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At least 199 records · Page 11

Coherent Control over Nuclear Hyperpolarization Using an Optically Initializable Chromophore-Radical System

Chromophore radicals (CR) are emerging as important components for molecular quantum information science (QIS), especially in the context of quantum sensing. Here, we demonstrate that the optically hyperpolarized electrons in a 1,6,7,12-tetrakis(4-tert-butylphenoxy)-perylene-3,4,9,10-bis(dicarboximide) (tpPDI) covalently linked to a partially deuterated 1,3-bis(diphenylene)-d 16 -2-phenylallyl radical (BDPA-d 16 ) can be coherently manipulated via pulsed dynamic nuclear polarization (DNP) methods to transfer polarization to nuclear spins and back. Under light illumination at 85 K, electron hyperpolarization in BDPA is enhanced 2.1- to 2.4-fold over thermal polarization and lasts for more than 100 ms. By applying nuclear orientation via electron spin-locking (NOVEL) DNP, this optically amplified electron hyperpolarization was successfully transferred to a 1 H nuclear spin within the CR system and efficiently returned to the electron spin for readout via reverse-NOVEL. The NOVEL transfer efficiency of 65% amounts to a 688-fold nuclear spin hyperpolarization of the target nuclear spin, considering the 2.1-fold electron spin hyperpolarization. This reversible coherent manipulation of hyperpolarization transfer highlights the utility of CR systems to initialize and read out nuclear spin states in a disordered matrix at moderate cryogenic temperatures. Coupled with CRs’ environmental compatibility, tunability, and precise state initialization, these results highlight the promising role of nuclear spins in CRs for QIS applications, including quantum sensing and memory.

charge transfer↗

Tunable Cr 4+ Molecular Color Centers

The inherent atomistic precision of synthetic chemistry enables bottom-up structural control over quantum bits, or qubits, for quantum technologies. Tuning paramagnetic molecular qubits that feature optical-spin initialization and readout is a crucial step toward designing bespoke qubits for applications in quantum sensing, networking, and computing. In this work, we demonstrate that the electronic structure that enables optical-spin initialization and readout for S = 1, Cr(aryl) 4 , where aryl = 2,4-dimethylphenyl (1), o-tolyl (2), and 2,3-dimethylphenyl (3), is readily translated into Cr(alkyl) 4 compounds, where alkyl = 2,2,2-triphenylethyl (4), (trimethylsilyl)methyl (5), and cyclohexyl (6). The small ground state zero field splitting values (<5 GHz) for 1–6 allowed for coherent spin manipulation at X-band microwave frequency, enabling temperature-, concentration-, and orientation-dependent investigations of the spin dynamics. Electronic absorption and emission spectroscopy confirmed the desired electronic structures for 4–6, which exhibit photoluminescence from 897 to 923 nm, while theoretical calculations elucidated the varied bonding interactions of the aryl and alkyl Cr 4+ compounds. The combined experimental and theoretical comparison of Cr(aryl) 4 and Cr(alkyl) 4 systems illustrates the impact of the ligand field on both the ground state spin structure and excited state manifold, laying the groundwork for the design of structurally precise optically addressable molecular qubits.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Juno at Jupiter: The Mission and Its Path to Unveiling Secrets of the History of the Solar System

The Juno mission is described, focusing on its orbits at Jupiter, how the plan evolved, and science return so far. Juno is a NASA New Frontiers spacecraft in a near-polar highly elliptical 53-day orbit at Jupiter. Since arrival in July 2016, it has used 9 science investigations to study the planet’s atmospheric composition and structure, magnetic and gravity fields, and polar and extended magnetosphere. A radiation monitoring investigation contributes to our understanding of Jupiter’s environment. Juno’s primary science goal is to understand the origin and evolution of Jupiter, to shed light on how the Earth and other planets formed. Baseline objectives will be satisfied with 32 science orbits, a spin-stabilized solar powered spacecraft, an electronics vault for radiation shielding, and a robust payload with microwave receivers, X- and Ka-band radio science hardware, vector magnetometers, high- and low-energy charged particle detectors, radio and plasma wave antennas, UV and IR spectroscopic imagers, and a visible light camera for public outreach. Observations are made in a limited number of orientations, including Gravity Science (spin axis and main antenna pointing to Earth), and microwave atmospheric sounding (spin plane passing through Jupiter’s center). Prime science data are collected near closest approach (perijove), plus calibrations, occasional remote sensing, and continued magnetospheric observations in the outer parts of the orbit. Juno’s mission plan has evolved since the 2005 proposal due to design and ops choices, e.g., mission design (cruise or early orbital trajectory), orbit period (11, 14, then 53 days), perijove attitudes (2 or more), and DSN coverage (34- and 70-m stations). Choices were partly motivated by the effect on science return. Selected preliminary science results are summarized, including the benefits of decisions as the plan evolved. Juno has begun to unveil Jupiter – peeling apart its interior by measuring gravity and magnetic fields, using microwaves to probe its atmosphere down to 100s of km, exploring its polar and extended magnetosphere, and imaging the poles for the first time. In doing so, it is revealing secrets of the history of the Earth and solar system.

