SEARCH · Engineering Papers

Results for “Spectral shape”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

SourceResearch connectionFrom yearThrough year

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 199 records · Page 11

All sources NASA NTRS DOE OSTI

DOE OSTI2020

XANES spectroscopy of sulfides stable under reducing conditions

X-ray absorption near-edge structure (XANES) spectroscopy is a powerful technique to quantitatively investigate sulfur speciation in geologically complex materials such as minerals, glasses, soils, organic compounds, industrial slags, and extraterrestrial materials. This technique allows non-destructive investigation of the coordination chemistry and oxidation state of sulfur species ranging from sulfide (2–oxidation state) to sulfate (6+ oxidation state). Each sulfur species has a unique spectral shape with a characteristic K-edge representing the s → p and d hybridization photoelectron transitions. As such, sulfur speciation is used to measure the oxidation state of samples by comparing the overall XANES spectra to that of reference compounds. Although many S XANES spectral standards exist for terrestrial applications under oxidized conditions, new sulfide standards are needed to investigate reduced (oxygen fugacity, f O 2 , below IW) silicate systems relevant for studies of extraterrestrial materials and systems. Sulfides found in certain meteorites (e.g., enstatite chondrites and aubrites) and predicted to exist on Mercury, such as CaS (oldhamite), MgS (niningerite), and FeCr 2 S 4 (daubréelite), are stable at f O 2 below IW-3 but rapidly oxidize to sulfate and/or produce sulfurous gases under terrestrial surface conditions. XANES spectra of these compounds collected to date have been of variable quality, possibly due to the unstable nature of certain sulfides under typical (e.g., oxidizing) laboratory conditions. A new set of compounds was prepared for this study and their XANES spectra are analyzed for comparison with potential extraterrestrial analogs. S K -edge XANES spectra were collected at Argonne National Lab for FeS (troilite), MnS (alabandite), CaS (oldhamite), MgS (niningerite), Ni 1–x S, NiS 2 , CaSO 4 (anhydrite), MgSO 4 , FeSO 4 , Fe 2 (SO 4 ) 3 , FeCr 2 S 4 (daubréelite), Na 2 S, Al 2 S 3 , Ni 7 S 6 , and Ni 3 S 2 ; the latter five were analyzed for the first time using XANES. These standards expand upon the existing S XANES end-member libraries at a higher spectral resolution (0.25 eV steps) near the S K -edge. Processed spectra, those that have been normalized and “flattened,” are compared to quantify uncertainties due to data processing methods. Future investigations that require well-characterized sulfide standards, such as the ones presented here, may have important implications for understanding sulfur speciation in reduced silicate glasses and minerals with applications for the early Earth, Moon, Mercury, and enstatite chondrites.

Anzures, Brendan A.↗

DOE OSTI2023

Modelling populations of kilonovae

Abstract The 2017 detection of a kilonova coincident with gravitational-wave emission has identified neutron star mergers as the major source of the heaviest elements and dramatically constrained alternative theories of gravity. Observing a population of such sources has the potential to transform cosmology, nuclear physics, and astrophysics. However, with only one confident multi-messenger detection currently available, modelling the diversity of signals expected from such a population requires improved theoretical understanding. In particular, models that are quick to evaluate and are calibrated with more detailed multi-physics simulations are needed to design observational strategies for kilonovae detection and to obtain rapid-response interpretations of new observations. We use grey-opacity models to construct populations of kilonovae, spanning ejecta parameters predicted by numerical simulations. Our modelling focuses on wavelengths relevant for upcoming optical surveys, such as the Rubin Observatory Legacy Survey of Space and Time (LSST). In these simulations, we implement heating rates that are based on nuclear reaction network calculations. We create a Gaussian-process emulator for kilonova grey opacities, calibrated with detailed radiative transfer simulations. Using recent fits to numerical relativity simulations, we predict how the ejecta parameters from binary neutron star (BNS) mergers shape the population of kilonovae, accounting for the viewing-angle dependence. Our simulated population of BNS mergers produce peak i-band absolute magnitudes of −20 ≤ Mi ≤ −11. A comparison with detailed radiative transfer calculations indicates that further improvements are needed to accurately reproduce spectral shapes over the full light curve evolution.

