vaporization because of temperature restrictions redounding from thermophysicochemical stability considerations. Topics discussed include: (1) successful limitation of alkali-metal corrosion; (2) protection against external hot corrosive gases; (3) coping with external and internal vaporization; (4) controlling interfacial reactions and diffusion; and (5) meeting other thermophysical challenges; expansion matches and creep.

Morris, J. F.↗

Thermionic cathode life-test studies

A NASA-Lewis Research Center program for life testing commercial, high-current-density thermionic cathodes has been in progress since 1971. The purpose of the program is to develop long-life power microwave tubes for space communications. Four commercial-type cathodes are being evaluated in this investigation. They are the 'Tungstate', 'S' type, 'B' type, and 'M' type cathodes, all of which are capable of delivering 1 A/ sq cm or more of emission current at an operating temperature in the range of 1000-1100 C. The life test vehicles used in these studies are similar in construction to that of a high-power microwave tube and employ a high-convergence electron-gun structure; in contrast to earlier studies that used close-space diodes. These guns were designed for operation at 2 A/sq cm of cathode loading. The 'Tungstate' cathodes failed at 700 h or less and the 'S' cathode exhibited a lifetime of about 20,000 h. One 'B' cathode has failed after 27,000 h, the remaining units continuing to operate after up to 30,000 h. Only limited data are now available for the 'M' cathode, because only one has been operated for as long as 19,000 h. However, the preliminary results indicate the emission current from the 'M' cathode is more stable than the 'B' cathode and that it can be operated at a true temperature approximately 100 C lower than for the 'B' cathode.

Forman, R.↗

Cogeneration Technology Alternatives Study (CTAS). Volume 3: Industrial processes

Cogenerating electric power and process heat in single energy conversion systems rather than separately in utility plants and in process boilers is examined in terms of cost savings. The use of various advanced energy conversion systems are examined and compared with each other and with current technology systems for their savings in fuel energy, costs, and emissions in individual plants and on a national level. About fifty industrial processes from the target energy consuming sectors were used as a basis for matching a similar number of energy conversion systems that are considered as candidate which can be made available by the 1985 to 2000 time period. The sectors considered included food, textiles, lumber, paper, chemicals, petroleum, glass, and primary metals. The energy conversion systems included steam and gas turbines, diesels, thermionics, stirling, closed cycle and steam injected gas turbines, and fuel cells. Fuels considered were coal, both coal and petroleum based residual and distillate liquid fuels, and low Btu gas obtained through the on site gasification of coal. An attempt was made to use consistent assumptions and a consistent set of ground rules specified by NASA for determining performance and cost. Data and narrative descriptions of the industrial processes are given.

Palmer, W. B.↗

Cogeneration Technology Alternatives Study (CTAS). Volume 5: Cogeneration systems results

The use of various advanced energy conversion systems is examined and compared with each other and with current technology systems for savings in fuel energy, costs, and emissions in individual plants and on a national level. About fifty industrial processes from the largest energy consuming sectors were used as a basis for matching a similar number of energy conversion systems that are considered as candidate which can be made available by the 1985 to 2000 time period. The sectors considered included food, textiles, lumber, paper, chemicals, petroleum, glass, and primary metals. The energy conversion systems included steam and gas turbines, diesels, thermionics, stirling, closed cycle and steam injected gas turbines, and fuel cells. Fuels considered were coal, both coal and petroleum based residual and distillate liquid fuels, and low Btu gas obtained through the on site gasification of coal. The methodology and results of matching the cogeneration energy conversion systems to approximately 50 industrial processes are described. Results include fuel energy saved, levelized annual energy cost saved, return on investment, and operational factors relative to the noncogeneration base cases.

Gerlaugh, H. E.↗

Simulations of divertor plasmas with inverse sheaths

The effect of strong electron emission from material surfaces has been proposed to form an “inverse sheath”: a region with a positive potential relative to the near-wall plasma which prevents the flow of ions to the wall [M. D. Campanell, “Negative plasma potential relative to electronemitting surfaces,” Phys. Rev. E. 88, 033103 (2013); M. D. Campanell and M. V. Umansky, “Strongly emitting surfaces unable to float below plasma potential,” Phys. Rev. Lett. 116, 1–5 (2016); M. D. Campanell and G. R. Johnson, “Thermionic cooling of the target plasma to a sub-ev temperature,” Phys. Rev. Lett. 122, 1–5 (2019)]. We assess the viability of this regime in a tokamak device using the 2D edge plasma transport code UEDGE [T. Rognlien et al ., “A fully implicit, time dependent 2-D fluid code for modeling tokamak edge plasmas,” J. Nucl. Mater. 196–198, 347–351 (1992)]. Since the UEDGE code does not consider the sheath region directly, we apply boundary conditions at the divertor targets which emulate the physics of both “standard” and “inverse” sheath regimes [R. Masline et al ., “Influence of the inverse sheath on divertor plasma performance in tokamak edge plasma simulations,” Contrib. Plasma Phys. 60, e201900097 (2020)]. Using these boundary conditions, we perform scoping studies to assess plasma parameters near the target by varying the density at the core-edge interface. We observe a smooth transition in the resultant profiles of plasma parameters for the standard sheath, and a bifurcation across the simulation set for plasmas with an inverse sheath. The cause of this bifurcation is assessed by performing the parameter scan both with and without impurity radiation; we observe that the bifurcation persists in both cases, indicating that this bifurcation is caused by plasma recombination.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Carrier diffusion in long wavelength InGaN quantum well LEDs after injection through V-defects

