Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “IV&V”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 199 records · Page 11
All sourcesNASA NTRSDOE OSTI
DOE OSTI2024

Exceptional hardness in multiprincipal element alloys via hierarchical oxygen heterogeneities

Refractory multiprincipal element alloys (RMPEAs) are potential successors to incumbent high-temperature structural alloys, although efforts to improve oxidation resistance with large additions of passivating elements have led to embrittlement. RMPEAs containing group IV and V elements have a balance of properties including moderate ductility, low density, and the necessary formability. We find that oxidation of group IV-V RMPEAs induces hierarchical heterogeneities, ranging from nanoscale interstitial complexes to tertiary phases. This microstructural hierarchy considerably enhances hardness without indentation cracking, with values ranging between 12.1 and 22.6 GPa from the oxide-adjacent metal to the surface oxides, a 3.7 to 6.8× increase over the interstitial-free alloy. Our fundamental understanding of the oxygen influence on phase formation informs future alloy design to enhance oxidation resistance and obtain exceptional hardness while preserving plasticity.

Science & Technology - Other Topics↗
NASA NTRS1986

Ultraviolet observations of Be stars. II - Superionization in Be stars of different spectral types

The results of an investigation of the dependence of the strength/presence of lines from superionized species (N V, C IV, Si IV) on spectral type and v sin i in the ultraviolet spectra of Be stars are presented. No evidence is found for N V in stars later than B2; this apparent absence may, however, simply reflect problems with the IUE reduction procedure. The C IV and Si IV lines pervade the ultraviolet spectra of all B subtypes, with a trend toward increasing strength with increasing effective temperature. A similar trend in the 'edge velocity' of the feature with spectral type is found. The data also suggest a possible trend toward the presence of stronger C IV and a higher edge velocity in stars with larger values of v sin i. The observed temporal variability in N V, C IV, and Si IV in some Be stars is discussed.

Marlborough, J. M.↗
DOE OSTI2026

Oxygen Effects and Selective Oxidation of Group IV Alloying Additions in Group V-Based Refractory Multi-principal Element Alloys

Refractory multi-principal element alloys (RMPEAs) hold significant potential for advancing ultra-high-temperature technologies due to their remarkable strength retention under these conditions. However, the beneficial effects of alloying on microstructural evolution and mechanical properties are often obscured by the presence of interstitial alloying elements. The intricate interactions between substitutional alloying elements of Groups IV, V, and VI and interstitial content, whether intentional or incidental, remain poorly understood. In this study, we investigate the impact of dissolved oxygen on the microstructural evolution and stability of RMPEAs primarily composed of Group V elements, Nb and V, along with Group IV elements Ti, Zr, and Hf. We show that the strong affinity of oxygen for Group IV elements Zr and Hf leads to the internal precipitation of oxides during heat treatment, which competes with the homogenization of the as-cast dendritic microstructure. Here, we demonstrate that careful control and design of oxygen content and Group IV alloying additions are essential to minimize micro-segregation and prevent the detrimental precipitation of internal oxides. To address these challenges, we propose employing non-equilibrium solidification calculations to predict and optimize as-cast solidification structures, thereby reducing the reliance on homogenization processes.

Alloy design↗
NASA NTRS1989

Consequences of a conductive boundary on the local cloud. I - No dust

Using boundary conditions appropriate to the Local Cloud embedded in the Local Bubble, the evaporation of the cloud is modeled assuming steady flow. Included in the model are the effects of radiative cooling and nonequilibrium ionization structure in the interface, and pressure support and heat conduction inhibition due to the magnetic field. The soft X-ray and EUV emission from the interface are calculated and compared with observations. It is found that the emission in the softest X-ray band, the Be band, is harder than that calculated for an equilibrium, normal abundance, 10 to the 6th K plasma. Column densities of C IV, N V, O VI, Si IV, and Si III in the interface are calculated. The column density for O VI is found to be very close to observed values for nearby stars, while all others are too small to contribute significantly to observed values. The ionization of the Local Cloud due to radiation from the interface is calculated. It is found that a significant amount of ionizing radiation is produced, dominating all other known sources. The hardness of the emission, however, results in ionization of helium as well as hydrogen. Thus, the type of boundary modeled cannot explain the ionization of the very local interstellar medium inferred from solar backscatter measurements.