79 ASTRONOMY AND ASTROPHYSICS↗

DOE OSTI2023

Highly multicolored light-emitting arrays for compressive spectroscopy

Miniaturized, multicolored light-emitting device arrays are promising for applications in sensing, imaging, computing, and more, but the range of emission colors achievable by a conventional light-emitting diode is limited by material or device constraints. In this work, we demonstrate a highly multicolored light-emitting array with 49 different, individually addressable colors on a single chip. The array consists of pulsed-driven metal-oxide-semiconductor capacitors, which generate electroluminescence from microdispensed materials spanning a diverse range of colors and spectral shapes, enabling facile generation of arbitrary light spectra across a broad wavelength range (400 to 1400 nm). When combined with compressive reconstruction algorithms, these arrays can be used to perform spectroscopic measurements in a compact manner without diffractive optics. As an example, we demonstrate microscale spectral imaging of samples using a multiplexed electroluminescent array in conjunction with a monochrome camera.

42 ENGINEERING↗

NASA NTRS1985

X-ray spectrum and variability of 3C 120

The X-ray luminosity of 3C 120 is variable by a factor of 2.5 on time scales of days to months. The spectral slope of the 2-10 keV X-rays changes systematically in the sense that the higher intensity states are steeper. Simple power laws fitted to the data are consistent with an energy index alpha of 0.51 + or - 0.13 at minimum intensity and 0.83 + or - 0.03 at maximum, with a continuous variation in between. A more complicated spectral shape cannot be ruled out, but changes in absorbing column density alone cannot explain the data. The results are interpreted in terms of beamed synchrotron emission from a relativistic jet, a model which has been invoked previously for the spectra of BL Lac objects. The spectral variability is in marked contrast to the behavior of 3C 273, another superluminal source in which the X-ray spectral index is constant to a high degree of accuracy despite variability in time scales and amplitudes which are quite similar to those of 3C 120. The difference may be due to the degree of beaming of the respective core components. Another model which is consistent with the data involves thermal emission from isothermal shocks in a hot (approximately 10 to the 8th K) medium. Thermal Compton and spherical accretion X-ray source models do not reproduce the correct behavior of alpha versus flux.

Halpern, J. P.↗

NASA NTRS1986

A comparison of SIR-B directional ocean wave spectra with aircraft scanning radar spectra

Directional ocean wave spectra derived from Shuttle Imaging Radar-B (SIR-B) L-band imagery collected off the coast of Southern Chile on 11 and 12 October 1984 were compared with independent spectral estimates from two airborne scanning radars. In sea states with significant wave heights ranging from 3 to 5 meters, the SIR-B-derived sspectra at 18 deg and 25 deg off nadir yielded reasonable estimates of wavelengths, directions, and spectral shapes for all wave systems encountered, including a purely azimuth-traveling system. A SIR-B image intensity variance spectrum containing predominantly range-traveling waves closely resembles an independent aircraft estimate of the slope variance spectrum. The prediction of a U.S. Navy global spectral ocean wave model on 11 October 1984 exhibited no significant bias in dominant wave number but contained a directional bias of about 30 deg with respect to the mean of the aircraft and spacecraft estimates.

Beal, R. C.↗

NASA NTRS1992

Detection of artificially created negative ion clouds with incoherent scatter radar

The physical mechanisms by which negative ions change the shape of the incoherent scatter spectrum, and the way in which shape changes may be used to detect the presence of heavy positive and negative ions in an ambient ionosphere are investigated. In order to detect heavy negative ions, the temperature structure of the ionosphere is fixed to a prevent average measurement, and any changes in spectral shape during the experiment are interpreted as being caused by changes in composition, and not by changes in the temperature ratio Te/Ti. The spatial and temporal development of heavy negative ion plasma clouds created during four active chemical release experiments was observed. Concentrations of 10-40-percent SF6(-) were detected in SPINEX 1, SPINEX 2, and IMS data sets. An average uncertainty of +/-10-percent SF6(-) is present in all three experiments. Concentrations of 30-percent Br(-) were detected in the NICARE 1 release, with uncertainties of +/-4 percent.

Sultan, Peter J.↗

NASA NTRS1972

Detailed measurements of the H beta line shape in a transient plasma using a fiber optics slit system

Stickford, G. H., Jr.↗

NASA NTRS1972

Detailed measurements of the H beta line shape in a transient plasma using a fiber optics slit system.