The efficiency of operation of GaN-based light emitting diodes (LEDs) to a large degree relies on realization of a uniform hole distribution between multiple quantum wells (QWs) of the active region. Since the direct thermionic transport between the QWs is inefficient, the hole injection through semipolar {$10\bar{1}1$} QWs that form on the facets of V-defects has been suggested as an alternative approach. However, for an efficient LED operation, the carrier distribution should be uniform not only vertically, between the QWs but also laterally, within individual QWs. In this work, the lateral carrier distribution in long wavelength InGaN/GaN QW LEDs is studied by the scanning near-field optical microscopy. The measurements have shown that emission is concentrated around the V-defect injectors. At high currents, the diffusion length of holes in polar QWs was found to be ∼0.6–1 μm and the hole diffusion coefficient ∼0.6 cm 2 /s. The obtained data should aid design of the V-defect injectors for a laterally uniform carrier distribution in the active region QWs.

Current crowding↗

Recent progress in hybrid mode thermionic converter development

Thermionic research has been conducted to investigate a hybrid-mode thermionic converter as a candidate for reducing the barrier index. The hybrid-mode thermionic converter is designed to operate in a combination ignited mode and unignited mode by using a series of parallel grooves in the emitter. The emitter material is molybdenum and the non-grooved land area is thinly coated with rhenium metal. When the emitter is exposed to cesium vapor, as it is during the converter operation, the rhenium-coated land area achieves a lower work function than the grooved molybdenum surface by as much as 0.5 eV. The low work function land area provides a major portion of electron emission, and the high work function grooved area provides cesium ions required for efficient transport of electrons generated in adjacent land areas to the collector. Experimental results obtained from two different converters and a numerical analysis of converter characteristics are presented in this paper.

Shimada, K.↗

Cogeneration Technology Alternatives Study (CTAS). Volume 1: Summary report

Large savings can be made in industry by cogenerating electric power and process heat in single energy conversion systems rather than separately in utility plants and in process boilers. About fifty industrial processes from the largest energy consuming sectors were used as a basis for matching a similar number of energy conversion systems that are considered as candidates which can be made available by the 1985 to 2000 time period. The sectors considered included food, textiles, lumber, paper, chemicals, petroleum, glass, and primary metals. The energy conversion systems included steam and gas turbines, diesels, thermionics, stirling, closed-cycle and steam injected gas turbines, and fuel cells. Fuels considered were coal, both coal and petroleum-based residual and distillate liquid fuels, and low Btu gas obtained through the on-site gasification of coal. An attempt was made to use consistent assumptions and a consistent set of ground rules for determining performance and cost in individual plants and on a national level. It was found that: (1) atmospheric and pressurized fluidized bed steam turbine systems were the most attractive of the direct coal-fired systems; and (2) open-cycle gas turbines with heat recovery steam generators and combined-cycles with NO(x) emission reduction and moderately increased firing temperatures were the most attractive of the coal-derived liquid-fired systems.

Gerlaugh, H. E.↗

LLNL FESP Theory Highlights: November 2024

This talk presented a refined understanding of plasma-facing thermionic emitter cathodes by examining the limitations of the conventional space charge-limited model, which overlooks ion trapping dynamics within the virtual cathode. While conventional theory distinguishes between temperature-limited and space charge-limited regimes based on electron current constraints, recent findings reveal that trapped ions can form a quasi-neutral "second plasma," expanding upstream and interacting with the primary plasma. These effects are amplified in non-planar geometries, such as cylindrical or spherical sheaths, where trapped ions create a positive feedback loop with the upstream plasma. To address these phenomena, a new "Aid-and-Compete" model was developed, offering insights into current enhancement and sheath mode transitions relevant for plasma devices, including emissive cathodes in electric propulsion, fusion applications, thin film deposition systems, and plasma diagnostics.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Optimal thermionic energy conversion with established electrodes for high-temperature topping and process heating

Applied research-and-technology (ART) work reveals that optimal thermionic energy conversion (TEC) with approximately 1000 K to approximately 1100 K collectors is possible using well established tungsten electrodes. Such TEC with 1800 K emitters could approach 26.6% efficiency at 27.4 W/sq cm with approximately 1000 K collectors and 21.7% at 22.6 W/sq cm with approximately 1100 K collectors. These performances require 1.5 and 1.7 eV collector work functions (not the 1 eV ultimate) with nearly negligible interelectrode losses. Such collectors correspond to tungsten electrode systems in approximately 0.9 to approximately 6 torr cesium pressures with 1600 K to 1900 K emitters. Because higher heat-rejection temperatures for TEC allow greater collector work functions, interelectrode loss reduction becomes an increasingly important target for applications aimed at elevated temperatures. Studies of intragap modifications and new electrodes that will allow better electron emission and collection with lower cesium pressures are among the TEC-ART approaches to reduced interelectrode losses. These solutions will provide very effective TEC to serve directly in coal-combustion products for high-temperature topping and process heating. In turn this will help to use coal and to use it well.

Morris, J. F.↗