Slavin, Jonathan D.↗
NASA NTRS2019

The Broad Absorption Line Tidal Disruption Event iPTF15af: Optical and Ultraviolet Evolution

We present multiwavelength observations of the tidal disruption event (TDE) iPTF15af, discovered by the intermediate Palomar Transient Factory survey at redshift z = 0.07897. The optical and ultraviolet (UV) light curves of the transient show a slow decay over 5 months, in agreement with previous optically discovered TDEs. It also has a comparable blackbody peak luminosity of L(sub peak) approx. = 1.5 x 10(exp 44) erg s(exp -1). The inferred temperature from the optical and UV data shows a value of (3–5) × 10(exp 4) K. The transient is not detected in X-rays up to L(sub X) < 3 x 10(exp 42) erg s(exp -1) within the first 5 months after discovery. The optical spectra exhibit two distinct broad emission lines in the He ii region, and at later times also Hα emission. Additionally, emission from [N iii] and [O iii] is detected, likely produced by the Bowen fluorescence effect. UV spectra reveal broad emission and absorption lines associated with high-ionization states of N v, C iv, Si iv, and possibly P v. These features, analogous to those of broad absorption line quasars (BAL QSOs), require an absorber with column densities N(sub H) > 10(exp 23) cm(exp -2). This optically thick gas would also explain the nondetection in soft X-rays. The profile of the absorption lines with the highest column density material at the largest velocity is opposite that of BAL QSOs. We suggest that radiation pressure generated by the TDE flare at early times could have provided the initial acceleration mechanism for this gas. Spectral UV line monitoring of future TDEs could test this proposal.

Blagorodnova, N.↗
DOE OSTI2020

Neptunium extraction by N,N-dialkylamides

Separation of neptunium by solvent extraction has been based on tributylphosphate (TBP) for decades, but TBP is not fully incinerable, which adds to the burden of long-lived radioactive waste. Alternatives to TBP for uranium and plutonium extraction, such as the N , N -diakylamides, previously have been explored in the hopes of transitioning to an extractant that is incinerable. Four N , N -diakylamides, N , N -dihexylhexanamide (DHHA), N , N -dihexyloctanamide (DHOA), N , N -di(2-ethylhexyl)butanamide (DEHBA), and N , N -di(2-ethylhexyl)-iso-butanamide (DEHiBA) were considered in this work for their potential to extract millimolar concentrations of Np(IV), Np(V), and Np(VI) from nitric acid solutions into organic solutions containing 1 M extractant in Exxsol D60. Furthermore, under these conditions the branching of the alkyl substituents affects the extractability of Np(VI) and Np(IV), causing three of the dialkylamides, DHHA, DHOA and DEHBA, to extract neptunium in the expected order Np(VI) > Np(IV) > > Np(V). In contrast, branched DEHiBA is so poor an extractant for Np(IV) that the extraction order becomes Np(VI) > > Np(V) > Np(IV) between 0.1 and 5.6 M HNO 3 due to partial oxidation of the Np(V) in nitric acid.

07 ISOTOPE AND RADIATION SOURCES↗
NASA NTRS1980

Highly-ionized species in the interstellar medium

Interstellar absorption lines have been observed toward 25 stars with the International Ultraviolet Explorer satellite. Results are presented for observations of interstellar lines of C III, C IV, N V, Si III, and Si IV. Strong lines of Si IV or C IV are seen toward 11 stars. The strengths of these lines are inconsistent with their formation in the same hot gas responsible for the interstellar O IV lines observed with the Copernicus ultraviolet spectrometer. Comparison with simple models of the ionization structures of H II regions around hot stars suggests that the observed column densities of Si III, Si IV, and C IV are in harmony with those expected in normal photoionized nebulae. The line of sight to HD 93250, and O3 V star near Eta Carinae, passes through highly ionized gas that shows features spanning 250 km/s in radial velocity. Stellar wind velocities are presented for 21 of the stars observed in this survey of interstellar absorption lines.

