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At least 199 records · Page 11

A New Analytical Approach to Predict Spacing Selection in Lamellar and Rod Eutectic Systems

The Jackson and Hunt (JH) theory has been modified to relax the assumption of isothermal solid liquid interface used in their treatment. Based on the predictions of this modified theory, the traditional definitions of regular and irregular eutectics are revised. For regular eutectics, the new model identifies a range of spacing within the limits defined by the minimum undercooling of the a and beta phases. For the irregular Al-Si eutectic system, two different spacing selection mechanisms were identified: (1) for a particular growth rate, a nearly isothermal interface can be achieved at a unique minimum spacing lambda (sub t); (2) the average spacing (lambda (sub av) greater than lambda (sub t) is essentially dictated by the undercooling of the faceted phase. Based on the modified theoretical model, a semiempirical expression has been developed to account for the influence of the temperature gradient, which is dominant in the irregular Al-Si system. The behavior of the Fe-Fe3C eutectic is also discussed. The theoretical calculations have been found to be in good agreement with the published experimental measurements.

Catalina, Adrian V.↗

EAGLE Monitors by Collecting Facts and Generating Obligations

We present a rule-based framework, called EAGLE, that has been shown to be capable of defining and implementing a range of finite trace monitoring logics, including future and past time temporal logic, extended regular expressions, real-time and metric temporal logics, interval logics, forms of quantified temporal logics, and so on. A monitor for an EAGLE formula checks if a finite trace of states satisfies the given formula. We present, in details, an algorithm for the synthesis of monitors for EAGLE. The algorithm is implemented as a Java application and involves novel techniques for rule definition, manipulation and execution. Monitoring is achieved on a state-by-state basis avoiding any need to store the input trace of states. Our initial experiments have been successful as EAGLE detected a previously unknown bug while testing a planetary rover controller.

Barrnger, Howard↗

EAGLE can do Efficient LTL Monitoring

We briefly present a rule-based framework, called EAGLE, that has been shown to be capable of defining and implementing finite trace monitoring logics, including future and past time temporal logic, extended regular expressions, real-time logics, interval logics, forms of quantified temporal logics, and so on. In this paper we show how EAGLE can do linear temporal logic (LTL) monitoring in an efficient way. We give an upper bound on the space and time complexity of this monitoring.

Barringer, Howard↗

Rule-Based Runtime Verification

We present a rule-based framework for defining and implementing finite trace monitoring logics, including future and past time temporal logic, extended regular expressions, real-time logics, interval logics, forms of quantified temporal logics, and so on. Our logic, EAGLE, is implemented as a Java library and involves novel techniques for rule definition, manipulation and execution. Monitoring is done on a state-by-state basis, without storing the execution trace.

Barringer, Howard↗

Analytical Solution for the Critical Velocity of Pushing/Engulfment Transition

The distribution of ceramic particles in a metal matrix composite material depends primarily on the interaction of the particles with the solid/liquid interface during the solidification process. A numerical model that describes the evolution of the shape of the solid/liquid interface in the proximity of a foreign particle will presented in this paper. The model accounts for the influence of the temperature gradient and the Gibbs-Thomson and disjoining pressure effects. It shows that for the systems characterized by k(sub p) < k(sub L) the disjoining pressure causes the interface curvature to change its sign in the close-contact particle/interface region. It also shows that the increase of the temperature gradient diminishes the effect of the disjoining pressure. The analysis of the numerical results obtained for a large range of processing conditions and materials parameters has led to the development of an analytical solution for the critical velocity of pushing/engulfinent transition. The theoretical results will be discussed and compared with the experimental measurements performed under microgravity conditions.

Catalina, Adrian V.↗

Triggering of the Two X-class Flares of 28 and 29 October 2003

From H-alpha movies from Aryabhatta Research Institute of Observational Sciences and from Prairie View Solar Observatory, hard X-ray movies from RHESSI, line-of-sight magnetogram movies from SOHO/MDI, and vector magnetograms from Marshal Space Flight Center, we examine the magnetic structure and evolution of the large delta-sunspot active region NOAA 10486 in relation to the onset and development of the two X-class flares that occurred in this active region on 28 and 29 October 2003. We find evidence that each of these flares was triggered by strongly sheared magnetic field via "tether-cutting" reconnection with adjacent/overlying strongly sheared field. In the first flare, the initial brightening in H-alpha: (1) was partly rooted in emerging sheared magnetic field along the edge of the large positive-polarity flux domain of the delta sunspot, and (2) consisted of four flare kernels, two in negative magnetic flux and two in positive magnetic flux. In the second flare, the brightening started in the core of a Z-shaped sigmoidal sheared magnetic field and the inner two of four H-alpha kernels were visible in 30-50 Kev hard X-ray image from RHESSI. Each flare spread from the initial quadrupolar brightening to develop into a much larger two-ribbon flare straddling a much more extensive swath of strongly sheared field along the edge of the large positive-flux domain of the delta sunspot, the first flare on the leading side and the second flare on the trailing side of this domain. Thus, localized internal reconnection triggered the explosion of these extensive sheared magnetic fields.

