SEARCH · Engineering Papers

Results for “Shale”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

SourceResearch connectionFrom yearThrough year

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 199 records · Page 11

All sources NASA NTRS DOE OSTI

NASA NTRS1991

Compositional variability of the Martian surface

Spectral reflectance data from Viking Landers and Orbiters and from telescopic observations were analyzed with the objective of isolating compositional information about the Martian surface and assessing compositional variability. Two approaches were used to calibrate the data to reflectance to permit direct comparisons with laboratory reference spectra of well characterized materials. In Viking Lander multispectral images (six spectral bands) most of the spectral variation is caused by changes in lighting geometry within individual scenes, from scene to scene, and over time. Lighting variations are both wavelength independent and wavelength dependent. By calibrating lander image radiance values to reflectance using spectral mixture analysis, the possible range of compositions was assessed with reference to a collection of laboratory samples, also resampled to the lander spectral bands. All spectra from the lander images studied plot (in six-space) within a planar triangle having at the apexes the respective spectra of tan basaltic palagonite, gray basalt, and shale. Within this plane all lander spectra fit as mixtures of these three endmembers. Reference spectra that plot outside of the triangle are unable to account for the spectral variation observed in the images.

Adams, John B.↗

NASA NTRS1991

The environmental distribution of late proterozoic organisms

Along present day coast lines, the environmental distributions of prokaryotic and protistan populations are often sharply delimited. Realized habitat ranges are generally narrower than those circumscribed by physiological tolerances, suggesting the importance of organism-organism interactions in the determination of population distributions. Microfossil populations preserved in silicified carbonates, dolomites, and shales of the 700-800 Ma old Akademikerbreen Group, Svalbard, and elsewhere indicate that the environmental distributions were defined equally clearly during the Proterozoic Eon. The Draken Conglomerate Formation is a tidal flat/lagoonal complex in which we have distinguished five principle biofacies containing a total of 42 taxa. Supratidal to subtidal gradients include the increasing abundance and diversity of both mat dweller microbenthos and allochthonous (principally planktonic) organisms, as well as a taphonomically important pattern of decreasing sheath thickness among mat builder microorganisms. The seaward barriers of Akademikerbreen lagoons were oolitic shoals, and these contain about a dozen endolithic and epilithic species not observed elsewhere in the group. Subtidal environments below fair weather wave base are represented by mudstones of the Svanbergfjellet Formation. These contain abundant and diverse cyanobacteria-like fossils generally similar to but specifically different from those found in tidal flat sediments, as well as diverse unicellular protists (some of impressive morphological complexity) and at least half a dozen cellularly preserved metaphyte populations. In all, more than 80 species are distributed among Akademikerbreen lithologies. Fossil assemblages from Svalbard and elsewhere illustrate the potential for a much finer paleoecological, biostratigraphic, and, hence, evolutionary resolution of the early fossil record.

Knoll, A. H.↗

NASA NTRS1992

Mobilization of the platinum group elements by low-temperature fluids: Implications for mineralization and the iridium controversy

Geochemical investigations on the widely dispersed Late Proterozoic Acraman impact ejecta horizon and its host marine shales in the Adelaide Geosyncline provide strong evidence for low-temperature mobilization of the platinum group elements (PGE), including Ir. The ejecta horizon was formed when the middle Proterozoic dacitic volcanics in the Gawler Ranges, central South Australia, were impacted by a very large (ca. 4 km) meteorite. The resulting structure, now represented by Lake Acraman, is Australia's largest meteorite impact structure. Debris from the impact was blasted for many hundreds of kilometers, some falling into the shallow sea of the Adelaide Geosyncline, some 300 km to the east of the impact site.

