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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 199 records · Page 11
All sourcesNASA NTRSDOE OSTI
NASA NTRS2005

Instrumentation for Sensitive Gas Measurements

An improved instrument for optical absorption spectroscopy utilizes off-axis paths in an optical cavity in order to increase detection sensitivity while suppressing resonance effects. The instrument is well suited for use in either cavity ring-down spectroscopy (CRDS) [in which one pulses an incident light beam and measures the rate of decay of light in the cavity] or integrated cavity output spectroscopy (ICOS) [in which one uses a continuous-wave incident light beam and measures the power of light in the cavity as a function of wavelength]. Typically, in optical absorption spectroscopy, one seeks to measure absorption of a beam of light in a substance (usually a gas or liquid) in a sample cell. In CRDS or ICOS, the sample cell is placed in (or consists of) an optical cavity, so that one can utilize multiple reflections of the beam to increase the effective optical path length through the absorbing substance and thereby increase the sensitivity for measuring absorption. If an absorbing substance is not present in the optical cavity, one can utilize the multiple passes of the light beam to increase the sensitivity for measuring absorption and scattering by components of the optical cavity itself. It is desirable to suppress the effects of resonances in the cavity in order to make the spectral response of the cavity itself as nearly constant as possible over the entire wavelength range of interest. In the present instrument, the desired flattening of the spectral response is accomplished by utilizing an off-axis beam geometry to effectively decrease the frequency interval between longitudinal electromagnetic modes of the cavity, such that the resulting transmission spectrum of the cavity is nearly continuous: in other words, the cavity becomes a broad-band optical device.

OKeefe, Anthony↗
DOE OSTI2020

Integrated Evaporator for Efficient Solar-Driven Interfacial Steam Generation

Solar-driven interfacial steam generation is a promising technique for clean water production as it can minimize thermal loss by localizing solar-to-heat conversion at the air/liquid interface. Here we report an integrated solar-evaporator by partially growing two-dimensional polypyrrole microsheets within a melamine foam through chemical vapor polymerization. These microsheets can induce multiple light reflections within the foam, enable omnidirectional light absorption, provide abundant surfaces to promote heat transfer, and achieve spatially-defined hydrophobicity to facilitate vapor escape. Meanwhile, the inherent hydrophilicity of the bottom part of the foam promotes spontaneous upward water transport and suppresses heat loss. The composite foam exhibits an excellent apparent evaporation rate of ~2 kg/(m 2 ·h) and solar-to-vapor efficiency of ~91%. Here, the combined advantages of large surface area, high efficiency, low cost, all weather application, excellent durability, and scalable manufacturing make our integrated design promising for fabricating large-scale solar steam generation systems that are suitable for practical clean water production.

36 MATERIALS SCIENCE↗
NASA NTRS1994

Gravitational instabilities in a proto-planetary disk including the effects of magnetic fields

We investigate the gravitational instability of a thin, Keplerian protoplanetary disk including the effects of a largely azimuthal magnetic field. The model follows that of our previous work (Noh, Vishniac, & Cochran 1991) except for the inclusion of a magnetic field. The disk is assumed to consist of neutral and ionized gas and neutral dust which are coupled by gravity and friction. The growth rates and eigenfunctions are calculated numerically using nonaxisymmetric linear perturbation methods. The results show that the growth rate has a maximum at some intermediate azimuthal number m, but for each value of m it is reduced relative to the unmagnetized case. The effects of the magnetic field appear more strongly on small scales. As the strength of the equilibrium magnetic field increases the growth rates decrease, and the maximum instability occurs at a lower value on m due to the increasing magnetic pressure. The response of each component to the magnetic field is discussed using the behavior of the eigenfunctions in the radial direction. With the inclusion of the magnetic field, the effects of the ionization fraction and friction on the growth rates also appear to be important for high m modes. Increasing the ionization fraction or the friction suppresses instability, but only slightly changes the maximally unstable azimuthal scales. The enhanced growth rates due to a dust component for which thermal pressure is negligible are somewhat reduced by the inclusion of a magnetic field. The effects of different boundary conditions (reflecting and transmitting) on the growth rates are also shown.

