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At least 199 records · Page 11
All sourcesNASA NTRSDOE OSTI
NASA NTRS2013

Multi-Model Mean Nitrogen and Sulfur Deposition from the Atmospheric Chemistry and Climate Model Intercomparison Project (ACCMIP): Evaluation of Historical and Projected Future Changes

We present multi-model global datasets of nitrogen and sulfate deposition covering time periods from 1850 to 2100, calculated within the Atmospheric Chemistry and Climate Model Intercomparison Project (ACCMIP). The computed deposition fluxes are compared to surface wet deposition and ice core measurements.We use a new dataset of wet deposition for 2000-2002 based on critical assessment of the quality of existing regional network data. We show that for present day (year 2000 ACCMIP time slice), the ACCMIP results perform similarly to previously published multi-model assessments. For this time slice, we find a multimodel mean deposition of approximately 50 Tg(N) yr−1 from nitrogen oxide emissions, 60 Tg(N) yr−1 from ammonia emissions, and 83 Tg(S) yr−1 from sulfur emissions. The analysis of changes between 1980 and 2000 indicates significant differences between model and measurements over the United States but less so over Europe. This difference points towards a potential misrepresentation of 1980 NH3 emissions over North America. Based on ice core records, the 1850 deposition fluxes agree well with Greenland ice cores, but the change between 1850 and 2000 seems to be overestimated in the Northern Hemisphere for both nitrogen and sulfur species. Using the Representative Concentration Pathways (RCPs) to define the projected climate and atmospheric chemistry related emissions and concentrations, we find large regional nitrogen deposition increases in 2100 in Latin America, Africa and parts of Asia under some of the scenarios considered. Increases in South Asia are especially large, and are seen in all scenarios, with 2100 values more than double their 2000 counterpart in some scenarios and reaching >1300 mg(N)m−2 yr−1 averaged over regional to continental-scale regions in RCP 2.6 and 8.5, 30-50% larger than the values in any region currently (circa 2000). However, sulfur deposition rates in 2100 are in all regions lower than in 2000 in all the RCPs. The new ACCMIP multimodel deposition dataset provides state-of-the-science, consistent and evaluated time slice (spanning 1850-2100) global gridded deposition fields for use in a wide range of climate and ecological studies.

Lamarque, J.-F.↗
NASA NTRSDate not supplied

Analysis of Nitrogen Shockwave Radiation at Velocity Around 7km/s

In the last decade, the Electric Arc Shock Tube (EAST) facility has been widely used to provide experimental data aiming to validate radiative heating models used for atmospheric entry, mostly at velocities above 9km/s in air. In more recent years, another experimental campaign aimed to look at velocity below 9 km/s and its analysis resulted in a significant improvement of the air kinetic model using new rates found in the literature but discrepancies were still observed, especially for the N2 second positive system. Despite these previous studies, the overall uncertainties related to surface heating for lunar return remain around 50% To reduce these uncertainties, the last experimental campaign at EAST, named test 62, was conducted in pure nitrogen at velocity ranging from 6 to 11 km/s at a freestream pressure of 0.2 Torr to provide more fundamental data on nitrogen. A previous study analyzed the data obtained at a velocity of 10.3 km/s, where atomic radiation is dominant, and provided spatially resolved density measurements of different states of nitrogen. This study will focus on experimental data obtained at shock velocity of 6.88 and 7.15 km/s where molecular nitrogen is expected to be the dominant source of radiation.

Augustin Tibere-Inglesse↗
NASA NTRSDate not supplied

Joule-Thomson Cryogenic Nitrogen Orifice Flows

The Joule-Thomson Effect involves the expansion of a fluid through a throttling device, often a simple orifice, resulting in a change in the fluid's temperature. It has been leveraged in the design and analysis of Thermodynamic Vent Systems and integrated into injector designs for cryogenic no-vent fill tank-to-tank transfer testing. There is a scarcity of comprehensive data available to model the phenomenon effectively using tools such as GFSSP for cryogenic nitrogen flows. This experiment aims to model the Joule-Thomson effect of liquid nitrogen through seven traditionally manufactured, sharp-edged orifices manufactured by O’Keefe and three additively manufactured (AM) orifices manufactured by Cumberland Additive. The traditional orifice sizes were 0.016, 0.02, 0.024, 0.032, 0.037, and 0.04 inch in diameter. The three additive orifices had diameters with target/nominal sizes equal to the 0.016, 0.024, and 0.04 inch O’Keefe orifices. However, the actual diameters of the AM orifices were found to be 0.014, 0.024, and 0.035 inches due to additive manufacturing restrictions. Water was flowed through the orifices to verify that their flow coefficients matched published values and to establish flow coefficients for the AM orifices. Liquid nitrogen was flowed through the orifices in a separate test apparatus. The liquid nitrogen started as a subcooled liquid upstream of the orifice and transitioned into a two-phase gas-liquid mixture after passing through each orifice. The upstream pressure was set to 29 psia, 34 psia, 39 psia, and/or 42 psia or 44 psia. The pressure, temperature, and flow rate were measured upstream and downstream of the orifice for three trials at each set point. The average volumetric flow rate and Joule-Thomson Coefficients were calculated from this data. The AM orifices and traditionally manufactured orifices displayed similar results. This data will refine the dataset GFSSP uses to model the J-T Effect more accurately.

