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At least 199 records · Page 11

The morphology of energetic O/+/ ions during two magnetic storms - Latitudinal variations

Results are presented for a statistical analysis of the latitudinal variations of precipitating O(+) and H(+) ions with energies between 0.7 and 12 keV during the magnetic storms of Dec. 16 and 17, 1971. Particular attention is given to some typical characteristics of the O(+) energy spectra along with an intercomparison of the O(+) and H(+) average energies during each storm. Major findings are that (1) the O(+) energy spectra were quite structured, one or more peaks being frequently observed; (2) the O(+) energy spectra which were still rising at 12 keV were not uncommon, especially at high latitudes; and (3) a significant hardening of the O(+) spectrum with increasing latitude was observed at the higher latitudes during the December 17 storm, along with a significant hardening with decreasing latitude at the low-latitude edge of the precipitation zone on the night side. A statistically significant difference in average energies between the two ionic species was revealed.

Sharp, R. D.↗

The O I /5577-A wavelength/ airglow - Observations and excitation mechanisms

Analysis of the O I /5577-A wavelength/ airglow observations conducted on board the Atmosphere Explorer C satellite yields the following results when combined with simultaneous measurements of ion and neutral composition. A volume emission rate profile derived after sunset requires the production of an O(1S) atom in 8% of the O2(+) recombinations. Photoelectric impact on atomic oxygen and the dissociative recombination of O2(+) are important sources of O(1S) in the dayglow; however, the airglow measurements require a large additional production of O(1S) below 200 km in addition to these. The reaction N + O2(+) yielding NO(+) + O(1S) can provide the missing O(1S) source if the rate coefficient is near 2.5 times 10 to the minus 11th cu cm per sec.

Frederick, J. E.↗

Spectroscopic studies of O-type stars. VIII - Radial velocities and the K-term

Radial velocities are measured on coude spectrograms of over 200 O-type stars in both hemispheres. The selection of effective wavelengths for the stellar lines to be measured is reviewed, and the measured velocities are compared with those available in a catalog of O stars. The Trumpler (1935) effect (a reported anomalous redshift in certain O stars) is inconclusively reinvestigated, atmospheric motions in Of stars are examined, and some kinematic properties of O stars are discussed statistically. It is found that 58% of all O stars and 41% of all the Of stars considered are certain or probable binaries. A K-term in the range from 1 to 2 km/s is derived for the O stars, but the Of stars are shown to have a highly significant negative K-term. It is suggested that the systematically negative peculiar velocities of the Of stars are due to outflow of material beginning at the photospheric level.

Conti, P. S.↗

Determination of the thermal rate coefficient, products, and branching ratios for the reaction of O/+/ /D-2/ with N2

Atmosphere Explorer-C satellite measurements are used to determine rate coefficients (RCs) for the following reactions: O(+)(D-2) + N2 yields N2(+) + O (reaction 1), O(+)(D-2) + N2 yields O(+)(S-4) + N2 (reaction 2), and O(+)(D-2) + N2 yields NO(+) + N (reaction 3). Results show the RC for reaction 1 to be 1 (plus 1 or minus 0.5) x 10 to the -10th cu cm per sec, for reaction 2 to be 3 (plus 1 or minus 2) x 10 to the -11th cu cm per sec, and 3 to be less than 5.5 x 10 to the -11th cu cm per sec. It is also found that the reaction of O(+)(D-2) with N2 does not constitute a detectable source of NO(+) ions in the thermosphere.

Torr, D. G.↗

A deficiency of O III in the Io plasma torus

Evidence for a deficiency of O III ions in the Io plasma torus is reported and implications of this deficiency for the physical processes controlling the plasma are considered. Observations of the O III 5007-A as well as Cl III and S III emissions from the Io plasma torus were made by a ground-based echelle spectrograph and intensified Reticon detector in February and May, 1981. The O III observations allow an upper limit of 4/cu cm to be placed on torus O III abundance, which is inconsistent with expectations for a low density plasma controlled by electron collisions. The inclusion of ion-ion and ion-atom charge exchange reactions and a depleted high energy electron component in the model is found to suppress O III levels, however observed limiting values are only achieved if it is assumed that the O III is kinetically hot. In addition, the charge-exchange model developed is inconsistent with previous observations of the kinetics of the S II-S III system. The present observations also establish upper limits of 2 R on 5518-A and 5538-A Cl III emission, and an emission rate of 58 + or - 40 R for the S III 6312-A line in the hot torus.