Dowling, Kim↗

NASA NTRS1992

The Acraman impact and its widespread ejecta, South Australia

Discovery of a widespread horizon of shock-deformed volcaniclastic ejecta preserved in Late Proterozoic (approx. 600 Ma) shales in South Australia and its probable link to the Acraman impact structure in the Middle Proterozoic Gawler Range. Volcanics provide a rare opportunity to study the effects of a major terrestrial impact, including the sedimentology and distribution of an ejecta blanket and its precious-metal signature. The ejecta horizon occurs in the Bunyeroo Formation at many localities within the Adelaide Geosyncline, including the Wearing Hills, which are approx. 350 km northeast of the Acraman impact site. Following a search at the same stratigraphic level in other basins in South Australia, the ejecta has been located within the Lower Rodda beds of the Officer Basin, extending the limits of the ejecta to approx. 470 km northwest of the Acraman impact structure. The ejecta is therefore widely dispersed, and provides an important chronostratigraphic marker enabling precise correlation of Late Proterozoic sequences in southern Australia. In summary, the Bunyeroo ejecta is unique as the only known example of a widely dispersed, coarse-grained ejecta blanket that is, moreover, strongly linked to a known major impact structure. The marked Ir-PGE anomalies in the ejecta horizon provide support for the hypothesis that meteorite impact events can produce Ir anomalies interrestrial sediments. The findings also indicate that Ir can be mobilized and concentrated in sediments by low-temperature diagenetic processes. The identification of ejecta horizons in sedimentary rocks therefore should be based on the coincidence of shock-metamorphic features in the detritus and clear Ir anomalies.

Gostin, V. A.↗

NASA NTRS1993

Final report

In eastern Nevada and western Utah is an extensive terrane that has experienced a complex tectonic history of Mesozoic deformation and superposed Tertiary extension. The Mesozoic tectonic history of this area has been the subject of controversy for the past twenty or more years. The debate has centered on whether major Mesozoic geologic structures were due to compressional or extensional tectonic regimes. The goal of our research was to decipher the deformational history of the area by combining detailed geologic mapping, remote sensing data analysis, and U-Pb and K-Ar geochronology. This study area includes the Dolly Varden Mountains and adjacent Currie Hills, located in the semi-arid environment of the northeastern Great Basin in Nevada. Vegetation cover in the Dolly Varden Mountains typically ranges from about 10 percent to 50 percent, with some places along drainages and on high, north-facing slopes where vegetation cover approaches 100 percent. Sagebrush is found at less vegetated lower elevations, whereas pinon pine and juniper are prevalent above 2,000 meters. A variety of geologic materials is exposed in the study area. A sequence of Late Paleozoic and Triassic sedimentary rocks includes limestone, dolomite, chert, sandstone, siltstone and shale. A two-phase granitic stock, called the Melrose, intruded these rocks, resulting in metamorphism along the intrusive contact. Tertiary volcanic rocks cover most of the eastern part of the Dolly Varden Mountains and low-lying areas in the Currie Hills.

Zamudio, Joe↗

NASA NTRS1992

Episodes of terrestrial geologic activity during the past 260 million years - A quantitative approach

Records of major geologic events of the past about 260 Myr including: biologic extinction events, ocean-anoxic and black-shale events, major changes in sea level, major evaporite (salt) deposits, continental flood-basalt eruptions, first-order discontinuities in sea-floor spreading, and major mountain building events, have been aggregated and analyzed with moving-window and spectral techniques that facilitate recognition of clustering and possible cyclicity. Significant clustering of events suggests a model in which changes in rates and directions of sea-floor spreading ('ridge jumps') are associated with episodic rifting, volcanism, mountain building, global sea level and changes in the composition of the earth's atmosphere via the carbon cycle. The geologic data formally show a statistically significant underlying periodicity of 26.6 Myr for the Mesozoic and Cenozoic. Phase information suggests that the most recent maximum of the cycle occurred with the last 9 Myr, and may be close to the present time.

Rampino, Michael R.↗

NASA NTRS1993

Petrography and preliminary interpretations of the crystalline breccias from the Manson M-1 core

The M-1 core was drilled on the eastern edge of the central uplift within the Manson Impact Structure in Iowa. The lower 107.9 m of the core consists of crystalline breccias. Twelve intervals of thin sections from this core have been studied for preliminary discussion. The breccias are divided into three units by matrix size and abundance. Unit 1 is characterized by a high volume fraction of matrix, and a decreasing proportion of matrix with depth. This matrix is nearly isotropic and consists of grains less than 0.005 to less than 0.02 mm in length. The matrix between 112 and 146 meters depth consists of a crystalline intergrowth of felsic and opaque minerals with or without chlorite. This was the hottest section of the core after impact, and may have undergone high temperature metamorphic recrystallization. Unit 2 is transitional between units 1 and 3, and is delineated by a rapid increase in grain size to .01-.04 mm and a decrease in matrix abundance to 10 percent. Unit 3 has a coarse, often porous matrix, whose abundance changes from about 10 percent at the top to about 2 percent at the base. Grain sizes range from 0.01-0.1 mm over this interval and coarsen with depth. Changes in the character of the matrix as well as the changes in clast lithology and abundance outlined below suggest that unit 3 is in-situ brecciated basement with injected melt and shale fragments; unit 1 is a crater veneer deposit consisting of transported basement materials and unit 2 is a mixed zone between units 1 and 3.