Choudhary, Debi Prasad↗

The Pore Formation and Mobility Investigation: The Apparatus, Operations, Science Obtained, and Potential for Continued Usage

The objective of the presentation is to provide an overview of the Pore Formation and Mobility Investigation (PFMI) hardware that is currently aboard the International Space Station and to identify European experiments could utilize it. The hardware, integration in the Glovebox, operations,-science results, and instrument performance assessment will be presented. The possibilities of adapting the optical observation system will also be reviewed.

Gurgel, R. N.↗

Interaction of Porosity with a Planar Solid/Liquid Interface

In this article, an investigation of the interaction between gas porosity and a planar solid/liquid (SL) interface is reported. A two-dimensional numerical model able to accurately track sharp SL interfaces during solidification of pure metals and alloys is proposed. The finite-difference method and a rectangular undeformed grid are used for computation. The SL interface is described through the points of intersection with the grid lines. Its motion is determined by the thermal and solute gradients at each particular point. Changes of the interface temperature because of capillarity or solute redistribution as well as any perturbation of the thermal and solute field produced by the presence of non-metallic inclusions can be computed. To validate the model, the dynamics of the interaction between a gas pore and a solidification front in metal alloys was observed using a state of the art X-ray transmission microscope (XTM). The experiments included observation of the distortion of the SL interface near a pore, real-time measurements of the growth rate, and the change in shape of the porosity during interaction with the SL interface in pure Al and Al-0.25 wt pct Au alloy. In addition, porosity-induced solute segregation patterns surrounding a pore were also quantified.

Catalina, Adrian V.↗

The narrow pulse approximation and long length scale determination in xenon gas diffusion NMR studies of model porous media

We report a systematic study of xenon gas diffusion NMR in simple model porous media, random packs of mono-sized glass beads, and focus on three specific areas peculiar to gas-phase diffusion. These topics are: (i) diffusion of spins on the order of the pore dimensions during the application of the diffusion encoding gradient pulses in a PGSE experiment (breakdown of the narrow pulse approximation and imperfect background gradient cancellation), (ii) the ability to derive long length scale structural information, and (iii) effects of finite sample size. We find that the time-dependent diffusion coefficient, D(t), of the imbibed xenon gas at short diffusion times in small beads is significantly affected by the gas pressure. In particular, as expected, we find smaller deviations between measured D(t) and theoretical predictions as the gas pressure is increased, resulting from reduced diffusion during the application of the gradient pulse. The deviations are then completely removed when water D(t) is observed in the same samples. The use of gas also allows us to probe D(t) over a wide range of length scales and observe the long time asymptotic limit which is proportional to the inverse tortuosity of the sample, as well as the diffusion distance where this limit takes effect (approximately 1-1.5 bead diameters). The Pade approximation can be used as a reference for expected xenon D(t) data between the short and the long time limits, allowing us to explore deviations from the expected behavior at intermediate times as a result of finite sample size effects. Finally, the application of the Pade interpolation between the long and the short time asymptotic limits yields a fitted length scale (the Pade length), which is found to be approximately 0.13b for all bead packs, where b is the bead diameter. c. 2002 Elsevier Sciences (USA).

NASA Discipline Life Sciences Technologies↗

Balloon observations of organic and inorganic chlorine in the stratosphere: the role of HClO4 production on sulfate aerosols

Simultaneous observations of stratospheric organic and inorganic chlorine were made in September 1993 out of Fort Sumner, New Mexico, using JPL balloon-borne MkIV interferometer. Between 15 and 20 km, a significant fraction (20-60%) of the inorganic chlorine could not be accounted for by the sum of measured HCl, ClONO2, and HOCl. Laboratory measurements of the reaction of ClO radicals on sulfuric acid solutions have indicated that, along with HCl, small amounts of perchloric acid, HClO4, were formed. Very little is known about the fate of HClO4 in the stratosphere and we use a photochemical box model to determine the impact of this new species on the partitioning of inorganic chlorine in the stratosphere. Assuming that HClO4 is photochemically stable, it is shown that in the enhanced aerosol loading conditions resulting from Mt. Pinatubo's eruption, HClO4 could represent a significant reservoir of chlorine in the lower stratosphere, sequestering up to 0.2 ppbv (or 50%) of the total inorganic chlorine at 16 km. The occurrence of this new species could bring to closure the inorganic chlorine budget deficiency made apparent by recent ER-2 aircraft in situ measurements of HCl.