Through the use of fiber optics, a series of very narrow slits have been constructed and placed at the exit plane of a spectrograph. Plasma radiation which is dispersed by the spectrograph is incident on the slits and is transmitted to separate phototubes via the quartz fibers. With this technique, time resolved measurements of the spectral shape of the hydrogen H beta line have been made and used to determine the electron density of a transient plasma. Data obtained in a shock tube indicated that the thermodynamic conditions behind the reflected shock in a mixture of 20% H2-80% He, at incident shock speeds of 12 to 14 km/sec and pressures of 66.6 to 133.3 N/sq m (0.5 to 1.0 mm Hg), correspond to theoretically predicted conditions. Immediately behind the incident shock at speeds of 17 to 24 km/sec the data indicate that the plasma reached equilibrium then demonstrated a drop in intensity which has been attributed to radiative cooling.

Stickford, G. H., Jr.↗

DOE OSTI2024

A novel methodology for gamma-ray spectra dataset procurement over varying standoff distances and source activities

The adoption of machine learning approaches for gamma-ray spectroscopy has received considerable attention in the literature. Many studies have investigated the deployment of various algorithm architectures to a specific task. However, little attention has been afforded to the development of the datasets leveraged to train the models. Such training datasets typically span a set of environmental or detector parameters to encompass a problem space of interest to a user. Variations in these measurement parameters will also induce fluctuations in the detector response, including expected pile-up and ground scatter effects. Fundamental to this work is the understanding that 1) the underlying spectral shape varies as the measurement parameters change and 2) the statistical uncertainties associated with two spectra impact their level of similarity. While previous studies attribute some arbitrary discretization to the measurement parameters for the generation of their synthetic training data, this work introduces a principled methodology for efficient spectral-based discretization of a problem space. A signal-to-noise ratio (SNR) respective spectral comparison measure and a Gaussian Process Regression (GPR) model are used to predict the spectral similarity across a range of measurement parameters. This innovative approach effectively showcased its capability by dividing a problem space, ranging from 5 cm to 100 cm standoff distances and 5 μCi–100 μCi of 137 Cs, into three unique combinations of measurement parameters. The findings from this work will aid in creating more robust datasets, which incorporate many possible measurement scenarios, reduce the number of required experimental test set measurements, and possibly enable experimental training data collection for gamma-ray spectroscopy.

data science↗

NASA NTRS1979

The diffuse X-ray background spectrum from 3 to 50keV

The spectrum of the extragalactic diffuse X-ray background was measured with the GSFC cosmic X-ray experiment on HEAO-1 for regions of the sky away from known point sources and more than 20 deg from the galactic plane. A total exposure of 80 sq m-sec-sr is available at present. Free-free emission from an optically thin plasma of 40 plus or minus 5 keV provides an excellent description of the observed spectrum from 3 to 50 keV. This spectral shape is confirmed by measurements from 5 separate layers of three independent detectors. With an estimated absolute precision of about 10 percent, the intensity of the emission at 10 keV is 3.2 keV/keV-sq cm-sec-sr, a value consistent with the average of previously reported spectra. No other spectral features, such as iron line emission, are evident. This spectrum is not typical of known extragalactic objects. A uniform hot intergalactic medium of approximately 36 percent of the closure density of the universe would produce such a flux, although non-uniform models indicating less total matter are probably more realistic.

Marshall, F. E.↗

DOE OSTI2023

Parameterization and Explicit Modeling of Cloud Microphysics: Approaches, Challenges, and Future Directions

Cloud microphysical processes occur at the smallest end of scales among cloud-related processes and thus must be parameterized not only in large-scale global circulation models (GCMs) but also in various higher-resolution limited-area models such as cloud-resolving models (CRMs) and large-eddy simulation (LES) models. Instead of giving a comprehensive review of existing microphysical parameterizations that have been developed over the years, this study concentrates purposely on several topics that we believe are understudied but hold great potential for further advancing bulk microphysics parameterizations: multi-moment bulk microphysics parameterizations and the role of the spectral shape of hydrometeor size distributions; discrete vs “continuous” representation of hydrometeor types; turbulence-microphysics interactions including turbulent entrainment-mixing processes and stochastic condensation; theoretical foundations for the mathematical expressions used to describe hydrometeor size distributions and hydrometeor morphology; and approaches for developing bulk microphysics parameterizations. Also presented are the spectral bin scheme and particle-based scheme (especially, super-droplet method) for representing explicit microphysics. Their advantages and disadvantages are elucidated for constructing cloud models with detailed microphysics that are essential to developing processes understanding and bulk microphysics parameterizations. Particle-resolved direct numerical simulation (DNS) models are described as an emerging technique to investigate turbulence-microphysics interactions at the most fundamental level by tracking individual particles and resolving the smallest turbulent eddies in turbulent clouds. Outstanding challenges and future research directions are explored as well.