Noh, Hyerim↗
DOE OSTI2020

In Situ ATR–SEIRAS of Carbon Dioxide Reduction at a Plasmonic Silver Cathode

Illumination of a voltage-biased plasmonic Ag cathode during CO 2 reduction results in a suppression of the H 2 evolution reaction while enhancing CO 2 reduction. This effect has been shown to be photonic rather than thermal, but the exact plasmonic mechanism is unknown. Here in this paper, we conduct an in situ ATR–SEIRAS (attenuated total reflectance–surface-enhanced infrared absorption spectroscopy) study of a sputtered thin film Ag cathode on a Ge ATR crystal in CO 2 -saturated 0.1 M KHCO 3 over a range of potentials under both dark and illuminated (365 nm, 125 mW cm –2 ) conditions to elucidate the nature of this plasmonic enhancement. We find that the onset potential of CO 2 reduction to adsorbed CO on the Ag surface is -0.25 V RHE and is identical in the light and the dark. As the production of gaseous CO is detected in the light near this onset potential but is not observed in the dark until -0.5 V RHE , we conclude that the light must be assisting the desorption of CO from the surface. Furthermore, the HCO 3 – wavenumber and peak area increase immediately upon illumination, precluding a thermal effect. We propose that the enhanced local electric field that results from the localized surface plasmon resonance (LSPR) is strengthening the HCO 3 – bond, further increasing the local pH. This would account for the decrease in H 2 formation and increase the CO 2 reduction products in the light.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2023

Uptake of Pb and the Formation of Mixed (Ba,Pb)SO 4 Monolayers on Barite During Cyclic Exposure to Lead-Containing Sulfuric Acid

Barite (BaSO 4 ) is a common additive in lead-acid batteries, where it acts as a nucleating agent to promote the reversible formation and dissolution of PbSO 4 during battery cycling. However, little is known about the molecular-scale mechanisms the nucleation and cyclic evolution of PbSO 4 over a battery’s lifetime. In this study, we explore the responses of a barite (001) surface to cycles of high and low lead concentrations in the presence of 100 mM sulfuric acid using in-situ atomic force microscopy and high-resolution X-ray reflectivity. Here we find that PbSO 4 epitaxial films readily nucleate on the barite surface, even from solutions that are undersaturated relative to bulk PbSO 4 . Despite this, barite (001) proves to be an ineffective nucleator of bulk PbSO 4 , as multilayer growth is suppressed even in highly supersaturated solutions. Instead, we find evidence that Pb 2+ ions can directly exchange with Ba 2+ to create mixed (Ba,Pb)SO 4 surfaces. These chemically mixed surfaces do not host PbSO4 monolayers as readily as pristine barite, and the original reactivity is not regained until a fresh surface is reestablished by aggressive etching. Our results can be partly explained by traditional models of Stranski-Krastanov (S-K) growth, in which monolayer films are stabilized by a reduction in surface energy, but multilayer growth is inhibited by epitaxial strain. Complementary density functional theory calculations confirmed the basic energetic-terms of traditional S-K models, but also showed evidence form more complex, thickness-dependent, energetics than would be predicted from the S-K models. The experimental results can be better understood by extending the S-K model to consider the formation of mixed surfaces and films, which can have reduced strain and interfacial energies relative to pure films, while also being stabilized by entropy of mixing. These insights into non-stoichiometric heteroepitaxy will enable better predictions of how barite affects PbSO 4 nucleation in battery environments.