Joule-Thomson↗
NASA NTRS1962

BOILING HEAT TRANSFER TO LIQUID HYDROGEN AND NITROGEN IN FORCED FLOW

Boiling heat transfer to liquid hydrogen and nitrogen was investigated experimentally. Results are presented from a study of bulk boiling inside a cylindrical tube under vertically upward forced-flow conditions. A 0.555-inch-inside-diameter and 16 (1/8)-inch-long electrically heated stainless-steel tube was used. The range of variables studied for hydrogen were mass velocity of 2850 to 17,000 pounds per hour per square foot, local heat flux of 3600 to 40,000 Btu per hour per square foot, inlet pressure of 30 to 74 pounds per square inch absolute, and inlet subcooling of 0° to 9° R. Nitrogen test conditions were mass velocity of 15,000 to 56,000 pounds per hour per square foot, local heat flux of 2300 to 40,000 Btu per hour per square foot, inlet pressure of 47 to 56 pounds per square inch absolute, and inlet sub cooling of 1° to 6° R. The axial distribution of the tube-wall temperatures is presented. A transition in the type of boiling heat transfer was obtained. The critical heat flux corresponding to this transition was determined over a range of flow and heating rates and local qualities. At specific combinations of flow and transition location, a range of critical-heat-flux values was obtained and maximum values were determined. The maximum critical heat flux increased with increasing fluid-flow rate and decreased with increasing length of tube before transition. Similar variations of the maximum critical heat flux have been reported for water. The tube-inner-wall temperatures upstream of transition were essentially uniform and were only slightly greater than the fluid saturation temperature. The Wall-temperature profiles downstream of transition generally resembled those obtained in film-boiling studies and appeared to be strongly dependent upon local quality at the point of transition. Maximum wall temperatures of 9000 and 18000 R were obtained with hydrogen and nitrogen, respectively. Fluctuations of pressure, flow rate, and temperature occurred during some of the boiling tests. Under some conditions, maximum critical-heat-flux values were attained during steady-state operation with fluctuations. In other cases the fluctuations became uncontrolled, and critical-flux values less than the maximum values were obtained upon restabilization of the test conditions. No measurable pressure drop across the test section was obtained at any condition.

LIQUID HYDROGEN↗
NASA NTRS2000

Measuring the spectrum of mutation induced by nitrogen ions and protons in the human-hamster hybrid cell line A(L)C

Astronauts can be exposed to charged particles, including protons, alpha particles and heavier ions, during space flights. Therefore, studying the biological effectiveness of these sparsely and densely ionizing radiations is important to understanding the potential health effects for astronauts. We evaluated the mutagenic effectiveness of sparsely ionizing 55 MeV protons and densely ionizing 32 MeV/nucleon nitrogen ions using cells of two human-hamster cell lines, A(L) and A(L)C. We have previously characterized a spectrum of mutations, including megabase deletions, in human chromosome 11, the sole human chromosome in the human-hamster hybrid cell lines A(L)C and A(L). CD59(-) mutants have lost expression of a human cell surface antigen encoded by the CD59 gene located at 11p13. Deletion of genes located on the tip of the short arm of 11 (11p15.5) is lethal to the A(L) hybrid, so that CD59 mutants that lose the entire chromosome 11 die and escape detection. In contrast, deletion of the 11p15.5 region is not lethal in the hybrid A(L)C, allowing for the detection of chromosome loss or other chromosomal mutations involving 11p15.5. The 55 MeV protons and 32 MeV/nucleon nitrogen ions were each about 10 times more mutagenic per unit dose at the CD59 locus in A(L)C cells than in A(L) cells. In the case of nitrogen ions, the mutations observed in A(L)C cells were predominantly due to chromosome loss events or 11p deletions, often containing a breakpoint in the pericentromeric region. The increase in the CD59(-) mutant fraction for A(L)C cells exposed to protons was associated with either translocation of portions of 11q onto a hamster chromosome, or discontinuous or "skipping" mutations. We demonstrate here that A(L)C cells are a powerful tool that will aid in the understanding of the mutagenic effects of different types of ionizing radiation.