Brown, R. A.↗

O(+) ions in the polar wind

A semikinetic model was used to describe the steady state collisionless flow of the polar wind along diverging geomagnetic field lines at high latitues. Emphasis was given to studying the behavior of O(+) ions for a wide range of boundary conditions at the baropause (4500 km). The main result obtained was that for high electron temperatures Te = about 10,000 K) O(+) is not gravitationally bound and significant escape fluxes (about 10 to the 7th/sq cm sec) of suprathermal (2eV) O(+) ions occur. The O(+) flow is supersonic over most of the altitude range considered, and O(+) Mach numbers as large as 20 are predicted at 10 earth radii. Also, depending on the boundary conditions, the O(+) density can be comparable to or greater than the H(+) density at high altitudes above the baropause when the electron temperature is high.

Barakat, A. R.↗

Origin of the coverage-dependent vibrational shift for O on Ni(100)

The p(2 x 2) and c(2 x 2) coverages of O on Ni(100) are studied with a cluster model. The p(2 x 2) coverge is modeled by the addition of a single O at a fourfold site. The c(2 x 2) is modeled by the explicit inclusion of four additional O atoms. Consistent with electron-energy-loss spectroscopy results, the O-Ni vibration is 85/cm lower for the c(2 x 2) cluster than for the p(2 x 2). The height of O above the surface is 11 pm smaller for the c(2 x 2) coverage. The nature of the O-to-Ni bonding is similar for both coverages.

Bauschlicher, C. W., Jr.↗

A new source of suprathermal O(+) ions near the dayside polar cap boundary

A large number of data on suprathermal O(+) ions taken during the retarding ion mass spectrometer (RIMS) experiment aboard the DE 1 satellite are surveyed. Examples are found of low-energy, upflowing O(+) which are consistent with one or more of the proposed ionospheric escape mechanisms. These include transversely accelerated O(+) ions, indicating low-altitude transverse acceleration, and O(+) field-aligned flows which indicate low-altitude parallel acceleration by either ambipolar or current-driven electric fields. However, by far the most common pitch angle distribution of escaping O(+) is found to be a new type of O(+) flow event which provides evidence for both perpendicular and parallel ion acceleration below the satellite and is found exclusively in the lower latitudes of the dayside polar cap. All species of ions are observed to move upward during these events, with an upward heat flux.

Lockwood, M.↗

High-pressure study of the new Y-Ba-Cu-O superconducting compound system

Hydrostatic effects on the superconducting transition temperature of the Y-Ba-Cu-O compound system, resistively, up to 19 kbar are investigated. It is found that pressure has little effect on the superconducting state of Y-Ba-Cu-O, in marked contrast to the behavior of the K2NiF4-phase La-Ba-Cu-O and La-Sr-Cu-O systems. It is suggested that this effect may be due to chemical pressure associated with the smaller Y atoms already present in Y-Ba-Cu-O. X-ray powder-diffraction studies show that the high-temperature superconductivity in Y-Ba-Cu-O can only be attributed to one or more phases with structures different from the cubic perovskite or tetragonal layered ones.

Hor, P. H.↗

O-ring sealing verification for the space shuttle redesign solid rocket motor

As a part of the redesign of the Space Shuttle Solid Rocket Motor, the field and nozzle-to-case joints were redesigned to minimize the dynamic flexure caused by internal motor pressurization during ignition. The O-ring seals and glands for the joints were designed to accommodate both structural deflections and to promote pressure assistance. A test program was conducted to determine if a fluorocarbon elastomeric O-ring could meet this criteria in the redesigned gland. Resiliency tests were used to investigate the O-ring response to gap motion while static seal tests were used to verify design criteria of pressure assistance for sealing. All tests were conducted in face seal fixtures mounted in servo-hydraulic test machines. The resiliency of the O-ring was found to be extremely sensitive to the effects of temperature. The External Tank/Solid Rocket Booster attach strut loads had a negligible affect on the ability of the O-ring to track the simulated SRB field joint deflection. In the static pressure-assisted seal tests, as long as physical contact was maintained between the O-ring and the gland sealing surface, pressure assistance induced instantaneous sealing.