Stephens, Stuart K.↗

Field-free switching of perpendicular magnetization in a ferrimagnetic insulator with spin reorientation transition

Writing magnetic bits through spin-orbit torque (SOT) switching is promising for fast and efficient magnetic random-access memory devices. While SOT switching of out-of-plane (OOP) magnetized states requires lateral symmetry breaking, in-plane (IP) magnetized states suffer from low storage density. Here, we demonstrate a field-free switching scheme using a 5-nanometer europium iron garnet film grown with a (110) orientation that shows a spin reorientation transition from OOP to IP above room temperature. This scheme combines the benefits of high-density storage in the OOP states at room temperature and the efficient field-free SOT switching in the IP states at elevated temperatures. While conventional switching of OOP bits faces the dilemma that high OOP anisotropy is required to improve bit stability and low OOP anisotropy is required to lower switching current density, this scheme disentangles this interdependence, allowing for low switching currents to be possible without sacrificing the bit stability, offering opportunities for future memory devices.

Science & Technology - Other Topics↗

Uranus' rotational period

A modified spectroscopic technique was applied to determine the rotational period of Uranus and the orientation of the projected spin axis of the planet. The method consists in obtaining a series of spectra for both a nonrotated planet disk and for a disk rotated 180 degrees. Ignoring the effects of seeing in analyzing the spectra for no rotation of the disk leads to a lower limit on the period, and for a disk rotated 180 degrees, ignoring the seeing in the modeling of the spectra leads to an upper limit on the period. When blurring from seeing and guiding errors are added to the modeling for both image orientations and the model spectra are compared to the observations, both the period and the degree of blurring are obtained simultaneously. The results gave a period of rotation of Uranus 23 + 5 or - 2 hr.

Trafton, L.↗

SDSS-IV MaNGA: 3D spin alignment of spiral and S0 galaxies

ABSTRACT We investigate the 3D spin alignment of galaxies with respect to the large-scale filaments using the MaNGA survey. The cosmic web is reconstructed from the Sloan Digital Sky Survey using disperse and the 3D spins of MaNGA galaxies are estimated using the thin disc approximation with integral field spectroscopy kinematics. Late-type spiral galaxies are found to have their spins parallel to the closest filament’s axis. The alignment signal is found to be dominated by low-mass spirals. Spins of S0-type galaxies tend to be oriented preferentially in perpendicular direction with respect to the filament’s axis. This orthogonal orientation is found to be dominated by S0s that show a notable misalignment between their kinematic components of stellar and ionized gas velocity fields and/or by low-mass S0s with lower rotation support compared to their high-mass counterparts. Qualitatively similar results are obtained when splitting galaxies based on the degree of ordered stellar rotation, such that galaxies with high spin magnitude have their spin aligned, and those with low spin magnitude in perpendicular direction to the filaments. In the context of conditional tidal torque theory, these findings suggest that galaxies’ spins retain memory of their larger scale environment. In agreement with measurements from hydrodynamical cosmological simulations, the measured signal at low redshift is weak, yet statistically significant. The dependence of the spin-filament orientation of galaxies on their stellar mass, morphology, and kinematics highlights the importance of sample selection to detect the signal.

Kraljic, Katarina↗

Multiphase magnetism in Yb 2 Ti 2 O 7

We use neutron scattering to show that ferromagnetism and antiferromagnetism coexist in the low T state of the pyrochlore quantum magnet Yb 2 Ti 2 O 7 . While magnetic Bragg peaks evidence long-range static ferromagnetic order, inelastic scattering shows that short-range correlated antiferromagnetism is also present. Small-angle neutron scattering provides direct evidence for mesoscale magnetic structure that we associate with metastable antiferromagnetism. Classical Monte Carlo simulations based on exchange interactions inferred from ⟨ 111 ⟩ -oriented high-field spin wave measurements confirm that antiferromagnetism is metastable within the otherwise ferromagnetic ground state. The apparent lack of coherent spin wave excitations and strong sensitivity to quenched disorder characterizing Yb 2 Ti 2 O 7 is a consequence of this multiphase magnetism.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Power-Law Entanglement and Hilbert Space Fragmentation in Nonreciprocal Quantum Circuits