25 ENERGY STORAGE↗
DOE OSTI2026

Comparison of plasma response models for RMP effects on the divertor and scrape-off layer in KSTAR

Resonant magnetic perturbations (RMPs) are beneficial for control of edge localized modes (ELMs) in tokamaks. Nevertheless, a side effect of RMPs is the appearance of helical striations in the particle and heat loads onto divertor targets. The extent and field line connection of these striations is significantly altered by the plasma response to external perturbations. For an ELM suppressed high confinement (H-mode) plasma at KSTAR, magnetic footprints are computed by FLARE based on plasma response from GPEC, MARS-F, M3D-C1 and JOREK with substantial differences in the resulting footprints (from 2 cm to 14 cm). This is reflected in EMC3-EIRENE simulations of the resulting heat loads: it is found that either the peak value or the extent of the striations appears to be overestimated compared to infrared camera measurements. Reasonable agreement can only be achieved for the smallest footprint for lower input power and lower cross-field transport, or for higher upstream density and radiative power losses.

Frerichs, H. [Univ. of Wisconsin, Madison, WI (Uni↗
DOE OSTI2020

Sub-molecular structural relaxation at a physisorbed interface with monolayer organic single-crystal semiconductors

Arranging molecules into highly symmetric, topological crystal structures has been recognized as the best approach to functionalize electronic properties in molecular crystals, where the constituent molecules have been assumed to be rigid in shape. Here, in striking contrast, we demonstrate that the molecules in a monolayer organic crystal can undergo a significant deformation in proximity to the substrate, which is reflected by an asymmetry in the electron density profile. X-ray reflectivity and X-ray absorption spectroscopies in conjunction with density-functional theory calculations reveal that the highly planarized π-core are deformed into a bent shape, while the bulk lattice parameters are maintained. The molecular shape change is found to be perfectly suppressed in a bilayer single crystal, which leads to a 40% increase in mobility in the bilayer crystal. Our finding of a unique, sub-molecular scale shape change in monolayer single crystals can offer possibilities for functionalizing electrical properties via nano-scale physisorption.

36 MATERIALS SCIENCE↗
DOE OSTI2020

III/V silicon hybrid laser based on a resonant Bragg structure

We demonstrate a laser tunable in intensity with gigahertz tuning speed based on a III/V reflective semiconductor optical amplifier (RSOA) coupled to a silicon photonic chip. The silicon chip contains a Bragg-based Fabry–Perot resonator to form a passive bandpass filter within its stopband to enable single-mode operation of the laser. We observe a side mode suppression ratio of 43 dB, linewidth of 790 kHz, and an optical output power of 1.65 mW around 1530 nm. We also investigate using a micro-ball lens as an alternative coupling method between the RSOA and the silicon chip.

Davis, Jordan A. (ORCID:0000000343483295)↗
NASA NTRS2023

Changing Characteristics of Tropical Extreme Precipitation-Cloud Regimes in Warmer Climates

In this paper, we have investigated the changing characteristics of climatic scale (monthly) tropical extreme precipitation in warming climates using the Energy Exascale Earth System Model (E3SM). Results are from Atmospheric Model Intercomparison Project (AMIP)-type simulations driven by a) control experiment with present-day sea surface temperature (SST) and CO 2 concentration, b) P4K, same as in a) but with uniform increase by 4K in SST globally, and c) same as in a), but with imposed SST and CO 2 concentration from outputs of coupled E3SM forced by 4xCO 2 concentration. We find that as the surface warms under P4K and 4xCO 2 , both convective and stratiform rain increase. Importantly, there is increasing fractional contribution of stratiform rain as a function of precipitation intensity, with the most extreme but rare events occurring preferentially over land more than ocean, more so under 4xCO 2 than P4K. Extreme precipitation is facilitated by increased precipitation efficiency, reflecting accelerated rates of recycling of precipitation-cloud water (both liquid and ice phases) in regions with colder anvil cloud tops. Changes in vertical profiles of clouds, condensation heating and vertical motions indicate increasing precipitation-cloud-circulation organization from control, P4K to 4xCO 2 . Results suggest that large-scale ocean warming, i.e., P4K, is the primary cause contributing to organization structure resembling the well-known Mesoscale Convective System (MCS) for increased extreme precipitation on shorter (hourly to daily) time scales. Additional 4xCO 2 atmospheric radiative heating, and dynamically consistent anomalous SST further amplifies the MCS organization under P4K. Analyses of the surface moist static energy distribution show that increase in surface moisture (temperature) under P4K and 4xCO 2 is the key driver leading to enhanced convective instability over tropical ocean (land). However, the fast and large increase in land surface temperature and lack of available local moisture result in strong reduction in land surface relative humidity, reflecting severe drying and enhanced convective inhibition (CIN). It is argued that very extreme and rare “record-breaking” precipitation events found over land under P4K, more so under 4xCO 2 , are likely due to the delayed onset of deep convection, i.e., the longer the suppression of deep convection by CIN, the more severe the extreme precipitation when eventually occur, due to the release of large amount of stored surplus convective available potential energy in the lower troposphere during prolonged CIN.