Lach, Cynthia L.↗

Phase compatibilities of YBa2Cu3O(9-delta) type structure in quintenary systems Y-Ba-Cu-O-X (impurity)

Electrical transport properties of the oxidic high T(sub c) superconductors are significantly affected by the presence of minor amounts of various elements adventing as impurities, e.g., from the chemical environment during manufacturing. YBa2Cu3O(9-delta) is prone to an extinction of the superconductivity on (partial) substitution of all four elemental components. E.g., Pr (for Y), La (for Ba), Zn (for Cu) or peroxygroup (for O) substituents will alter some of the superconductivity preconditions, like mixed valence state in Cu3O7/O(9-delta) network or structural distortion of the network. Although various pseudoternary chemical equilibrium phase diagrams of the Y(O)-Ba(O)-Cu(O) system now are available, no consensus is generally shown, however, this is partly due to lack of compatible definitions of the equilibrium conditions. Less information is available about the phase compatibilities in the appropriate quaternary phase diagram (including oxygen) and virtually no information exists about any pentenary phase diagrams (including one impurity). Unfortunately, complexity of such systems, stemming both from number of quaternary or pentenary compounds and from visualizing the five-component phase system, limits this presentation to more or less close surroundings of the YBa2Cu3O(9-delta) type phase in appropriate pseudoquaternary or pseudopseudoternary diagrams, involving Y-Ba-Cu and O, O-CO2, alkaline metals, Mg and alkaline earths, and Sc and most of the 3-d and 4-f elements. The systems were investigated by means of x ray diffraction, neutron diffraction and chemical analytical methods on samples prepared by sol-gel technique from citrates. The superconductivity was characterized by measuring the diamagnetic susceptibility by SQUID.

Karen, P.↗

X-ray photoelectron spectroscopy characterization of a nonsuperconducting Y-Ba-Cu-O superconductor-normal-metal-superconductor barrier material

A film of a novel nonsuperconducting Y-Ba-Cu-O (YBCO) barrier material was grown using conditions similar to those reported by Agostinelli et al. (1991) for forming a cubic semiconducting (c-YBCO) phase, and the material was characterized using X-ray photoelectron spectroscopy (XPS). A comparison of the XPS spectra of this material to those obtained from the orthorhombic and tetragonal phases of YBCO (o-YBCO and t-YBCO, respectively) showed that the barrier material had spectral characteristics different from those of o-YBCO and t-YBCO, particularly in the O 1s region. Features associated with the Cu-O chain and surface-reconstructed Cu-O planes were absent, consistent with expectations for the simple perovskite crystal structure of c-YBCO proposed by Agostinelli et al.

Vasquez, R. P.↗

Reevaluation of the O(+)(2P) reaction rate coefficients derived from Atmosphere Explorer C observations

O(+)(2P) is an important species for studies of the ionosphere and thermosphere: its emission at 7320 A can be used as a diagnostic of the thermospheric atomic oxygen density. Unfortunately, there are no laboratory measurements of the O and N2 reaction rates which are needed to determine the major sinks of (O+)(2p). We have recalculated the O and N2 reaction rates for O(+) (2P) using recent improvements in the solar EUV flux, cross sections, and photoelectron fluxes. For the standard solar EUV flux, the new N2 reaction rate of 3.4 +/- 1.5 x 10 exp -10 cu cm/s is close to the value obtained by Rusch et al. (1977), but the new O reaction rate of 4.0 +/- 1.9 x 10 exp -10 cu cm/sec is about 8 times larger. These new reaction rates are derived using neutral densities, electron density, and solar EUV fluxes measured by Atmosphere Explorer C in 1974 during solar minimum. The new theoretical emission rates are in good agreement with the data for the two orbits studied by Rusch et al.

Chang, T.↗

Extreme Mg-26 and O-17 enrichments in an Orgueil corundum: Identification of a presolar oxide grain

A corundum (Al2O3) grain from the Orgueil meteorite is greatly enriched in O-17 and (Mg-26)(sup *). The measured O-16/O-17 is 1028 +/- 11 compared to solar(O-16/O-17) = 2610. This is the largest O-17 excess so far observed in any meteoritic material. The Mg-26 excess ((Mg-26)(sup *)) is most plausibly due to in situ decay of Al-26. The inferred (Al-26/Al-27)(sub 0) ratio of 8.9 x 10(exp -4) is approximately 18 times larger than the 5 x 10(exp -5) value commonly observed in refractory inclusions formed in the solar system. The large O-17 excess and high (Mg-26)(sup *) Al-27 ratio unambiguously identify this corundum as a presolar oxide grain. Enrichments in O-17 and Al-26 are characteristic of H-burning and point to red giant or asymptotic giant branch (AGB) stars as likely sources.