54 ENVIRONMENTAL SCIENCES↗

NASA NTRS1976

Ames collaborative study of cosmic ray neutrons

The results of a collaborative study to define both the neutron flux and the spectrum more precisely and to develop a dosimetry package that can be flown quickly to altitude for solar flare events are described. Instrumentation and analysis techniques were used which were developed to measure accelerator-produced radiation. The instruments were flown in the Ames Research Center high altitude aircraft. Neutron instrumentation consisted of Bonner spheres with both active and passive detector elements, threshold detectors of both prompt-counter and activation-element types, a liquid scintillation spectrometer based on pulse-shape discrimination, and a moderated BF3 counter neutron monitor. In addition, charged particles were measured with a Reuter-Stokes ionization chamber system and dose equivalent with another instrument. Preliminary results from the first series of flights at 12.5 km (41,000 ft) are presented, including estimates of total neutron flux intensity and spectral shape and of the variation of intensity with altitude and geomagnetic latitude.

Hewitt, J. E.↗

NASA NTRS1994

New composite reflectance spectra of Mars from 0.4 to 3.14 micron

To verify the quality and accuracy of Phobos-2 Imaging Spectrometer for Mars (ISM) spectra of Mars, we have performed comparisons with telescopic data obtained contemporaneously and which have spatial and spectral overlap with the ISM measurements. We find general agreement between the independently-calibrated data sets in terms of spectral shape and absorption band strength and position in the 0.77 to 0.93 micron overlap region. The telescopic data were scaled to the ISM reflectance values in this overlap region to yield new bright and dark region composite reflectance spectra from 0.40 to 3.14 microns. We ascribe the increase in band depth and overall spectral heterogeneity of the ISM data relative to previous telescopic observations to the more than order of magnitude increase in spatial resolution achieved by ISM from Martian orbit. Further increases in spatial resolution from future orbital imaging spectroscopic instruments can be expected to reveal even greater degrees of compositional and mineralogic diversity on Mars.

Mustard, John F.↗

DOE OSTI2025

Antiprotons and Elementary Particles over a Solar Cycle: Results from the Alpha Magnetic Spectrometer

We present results over an 11-year Solar cycle of cosmic antiprotons based on 1.1 × 10 6 events in the rigidity range from 1.00 to 41.9 GV. The $\bar{𝑝}$ fluxes exhibit distinct properties. The magnitude of the $\bar{𝑝}$ flux temporal variation is significantly smaller than those of 𝑝, 𝑒 − , and 𝑒 + . A hysteresis between the $\bar{𝑝}$ fluxes and the 𝑝 fluxes is observed, whereas the $\bar{𝑝}$ and 𝑒 − fluxes show a linear correlation. With a model-independent analysis, we found a universal relation between the shape of the rigidity spectrum and the magnitude of flux temporal variation over an 11-year Solar cycle for both positively and negatively charged particles. The simultaneous results on $\bar{𝑝}$ and 𝑝, 𝑒 − , and 𝑒 + provide unique information for understanding particle transport in the Solar System as a function of mass, charge, and spectral shape.

cosmic ray composition & spectra↗

NASA NTRS2010

Chandra and RXTE Observations of 1E 1547.0-5408: Comparing the 2008 and 2009 Outbursts

We present results from observations of the magnetar 1E 1547.0-5408 (SGR J1550-5418) taken with the Chandra X-ray Observatory and the Rossi X-ray Timing Explorer (RXTE) following the source s outbursts in 2008 October and 2009 January. During the time span of the Chandra observations, which covers days 4 through 23 and days 2 through 16 after the 2008 and 2009 events, respectively, the source spectral shape over the Chandraband remained stable, while the pulsar s spindown rate in the same span in 2008 increased by a factor of 2.2 as measured by RXTE. This suggests decoupling between the source s spin-down and radiative changes, hence between the spin-down-inferred magnetic field strength and that inferred spectrally. The lack of spectral variation during flux decay is surprising for models of magnetar outbursts. We also found a strong anti-correlation between the phase-averaged flux and the pulsed fraction in the 2008 and 2009 Chandra data, but not in the pre-2008 measurements. We discuss these results in the context of the magnetar model.