Non-NASA Center↗
NASA NTRS2012

The Cabauw Intercomparison Campaign for Nitrogen Dioxide Measuring Instruments (CINDI): Design, Execution, and Early Results

From June to July 2009 more than thirty different in-situ and remote sensing instruments from all over the world participated in the Cabauw Intercomparison campaign for Nitrogen Dioxide measuring Instruments (CINDI). The campaign took place at KNMI's Cabauw Experimental Site for Atmospheric Research (CESAR) in the Netherlands. Its main objectives were to determine the accuracy of state-ofthe- art ground-based measurement techniques for the detection of atmospheric nitrogen dioxide (both in-situ and remote sensing), and to investigate their usability in satellite data validation. The expected outcomes are recommendations regarding the operation and calibration of such instruments, retrieval settings, and observation strategies for the use in ground-based networks for air quality monitoring and satellite data validation. Twenty-four optical spectrometers participated in the campaign, of which twenty-one had the capability to scan different elevation angles consecutively, the so-called Multi-axis DOAS systems, thereby collecting vertical profile information, in particular for nitrogen dioxide and aerosol. Various in-situ samplers and lidar instruments simultaneously characterized the variability of atmospheric trace gases and the physical properties of aerosol particles. A large data set of continuous measurements of these atmospheric constituents has been collected under various meteorological conditions and air pollution levels. Together with the permanent measurement capability at the CESAR site characterizing the meteorological state of the atmosphere, the CINDI campaign provided a comprehensive observational data set of atmospheric constituents in a highly polluted region of the world during summertime. First detailed comparisons performed with the CINDI data show that slant column measurements of NO2, O4 and HCHO with MAX-DOAS agree within 5 to 15%, vertical profiles of NO2 derived from several independent instruments agree within 25% of one another, and MAX-DOAS aerosol optical thickness agrees within 20-30% with AERONET data. For the in-situ NO2 instrument using a molybdenum converter, a bias was found as large as 5 ppbv during day time, when compared to the other in-situ instruments using photolytic converters.

Atmospheric composition↗
NASA NTRS2014

Alteration of the Carbon and Nitrogen Isotopic Composition in the Martian Surface Rocks Due to Cosmic Ray Exposure

C-13/C-12 and N-15/N-14 isotopic ratios are pivotal for our understanding of the Martian carbon cycle, history of the Martian atmospheric escape, and origin of the organic compounds on Mars. Here we demonstrate that the carbon and nitrogen isotopic composition of the surface rocks on Mars can be significantly altered by the continuous exposure of Martian surface to cosmic rays. Cosmic rays can effectively produce C-13 and N-15 isotopes via spallation nuclear reactions on oxygen atoms in various Martian rocks. We calculate that in the top meter of the Martian rocks, the rates of production of both C-13 and N-15 due to galactic cosmic rays (GCRs) exposure can vary within 1.5-6 atoms/cm3/s depending on rocks' depth and chemical composition. We also find that the average solar cosmic rays can produce carbon and nitrogen isotopes at a rate comparable to GCRs in the top 5-10 cm of the Martian rocks. We demonstrate that if the total carbon content in a surface Martian rock is <10 ppm, then the "light," potentially "biological" C-13/C-12 ratio would be effectively erased by cosmic rays over 3.5 billion years of exposure. We found that for the rocks with relatively short exposure ages (e.g., 100 million years), cosmogenic changes in N-15/N-14 ratio are still very significant. We also show that a short exposure to cosmic rays of Allan Hills 84001 while on Mars can explain its high-temperature heavy nitrogen isotopic composition (N-15/N-14). Applications to Martian meteorites and the current Mars Science Laboratory mission are discussed.