Black, J. H.↗
NASA NTRS1994

Highly ionized gas absorption in the disk and halo toward HD 167756 at 3.5 kilometers per second resolution

High-resolution spectra of interstellar Si IV, C IV, and N V absorption lines along the 4 kpc path to the inner Galaxy star HD 167756 at z = -0.85 kpc are presented. The spectra were obtained with the echelle mode of Goddard High Resolution Spectrograph (GHRS) aboard the Hubble Space Telescope (HST) and have signal-to-noise ratios ranging from 23 to 38. The high resolution of the measurements full width at half maximum (FWHM = 3.5 km/s) results in fully resolved line profiles for the highly ionized gas absorption. The measurements provide information on the column density per unit velocity, N(v), as a function of velocity for Si IV, C IV, and N V. The C IV and N V profiles extend from -70 to +70 km/s, while the Si IV profiles extend from -40 to +70 km/s. The integrated logarithmic column densities are long N(Si IV) = 13.09 +/- 0.02, log N(C IV) = 13.83 +/- 0.02, and log N(N V) = 13.56 +/- 0.03. The N V profile is broad, asymmetric, and featureless, while the Si IV profile contains narrow absorption components near V(sub LSR) = -19, 0, +20, and +52 km/s with Doppler spread parameters, b about = 10-12 km/s. The C IV profile contains both broad and narrow structure. The high ion feature near +52 km/s is also detected in the low-ionization lines of Ca II, O I, Si II, and Fe II. The other narrow Si IV and C IV components occur within several km/s of components seen in low-ionization species. The sight line contains at least two types of highly ionized gas. One type gives rise to a broad N V profile, and the other results in the more structured Si IV profile. The C IV profile contains contributions from both types of highly ionized gas. The broad but asymmetric N V profile is well represented by a large Galactic scale height gas which is participating in Galactic rotation and has a combination of thermal and turbulent broadening with b(sub tot) about = 42 km/s. The C IV to N V abundance ratio of 1.0 +/- 0.3 for the gas implies T about 1.6 x 10(exp 5) K or about 8 x 10(exp 5) K if the gas is in collisional ionization equilibrium and has a solar carbon to nitrogen abundance ratio. This absorption may be associated with cooling hot gas situated in Galactic shells and supershells along the sight line. The gas producing the narrow Si IV and C IV absorption components has line widths that are compatible with origins in conductive interfaces between the warm and hot interstellar medium. Kinematic flows associated with the photoionized edges of clouds might also produce Si IV and C IV lines with Doppler spread parameters similar to those observed, but the C IV to Si IV ratio in this gas is 3.5, which leads us to favor the conductive interface interpretation.

Savage, Blair D.↗
NASA NTRS1975

The ultraviolet spectrum of B-type supergiants

OAO-2 spectral scans of several early-type main-sequence stars and the shell star zeta Tau are analyzed to derive a representative UV spectrum for B-type supergiants. The absorption lines in the spectra of the B-type supergiants are shown to be stronger than those in main-sequence stars and to have a broad pointed feature at 1720 A that is constant in all such stars. The UV resonance lines of C IV, N V, Si III, and Si IV are found to be displaced toward the shorter wavelengths by velocities of up to 1800 km/s, indicating an escaping atmosphere. For B5 stars, the atmosphere is estimated to be expanding at about 120 km/s. The spectrum of eta CMa (B5Ia) is found to be well represented by the LTE theory of line formation, the presence of a stationary circumstellar shell, and a slowly expanding model atmosphere.

Underhill, A. B.↗
NASA NTRS1996

The Hubble Space Telescope Quasar Absorption Line Key Project: The Unusual Absorption-Line System in the Spectrum of PG 2302+029--Ejected or Intervening?

