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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 199 records · Page 11
All sourcesNASA NTRSDOE OSTI
DOE OSTI2023

Metal–Organic Framework as a Dual Support for Organic Photosensitizers and Single-Atom Catalysts

Metal–organic framework (MOF)-supported single-atom catalysts (SACs) possess integrated unique capabilities of both MOF and SACs, which represent a promising class of catalysts for photocatalytic applications. Herein, we report the incorporation of nickel (Ni) SACs onto its zirconium node and the functionalization of the organic linker of the zirconium MOF with perylene tetracarboxylic dianhydride (PDA), resulting in the formation of a hybrid MOF (denoted as Ni-PiU) with significantly enhanced light absorption ability in the visible region. Using the combination of time-resolved emission and X-ray absorption spectroscopy, we show that efficient charge separation occurs by electron transfer from incorporated PDA to Ni SACs with super slow charge recombination dynamics. As a result of these important photophysical properties, Ni-PiU MOF exhibits excellent photocatalytic activity and durability for the hydrogen evolution reaction. Finally, this work demonstrates the unique ability of MOFs as a dual platform to incorporate both SACs and a light absorption unit into their framework, providing a promising strategy for rational design of next-generation photocatalytic materials.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2022

Origin of the injection-dependent emission blueshift and linewidth broadening of III-nitride light-emitting diodes

III-nitride light-emitting diodes (LEDs) exhibit an injection-dependent emission blueshift and linewidth broadening that is severely detrimental to their color purity. By using first-principles multi-scale modeling that accurately captures the competition between polarization-charge screening, phase-space filling, and many-body plasma renormalization, we explain the current-dependent spectral characteristics of polar III-nitride LEDs fabricated with state-of-the-art quantum wells. Our analysis uncovers a fundamental connection between carrier dynamics and the injection-dependent spectral characteristics of light-emitting materials. For example, polar III-nitride LEDs offer poor control over their injection-dependent color purity due to their poor hole transport and slow carrier-recombination dynamics, which forces them to operate at or near degenerate carrier densities. Designs that accelerate carrier recombination and transport and reduce the carrier density required to operate LEDs at a given current density lessen their injection-dependent wavelength shift and linewidth broadening.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2020

Timing resolution and rate capability of Photonis miniPlanacon XPM85212/A1-S MCP-PMT

In this paper we report on a set of experiments that focus on measuring the timing performance of the Photonis miniPlanacon XPM85212/A1-S microchannel plate photomultiplier tubes along with the detector response at high event rates. The detector has a single photoelectron timing resolution of 30 ps at low rates ( 10 kHz ). We show that both the gain and the timing start to deteriorate around 1 MHz with 20 photoelectrons per channel at 1 0 4 target gain, giving the current per unit of area limits of 1.38 μ A / cm 2 and 2.38 μ A / cm 2 for the two tested devices. Photo-multiplier tubes with lower micro-channel plate resistivity exhibit a better rate capability due to the faster replenishment of the charge inside the microchannels. As we demonstrate, another method to improve the rate capability is to operate the photon detector tubes at a lower gain by reducing the supply voltage and compensating for the loss of amplitude by an additional amplification stage at the expense of the achieved timing resolution. The tube active area over which the beam is spread also plays a role since the same amount of light yields a better rate capability when spread over a larger area. The tubes exposed to high event rates showed an uncharacteristically slow recovery back to its initial gain with 80 % of the initial gain recovered only after several tens of minutes.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗
NASA NTRS2017

Autonomous Acquisition of Science Quality Spectra from Unmanned Aerial Systems

This is a presentation on a technique for using Unmanned Aerial Systems with intelligent sensing to create science quality data. In this particular case, the team used two spectrometers with high spectral resolution and developed a technique to have the spectrometers self calibrate so that it is possible to take the measurements within the allocated 10 minute flight times. Because there is both upwelling and downwelling foreoptics on each of the two spectrometers, it becomes slow to set the calibration up for all four possibilities which relates to the integration time and then take the measurements. If light conditions change too rapidly then the measurements won't be scaled so that the spectra max is at least 85% of the instrument max but not saturated. This process was more difficult then it appeared due to the complexity of determining the integration time before light conditions changed and before the battery runs our of charge to fly the Unmanned Aerial System. This presentation goes over the results for the first few flight days and the planned future flight experiments.