Bell, M. S.↗

NASA NTRS1993

Minor and trace element composition and age of Yukon probable-microtektites

Major, minor, and trace element composition of the candidate micro tektites from Yukon Territory suggest a possible impact site of hydrothermally altered limestone and sand or chert, or possibly a carbonatite. Their REE/chondrite curve is similar in character to, but higher than, shale composites of North America, Australia, and Europe. Relative to these same composites, the Yukon droplets are enriched in Y, F, S, Sr, P, Mn, Mg, and Ca. They are depleted in Rb, Li, Th, Nb, Ti, K, Na, Fe, Si, and Al. Biostratigraphic constraints on the droplets indicate they are Middle to Late Devonian, more likely Middle Devonian, in age.

Boundy-Sanders, S. Q.↗

NASA NTRS1993

Geochemical evidences for two chondritic-like cometary or asteroidal impacts before and at the K/T boundary

A number of geological and palaeontological evidences support multiple impacts of cometary showers within a short time (approximately 1-3 Ma) and their connection with mass extinctions. Observations include clustered crater ages, stratigraphic horizons of impact ejecta closely spaced in time, and evidence for stepwise mass extinctions spanning intervals of 1-3 Ma. For the K/T boundary, three candidates, Popigai, Manson, and Yucatan, have been proposed as impact craters. Two distinct strata at the K/T boundary in western North America have been interpreted as evidence for two sequential impacts. If multiple impacts occurred within a time span of about 1 Ma then multiple Ir enrichments should be observed. DSDP Hole 577B on the Shatsky Plateau in the northern Pacific at K/T time is the first site. Samples contain approximately greater than 97 percent CaCO3, which exhibit clear chemical signals associated with asteroidal/cometary impact. Ir, Fe, and Cr data are presented. From the Th-normalized data, two satellite peaks below the major peak at 78 cm and 81 cm of 577B-1-4 are clearly shown. The major Ir peak (K/T boundary) is at 72 cm. Fe and Cr, from C1-like impactor ejecta fallout, also show two peaks at the same positions. For hole 738C on the southern Kerguelen Plateau, Ir values reach a peak concentration of 18 ppb in the clay layer at 96.0-96.2 cm in section 20R-5, and gradually tail off. In the sample 115 cm above the boundary, Ir concentrations have still not reached background levels. From the Ir peak downward to the lowermost sample analyzed at 102 cm, the Ir concentration is still as high as 1.7 ppb. From the Th-normalized data, we observe a small Ir/Th peak at 100-101 cm. Though this peak is within the error margin, the trend is clear. Fe and Cr exhibit the same pattern. The third case is Hole 690C on the Queen Maud Ridge. Again, the Ir/Th plot indicates the strong possibility of satellite peaks at approximately 52 cm. The main peak is at 39-40 cm. For the Stevns Klint K/T boundary layers, the stratification of trace elements appears threefold with peak concentrations in sublayers A1, A3, and B2 for different element groups, including Ir. C1 ratios for many siderophile elements found in combined layers III and IV, corresponding to layers A, B, C, and D, strongly support the impact hypothesis. Also, multiple Ir anomalies in the K/T section at Lattengebirge, Bavarian Alps are reported. Recent works on Ni-rich spinels and Ir at the K/T boundaries clearly establish cometary/asteroidal impacts at the K/T boundary. Lastly, cometary showers can explain the enhanced Ir contents over approximately a 1 Ma interval in Gubbio shales.