We report the discovery of a high-ionization broad absorption line system at a redshift of z(sub abs) = 0.695 in the spectrum of the z(sub em) = 1.052 radio-quiet quasar PG 2302+029. Broad absorption with FWHM from 3000 to 5000 km/s is detected from C iv, N v, and O vi in Hubble Space Telescope (HST) Faint Object Spectrograph spectra of the quasar. A narrow-line system (FWHM approx. 250 km/s) at z(sub abs) = 0.7016 is resolved from the broad blend and includes absorption by Ly alpha and the C iv, N v, and O vi doublets. No absorption by low-ionization metal species (e.g., Si II and Mg II) is detected in the HST or ground-based spectra for either the broad or the narrow system. The centroids of the broad system lines are displaced by approx. 56,000 km/s to the blue of the quasar's broad emission lines. The reddest extent of the broad-line absorption is more than 50,000 km/s from the quasar. The properties of this system are unprecedented, whether it is an intervening or an ejected system.

Jannuzi, B. T.↗
NASA NTRS1994

Evidence for a disk in the wind of HD 93521: UV line profiles from an axisymmetric model

Recently it has been suggested (Massa 1992; Howarth & Reid 1993), from the C IV ultraviolet resonance line profile of HD 93521, that there is a high-speed component in the polar outflow from the star as well as a low-speed component in the equatorial regions. In this paper we present theoretical calculations of the line profiles that would be produced by such a model. We find from Hubble Space Telescope (HST) Goddard High Resolution Spectrograph (GHRS) observations of HD 93521 that the observed C IV profile can be produced if the star has an inclination angle very close to 90 deg and if the star is surrounded by a thin disk, whose half-width is approximately 3 deg in latitude. The geometry of this disk is similar to what one would expect from the wind-compressed disk model of Bjorkman & Cassinelli, so this star may provide an ideal observational test of that model. In addition to the C IV resonance line, we examine both the Si IV and N V resonance lines. The Si IV line exhibits low-velocity absorption that is similar to that seen in the C IV line, but the emission is much weaker. On the other hand, the N V line has weaker absorption and much stronger emission than the C IV line. N V is a higher ionization state than C IV, so it is likely that N V is one stage above the dominant state, N IV. Apart from fitting individual line profiles, we also examine the differences between the two Hubble Space Telescope observations of HD 93521. We find evidence for a pair of narrow absorption components, seen at low velocity, as well as evidence for a discrete emission feature in the blueshifted absorption cores of the lines. This blueshifted emission at low velocity can cause what instead appears to be an interstella absorption line. Without multiple observations that can reveal the temporary emission, one must be very careful when determining interstellar column densities to stars like HD 93521.

Bjorkman, J. E.↗
NASA NTRS1982

Ultraviolet spectra of the X-ray transient A0538-66

Ultraviolet spectra were obtained before and after the optical spectrum changed from absorption to emission lines. The continuum brightness dropped by a factor of 2. Spectra with bright continua show N V, Si IV, and C IV in absorption, while the spectrum with fainter continuum has these lines in emission. The emission lines of N V and Si IV are anomalously bright compared with C IV. The brighter spectra indicate an effective temperatury of 25,000 K, while the fainter continuum indicates a somewhat lower temperature. Probable interstellar absorption lines due to galactic halo and the LMC interstellar medium are observed.

Raymond, J. C.↗
DOE OSTI2023

Sweeping Horndeski canvas: new growth-rate parameterization for modified-gravity theories

We propose and numerically validate a new fitting formula that is sufficiently accurate to model the growth of structure in Horndeski theories of modified gravity for upcoming Stage IV and V large-scale structure surveys. Based on an analysis of more than 18,000 Horndeski models and adopting the popular parameterization of the growth rate f(z) = Ω M (z) γ , we generalize the constant growth index γ to a two-parameter redshift-dependent quantity, γ(z), that more accurately fits these models. We demonstrate that the functional form γ(z) = γ 0 + γ 0 z 2 /(1 + z) improves the median χ2 of the fit to viable Horndeski models by a factor of ~40 relative to that of a constant γ, and is sufficient to obtain unbiased results even for precise measurements expected in Stage IV and V surveys. Finally, we constrain the parameters of the new fitting formula using current cosmological data.