unmanned↗

Dielectric constant of liquid alkanes and hydrocarbon mixtures

The complex dielectric constants of n-alkanes with two to seven carbon atoms have been measured. The measurements were conducted using a slotted-line technique at 1.2 GHz and at atmospheric pressure. The temperature was varied from the melting point to the boiling point of the respective alkanes. The real part of the dielectric constant was found to decrease with increasing temperature and correlate with the change in the molar volume. An upper limit to all the loss tangents was established at 0.001. The complex dielectric constants of a few mixtures of liquid alkanes were also measured at room temperature. For a pentane-octane mixture the real part of the dielectric constant could be explained by the Clausius-Mosotti theory. For the mixtures of n-hexane-ethylacetate and n-hexane-acetone the real part of the dielectric constants could be explained by the Onsager theory extended to mixtures. The dielectric constant of the n-hexane-acetone mixture displayed deviations from the Onsager theory at the highest fractions of acetone. The dipole moments of ethylacetate and acetone were determined for dilute mixtures using the Onsager theory and were found to be in agreement with their accepted gas-phase values. The loss tangents of the mixtures exhibited a linear relationship with the volume fraction for low concentrations of the polar liquids.

NASA Program Exobiology↗

Sulfur and nitrogen reactions for cometary comae ion chemistry

The low pressure reactions of sulfur dioxide, carbon disulfide, and hydrazine with H2O+ and H3O+ were studied by the ion cyclotron resonance technique. These reactions are potentially important for sulphur chemistry in cometary comae. Rate coefficients and branching ratios of product channels are presented.

NASA Center JPL↗

Tortuosity measurement and the effects of finite pulse widths on xenon gas diffusion NMR studies of porous media

We have extended the utility of NMR as a technique to probe porous media structure over length scales of approximately 100-2000 microm by using the spin 1/2 noble gas 129Xe imbibed into the system's pore space. Such length scales are much greater than can be probed with NMR diffusion studies of water-saturated porous media. We utilized Pulsed Gradient Spin Echo NMR measurements of the time-dependent diffusion coefficient, D(t), of the xenon gas filling the pore space to study further the measurements of both the pore surface-area-to-volume ratio, S/V(p), and the tortuosity (pore connectivity) of the medium. In uniform-size glass bead packs, we observed D(t) decreasing with increasing t, reaching an observed asymptote of approximately 0.62-0.65D(0), that could be measured over diffusion distances extending over multiple bead diameters. Measurements of D(t)/D(0) at differing gas pressures showed this tortuosity limit was not affected by changing the characteristic diffusion length of the spins during the diffusion encoding gradient pulse. This was not the case at the short time limit, where D(t)/D(0) was noticeably affected by the gas pressure in the sample. Increasing the gas pressure, and hence reducing D(0) and the diffusion during the gradient pulse served to reduce the previously observed deviation of D(t)/D(0) from the S/V(p) relation. The Pade approximation is used to interpolate between the long and short time limits in D(t). While the short time D(t) points lay above the interpolation line in the case of small beads, due to diffusion during the gradient pulse on the order of the pore size, it was also noted that the experimental D(t) data fell below the Pade line in the case of large beads, most likely due to finite size effects.

Non-NASA Center↗

Ten-fold augmentation of endothelial uptake of vascular endothelial growth factor with ultrasound after systemic administration