Liu, Y.-G.↗

NASA NTRS1992

Mapping the mineralogy and lithology of Canyonlands, Utah with imaging spectrometer data and the multiple spectral feature mapping algorithm

The sedimentary sections exposed in the Canyonlands and Arches National Parks region of Utah (generally referred to as 'Canyonlands') consist of sandstones, shales, limestones, and conglomerates. Reflectance spectra of weathered surfaces of rocks from these areas show two components: (1) variations in spectrally detectable mineralogy, and (2) variations in the relative ratios of the absorption bands between minerals. Both types of information can be used together to map each major lithology and the Clark spectral features mapping algorithm is applied to do the job.

Clark, Roger N.↗

NASA NTRS1995

A conflict of water and fire: Remote sensing imagery of the Uinkaret Volcanic Field, Grand Canyon, Arizona

The sedimentary geology of the western Grand Canyon consists of gently northeast dipping sandstones, shales, and carbonates. However, due to facies changes within the units, the geomorphology varies from that seen by visitors at the National Park Headquarters. There, the cliff and slope expression of the rocks is replaced in the west by a series of mesas, ridges, and horizontal platforms. The largest of these occurs on the Esplanade Sandstone within the Supai Formation. The Esplanade is formed by slope retreat of the overlying units and resistance to erosion by the underlying limestones. It is onto this platform that the lavas of the Uinkaret Plateau were emplaced. The Uinkaret lava field lies 120 km south of St. George, Utah and is tectonically defined by two major normal faults -- the Hurricane to the west and the Toroweap to the east. The purpose of this investigation was to collect visible, near and thermal infrared data at different periods of the day and year. It is expected that these data will provide the ability to retrieve water temperatures; monitor sediment loads; map and examine any changes in the near shore vegetation communities and understand some of the intricacies of the geology. This paper will serve, to some degree, as a progress report on the Grand Canyon study, since only a fraction of the data has been received and processed thus far. Data from the Thermal Infrared Multispectral Scanner (TIMS) and the Landsat Thematic Mapper simulator (NS001) were acquired simultaneously on April 4, 1994. A second data acquisition occurred on August 27, 1994. Initial analysis of the TIMS data indicates a remarkably noise-free data set with minimal atmospheric attenuation. environments is evident.

Ramsey, Michael S.↗

NASA NTRS1994

Spectral reflectance properties of carbon-bearing materials

The 0.3-2.6 micrometers spectral reflectance properties of carbon polymorphs (graphite, carbon black, diamond), carbides (silicon carbide, cementite), and macromolecular organic-bearing materials (coal, coal tar extract, oil sand, oil shale) are found to vary from sample to sample and among groups. The carbon polymorphs are readily distinguishable on the basis of their visible-near infrared spectral slopes and shapes. The spectra of macromolecular organic-bearing materials show increases in reflectance toward longer wavelengths, exceeding the reflectance rise of more carbon-rich materials. Reflectance spectra of carbonaceous materials are affected by the crystal structure, composition, and degree of order/disorder of the samples. The characteristic spectral properties can potentially be exploited to identify individual carbonaceous grains in meteorites (as separates or in situ) or to conduct remote sensing geothermometry and identification of carbonaceous phases on asteroids.

Cloutis, Edward A.↗

NASA NTRS1998

Evidence of Microfossils in Carbonaceous Chondrites

Investigations have been carried out on freshly broken, internal surfaces of the Murchison, Efremovka and Orgueil carbonaceous chondrites using Scanning Electron Microscopes (SEM) in Russia and the Environmental Scanning Electron Microscope (ESEM) in the United States. These independent studies on different samples of the meteorites have resulted in the detection of numerous spherical and ellipsoidal bodies (some with spikes) similar to the forms of uncertain biogenicity that were designated "organized elements" by prior researchers. We have also encountered numerous complex biomorphic microstructures in these carbonaceous chondrites. Many of these complex bodies exhibit diverse characteristics reminiscent of microfossils of cyanobacteria such as we have investigated in ancient phosphorites and high carbon rocks (e.g. oil shales). Energy Dispersive Spectroscopy (EDS) analysis and 2D elemental maps shows enhanced carbon content in the bodies superimposed upon the elemental distributions characteristic of the chondritic matrix. The size, distribution, composition, and indications of cell walls, reproductive and life cycle developmental stages of these bodies are strongly suggestive of biology' These bodies appear to be mineralized and embedded within the meteorite matrix, and can not be attributed to recent surface contamination effects. Consequently, we have interpreted these in-situ microstructures to represent the lithified remains of prokaryotes and filamentous cyanobacteria. We also detected in Orgueil microstructures morphologically similar to fibrous kerite crystals. We present images of many biomorphic microstructures and possible microfossils found in the Murchison, Efremovka, and Orgueil chondrites and compare these forms with known microfossils from the Cambrian phosphate-rich rocks (phosphorites) of Khubsugul, Northern Mongolia.