climate-scale extreme tropical precipitation↗
NASA NTRS1980

Study of stray light suppression for the large space telescope

Analysis of light scattering, using the APART computer program, begins at the image plane and progresses through the optical system to the front end of the telescope tube. The approach identifies all critical surfaces, computes the geometrical configuration factors (GCF) from each area of the system under study to all other areas of the system, and determines incident and reflected angles which are important for baffle surfaces which do not have Lambertian scattering characteristics. The power input into the optical surface from either point source objects or extended objects such as the bright Earth are computed. The surface scattering characteristics and the GCF values are combined so that the power transfer to the image plane is computed. Capabilities for handling light scattering from baffle surfaces, specular reflectance from black surfaces, scattering from mirror surfaces, diffraction, internal scattering from transmissive optics, and internal thermal emission are assessed.

Fannin, B. B.↗
DOE OSTI2020

High expression of PSF1 promotes drug resistance and cell cycle transit in leukemia cells

Abstract Escape of cancer cells from chemotherapy is a problem in the management of cancer patients. Research on chemotherapy resistance has mainly focused on the heterogeneity of cancer cells, multiple gene mutations, and quiescence of malignant cancer cells. However, some studies have indicated that interactions between cancer cells and vascular cells promote resistance to chemotherapy. Here, we established mouse leukemia models using the cell lines THP‐1 or MEG‐1. These were derived from acute and chronic myeloid leukemias, respectively, and highly expressed DNA replication factor PSF1, a member of the GINS complex. We found that, after anti‐cancer drug administration, surviving GFP‐positive leukemia cells in the bone marrow were located adjacent to blood vessels, as previously reported in a subcutaneous solid tumor transplantation model. Treating THP‐1 and MEG‐1 cells with anti‐cancer drugs in vitro revealed that those most strongly expressing PSF1 were most chemoresistant, suggesting that PSF1 induces not only cell cycle progression but also facilitates cell survival. Indeed, when PSF1 expression was suppressed by shRNA, the growth rate was reduced and cell death was enhanced in both cell lines. Furthermore, PSF1 knockdown in leukemia cells led to a change in their location at a distance from the blood vessels in a bone marrow transplantation model. These findings potentially reflect a mechanism of escape of leukemic cells from chemotherapy and suggest that PSF1 may be a possible therapeutic target to enhance the effect of chemotherapy.

Hsieh, Han‐Yun↗
NASA NTRS1994

A feasibility study for long-path multiple detection using a neural network

Least-squares inverse filters have found widespread use in the deconvolution of seismograms and the removal of multiples. The use of least-squares prediction filters with prediction distances greater than unity leads to the method of predictive deconvolution which can be used for the removal of long path multiples. The predictive technique allows one to control the length of the desired output wavelet by control of the predictive distance, and hence to specify the desired degree of resolution. Events which are periodic within given repetition ranges can be attenuated selectively. The method is thus effective in the suppression of rather complex reverberation patterns. A back propagation(BP) neural network is constructed to perform the detection of first arrivals of the multiples and therefore aid in the more accurate determination of the predictive distance of the multiples. The neural detector is applied to synthetic reflection coefficients and synthetic seismic traces. The processing results show that the neural detector is accurate and should lead to an automated fast method for determining predictive distances across vast amounts of data such as seismic field records. The neural network system used in this study was the NASA Software Technology Branch's NETS system.

