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At least 199 records · Page 11

Effect of Ionizing Radiation on the Mechanical and Structural Properties of Graphite Fiber Reinforced Composites

Graphite/epoxy (T300/5208) and graphite/polyimide composites (C6000/PMR 15) were exposed to various levels of 0.5 MeV electron radiation with the maximum dose being 10,000 Mrad. A three point bending test was used to evaluate the ultimate stress and modulus of the composites. In all composites except transverse samples of C6000/PMR 15 ultimate stress values remained approximately constant or increased slightly. The modulus values remained approximately constant for all composite types regardless of the radiation level. Interfacial aspects of composites were studied. Interlaminar shear tests were performed on T300/5208 and C6000/PMR 15 composites irradiated to 10,000 Mrad. There was an initial increase in interlaminar shear strength (up to 1,000 Mrad) followed by a sharp decrease with further radiation exposure. Using scanning electron microscopy no visual differences in the mode of fracture could be detected between ruptured control samples and those exposed to various levels of radiation. Electron spectroscopy for chemical analysis (ESCA) revealed little change in the surface elements present in control and highly irradiated T300/5208 composite samples.

Wolf, Kay Woodroof↗

Wear and Neutron Shielding Resilience of Titanium-Hexagonal Boron Nitride Coatings Against Extreme Lunar Radiation and Thermal Cycles

Ti6Al4V and Al6061 are aerospace alloys used in lunar structural components and rovers owing to their high specific strength. However, they deteriorate rapidly when subjected to demanding conditions of the lunar environment, such as extreme thermal cycles, solar particle radiation, and abrasive regolith. Cryo-milled powders were employed to deposit hBN-reinforced protective titanium coatings through plasma spray (atmospheric APS and vacuum-VPS) with 2 and 10 vol% of hBN on Ti6Al4V and Al6061 substrates. These coatings were evaluated for durability under extreme lunar-like conditions, including thermal cycling, electron radiation, and synergistic (electron radiation-thermal cycle) exposure. The coatings exhibited radiation-induced hardening, resulting in a substantial increase in their microhardness ~20–40% compared to virgin condition. Bright-field transmission electron microscopy (TEM) analysis reveals the presence of high dislocation densities, black dot defects, and dislocation clusters, providing evidence of the severe impact of synergistic environmental stresses. Ball-on-disk tribological tests were conducted in the presence of JSC-1 A lunar regolith simulant to evaluate the wear performance of coatings. Compared to conventional Ti6Al4V substrate, 50%, 90%, and 70% reductions in wear volume were observed in the Ti/2 vol% hBN coatings in thermal-only, radiation-only, and synergistic environments. Neutron shielding tests indicate that the synergistic coatings offer higher neutron shielding performance by up to 28% compared to virgin coatings, attributed to improved neutron capture by 10B isotopes. Upon a comprehensive assessment and ranking of multiple coatings under varying conditions, the VPS Ti/2 vol% hBN coating emerges as the top choice for protection against extreme radiation and thermal cycles for future lunar explorations.

Boron nitride↗

A beaming model of the Io-independent Jovian decameter radiation based on multipole models of the Jovian magnetic field

A geometrical model is presented in which the apparent source locations of the Io-independent decameter radiation are computed. The calculations assume that the radiation is produced by stably trapped electrons radiating near the local electron gyrofrequency and that the emission is then beamed onto a conical surface. The maximum occurrence probability of noise storms is associated with regions in the Jovian magnetosphere where the axis of the emission cone is most inclined toward the Jovian equatorial plane. The calculations utilize and compare two of the octopole spherical harmonic expansions of the Jovian magnetic field constructed from data accumulated by the fluxgate and vector helium magnetometers on board Pioneer 11.

Goldstein, M. L.↗

Synthetic Ligand Selection Affects Stoichiometry, Carrier Dynamics, and Trapping in CuInSe 2 Nanocrystals

CuInSe 2 nanocrystals exhibit tunable near-infrared bandgaps that bolster utility in photovoltaic applications as well as offer potential as substitutes for more-toxic Cd- and Pb-based semiconductor compositions. However, they can present a variety of defect states as well as unusual photophysics. In this work, we examine the effects of ligand composition (oleylamine, diphenylphosphine, and tributylphosphine) on carrier dynamics in these materials. Via spectroscopic measurements such as photoluminescence and transient absorption, we find that ligands present during the synthesis of CuInSe 2 nanocrystals impart non-radiative electronic states which compete with radiative recombination and give rise to low photoluminescence quantum yields. We characterize the nature of these defect states (hole vs. electron traps) and investigate whether they exist at the surface or interior of the nanocrystals. Carrier lifetimes are highly dependent on ligand identity where oleylamine-capped nanocrystals exhibit rapid trapping (< 20 ps) followed by diphenylphosphine (< 500 ps) and finally tributylphosphine (> 2 ns). A majority of carrier population localizes at indium copper antisites (electrons), copper vacancies (holes), or surface traps (electrons and/or holes), all of which are non-emissive.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Jupiter trapped radiation belts