Hoover, Richard B.↗

NASA NTRS1998

Evidence for Microfossils in Ancient Rocks and Meteorites

The McKay et all. detection of chemical biomarkers and possible microfossils in an ancient meteorite from Mars (ALH84001) stimulated research in several areas of importance to the newly emerging field of Astrobiology. Their report resulted in a search for additional evidence of microfossils in ancient terrestrial rocks and meteorites. These studies of ancient rocks and meteorites were conducted independently (and later collaboratively) in the United States and Russia using the SEM, Environmental Scanning Electron Microscope (ESEM), and Field Emission Scanning Electron Microscope (FESEM). We have encountered in-situ in freshly broken carbonaceous chondrites a large number of complex microstructures that appear to be lithified microbial forms. The meteoritic microstructures have characteristics similar to the lithified remains of filamentous cyanobacteria and bacterial microfossils we have found in ancient phosphorites, ancient graphites and oil shales. Energy Dispersive Spectroscopy (EDS) and Link microprobe analysis shows the possible microfossils have a distribution of chemical elements characteristic of the meteorite rock matrix, although many exhibit a superimposed carbon enhancement. We have concluded that the mineralized bodies encountered embedded in the rock matrix of freshly fractured meteoritic surfaces can not be dismissed as recent surface contaminants. Many of the forms found in-situ in the Murchison, Efremovka, and Orgueil carbonaceous meteorites are strikingly similar to microfossils of coccoid bacteria, cyanobacteria and fungi such as we have found in the Cambrian phosphorites of Khubsugul, Mongolia and high carbon Phanerozoic and Precambrian rocks of the Siberian and Russian Platforms.

Hoover, Richard B.↗

NASA NTRS1999

Bacterial Paleontology and Studies of Carbonaceous Chondrites

The study of the fossilization processes of modern cyanobacteria provides insights needed to recognize bacterial microfossils. The fossilization of cyanobacteria is discussed and images of recent and fossil bacteria and cyanobacteria from the Early Proterozoic to Neogene carbonaceous rocks (kerites, shungites, and black shales) and phosphorites are provided. These are compared with biomorphic microstructures and possible microfossils encountered in-situ in carbonaceous meteorites.

Gerasimenko, L. M.↗

NASA NTRS1997

Cryptoblemes: A New Discovery with Major Economic Implications and Profound Changes to the Geologic Paradigm

Cryptoblemes are subtle impact shock signatures imprinted by cosmic debris on the crustal surfaces of lunar planetary bodes. These signatures constitute a complex cumulative overprinting of topographic, structural geophysical, and tectonic patterns that have a conspicuous radial centric multiringed symmetry. The geometry and distribution of cryptoblemes on Earth is comparable to the size and density of impact features on lunar planetary surfaces. Analysis of satellite imagery, sea-floor sonar, side-looking radar and aerial photographs of specific sites reveals new criteria for the identification and confirmation of impact-shock signatures. These criteria include joint and foliation patterns with asbestiform minerals, ribbon-quartz, spheroidal weathering, domal exfoliation, pencil shale, and shock spheres, which may originate from hydrocavitation of water-saturated sedimentary rocks. Cryptoblemes may also be associated with breccia pipes, sinkholes, buttes, mesas, and bogs, high-Rn anomalies, nodular concentrations, and earthquake epicenters. Major implications of cryptobleme identification include exploratory targeting of hydrocarbon and mineral deposits and the explanation of their origins. Analysis of known mineral deposits, structural traps and sedimentary basins show a direct correlation with cryptobleme patterns. Significant geologic paradigm shifts related to cryptoblemes include mountain building processes, structural orogenies, induced volcanism, earthquake origins, hydrocarbon diagenesis, formation mineral deposits, continental rifting, and plate movements, magnetic overprinting and local regional, and global geologic extinction and speciation patterns. Two figures provide a comparison between a multiring impact overprint in water and multiring cryptobleme in the U.S. basin range. (Additional information is contained in the original document).