OBJECTIVES: In this study, the feasibility of delivering and enhancing the uptake of vascular endothelial growth factor (VEGF) into the intact endothelium by using ultrasound (US) facilitation was determined. BACKGROUND: A limitation of tissue-targeted drug delivery is the need for direct arterial cannulation. We postulate a mechanism by which agents injected intravenously may be targeted to a tissue using US and ultrasonic contrast agents. METHODS: We used a rat model to test the ability of US and an ultrasonic contrast agent perflurocarbon exposed sonicated dextrose albumin (PESDA) to increase uptake of VEGF in the myocardium. Continuous wave Doppler US (0.6 W/cm2 at 1 MHz for 15 min) was applied to the chest wall overlying the myocardium during intravenous injection with either VEGF (100 microg/kg) alone or a combination of VEGF and PESDA (0.1%). Control rats had VEGF infused without US or PESDA. The VEGF uptake was measured quantitatively in the heart, lung, liver and kidneys by enzyme-linked immunosorbent assay (ng/g of tissue) and morphologically by fluorescence microscopy. RESULTS: There was an eight-fold increase in VEGF uptake in the heart by US alone (16.86 +/- 1.56 vs. 2.11 +/- 0.953 ng/g of tissue, p < 0.0001) and a 13-fold increase with US + PESDA (26.78 +/- 2.88 vs. 2.11 +/- 0.953 ng/g of tissue, p < 0.0001) compared with control rats. Fluorescence microscopy revealed deposition of VEGF in the endothelium of small intramyocardial arterioles. CONCLUSIONS: These results show a marked increase in endothelial VEGF uptake with US and US + PESDA. Thus, US may be used to augment endothelial VEGF uptake 10-fold to 13-fold.

Non-NASA Center↗

Airframe Noise Sub-Component Definition and Model

Both in-house, and jointly with NASA under the Advanced Subsonic Transport (AST) program, Boeing Commerical Aircraft Company (BCA) had begun work on systematically identifying specific components of noise responsible for total airframe noise generation and applying the knowledge gained towards the creation of a model for airframe noise prediction. This report documents the continuation of the collection of database from model-scale and full-scale airframe noise measurements to compliment the earlier existing databases, the development of the subcomponent models and the generation of a new empirical prediction code. The airframe subcomponent data includes measurements from aircraft ranging in size from a Boeing 737 to aircraft larger than a Boeing 747 aircraft. These results provide the continuity to evaluate the technology developed under the AST program consistent with the guidelines set forth in NASA CR-198298.

Golub, Robert A.↗

Characteristics of Heavy Summer Rainfall in Southwestern Taiwan in Relation to Orographic Effects

On the windward side of southwestern Taiwan, about a quarter to a half of all rainfall during mid-July through August from 1994 to 2000 came from convective systems embedded in the southwesterly monsoon flow. k this study, the causes of two heavy rainfall events (daily rainfall exceeding 100 mm day over at least three rainfall stations) observed over the slopes and/or lowlands of southwestern Taiwan were examined. Data from European Center for Medium-Range Weather Forecasts /Tropical Ocean- Global Atmosphere (EC/TOGA) analyses, the rainfall stations of the Automatic Rainfall and Meteorological Telemetry System (ARMTS) and the conventional surface stations over Taiwan, and the simulation results from a regional-scale numerical model were used to accomplish the objectives. In one event (393 mm day on 9 August 1999), heavy rainfall was observed over the windward slopes of southern Taiwan in a potentially unstable environment with very humid air around 850 hPa. The extreme accumulation was simulated and attributed to orographic lifting effects. No preexisting convection drifted in from the Taiwan Strait into western Taiwan.

Chen, Ching-Sen↗

Mesoscale Simulations of CRYSTAL-FACE 23 July 2002 Case

A key objective of the Cirrus Regional Study of Tropical Anvils and Cirrus Layers - Florida Area Cirrus Experiment (CRYSTAL-FACE) is to understand the relationships between properties of tropical convective cloud systems and the lifecycle of the extended cirrus anvils they produce. We report here on a case study of 23 July 2002 where a line of land-based convective storms was generated between Lake Okeechobee and the Florida east coast as a result of complex interactions between lake and sea breeze fronts and outflow boundaries. A central goal of this study is to develop a description of convective input to the anvil system and to quantify the ongoing dynamical forcing of anvil processes by mesoscale and large-scale dynamics. This information is then used to force high-resolution cloud simulations with a model that explicitly resolves cloud microphysical processes (bin model) for study of cirrus anvil microphysical development.

Starr, David↗

Evolution of In-Situ Generated Reinforcement Precipitates in Metal Matrix Composites

Due to certain inherent advantages, in-situ production of Metal Matrix Composites (MMCs) have received considerable attention in the recent past. ln-situ techniques typically involve a chemical reaction that results in precipitation of a ceramic reinforcement phase. The size and spatial distribution of these precipitates ultimately determine the mechanical properties of these MMCs. In this paper we will investigate the validity of using classical growth laws and analytical expressions to describe the interaction between a precipitate and a solid-liquid interface (SLI) to predict the size and spatial evolution of the in-situ generated precipitates. Measurements made on size and distribution of Tic precipitates in a Ni&I matrix will be presented to test the validity of such an approach.

Sen, S.↗