Hutcheon, I. D.↗

The allowed lines of O IV near 1340 A in high electron density solar flares

Intersystem lines of O IV near 1400 A have long been used as electron density diagnostics for solar plasmas at temperatures of around 160,000 K. In addition, however, several allowed lines of O IV near 1340 A should become visible in conditions of high plasma electron number density (greater than 10(exp 12)/cu cm), such as during a solar flare. We present observations of the 1340 A and 1400 A regions of the solar spectrum for two solar flares, obtained by the SO82B spectrograph on board Skylab. We examine three candidate lines for allowed O IV in the flare spectra which occur at the correct wavelengths, but show that two of these are actually blends dominated by resonantly excited molecular lines of H2. The third candidate line, at 1343.51 A, we identify as the O IV allowd line. We present the density and temperature sensitivity of the ratio of allowed and intersystem O IV lines R = I(1343.51 A)/I(1407.39 A). The 1343.51 A line is clearly present in the first solar flare spectrum, and the ratio value implies an electron density of log N(sub e) = 12.6. The second flare has a much weaker 1343.51 A profile, but again the ratio value implies a high electron density. Both these electron density values are in good agreement with estimates for each flare from independent diagnostic ratios. The simple presence alone of a clearly observed O IV 1343.51 A emission line implies an electron density greater than 10(exp 12)/cu cm.

Cook, J. W.↗

Hot gas in the interstellar medium: A reanalysis of O VI absorption data

The Copernicus O(+5) column densities toward 72 stars provide a rare and valuable tracer of 10(exp 5.5) K gas in the interstellar medium. The original analysis of the data by Jenkins provided important clues about the distribution of interstellar O(+5) ions, but our understanding of the local interstellar medium has since grown substantially. We revisit that work, including the possibility that local hot gas may contribute a significant O(+5) column density to most lines of sight. Our reanalysis also includes slight improvements in the statistics and was found to be reliable when tested on simulated data sets. In the end, we come to conclusions about the distribution of interstellar O(+5) ions that differ considerably from those of the original analysis. With our reanalysis, some theoretical models now show promise. For example, our Local Bubble column density compares favorably with the estimated quantity of O(+5) within the remnant of an ancient local explosion. Similarly, our mean O(+5) column density per feature in more distant regions is like that found in models of hot interstellar bubbles from either stellar winds or ancient supernova explosions in a warm diffuse interstellar environment, suggesting that the hot gas in interstellar space may exist primarily within discrete regions of modest volume occupation rather than in a continuous and pervasive phase.

Shelton, R. L.↗

Excitation of the low lying vibrational levels of H2O by O(3P) as measured on Spacelab 2

The data from the infrared telescope (IRT), which was flown on space shuttle Challenger Spacelab 2 mission (July 1985), were originally reported by Koch et al. (1987) as originating from near orbital emissions, primarily H2O. In this study, analysis of this data was extended to determine the collisional cross sections for the excitation of the low lying vibrational levels of H2O, present in the orbiter cloud, by atmospheric O(3P). The evaluation of the contribution to the measured signal from solar excitation and ram O excitation of outgassing H2O permits the determination of the H2O column density and the excitation cross section of the (101) level at an O(3P) velocity of approximately 7.75 km/s. Contributions to the radiation in the 1.7-3.0 micron band by transitions from the (100), (001), and multiquantum excited levels are discussed. The findings of the study are (1) the IRT data for the 4.5-9.5 micron and the nighttime data for the 1.7-3.0 micron sensors are consistent with being explained by collision excitation of H2O by O(3P), (2) diurnal variations of 4.5-9.5 micron intensities follow the model predicted O density for a full orbit, (3) daytime increases in the H2O cloud density were not evident, (4) the cross sections for the collisional excitation process are derived and compared to values computated by Johnson (1986) and Redmon et al. (1986), (5) theoretical investigation suggests greater than 60% of the radiation from H2O is a result of multiphoton emission resulting from collisional multiquanta excitation, and (6) the large daytime increase in the 1.7-3.0 micron intensity data suggests that O(+) may likely be instrumental in producing excited H2O(+) through charge exchange.

Meyerott, R. E.↗

Automated Inspection of the RSRM Case O-Ring Seal Surface

An automated inspection system has been developed to inspect the o-ring sealing surfaces on the Space Shuttle reusable solid rocket motor (RSRM) case segment joints. A laser digitizing system is used to create a three dimensional map of the o-ring sealing surfaces. This data is analyzed for any irregularities, which are noted for further inspection and disposition. This paper describes both the hardware and the software used to gather data as well as the methods developed to analyze the data. The RSRM is assembled from four casting segments. Each of the field joints between these segments is sealed with three o-rings. These o-rings are critical for the proper operation of the motor. After launch the booster segments are recovered and reused. As part of the refurbishment process the o-ring sealing surfaces are inspected for any irregularities. The system developed uses a combination of commercial and customized hardware and software. The system uses two computer systems in a real time environment to control a laser, an XYZ precision table, and case rotation and position information. The system is capable of inspecting both the tang end and the clevis end of the RSRM field joint. The o-ring grooves and flat sealing surfaces are inspected.

ODell, Keith P.↗