Mandl, Daniel↗
DOE OSTI2022

Scintillation Hydro-Gel for Isotopic Neutron (SHINE): Eco-Friendly Quantum Dot Neutron Detectors

The development of new neutron detectors to replace helium-3 (3He) detectors is imperative due to a worldwide shortage of 3He following the draw down in nuclear weapons production since the end of the Cold War. The United States Department of Homeland Security would like to deploy monitors for the detection of neutron emissions from shipping containers housing illicit nuclear material; however, this effort has been put on hold until new replacements for 3He detectors can be developed. Scintillation Hydro-Gel for isotopic Neutron Emitters (SHINE) is a unique, first of its kind, 6Li-loaded quantum dot gel scintillator developed at INL. By incorporating 6Li with quantum dots in a gel matrix, SHINE displays the best properties of liquid and solid scintillators without their disadvantages such as continuous filtering to keep liquids free of contaminates, slow throughput of containers, higher base component costs, ‘dead’ voids in solid scintillators, and a high loading of 6Li without compromising on light transparency. Additionally, SHINE is completely eco-friendly, a breakthrough in high-efficiency detection systems. SHINE is a unique combination of 6LiCl, a highly water-soluble compound, and InP/ZnS core/shell quantum dots, which are poured into a gel-form using cross-linking polymers. In this presentation, SHINE has been successfully tested for neutron detection and shows promise as both a replacement for current 3He neutron detectors as well as potential use in handheld, compact neutron detection units and antineutrino detection.

36 MATERIALS SCIENCE↗
DOE OSTI2024

Squeezed Light Stimulated Raman Scattering (SRS) Microscopy for Bioenergy Applications

Stimulated Raman scattering (SRS) microscopy using picosecond near-IR pulses have provided a great penetration depth with reduced fluorescence interference when imaging biological samples for bioenergy applications. These tools have provided insight into 1) tracking the degradation of chemical composites in biomass feedstocks to investigate the recalcitrant factors during the deconstruction processes, 2) monitoring the production of chemicals in photosynthetic plants and wood-digesting microorganisms, and 3) probing plant-bacteria interactions. However, the above processes are usually slow and require continuous imaging for an extended period. This is challenging for classic SRS because the laser power needed to achieve enough sensitivity causes photodamage in the samples during such long experiments. Quantum-squeezed light with reduced noise in the intensity quadrature can improve the sensitivity of classic SRS microscopy beyond the shot noise limit. The successful squeezing of one of the picosecond pulses in the above SRS will improve sensitivity and reduce photodamage, greatly expanding the range of studies available to SRS microscopy.

BIOMASS FUELS↗
NASA NTRS2000

STS-92 Crew Activity Report/Flight Day 10 Highlights

On this tenth day of the STS-92 mission, the flight crew, Commander Brian Duffy, Pilot Pamela A. Melroy, and Mission Specialists Koichi Wakata, Leroy Chiao, Peter J.K. Wisoff, Michael E. Lopez-Alegria, and William S. McArthur prepare for the undocking of Discovery from the International Space Station (ISS) as Lopez-Alegria is seen closing the hatch on the Unity Module. A slow sweep of the outside of the ISS shows the space station in detail against the backdrop of a dark Earth where the lights of a city shine. Lopez-Alegria closes the outer hatch and Discovery undocks from the ISS. As the two separate, the ISS is seen orbiting across a beautiful dark blue Earth.

Source record↗
NASA NTRS2001

Physics of the Inner Heliosphere 1-10 R(sub s): Plasma Diagnostics and Models

While the mechanisms responsible for heating the solar corona and accelerating the fast and slow solar wind streams are still unknown, model computations offer the only means for exploring and predicting the properties of such mechanisms in light of the empirical constraints currently available. During the time covered by this grant, modeling and data analysis efforts were aimed at: 1) the study of the propagation and damping of ion-cyclotron waves in the fast solar wind 2) the exploration of the role of instabilities in the development of temperature anisotropies in the inner corona 3) the coupling of neutral hydrogen and protons in the fast solar wind 4) the morphology of the source region of the solar wind. Summarized are some of the highlights of these studies. Two PhD theses by Xing Li and Lorraine Allen were partially supported by this grant.