Windolph, J., Jr.↗

NASA NTRS2000

The Precambrian Biogeochemical Carbon Isotopic Record: Contributions of Thermal Versus Biological Processes

Superplumes offer a new approach for understanding global C cycles. Isotopes help to discern the impacts of geological, environmental and biological processes ujpun the evolution of these cycles. For example, C-13/C-12 values of coeval sedimentary organics and carbonates give global estimates of the fraction of C buried as organics (Forg), which today lies near 0.2. Before Oxygenic photosynthesis arose, our biosphere obtained reducing power for biosynthesis solely from thermal volatiles and rock alteration. Thus Forg was dominated by the mantle redox state, which has remained remarkably constant for greater than Gy. Recent data confirm that the long-term change in Forg had been small, indicating that the mantle redox buffer remains important even today. Oxygenic photosynthesis enabled life to obtain additional reducing power by splitting the water molecule. Accordingly, biological organic production rose above the level constrained by the mantle-derived flux of reduced species. For example, today, chemoautotrophs harvesting energy from hydrothermal emanations can synthesize at most between 0.2 x 10(exp 12) and 2x 10(exp 12) mol C yr-1 of organic C globally. In contrast, global photosynthetic productivity is estimated at 9000 x 10(exp 12) mol C yr-1. Occasionally photosynthetic productivity did contribute to dramatically -elevated Forg values (to 0.4 or more) as evidenced by very high carbonate C-13/C-12. The interplay between biological, tectonic and other environmental factors is illustrated by the mid-Archean to mid-Proterozoic isotopic record. The relatively constant C-13/C-12 values of Archean carbonates support the view that photosynthetically-driven Forg increases were not yet possible. In contrast, major excursions in C-13/C-12, and thus also in Forg, during the early Proterozoic confirmed the global importance of oxygenic photosynthesis by that time. Remarkably, the superplume event at 1.9 Ga did not trigger another major Forg increase, despite the favorable conditions for organic burial that were evidenced by elevated sea levels and higher black shale abundances. Perhaps those superplume-rated processes that favored enhanced organic burial were offset by the ability of mantle-derived redox buffering, which was enhanced during the superplume event, to limit excursions in Forg.

DesMarais, David J.↗

NASA NTRS2003

Carbonate Platform Development and Stromatolite Morphogenesis: Constraints on Environmental and Biological Evolution

Work has been completed on the digital mapping of a terminal Proterozoic reef complex in Namibia. This complex formed an isolated carbonate platform developed downdip on a carbonate ramp of the Nama Group. The stratigraphic evolution of the platform was digitally reconstructed from an extensive dataset that was compiled by using digital surveying technologies. The platform comprises three accommodation cycles in which each subsequent cycle experienced progressively greater influence of a long-term accommodation increase. Aggradation and progradation during the first cycle resulted in a flat, uniform, sheet-like platform. The coarsening and shallowing-upward sequence representing the first cycle is dominated by columnar stromatolitic thrombolites and massive dolostones with interbedded mudstone-grainstone at the base of the sequence grading into cross-bedded dolostones. The second cycle features aggradation, formation of a distinct margin containing thrombolite mounds and domes, and the development of a bucket geometry. Columnar stromatolitic thrombolites dominate the platform interior. The final stage of platform development shows a deepening trend with initial aggradation and formation of well-bedded, thin deposits in the interior and mound development at the margins. While the interior drowned, the platform margin kept up with rising sea level and a complex pinnacle reef formed containing fused and coalesced thrombolite mounds flanked by bioclastic grainstones (containing Cloudina and Namacalathus fossils) and collapse breccias. A set of isolated large thrombolite mounds flanked by shales indicate the final stage of the carbonate platform. During a progressive increase in accommodation, a flat-topped isolated carbonate platform becomes aerially less extensive by either backstepping or formation of smaller pinnacles or a combination of both. The overall geometric evolution of the studied platform from flat-topped to bucket with elevated margins is recorded in many Proterozoic and Phanerozoic isolated carbonate platforms with similar dimensions. The terminal Proterozoic, microbial-dominated, isolated carbonate platform of this study clearly illustrates that the answer to accommodation changes was already familiar among carbonate platforms before the dawn of metazoan-dominated platforms.

Grotzinger, John P.↗