Quantum circuits utilizing measurement to evolve a quantum wave function offer a new and rich playground to engineer unconventional entanglement dynamics. Here, in this work, we introduce a hybrid, nonreciprocal setup featuring a quantum circuit, whose updates are conditioned on the state of a classical dynamical agent. In our example the circuit is represented by a Majorana quantum chain controlled by a classical N-state Potts chain undergoing pair flips. The local orientation of the classical spins controls whether randomly drawn local measurements on the quantum chain are allowed or not. This imposes a dynamical kinetic constraint on the entanglement growth, described by the transfer matrix of an N-colored loop model. It yields an equivalent description of the circuit by an SU(N)-symmetric Temperley-Lieb Hamiltonian or by a kinetically constrained surface growth model for an N-component height field. For N = 2, we find a diffusive growth of the half-chain entanglement toward a stationary profile S(L) ~ L 1/2 for L sites. For N ≥ 3, the kinetic constraints impose Hilbert space fragmentation, yielding subdiffusive growth toward S(L) ~ L 0.57 . This showcases how the control by a classical dynamical agent can enrich the entanglement dynamics in quantum circuits, paving a route toward novel entanglement dynamics in nonreciprocal hybrid circuit architectures.

1-dimensional spin chains↗

Performance of the SERT 2 spacecraft after 4 and one-half years in space

The SERT 2 satellite, launched in February, 1970, has recently been reactivated after being dormant for a year. The satellite orientation was changed to spin stabilization in 1973 and the satellite is now coning such that the active side of the solar arrays move into and out of the sun every 23 days. There is sufficient power to operate the ion thrusters for seven days of this cycle. The 2 ion thruster system was successfully operated; the electrical short in the accelerating grids had cleared during the year long dormant phase.

Ignaczak, L. R.↗

Photometric lightcurves of 21 asteroids

Forty-three light curves of 21 asteroids obtained during 1968-1978 are presented and briefly discussed. The light curves were obtained to increase the data base for studies in shapes, spin periods, and the orientation of the rotation axes.

Vesely, C. D.↗

Phobos and Deimos control networks

Viking Orbiter images of Phobos and Deimos have been measured to establish global control networks for 98 surface features of the former and 53 of the latter; photogrammetric triangulation has yielded body-fixed coordinates of these control-points, as well as mean triaxial radii of 13.3 x 11.1 x 9.3 km for Phobos and 7.5 x 6.2 x 5.4 for Deimos. Expressions are also obtained for the inertial orientations of these bodies' spin axes and prime meridians. While these expressions should be accurate to a few tenths of a deg for the 1971-1980 period, their accuracy will degrade with time as the orbit accuracy degrades.

Duxbury, Thomas C.↗

The gravity probe B relativity gyroscope program

The idea of testing general relativity through observations on Earth orbiting gyroscopes was suggested in 1959 to 1960. The direction, it was noted, of spin of a suitably oriented gyroscope should change with respect to the line of sight to a guide star for two reasons: a geodetic effect from the motion of the gyroscope through the curved space-time around the Earth, and a frame-dragging effect from the Earth's rotation. NASA began supporting laboratory research on the experiment, now called Gravity Probe B, in 1964. Technologies for it were progressively established, and an error analysis demonstrated the potential of measuring frame-dragging to 1 to 2 percent and the geodetic effect to 1 part in 10(exp 4). Later analyses, discussed herein, suggest possibilities for further improving those precisions each by a further factor of 10. In 1984, after technical and scientific reviews by the Space Science Board and other bodies, and completion by NASA Marshall Center of a Phase B Study, the NASA Administrator approved the start of a program known as STORE (Shuttle Test Of the Relativity Experiment). The purpose of STORE is to verify the final Gravity Probe B science payload, perform on the Shuttle a 7-day experiment rehearsal (including sophisticated gyro tests in low gravity), and then return the payload to Earth for refurbishment and integration into the Science Mission spacecraft. The payload comprises four gyroscopes, a telescope, and a drag-free proof mass, all mounted in a quartz block assembly within an evacuated magnetically shielded probe, which in turn is inserted into a 10-ft long, 6-ft diameter liquid helium dewar, operating at 1.8 K and maintaining low temperature for 2 years. STORE is manifested on Shuttle OV-105, for launch MSSN 69 in February 1993. The Science Mission is set tentatively for June 1995.