Habbal, Shadia R.↗
NASA NTRS2020

The Slow Demise of the Long-Lived Sn 2005ip

The Type IIn supernova (SN IIn) 2005ip is one of the most well-studied and long-lasting examples of an SN interacting with its circumstellar environment. The optical light curve plateaued at a nearly constant level for more than five years, suggesting ongoing shock interaction with an extended and clumpy circumstellar medium (CSM). Here, we present continued observations of the SN from ∼1000 to 5000 d post-explosion at all wavelengths, including X-ray, ultraviolet, near-infrared (NIR), and mid-infrared. The UV spectra probe the pre-explosion mass loss and show evidence for CNO processing. From the bolometric light curve, we find that the total radiated energy is in excess of 10 50 erg, the progenitor star’s pre-explosion mass-loss rate was >~ 1 × 10 −2 Mꙩ yr −1 , and the total mass lost shortly before explosion was >~1Mꙩ, though the mass lost could have been considerably larger depending on the efficiency for the conversion of kinetic energy to radiation. The ultraviolet through NIR spectrum is characterized by two high-density components, one with narrow high-ionization lines, and one with broader low-ionization H I, He I, [OI], Mg II, and Fe II lines. The rich Fe II spectrum is strongly affected by Lyα fluorescence, consistent with spectral modelling. Both the Balmer and He I lines indicate a decreasing CSM density during the late interaction period. We find similarities to SN 1988Z, which shows a comparable change in spectrum at around the same time during its very slow decline. These results suggest that, at long last, the shock interaction in SN 2005ip may finally be on the decline.

stars↗
NASA NTRS2017

Impacts of Solar-Absorbing Aerosol Layers on the Transition of Stratocumulus to Trade Cumulus Clouds

The effects of an initially overlying layer of solar-absorbing aerosol on the transition of stratocumulus to trade cumulus clouds are examined using large-eddy simulations. For lightly drizzling cloud the transition is generally hastened, resulting mainly from increased cloud droplet number concentration (Nc) induced by entrained aerosol. The increased Nc slows sedimentation of cloud droplets and shortens their relaxation time for diffusional growth, both of which accelerate entrainment of overlying air and thereby stratocumulus breakup. However, the decrease in albedo from cloud breakup is more than offset by redistributing cloud water over a greater number of droplets, such that the diurnal-average shortwave forcing at the top of the atmosphere is negative. The negative radiative forcing is enhanced by sizable longwave contributions, which result from the greater cloud breakup and a reduced boundary layer height associated with aerosol heating. A perturbation of moisture instead of aerosol aloft leads to a greater liquid water path and a more gradual transition. Adding absorbing aerosol to that atmosphere results in substantial reductions in liquid water path (LWP) and cloud cover that lead to positive short-wave and negative longwave forcings on average canceling each other. Only for heavily drizzling clouds is the breakup delayed, as inhibition of precipitation overcomes cloud water loss from enhanced entrainment. Considering these simulations as an imperfect proxy for biomass burning plumes influencing Namibian stratocumulus, we expect regional indirect plus semi-direct forcings to be substantially negative to negligible at the top of the atmosphere, with its magnitude sensitive to background and perturbation properties.

Zhou, Xiaoli↗
NASA NTRS2004

Peculiar Behaviors of Faint Galactic Bulge Transients

The Rossi X-ray Timing Explorer PCA scans of the Galactic bulge (galactic longitude plus or minus 11 degrees) have detected 8 recent transients which have peak intensities of 10 to 400 mCrab. Some of the transient events have a fast rise and slow decay typical of accretion disk instabilities. It is common for these decays to be oscillatory, rather than steady, as if there are waves within the disk. There are also outbursts with symmetric light curves. In particular, the source in Terzan 2 which had a very long (decade) doubling of intensity peaking near the beginning of 1997, in 2004 has had two 30 day brightenings by a factor of 5 only 100 days apart. During each of these a burst was observed in snapshot observations near the peak. The source SLX 1735-269, also a burster, though not in our observations, has had irregularly repeated occurrences of fast swings between close to zero and 2-4 times normal. Some examples, such as the increase, drop, and slow recovery of GS 1826-238 suggest a change in the accretion disk such as emptying and refilling or a peculiar alignment. Follow up observations have provided deeper information about these transient sources and possible explanations for their behavior will be addressed.