cosmic ray exposure↗
NASA NTRS2018

Shock Tube Radiation Measurements in Nitrogen

Spectrally and spatially resolved radiance has been measured in the Electric Arc Shock Tube (EAST) facility, with the aim of improving fundamental understanding of high enthalpy flows in pure nitrogen. These tests provide data to inform models used for simulations of high speed flight in nitrogen rich atmospheres, such as Earth or Titan. The experiments presented in this paper cover conditions from approximately 6 km/s to 11 km/s at an initial pressure of 0.2 Torr. A wide range of physics, with different degrees of non-equilibrium and nitrogen dissociation, are covered. The EAST data are presented in different formats for analysis and comparisons. These formats include the spectral radiance at equilibrium (where appropriate), the spatial dependence of radiance over defined wavelength ranges and the mean non-equilibrium spectral radiance (the so-called "spectral non-equilibrium metric"). All the information needed to simulate each experimental trace, including free-stream conditions, shock time of arrival (i.e. x-t) relation, and the spectral and spatial resolution functions, are provided. Equilibrium radiation calculations are shown as a reference. It is the intention of this paper to motivate code comparisons benchmarked against this data set.

shock tube↗
NASA NTRS2023

Coupled Fluid Dynamics and Material Response Simulations for Nitrogen High Enthalpy Flows

The study focuses on the interaction of nitrogen flows with thermal protection systems during atmospheric re-entry for NASA flight missions. The Ares multiphysics coupling tool is employed to investigate the coupling between the fluid (US3D) and material response (Icarus) solvers using various modeling approaches. These approaches include the equilibrium thin-film coefficients approach, a weakly coupled approach with temperature coupling, and an approach considering the full chemical composition of the surface and the transfer of pyrolysis gases. The objective is to understand and accurately represent the mechanisms of nitrogen interaction with the surface, such as nitridation and catalytic recombination. The study aims to assess the accuracy of the different approaches by comparing them to experimental results obtained from NASA arc-jet facilities. By addressing these challenges and improving the understanding of nitrogen-surface interactions, it is expected to enhance the design and performance analysis of thermal protection systems for future missions.

Ablation↗
NASA NTRS1972

Combined buoyancy and flow direction effects on saturated boiling critical heat flux in liquid nitrogen

Buoyancy effects on the critical heat flux and general data trends for a liquid nitrogen internal flow system were determined by comparison of upflow and downflow data under identical test conditions. The test section had a 1.28 cm diameter flow passage and a 30.5 cm heated length which was subjected to uniform heat fluxes through resistance heating. Test conditions covered a range of pressures from 3.4 to 10.2 atm, inlet velocities from 0.23 to 3.51 m/sec, with the liquid nitrogen temperature at saturated inlet conditions. Data comparisons showed that the critical heat flux for downflow could be up to 36 percent lower than for upflow. A nonmonotonic relationship between the critical heat flux and velocity was determined for upflow but not for downflow. A limiting inlet velocity of 4.12 m/sec was determined to be the minimum velocity required to completely suppress the influence of buoyancy on the critical heat flux for this saturated inlet flow system. A correlation of this limiting fluid velocity is presented that was developed from previously published subcooled liquid nitrogen data and the saturated data of this investigation.

Papell, S. S.↗
NASA NTRS1972

Thermodynamic properties of oxygen and nitrogen III

The final equation for nitrogen was determined. In the work on the equation of state for nitrogen, coefficients were determined by constraining the critical point to selected critical point parameters. Comparisons of this equation with all the P-density-T data were made, as well as comparisons to all other thermodynamic data reported in the literature. The extrapolation of the equation of state was studied for vapor to higher temperatures and lower temperatures, and for the liquid surface to the saturated liquid and the fusion lines. A new vapor pressure equation was also determined which was constrained to the same critical temperature, pressure, and slope (dP/dT) as the equation of state. Work on the equation of state for oxygen included studies for improving the equation at the critical point. Comparisons of velocity of sound data for oxygen were also made between values calculated with a preliminary equation of state and experimental data. Functions for the calculation of the derived thermodynamic properties using the equation of state are given, together with the derivative and integral functions for the calculation of the thermodynamic properties using the equations of state. Summary tables of the thermodynamic properties of nitrogen and oxygen are also included to serve as a check for those preparing computer programs using the equations of state.

Stewart, R. B.↗
NASA NTRS1973

Effect of nitrogen on tensile properties and structures of T-111 (tantalum, 8 percent tungsten, 2 percent hafnium) tubing

The effect of controlled nitrogen additions was evaluated on the mechanical properties of T-111 (Ta-8W-2Hf) fuel pin cladding material proposed for use in a lithium-cooled nuclear reactor concept. Additions of 80 to 1125 ppm nitrogen resulted in increased strengthening of T-111 tubular section test specimens at temperatures of 25 to 1200 C. Homogeneous distributions of up to 500 ppm nitrogen did not seriously decrease tensile ductility. Both single and two-phase microstructures, with hafnium nitride as the second phase, were evaluated in this study.