Everitt, C. W. Francis↗

Algorithmic information theory and the hidden variable question

The admissibility of certain nonlocal hidden-variable theories are explained via information theory. Consider a pair of Stern-Gerlach devices with fixed nonparallel orientations that periodically perform spin measurements on identically prepared pairs of electrons in the singlet spin state. Suppose the outcomes are recorded as binary strings l and r (with l sub n and r sub n denoting their n-length prefixes). The hidden-variable theories considered here require that there exists a recursive function which may be used to transform l sub n into r sub n for any n. This note demonstrates that such a theory cannot reproduce all the statistical predictions of quantum mechanics. Specifically, consider an ensemble of outcome pairs (l,r). From the associated probability measure, the Shannon entropies H sub n and H bar sub n for strings l sub n and pairs (l sub n, r sub n) may be formed. It is shown that such a theory requires that the absolute value of H bar sub n - H sub n be bounded - contrasting the quantum mechanical prediction that it grow with n.

Fuchs, Christopher↗

Fast Auroral Snapshot performance using a multi-body dynamic simulation

This paper examines the complex dynamic interaction between two 2.6 m long stacer booms, four 30 m long flexible wire booms and the attitude control system of the Fast Auroral SnapshoT (FAST) spacecraft. The FAST vehicle will nominally operate as a negative orbit spinner, positioned in a 83 deg inclination, 350 x 4200 km orbit. For this study, a three-axis, non-linear, seven body dynamic simulation is developed using the TREETOPS software package. The significance of this approach is the ability to model each component of the FAST spacecraft as an individual member and connect them together in order to better understand the dynamic coupling between structures and the control system. Both the wire and stacer booms are modeled as separate bodies attached to a rigid central body. The wire booms are oriented perpendicular to the spin axis at right angles relative to each other, whereas the stacer booms are aligned with the spin axis. The analysis consists of a comparison between the simulated in-plane and out-of-plane boom motions with theoretically derived frequencies, and an examination of the dynamic coupling between the control system and boom oscillations. Results show that boom oscillations of up to 0.36 deg are acceptable in order to meet the performance requirements. The dynamic motion is well behaved when the precession coil is operating, however, activation of the spin coil produces an erratic trend in the spin rate which approaches the spin rate requirement.

Zimbelman, Darrell↗

Chandra Confirmation of a Pulsar Wind Nebula in DA 495

As part of a multiwavelength study of the unusual radio supernova remnant DA 495, we present observations made with the Chandra X-ray Observatory. Imaging and spectroscopic analysis confirms the previously detected X-ray source at the heart of the annular radio nebula, establishing the radiative properties of two key emission components: a soft unresolved source with a blackbody temperature of 1 MK consistent with a neutron star, surrounded by a nontherma1 nebula 40" in diameter exhibiting a power-law spectrum with photon index Gamma = 1.63, typical of a pulsar wind nebula. Morphologically, the nebula appears to be slightly extended along a direction, in projection on the sky, previously demonstrated to be of significance in radio and ASCA observations; we argue that this represents the orientation of the pulsar spin axis. At smaller scales, a narrow X-ray feature is seen extending out 5" from the point source, but energetic arguments suggest that it is not the resolved termination shock of the pulsar wind against the ambient medium. Finally, we argue based on synchrotron lifetimes in the nebular magnetic field that DA 495 represents the first example of a pulsar wind nebula in which electromagnetic flux makes up a significant part, together with particle flux, of the neutron star's wind.