Swank, J. H.↗
DOE OSTI2021

Model for current drive induced crash cycles in W7-X

In the Wendelstein 7-X (W7-X) stellarator, the vacuum rotational transform, ι, has a flat radial profile and does not cross any major rational resonance. Nevertheless, during plasma operation the ι–profile can be strongly modified by electron cyclotron current drive in such a way that the resulting ι-profile passes through low-order rational values, and this can trigger magnetohydrodynamic (MHD) events. Indeed, W7-X plasmas are sometimes subject to repetitive collapses of core confinement, which can be observed regardless of the direction in which the EC current is driven. Even though the origin of these MHD instabilities is under investigation, the crashes may be connected to the formation of magnetic islands and magnetic reconnection. In the present work, we try to shed light on the dynamics of different events happening during the course of sawtooth cycles in W7-X by proposing a model that combines a slow current diffusion with a recipe for fast relaxation that conserves the corresponding helical flux (Kadomtsev 1975 Fiz. Plazmy 1 710–15). We also propose a simple model based on Taylor relaxation (Taylor 1974 Phys. Rev. Lett. 33 1139), (Taylor 1986 Rev. Mod. Phys. 58 741) to predict the nonlinear redistribution of plasma current caused by the largest of the observed events.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2020

The stellar mass Fundamental Plane: the virial relation and a very thin plane for slow rotators

ABSTRACT Early-type galaxies – slow and fast rotating ellipticals (E-SRs and E-FRs) and S0s/lenticulars – define a Fundamental Plane (FP) in the space of half-light radius Re, enclosed surface brightness Ie, and velocity dispersion σe. Since Ie and σe are distance-independent measurements, the thickness of the FP is often expressed in terms of the accuracy with which Ie and σe can be used to estimate sizes Re. We show that: (1) The thickness of the FP depends strongly on morphology. If the sample only includes E-SRs, then the observed scatter in Re is $\sim 16{{\ \rm per\ cent}}$, of which only $\sim 9{{\ \rm per\ cent}}$ is intrinsic. Removing galaxies with M* < 1011 M⊙ further reduces the observed scatter to $\sim 13{{\ \rm per\ cent}}$ ($\sim 4{{\ \rm per\ cent}}$ intrinsic). The observed scatter increases to $\sim 25{{\ \rm per\ cent}}$ usually quoted in the literature if E-FRs and S0s are added. If the FP is defined using the eigenvectors of the covariance matrix of the observables, then the E-SRs again define an exceptionally thin FP, with intrinsic scatter of only 5 per cent orthogonal to the plane. (2) The structure within the FP is most easily understood as arising from the fact that Ie and σe are nearly independent, whereas the Re−Ie and Re−σe correlations are nearly equal and opposite. (3) If the coefficients of the FP differ from those associated with the virial theorem the plane is said to be ‘tilted’. If we multiply Ie by the global stellar mass-to-light ratio M*/L and we account for non-homology across the population by using Sérsic photometry, then the resulting stellar mass FP is less tilted. Accounting self-consistently for M*/L gradients will change the tilt. The tilt we currently see suggests that the efficiency of turning baryons into stars increases and/or the dark matter fraction decreases as stellar surface brightness increases.

Bernardi, M.↗
DOE OSTI2023

Chloroplast phosphate transporter CrPHT4-7 regulates phosphate homeostasis and photosynthesis in Chlamydomonas