Feuerbacher, G. A.↗
DOE OSTI2025

Quantifying Size Effects on Thermal Transport in CsPbBr 3 Nanocrystal Films

Colloidal lead halide perovskite nanocrystals (LHP NCs) are promising semiconductor materials for optoelectronic applications due to their strong quantum confinement, near-unity photoluminescence quantum yields, and tunable emission characteristics. However, their modest thermal stability remains a challenge, particularly at smaller core diameters due to enhanced phonon scattering at inorganic core-organic ligand interfaces. In this work, we directly quantify size-dependent thermal conductivity (κ) in lecithin-capped CsPbBr 3 NC thin films using a transducer-free, vibrational pump–visible probe (VPVP) spectroscopy technique. A mid-infrared pump thermally excites the ligand shell, while a broadband probe tracks transient reflectance change correlated to lattice temperature decay. Finite-element modeling of the decay dynamics yields κ values from 0.13 to 0.16 W·m –1 ·K –1 for NC films with sub-10 nm core diameter, significantly lower than those of its bulk counterpart. A steep κ suppression with decreasing NC size emphasizes the dominant role of ligand shells and boundary effects in thermal transport.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2022

The Role of Phytoplankton Biomacromolecules in Controlling Ocean Surface Roughness

Satellite altimetric data routinely map sea surface topography by measuring the ocean return signal. One source of altimeter measurement contamination occurs when the radar ocean backscatter becomes unusually large, a situation termed a Sigma-0 bloom. Past research suggests Sigma-0 blooms are associated with weak wind and natural surface slick conditions where capillary waves at the air–sea interface are suppressed. To date, no explicit connection between these conditions and Sigma-0 bloom presence has been provided. Using a series of simplified equations, our reduced model determines capillary wave heights from estimates of planktonic carbon concentrations and regional wind speed. Our results suggest that the radar signal reflection increases as capillary wave height decreases. This relationship depends on surfactant concentration, surfactant composition, and wind speed. Model sensitivity analysis indicates that the interface reflectivity depends on biological activity and wind speed. Our proposed simplified model provides a method to identify potential Sigma-0 bloom regions. We conclude that because of the demonstrated impact of biological surfactants on ocean roughness, it is necessary to consider the biological activity, i.e., phytoplankton bloom events, when interpreting signals from radar altimetry and when developing ocean hydrology models.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2023

Changing Characteristics of Tropical Extreme Precipitation–Cloud Regimes in Warmer Climates

In this study, we investigated the changing characteristics of climatic scale (monthly) tropical extreme precipitation in warming climates using the Energy Exascale Earth System Model (E3SM). The results are from Atmospheric Model Intercomparison Project (AMIP)-type simulations driven by (a) a control experiment with the present-day sea surface temperature (SST) and CO 2 concentration, (b) P4K, the same as in (a) but with a uniform increase of 4K in the SST globally, and (c) the same as in (a), but with an imposed SST and CO 2 concentration from the outputs of the coupled E3SM forced by a 4xCO 2 concentration. We found that as the surface warmed under P4K and 4xCO 2 , both convective and stratiform rain increased. Importantly, there was an increasing fractional contribution of stratiform rain as a function of the precipitation intensity, with the most extreme but rare events occurring preferentially over land more than the ocean, and more so under 4xCO 2 than P4K. Extreme precipitation was facilitated by increased precipitation efficiency, reflecting accelerated rates of recycling of precipitation cloud water (both liquid and ice phases) in regions with colder anvil cloud tops. Changes in the vertical profiles of clouds, condensation heating, and vertical motions indicate increasing precipitation–cloud–circulation organization from the control and P4K to 4xCO 2 . The results suggest that large-scale ocean warming, that is, P4K, was the primary cause contributing to an organization structure resembling the well-known mesoscale convective system (MCS), with increased extreme precipitation on shorter (hourly to daily) time scales. Additional 4xCO 2 atmospheric radiative heating and dynamically consistent anomalous SST further amplified the MCS organization under P4K. Analyses of the surface moist static energy distribution show that increases in the surface moisture (temperature) under P4K and 4xCO 2 was the key driver leading to enhanced convective instability over tropical ocean (land). However, a fast and large increase in the land surface temperature and lack of available local moisture resulted in a strong reduction in the land surface relative humidity, reflecting severe drying and enhanced convective inhibition (CIN). It is argued that very extreme and rare “record-breaking” precipitation events found over land under P4K, and more so under 4xCO 2 , are likely due to the delayed onset of deep convection, that is, the longer the suppression of deep convection by CIN, the more severe the extreme precipitation when it eventually occurs, due to the release of a large amount of stored surplus convective available potential energy in the lower troposphere during prolonged CIN.