Arzoumanian, Z.↗

NASA Tech Briefs, July 2013

Dielectrophoresis-Based Particle Sensor Using Nanoelectrode Arrays; Multi-Dimensional Damage Detection for Surfaces and Structures; ULTRA: Underwater Localization for Transit and Reconnaissance Autonomy; Autonomous Cryogenic Leak Detector for Improving Launch Site Operations; Submillimeter Planetary Atmospheric Chemistry Exploration Sounder; Method for Reduction of Silver Biocide Plating on Metal Surfaces; Silicon Micromachined Microlens Array for THz Antennas; Forward-Looking IED Detector Ground Penetrating Radar; Fully Printed, Flexible, Phased Array Antenna for Lunar Surface Communication, Battery Charge Equalizer with Transformer Array; An Efficient, Highly Flexible Multi-Channel Digital Downconverter Architecture; Dimmable Electronic Ballast for a Gas Discharge Lamp; Conductive Carbon Nanotube Inks for Use with Desktop Inkjet Printing Technology; Enhanced Schapery Theory Software Development for Modeling Failure of Fiber-Reinforced Laminates; High-Performance, Low-Temperature-Operating, Long-Lifetime Aerospace Lubricants; Carbon Nanotube Microarrays Grown on Nanoflake Substrates; Differential Muon Tomography to Continuously Monitor Changes in the Composition of Subsurface Fluids; Microgravity Drill and Anchor System; 20 Granular Media-Based Tunable Passive Vibration Suppressor; 21 Miga Aero Actuator and 2D Machined Mechanical Binary Latch; Micro-XRF for In Situ Geological Exploration of Other Planets; Hydrogen-Enhanced Lunar Oxygen Extraction and Storage Using Only Solar Power; Uplift of Ionospheric Oxygen Ions During Extreme Magnetic Storms; Miniaturized, High-Speed, Modulated X-Ray Source; Hollow-Fiber Spacesuit Water Membrane Evaporator 25 High-Power Single-Mode 2.65-micrometers InGaAsSb/AlInGaAsSb Diode Lasers; Optical Device for Converting a Laser Beam Into Two Co-aligned but Oppositely Directed Beams; A Hybrid Fiber/Solid-State Regenerative Amplifier with Tunable Pulse Widths for Satellite Laser Ranging; X-Ray Diffractive Optics; SynGenics Optimization System (SynOptSys); 29 CFD Script for Rapid TPS Damage Assessment; radEq Add-On Module for CFD Solver Loci-CHEM; Science Opportunity Analyzer (SOA) Version 8; 30 Autonomous Byte Stream Randomizer; Distributed Engine Control Empirical/Analytical Verification Tools; Dynamic Server-Based KML Code Generator Method for Level-of-Detail Traversal of Geospatial Data; Automated Planning of Science Products Based on Nadir Overflights and Alerts for Onboard and Ground Processing; Linked Autonomous Interplanetary Satellite Orbit Navigation; Risk-Constrained Dynamic Programming for Optimal Mars Entry, Descent, and Landing; Scheduling Operations for Massive Heterogeneous Clusters; Deepak Condenser Model (DeCoM); Flight Software Math Library; Recirculating 1-K-Pot for Pulse-Tube Cryostats; 35 Method for Processing Lunar Regolith Using Microwaves; Wells for In Situ Extraction of Volatiles from Regolith (WIEVR); and Estimating the Backup Reaction Wheel Orientation Using Reaction Wheel Spin Rates Flight Telemetry from a Spacecraft.

Source record↗

Evidence for a non-random magnetization of the moon

An approximate inversion, using a specific model, of Apollo subsatellite vector magnetometer data has provided estimates for the locations, scale sizes, and magnetization characteristics of strongly magnetized lunar crustal materials across a portion of the lunar far side. The nearly model-independent local bulk directions of magnetization, while otherwise random, exhibit a tendency to lie in or near planes perpendicular to the present lunar spin axis. The apparent existence of such a preferred plane of magnetization must be regarded as unfavorable for proposed local, presumably random sources of large-scale, coherent magnetization and implies that any assumed internal magnetizing dipole or external linear magnetizing field must also have been oriented mainly perpendicular to the present spin axis. The otherwise random orientations of these vectors when projected onto the equatorial plane suggests a simple explanation for the negligible lunar global dipole moment.

Hood, L.↗

From hard spheres to hard-core spins

A system of hard spheres exhibits physics that is controlled only by their density. This comes about because the interaction energy is either infinite or zero, so all allowed configurations have exactly the same energy. The low-density phase is liquid, while the high-density phase is crystalline, an example of “order by disorder” as it is driven purely by entropic considerations. Here we study a family of hard spin models, which we call hard-core spin models, where we replace the translational degrees of freedom of hard spheres with the orientational degrees of freedom of lattice spins. Their hard-core interaction serves analogously to divide configurations of the many spin system into allowed and disallowed sectors. We present detailed results on the square lattice in d = 2 for a set of models with $\mathbb{Z}_n$ symmetry, which generalize Potts models, and their U(1) limits, for ferromagnetic and antiferromagnetic senses of the interaction, which we refer to as exclusion and inclusion models. As the exclusion and inclusion angles are varied, we find a Kosterlitz-Thouless phase transition between a disordered phase and an ordered phase with quasi-long-ranged order, which is the form order by disorder takes in these systems. These results follow from a set of height representations, an ergodic cluster algorithm, and transfer matrix calculations.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