Ng, C.-Y.↗

NASA NTRS2006

Coloration Determination of Spectral Darkening Occurring on a Broadband Earth Observing Radiometer: Application to Clouds and the Earth's Radiant Energy System (CERES)

It is estimated that in order to best detect real changes in the Earth s climate system, space based instrumentation measuring the Earth Radiation Budget (ERB) must remain calibrated with a stability of 0.3% per decade. Such stability is beyond the specified accuracy of existing ERB programs such as the Clouds and the Earth s Radiant Energy System (CERES, using three broadband radiometric scanning channels: the shortwave 0.3 - 5microns, total 0.3. > 100microns, and window 8 - 12microns). It has been shown that when in low earth orbit, optical response to blue/UV radiance can be reduced significantly due to UV hardened contaminants deposited on the surface of the optics. Since typical onboard calibration lamps do not emit sufficient energy in the blue/UV region, this darkening is not directly measurable using standard internal calibration techniques. This paper describes a study using a model of contaminant deposition and darkening, in conjunction with in-flight vicarious calibration techniques, to derive the spectral shape of darkening to which a broadband instrument is subjected. Ultimately the model uses the reflectivity of Deep Convective Clouds as a stability metric. The results of the model when applied to the CERES instruments on board the EOS Terra satellite are shown. Given comprehensive validation of the model, these results will allow the CERES spectral responses to be updated accordingly prior to any forthcoming data release in an attempt to reach the optimum stability target that the climate community requires.

Matthews, Grant↗

DOE OSTI2023

The active CGCG 077-102 NED02 galaxy within the Abell 2063 galaxy cluster

Context.Within the framework of investigating the link between the central super massive black holes in the cores of galaxies and the galaxies themselves, we detected a variable X-ray source in the center of CGCG 077-102 NED02, which is a member of the CGCG 077-102 galaxy pair within the Abell 2063 cluster of galaxies. Aims.Our goal is to combine X-ray and optical data to demonstrate that this object harbors an active super massive black hole in its core, and to relate this to the dynamical status of the galaxy pair within the Abell 2063 cluster. Methods.We usedChandraandXMM-Newtonarchival data to derive the X-ray spectral shape and variability. We also obtained optical spectroscopy to detect the expected emission lines that are typically found in active galactic nuclei. Finally, we used public ZTF imaging data to investigate the optical variability. Results.There is no evidence of multiple X-ray sources or extended components within CGCG 077-102 NED02. Single X-ray spectral models fit the source well. We detect significant, nonrandom inter-observation 0.5–10 keV X-ray flux variabilities, for observations separated by ∼4 days for short-term variations and by up to ∼700 days for long-term variations. Optical spectroscopy points toward a passive galaxy for CGCG 077-102 NED01 and a Seyfert for CGCG 077-102 NED02. The classification of CGCG 077-102 NED02 is also consistent with its X-ray luminosity of over 10 42 erg s −1 . We do not detect short-term variability in the optical ZTF light curves. However, we find a significant long-term stochastic variability in theg-band that can be well described by the damped random walk model with a best-fit characteristic damping timescale ofτ DRW = 30 −12 +28 days. Finally, the CGCG 077-102 galaxy pair is deeply embedded within the Abell 2063 potential, with a long enough history within this massive structure to have been affected by the influence of this cluster for a long time. Conclusions.Our observations point toward a moderately massive black hole in the center of CGCG 077-102 NED02 of ∼10 6 M ⊙ . As compared to another similar pair in the literature, CGCG 077-102 NED02 is not heavily obscured, perhaps because of the surrounding intracluster medium ram-pressure stripping.

Astronomy & Astrophysics↗

NASA NTRS1986

Near-simultaneous ultraviolet and optical spectrophotometry of T Tauri stars

A set of near-simultaneous ultraviolet and optical spectra and UBVR(J)I(J) photometry of five T Tauri stars has been analyzed for the shape of the energy distribution shortward of 3000 A. The far-ultraviolet continua of these stars are very much stronger than the level of light scattered from longer wavelengths in the IUE spectrograph. The results, expressed as two-color plots, show that the UV colors of T Tauri stars differ significantly from those expected from their optical spectral types. Although these particular K-type T Tauri stars are not extreme members of the class, they have the UV colors of A stars. The spectral shape of this UV excess is approximately that expected from published chromospheric models of T Tauri stars.

Goodrich, Robert W.↗