79 ASTRONOMY AND ASTROPHYSICS↗
NASA NTRS1989

Initial Ada components evaluation

The SAIC has the responsibility for independent test and validation of the SSE. They have been using a mathematical functions library package implemented in Ada to test the SSE IV and V process. The library package consists of elementary mathematical functions and is both machine and accuracy independent. The SSE Ada components evaluation includes code complexity metrics based on Halstead's software science metrics and McCabe's measure of cyclomatic complexity. Halstead's metrics are based on the number of operators and operands on a logical unit of code and are compiled from the number of distinct operators, distinct operands, and total number of occurrences of operators and operands. These metrics give an indication of the physical size of a program in terms of operators and operands and are used diagnostically to point to potential problems. McCabe's Cyclomatic Complexity Metrics (CCM) are compiled from flow charts transformed to equivalent directed graphs. The CCM is a measure of the total number of linearly independent paths through the code's control structure. These metrics were computed for the Ada mathematical functions library using Software Automated Verification and Validation (SAVVAS), the SSE IV and V tool. A table with selected results was shown, indicating that most of these routines are of good quality. Thresholds for the Halstead measures indicate poor quality if the length metric exceeds 260 or difficulty is greater than 190. The McCabe CCM indicated a high quality of software products.

Moebes, Travis↗
DOE OSTI2024

In-situ hydrogen microstructural characterization of Si heterojunction passivation: Addressing V OC degradation and mitigation pathways

Si heterojunction (SHJ) solar cells have demonstrated record efficiency >27%, approaching the theoretical limit of ≈ 29%, primarily due to best surface/interface defect passivation provided by deposited thin layers of hydrogenated amorphous silicon (a-Si:H). Such excellent surface/interface passivation reduces recombination loss and result in >100 mV improvement of cell open circuit voltage (V OC ) to ≈ 750 mV, thus the cell efficiency. However, fielded SHJ modules exhibit loss of V OC and hence efficiency over time in years, presumably due to degradation related to a-Si:H layers. This adversely affects the technology’s market acceptance, and levelized cost of energy (LCOE). It is hypothesized that the origin of a-Si:H degradation is somehow related to the presence of weak Si–Si bonds and hydrogen in a-Si:H films. The objective of this project is to test this hypothesis by directly measuring chemical and structural changes occurring within SHJ component layers and solar cells. This is achieved by developing an innovative in-situ Fourier transform infrared (FTIR) spectrometry apparatus to monitor hydrogen microstructural changes occurring within amorphous silicon and decipher hydrogen evolution kinetics over time when samples are exposed to heat and/or light stress. These in-situ measured hydrogen microstructural changes are correlated to the changes in effective minority carrier lifetime (τ eff ), implied V OC (iV OC ), surface recombination velocity (S), and cell V OC . These mechanistic understandings will provide critical guidance to mitigate the V OC -driven degradation of SHJ solar cell performance. Passivation optimization and degradation analysis of individual SHJ component structures were achieved through systematic deposition of three symmetric structures and the completed SHJ solar cell structure. The three symmetric structures used were intrinsic a-Si:H [(i)a-Si:H] layers in a bilayer structure, intrinsic and p-type doped stacked layers [(i-p)a-Si:H] representing the front heterojunction in the SHJ cell, and intrinsic and n-typed doped stacked layers [(i-n)a-Si:H] representing the back-side back surface field (BSF) in the SHJ cell. State-of-the-art passivation qualities are demonstrated by a champion iV OC of 740 mV for the (i)a-Si:H layers, and the (i-n)a-Si:H symmetric structure. A 725 mV iV OC is observed for the (i-p)a-Si:H symmetric structure. These symmetric passivated SHJ component structures were subsequently subjected to different accelerated lifetime (ALT) stressors to identify which conditions contribute the most to iV OC degradation. Degradation of the thin (10 nm) (i)a-Si:H passivation layers without any additional overlying layers is minimal; complexity of this study arises due to unavoidable surface oxidation of (i)a-Si:H layer during most of the stress application, which is likely irrelevant for a full SHJ cell configuration with overlying protective layers. The iV OC degradation of symmetric structures is found to occur primarily at the (i-p)a-Si:H passivation stack under dark heat stress with associated hydrogen loss from the (p)a-Si:H layer. An activation energy for increase in S (defect creation) of 0.65 eV can be correlated to the activation energy of ≈ 0.4 eV for hydrogen loss from the (i-p)a-Si:H stack. This also suggests the presence of weakly bonded hydrogen in the (p)a-Si:H films, which effuses out of the film stack at such low activation energy. When light and heat stress are applied together, similar hydrogen loss from (i-p)a-Si:H stack is observed, however, does not appreciably degrade iV OC or increase S. This is an important result and departure from direct correlation between hydrogen loss and defect creation. This perhaps indicates additional defect chemistries or annealing that might be occurring in the presence of light requiring further detailed defect measurements. The full SHJ cell structure used for this project is depicted in Fig.1(d). SHJ cells with an initial V OC ≈ 700 mV were fabricated and subjected to similar ALT stress conditions. Cell V OC is found to degrade the most under dark heat stress and is confirmed by observed hydrogen migration out of the (i-p)a-Si:H stack. However, hydrogen cannot escape from the cell stack, it accumulates near the (p)a-Si:H/ITO contact interface, where ITO acts as a barrier preventing hydrogen loss. Furthermore, light-heat combined stress does not degrade V OC appreciably, confirming the occurrence of a defect annealing process.