Abstract In eukaryotic cells, phosphorus is assimilated and utilized primarily as phosphate (Pi). Pi homeostasis is mediated by transporters that have not yet been adequately characterized in green algae. This study reports on PHOSPHATE TRANSPORTER 4-7 (CrPHT4-7) from Chlamydomonas reinhardtii, a member of the PHT4 transporter family, which exhibits remarkable similarity to AtPHT4;4 from Arabidopsis (Arabidopsis thaliana), a chloroplastic ascorbate transporter. Using fluorescent protein tagging, we show that CrPHT4-7 resides in the chloroplast envelope membrane. Crpht4-7 mutants, generated by the CRISPR/Cas12a-mediated single-strand templated repair, show retarded growth, especially in high light, reduced ATP level, strong ascorbate accumulation, and diminished non-photochemical quenching in high light. On the other hand, total cellular phosphorous content was unaffected, and the phenotype of the Crpht4-7 mutants could not be alleviated by ample Pi supply. CrPHT4-7-overexpressing lines exhibit enhanced biomass accumulation under high light conditions in comparison with the wild-type strain. Expressing CrPHT4-7 in a yeast (Saccharomyces cerevisiae) strain lacking Pi transporters substantially recovered its slow growth phenotype, demonstrating that CrPHT4-7 transports Pi. Even though CrPHT4-7 shows a high degree of similarity to AtPHT4;4, it does not display any substantial ascorbate transport activity in yeast or intact algal cells. Thus, the results demonstrate that CrPHT4-7 functions as a chloroplastic Pi transporter essential for maintaining Pi homeostasis and photosynthesis in C. reinhardtii.

59 BASIC BIOLOGICAL SCIENCES↗
NASA NTRS1983

Interstellar carbon in meteorites

The Murchison and Allende chondrites contain up to 5 parts per million carbon that is enriched in carbon-13 by up to +1100 per mil (the ratio of carbon-12 to carbon-13 is approximately 42, compared to 88 to 93 for terrestrial carbon). This 'heavy' carbon is associated with neon-22 and with anomalous krypton and xenon showing the signature of the s-process (neutron capture on a slow time scale). It apparently represents interstellar grains ejected from late-type stars. A second anomalous xenon component ('CCFXe') is associated with a distinctive, light carbon (depleted in carbon-13 by 38 per mil), which, however, falls within the terrestrial range and hence may be of either local or exotic origin.

Swart, P. K.↗
NASA NTRS1996

Emerging flux and flares in NOAA 7260

We have studied the relation between flux emergence and flare activity in the active region NOAA 7260, using images from the Soft X-ray Telescope (SXT) aboard the Yohkoh spacecraft and other supporting ground-based data. It is found that microflares start around the time of flux emergence as recorded in white-light data, which generally precedes a major flare by several hours. We interpret the microflares as due to fast reconnection that takes place intermittently in the slow reconnection stage while more energy is accumulated in preparation for a larger flare.

Nitta, N.↗
DOE OSTI2023

A matched-filter approach to radio variability and transients: searching for orphan afterglows in the VAST Pilot Survey

Radio transient searches using traditional variability metrics struggle to recover sources whose evolution time-scale is significantly longer than the survey cadence. Motivated by the recent observations of slowly evolving radio afterglows at gigahertz frequency, we present the results of a search for radio variables and transients using an alternative matched-filter approach. We designed our matched-filter to recover sources with radio light curves that have a high-significance fit to power-law and smoothly broken power-law functions; light curves following these functions are characteristic of synchrotron transients, including ‘orphan’ gamma-ray burst afterglows, which were the primary targets of our search. Applying this matched-filter approach to data from Variables and Slow Transients Pilot Survey conducted using the Australian SKA Pathfinder, we produced five candidates in our search. Subsequent Australia Telescope Compact Array observations and analysis revealed that: one is likely a synchrotron transient; one is likely a flaring active galactic nucleus, exhibiting a flat-to-steep spectral transition over 4 months; one is associated with a starburst galaxy, with the radio emission originating from either star formation or an underlying slowly evolving transient; and the remaining two are likely extrinsic variables caused by interstellar scintillation. The synchrotron transient, VAST J175036.1–181454, has a multifrequency light curve, peak spectral luminosity, and volumetric rate that is consistent with both an off-axis afterglow and an off-axis tidal disruption event; interpreted as an off-axis afterglow would imply an average inverse beaming factor $\langle f^{-1}_{\text{b}} \rangle = 860^{+1980}_{-710}$, or equivalently, an average jet opening angle of $\langle \theta _{\textrm {j}} \rangle = 3^{+4}_{-1}\,$ deg.

79 ASTRONOMY AND ASTROPHYSICS↗