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS1985

Automated Extraction of Absorption Bands from Reflectance Special

A multiple high order derivative spectroscopy technique has been developed for deriving wavelength positions, half widths, and heights of absorption bands in reflectance spectra. The technique is applicable to laboratory spectra as well as medium resolution (100-200/cm) telescope or spacecraft spectra with moderate (few percent) noise. The technique permits absorption band positions to be detected with an accuracy of better than 3%, and often better than 1%. The high complexity of radiative transfer processes in diffusely reflected spectra can complicate the determination of absorption band positions. Continuum reflections, random illumination geometries within the material, phase angle effects, composite overlapping bands, and calibration uncertainties can shift apparent band positions by 20% from their actual positions or mask them beyond detection. Using multiple high order derivative analysis, effects of scattering continua, phase angle, and calibration (smooth features) are suppressed. Inflection points that characterize the positions and half widths of constituent bands are enhanced by the process and directly detected with relatively high sensitivity.

Huguenin, R. L.↗
NASA NTRS1999

Non-Equilibrium Superconductivity and Magnetic Pair Breaking in Perovskite Half-Metallic Ferromagnet-Insulator-Superconductor (F-I-S) Heterostructures

The effect of spin-polarized quasiparticle currents on the critical current density (J-c) of cuprate superconductors is studied in perovskite F-I-S heterostructures as a function of insulator thickness and of underlying magnetic materials. A pulsed current technique is employed to minimize extraneous Joule heating on the superconductor. At temperatures near T-c, F-I-S samples with insulator thicknesses\1e2nm show precipitous decrease in J_c as current injection (I_m) is increased. In contrast, J_c in a controlled sample with a substituted non-magnetic material (N-I-S) exhibit no dependence on I_m. Similarly, a F-I-S sample with a 10 mn insulating barrier also show little J_c effect versus I_m. At low temperatures with I_m = 0, significant suppression of J-c is observed only in the thin barrier F-I-S samples, although T_c and the normal-state resistivity of all samples are comparable. These phenomena can be attributed to the Cooper pair breaking induced by externally-injected and internally-reflected spin-polarized quasiparticle currents. We estimate an order of magnitude range for the spin diffusion length of 100 nm to 100\ mum.

Fu, C.-C.↗
NASA NTRS1988

Effect of alcohol addition on shock-initiated formation of soot from benzene

Soot formation in benzene-methanol and benzene-ethanol argon-diluted mixtures was studied behind reflected shock waves by monitoring the attenuation of an He-Ne laser beam. The experiments were performed at temperatures 1580-2250 K, pressures 2.0-3.0 bar, and total carbon atom concentrations (2.0-2.7) x 10 to the 17th atoms/cu cm. The results obtained indicate that the addition of alcohol suppresses the formation of soot from benzene at all temperatures, and that the reduction in soot yields is increased with the amount of alcohol added. The analysis of the results indicates that the suppression effect is probably due to the oxidation of soot and soot precursors by OH and the removal of hydrogen atoms by alcohol and water molecules.

Frenklach, Michael↗