14 SOLAR ENERGY↗
DOE OSTI2024

Venturing Past Uranium: Synthesis of a Np(IV) Polyoxomolybdate–Alkoxide Sandwich Complex

The synthesis of a Np(IV) polyoxomolybdate– alkoxide sandwich complex, (TBA) 2 [Np{Mo 5 O 13 (OMe) 4 NO} 2 ] (TBA = tetrabutylammonium), is reported. This compound represents a rare example of a neptunium polyoxometalate cluster isolated outside of water, allowing for characterization of its electrochemical properties in nonaqueous solvents. Complexation of An(IV) cations fine-tunes the redox properties of the cluster, with the observed four reversible reductive events varying slightly both in potential and peak separation depending on the actinide present. The new Np(IV) complex also shows an irreversible event assigned to oxidation of Np(IV) to Np(V). New methodology for facile 17 O enrichment of (TBA) 2 [Mo 5 O 13 (OMe) 4 NO][Na(MeOH)] is presented, which provides a simple pathway to 17 O enriched analogues of the sandwich complexes discussed (Zr(IV), Hf(IV), Th(IV), U(IV), U(V), Np(IV)). 17 O NMR spectroscopy subsequently provides insights into both the nature of metal–oxygen bonding, as well as the influence of unpaired f-electrons on the local environment of the oxygen nuclei.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1982

Variation of anomalous stages of ionization with spectral type for Be stars

Results are presented of a preliminary survey of IUE spectra of Be stars covering a wide range of spectral types. For each of 25 UV spectra 23 Be stars obtained six months apart at wavelengths between 1150 and 1950 A, the presence of resonance lines of N V, C IV, and Si IV was studied. The chance of detecting these lines was quantitatively evaluated, and the presence of N V in early Be stars and of both C IV and Si IV in Be stars as cool as B8 demonstrates that at least some Be stars in almost all spectral subdivisions show anomalous stages of ionization in their UV spectra and thus require ionization sources in addition to their photospheric radiation fields. It is suggested that the absence of N V in Be stars cooler than about B2 together with the presence of C IV and Si IV in later types is a real phenomenon and reflects some dependence of the additional ionization source on basic stellar parameters. An attempt is made to determine whether the behavior at B2 and B3 reflects some dependence on v sin i.

Marlborough, J. M.↗