Previously developed models for trapped electron radiation belts and trapped proton radiation belts in the Jovian magnetosphere are described. The spatial distribution of flux and the L shell dependence of the characteristic energy are displayed for both models. Based on these models, the fluence accumulated by a Jupiter flyby spacecraft is given in terms of the equivalent 3-MeV fluence for electrons and the equivalent 20-MeV proton fluence. Finally, some impacts of these fluences on outer planet missions are described.

Beck, A. J., Jr.↗

Observations of radiation from an electron beam artificially injected into the ionosphere

This paper reports the observations of waves generated by a controlled beam of particles artificially injected into the ionosphere and magnetosphere. The measurements were made during the Electron Echo 1 experiment, in which an electron accelerator was carried to a height of 350 km in the ionosphere from Wallops Island, Virginia, on an Aerobee 350 sounding rocket. It injected into the earth's magnetic field over 3000 16-ms pulses of electrons with 40-keV energy and a current of 70 mA at pitch angles between 70 and 110 deg. The ejected fiber glass nose cone carried antennas and receivers to measure the electric field of waves generated by the beam. Associated with the electron beam was radiation detected at frequencies near the electron plasma frequency of the background ionosphere, near twice the electron cyclotron frequency in the whistler mode, and near zero frequency. Associated with the operation of an argon plasma generator used to keep the accelerator neutralized were continuous emissions detected at frequencies near the lower-hybrid resonance (LHR).

Cartwright, D. G.↗

Dielectronic recombination rates, ionization equilibrium, and radiative emission rates for calcium and nickel ions in low-density high-temperature plasmas

The total dielectronic recombination rates for Ca and Ni ions were calculated taking into account autoionization to excited states of the recombining ion and stabilizing radiative transitions of the recombining electron. Radiative transitions of the recombining ion are found to be the dominant stabilizing processes, and the relative importance of Delta n = 0 and Delta n not equal to 0 transitions in the relevant temperature region is determined for each ion. The relative importance of the Delta n = 0 and Delta n not equal to 0 contributions is significantly altered for some ions by the inclusion of autoionization to excited levels. The relative abundance of the various ionization stages has been determined by using a corona equilibrium model in which collisional ionization and inner-shell excitation followed by autoionization are balanced by direct radiative and dielectronic recombination.

Jacobs, V. L.↗

Grid2: A Program for Rapid Estimation of the Jovian Radiation Environment

Grid2 is a program that utilizes the Galileo Interim Radiation Electron model 2 (GIRE2) Jovian radiation model to compute fluences and doses for Jupiter missions. (Note: The iterations of these two softwares have been GIRE and GIRE2; likewise Grid and Grid2.) While GIRE2 is an important improvement over the original GIRE radiation model, the GIRE2 model can take as long as a day or more to compute these quantities for a complete mission. Grid2 fits the results of the detailed GIRE2 code with a set of grids in local time and position thereby greatly speeding up the execution of the model-minutes as opposed to days. The Grid2 model covers the time period from 1971 to 2050 and distances of 1.03 to 30 Jovian diameters (Rj). It is available as a direct-access database through a FORTRAN interface program. The new database is only slightly larger than the original grid version: 1.5 gigabytes (GB) versus 1.2 GB.

Evans, R. W.↗

Grid2: A Program for Rapid Estimation of the Jovian Radiation Environment: A Numeric Implementation of the GIRE2 Jovian Radiation Model for Estimating Trapped Radiation for Mission Concept Studies

Grid2 is a program that utilizes the Galileo Interim Radiation Electron model 2 (GIRE2) Jovian radiation model to compute fluences and doses for Jupiter missions. (Note: The iterations of these two softwares have been GIRE and GIRE2; likewise Grid and Grid2.) While GIRE2 is an important improvement over the original GIRE radiation model, the GIRE2 model can take as long as a day or more to compute these quantities for a complete mission. Grid2 fits the results of the detailed GIRE2 code with a set of grids in local time and position thereby greatly speeding up the execution of the model--minutes as opposed to days. The Grid2 model covers the time period from 1971 to 2050and distances of 1.03 to 30 Jovian diameters (Rj). It is available as a direct-access database through a FORTRAN interface program. The new database is only slightly larger than the original grid version: 1.5 gigabytes (GB) versus 1.2 GB.

Europa↗