Buzzard, R. J.↗
NASA NTRS1973

Comparison of electron and electronic temperatures in recombining nozzle flow of ionized nitrogen-hydrogen mixture. I, II.

Relaxation of the population distribution of electronic states is studied theoretically for a highly ionized nitrogen-hydrogen mixture expanding through a nozzle wherein the hydrogen content is less than 0.1%. The analysis incorporates quantum-mechanical rate coefficients, and considers the effects of wall cooling and absorption of radiation. Calculations are carried out for a condition produced experimentally. Visible and infrared line radiations from nitrogen and hydrogen were measured with a spectrograph. The geometry and stagnation conditions were those calculated theoretically. The experiment confirms quantitatively the predictions that the electronic excitation temperatures of hydrogen and (3P) core states of nitrogen are higher than the electron temperature, and that (3P) excitation temperatures exhibit maxima within the nozzle.

Park, C.↗
NASA NTRS1974

Polymer-lined filament-wound pressure vessels for nitrogen containment

A program has been started to develop fatigue-resistant polymeric liners for a filament-wound pressure vessel to contain nitrogen gas at room temperature. First, nitrogen permeation of butyl rubber sheet coated with Saran and Parylene C was studied in flat specimens. Then four 10-cm-diam cylindrical pressure vessels were prepared with chlorobutyl rubber liners coated with the same materials. These vessels were valved off after nitrogen gas pressurization to approximately 65% (approximately 11.7 MPa or 1700 psig) of their expected failure pressure. One vessel leaked. The other three vessels showed an average pressure loss of less than 1% per month. These pressure vessels have an average performance factor of approximately 370 kPa-cu m/kg (1,500,000 in.) based on composite mass.

Hamstad, M. A.↗
NASA NTRS1974

Vibrationally excited nitrogen in stable auroral red arcs and its effect on ionospheric recombination

The time-dependent continuity equations, including diffusion, were solved for the first six energy levels of molecular nitrogen for conditions in the thermosphere corresponding to stable auroral red (SAR) arcs. The results show that molecular nitrogen is excited vibrationally to the degree that the rate constant for the ionospheric loss process, O(+) + N2 yields NO(+) + N, is increased by as much as a factor of 7.6 at F2 region altitudes. It was found that deviations from the energetically equivalent Boltzmann distribution were large, causing the rate constant to be as much as 1.6 times the rate constant calculated for the Boltzmann distribution. These results indicate that SAR arc intensities as small as 58 R can produce noticeable increases in the ionosphere ion-atom interchange reaction rate and hence in the rate of loss of ionospheric electrons. It is suggested that the observed decrease of electron density in the F2 region in SAR arcs can probably be explained by enhanced reaction rates for ion-atom interchange between O(+) and N2 caused by vibrational excitation of molecular nitrogen by electron impact.

Newton, G. P.↗
NASA NTRS1974

Decomposition of nitric oxide in a hot nitrogen stream to synthesize air for hypersonic wind tunnel combustion testing

A clean source of high enthalpy air was obtained from the exothermic decomposition of nitric oxide in the presence of strongly heated nitrogen. A nitric oxide jet was introduced into a confined coaxial nitrogen stream. Measurements were made of the extent of mixing and reaction. Experimental results are compared with one- and two-dimensional chemical kinetics computations. Both analyses predict much lower reactivity than was observed experimentally. Inlet nitrogen temperatures above 2400 K were sufficient to produce experimentally a completely reacted gas stream of synthetic air.

Zumdieck, J. F.↗
NASA NTRS1974

Polymer-lined filament-wound pressure vessels for nitrogen containment

A program has been started to develop fatigue-resistant polymeric liners for a filament-wound pressure vessel to contain nitrogen gas at room temperature. First, nitrogen permeation of butyl rubber sheet coated with Saran and Parylene C was studied in flat specimens. Then four 10-cm-diam cylindrical pressure vessels were prepared with chlorobutyl rubber liners coated with the same materials. These vessels were valved off after nitrogen gas pressurization to approximately 65% of their expected failure pressure. One vessel leaked. The other three vessels showed an average pressure loss of less than 1% per month. These pressure vessels have an average performance factor of about 370 kPa x cu m/kg based on composite mass.

Hamstad, M. A.↗